CN107805976A - The preparation method of calligraphy and painting protection against the tide rice paper - Google Patents
The preparation method of calligraphy and painting protection against the tide rice paper Download PDFInfo
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- CN107805976A CN107805976A CN201711022454.9A CN201711022454A CN107805976A CN 107805976 A CN107805976 A CN 107805976A CN 201711022454 A CN201711022454 A CN 201711022454A CN 107805976 A CN107805976 A CN 107805976A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/002—Tissue paper; Absorbent paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses the preparation method of calligraphy and painting protection against the tide rice paper, is related to art work mounting technical field, and calligraphy and painting protection against the tide rice paper includes following component：Chu's bark powder, decentralized medium, wingceltis bark powder, reed straw powder, adhesive, atlapulgite, chitosan oligosaccharide ceramic, modified meerschaum particle, polyvinyl alcohol resin, sepiolite fibre, N NMAs, asbestos wool, mica powder, land plaster, nano medical stone powder, Tissuemat E, lauric monoglyceride, Glycerin, mixed triester with caprylic acid capric acid, modified polyvinyl chloride emulsion, sodium gluconate, carboxymethyl chitosan；The present invention prepares calligraphy and painting protection against the tide rice paper, humidity resistance is stable, with good wet-heat resisting, ageing-resistant performance, preparation method is simple, process conditions are easily realized, stable performance, the calligraphy and painting protection against the tide rice paper of resting period length are obtained, available for calligraphy and painting various forms mounting, and reduces production cost and maintenance cost.
Description
Technical field：
The present invention relates to art work field of mounting, and in particular to the preparation method of calligraphy and painting protection against the tide rice paper.
Background technology：
The complete calligraphy and painting of one width is to be unable to do without mounting, it is necessary to make its more aesthetically pleasing, and be easy to preserve, spread and collect
's.Because calligraphy and painting be drawn in mostly on breakable rice paper or thin,tough silk class article on.Mounting is a kind of distinctive protection in China and U.S.
Change the technology of painting and calligraphy and rubbings, can reach taller and bigger on aesthetic.
Mounting is further divided into former mounting and remounted, and original mounting is exactly that the picture newly finished is entered luggage by the program of mounting
Mounting.Remount exactly to those original mounting it is bad or due to management collection keeping be not good at, occur ghost come off, make moist it is mouldy,
The rotten fracture of grain, the painting and calligraphy handed down from ancient times for damaged by rats of damaging by worms carry out mounting.It is firm, attractive in appearance by the painting and calligraphy of mounting, it is easy to collect and arranges sight
Reward.And the ancient painting remounted, it can also extend its vitality.
Either former mounting is still remounted, and the mounting such as calligraphy and painting is completed, it is desirable to is reached firm, attractive in appearance, is easy to collection and cloth
Put and view and admire.Rice paper ferments, grass bleaching, some processes such as mashing add using Chu's bark or wingceltis bark or rice straw as raw material through lime
The work system of copying forms；With soft texture, water absorbing properties are good, and fiber length, toughness is big, colours the features such as firm, not only calligraphy and drawing
Rice paper is be unable to do without, and rice paper is also indispensable material in mounting work.
The present invention provides the preparation method of calligraphy and painting protection against the tide rice paper, extends the Xuan paper calligraphy and painting holding time, prevents during preservation
Phenomena such as making moist, mildew, be infested occurs.
The content of the invention：
The technical problems to be solved by the invention are the preparation method for providing calligraphy and painting protection against the tide rice paper, prevent during preservation
Because phenomena such as making moist, mildew, be infested occurs, extend the calligraphy and painting holding time.
The technical problems to be solved by the invention are realized using following technical scheme：
The preparation method of calligraphy and painting protection against the tide rice paper：
The calligraphy and painting protection against the tide rice paper includes each component of following parts by weight：Chu bark powder 25-40 parts, decentralized medium 26-50
Part, wingceltis bark powder 23-35 parts, reed straw powder 5-12 parts, adhesive 5-11 parts, atlapulgite 15-20 parts, chitosan oligosaccharide-ceramics
Micro mist 5-10 parts, modified meerschaum particle 2-3 parts, polyvinyl alcohol resin 1-2 parts, sepiolite fibre 0.5-1 parts, N- methylols third
Acrylamide 0.3-0.5 parts, asbestos wool 0.1-0.3 parts, mica powder 25-35 parts, land plaster 20-25 parts, nano medical stone powder 2-4
Part, Tissuemat E 3-5 parts, lauric monoglyceride 0.3-0.5 parts, Glycerin, mixed triester with caprylic acid capric acid 0.3-0.5 parts, modified polyvinyl chloride breast
Liquid 10-15 parts, sodium gluconate 1-2 parts, carboxymethyl chitosan 0.2-0.4 parts.
Wherein described modified polyvinyl chloride emulsion is made from the following raw materials in parts by weight：Vinyl chloride 10-15 parts, acrylic acid 3-
5 parts, carboxymethyl cellulose 0.5-1 parts, trifluoro propyl methyl cyclotrisiloxane 0.3-0.5 parts, potassium peroxydisulfate 0.01-0.02 parts,
Nano titanium oxide 1-2 parts, lauryl sodium sulfate 0.05-0.1 parts, water 20-30 parts；The preparation side of modified polyvinyl chloride emulsion
Method is that lauryl sodium sulfate and carboxymethyl cellulose first are added to the water into stirring until be completely dissolved, then add vinyl chloride,
Acrylic acid, nano titanium oxide and trifluoro propyl methyl cyclotrisiloxane 800-1000r/min stirring 0.5-1h, are eventually adding it
Remaining 70-80 DEG C of reaction 2-4h of raw material, is produced after cooling.
Chitosan oligosaccharide-the ceramic is made up of the raw material of following parts by weight：Chitosan oligosaccharide 10-15 parts, ceramic
3-5 parts, hydroxyethyl cellulose 1-2 parts, PVPP 0.5-1 parts, poly-aspartate 0.1-0.3 parts, HPMA
0.05-0.1 parts, water 5-8 parts, its preparation method are：PVPP and poly-aspartate are added into chitosan oligosaccharide, is risen under grinding
Temperature adds ceramic, hydroxyethyl cellulose and HPMA, continued to 115-120 DEG C of insulation grinding 15min
115-120 DEG C of insulation grinding 15min, is then transferred to sealing and standing 1h in 0-5 DEG C of environment, and adds 50-55 DEG C of water, is sufficiently mixed
30min is stood after 50-55 DEG C of insulation, gained mixed liquor is sent into spray dryer, dries gained particle through micronizer
Micro mist is made, as chitosan oligosaccharide-ceramic.
Chu's bark, wingceltis bark, reed straw processing and preparation method are：
(1) choose without rotten, the high-quality Chu's bark of quality, wingceltis bark, reed straw, first by Chu's bark, wingceltis bark, reed straw
Stalk, which is positioned in 2-10% aqueous slkalis, soaks 6-24h；
(2) Chu's bark after immersion, wingceltis bark, reed straw are taken out and are placed in drying frame and drain away the water, after by Chu's bark, wingceltis
Bark, reed straw allow in dryer, 30-45 DEG C of baking 5-12h, until Chu's bark, wingceltis bark, reed straw moisture are 20%
Within；
(3) by Chu's bark, wingceltis bark, reed straw input pulverizer after, comminuted powder can be treated within 200 mesh
With.
The aqueous slkali is sodium acid carbonate, sodium hydroxide, sodium acetate one or two.
The preparation method of calligraphy and painting protection against the tide rice paper, preparation process are as follows：
(1) polyvinyl alcohol resin 1-2 parts, sepiolite fibre 0.5-1 parts are added into 35-40 DEG C of heating for dissolving in 8-10 part water
Completely, pH is then adjusted to 6.5-7.5, adds mica powder 25-35 parts, land plaster 20-25 parts and Glycerin, mixed triester with caprylic acid capric acid 0.3-0.5
Simultaneously mixed at high speed is uniform for part, obtains polyvinyl alcohol resin mixed liquor；
(2) by Chu bark powder 25-40 parts, wingceltis bark powder 23-35 parts, reed straw powder 5-12 parts, chitosan oligosaccharide-ceramic
5-10 parts, modified meerschaum particle 2-3 parts add 70-80 DEG C of reaction 3-5h in container jointly, add 2-13 parts by weight steps
(1) the polyvinyl alcohol resin mixed liquor obtained is stirred at same temperature, and Tissuemat E 3-5 parts, bay are added after cooling
Sour monoglyceride 0.3-0.5 parts, modified polyvinyl chloride emulsion 10-15 parts, and asbestos wool 0.1-0.3 parts stirring 10-15min, obtain
It is standby to calligraphy and painting protection against the tide rice paper matrix；
(3) each component is prepared according to foregoing parts by weight, it is standby；
(4) decentralized medium 26-50 parts, adhesive 50-80 parts are poured into retort, then activity is added in vain into retort
Native 15-20 parts, N hydroxymethyl acrylamide 0.3-0.5 parts, nano medical stone powder 2-4 parts, are uniformly mixed, and stand 3-5h；
(5) sodium gluconate 1-2 parts, carboxymethyl chitosan 0.2-0.4 parts, calligraphy and painting protection against the tide rice paper matrix are added into reaction again
In tank, it is uniformly mixed；
(6) be placed in after retort is sealed in water-bath, heating water bath to constant temperature underwater curing 1-3h after 80 DEG C, after will be solid
Material adds rice paper paper making equipment after change, prepares the calligraphy and painting protection against the tide rice paper of different model.
The decentralized medium is deionized water or absolute ethyl alcohol.
The adhesive is epoxy resin adhesive；Specially epoxy resin E-51, epoxy resin E-44, double aminobenzenes
One or more in phenol epoxy resin and butadiene bifunctional epoxy resin.
The present invention is advantageous in that：Calligraphy and painting protection against the tide rice paper prepared by the present invention, cooperate between its selection of material each component
Effect, obtained humidity resistance is stable, has good wet-heat resisting, ageing-resistant performance, bonding strength is high, solves traditional word
Draw mounting rice paper because caused by after moisture absorption humidity resistance decline the problems such as and caused by calligraphy and painting preserve it is improper；This method preparation method
Simply, process conditions are easily realized, stable performance, the calligraphy and painting protection against the tide rice paper of resting period length are obtained, available for the various shapes of calligraphy and painting
Formula mounting, and reduce production cost and maintenance cost.
Embodiment：
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1：
The preparation method of calligraphy and painting protection against the tide rice paper：
The technical problems to be solved by the invention are realized using following technical scheme：
The preparation method of calligraphy and painting protection against the tide rice paper：
The calligraphy and painting protection against the tide rice paper includes each component of following parts by weight：27 parts of Chu's bark powder, 26 parts of decentralized medium, Tan Shu
23 parts of skin powder, 5 parts of reed straw powder, 7 parts of adhesive, 15 parts of atlapulgite, 9 parts of chitosan oligosaccharide-ceramic, modified meerschaum
3 parts of grain, 2 parts of polyvinyl alcohol resin, 0.5 part of sepiolite fibre, 0.3 part of N hydroxymethyl acrylamide, 0.2 part of asbestos wool, mica
25 parts of powder, 20 parts of land plaster, 2 parts of nano medical stone powder, 3 parts of Tissuemat E, 0.3 part of lauric monoglyceride, pungent capric acid glycerine
0.4 part of ester, 11 parts of modified polyvinyl chloride emulsion, 2 parts of sodium gluconate, 0.2 part of carboxymethyl chitosan.
Wherein described modified polyvinyl chloride emulsion is made from the following raw materials in parts by weight：10 parts of vinyl chloride, 3 parts of acrylic acid,
0.5 part of carboxymethyl cellulose, 0.3 part of trifluoro propyl methyl cyclotrisiloxane, 0.01 part of potassium peroxydisulfate, nano titanium oxide part,
0.05 part of lauryl sodium sulfate, 20 parts of water；The preparation method of modified polyvinyl chloride emulsion be first by lauryl sodium sulfate and
Carboxymethyl cellulose is added to the water stirring until being completely dissolved, and then adds vinyl chloride, acrylic acid, nano titanium oxide and trifluoro
Hydroxypropyl methyl cyclotrisiloxane 1000r/min stirs 0.5h, is eventually adding 80 DEG C of reaction 4h of remaining raw material, is produced after cooling.
Chitosan oligosaccharide-the ceramic is made up of the raw material of following parts by weight：10 parts of chitosan oligosaccharide, 3 parts of ceramic,
1 part of hydroxyethyl cellulose, 0.5 part of PVPP, 0.1 part of poly-aspartate, 0.05 part of HPMA, 5 parts of water, its
Preparation method is：PVPP and poly-aspartate are added into chitosan oligosaccharide, 120 DEG C of insulation grindings are warming up under grinding
15min, ceramic, hydroxyethyl cellulose and HPMA are added, continued in 115-1118 DEG C of insulation grinding
15min, sealing and standing 1h in 0-5 DEG C of environment is then transferred to, and adds 50-55 DEG C of water, be sufficiently mixed quiet after 50-55 DEG C of insulation
30min is put, gained mixed liquor is sent into spray dryer, dries gained particle and micro mist is made through micronizer, as shell is few
Sugar-ceramic.
Chu's bark, wingceltis bark, reed straw processing and preparation method are：
(1) choose without rotten, the high-quality Chu's bark of quality, wingceltis bark, reed straw, first by Chu's bark, wingceltis bark, reed straw
Stalk, which is positioned in 5% aqueous slkali, soaks 12h；
(2) Chu's bark after immersion, wingceltis bark, reed straw are taken out and are placed in drying frame and drain away the water, after by Chu's bark, wingceltis
Bark, reed straw allow in dryer, 45 DEG C of baking 5h, until Chu's bark, wingceltis bark, reed straw moisture are within 20%；
(3) by Chu's bark, wingceltis bark, reed straw input pulverizer after, comminuted powder can be treated within 200 mesh
With.
The aqueous slkali is sodium acid carbonate, sodium hydroxide.
Calligraphy and painting protection against the tide rice paper preparation method, preparation process are as follows：
(1) completely, then 40 DEG C in 2 parts of polyvinyl alcohol resin, sepiolite fibre 0.5 part of addition, 8 parts of water are dissolved by heating
PH is adjusted to 6.5,0.4 part of 25 parts of mica powder, 20 parts of land plaster and Glycerin, mixed triester with caprylic acid capric acid is added and mixed at high speed is uniform, obtain poly- second
Enol resin mixture liquor；
(2) by 27 parts of Chu's bark powder, 23 parts of wingceltis bark powder, 5 parts of reed straw powder, 9 parts of chitosan oligosaccharide-ceramic, modification
3 parts of sepiolite particle is common to add 80 DEG C of reaction 5h in container, adds the polyvinyl alcohol resin that 6 parts by weight steps (1) obtain
Mixed liquor is stirred at same temperature, and 3 parts of Tissuemat E, 0.3 part of lauric monoglyceride, modified polychlorostyrene are added after cooling
10 parts of vac emulsion, and 0.1 part of stirring 15min of asbestos wool, obtain calligraphy and painting protection against the tide rice paper matrix, standby；
(3) each component is prepared according to foregoing parts by weight, it is standby；
(4) 26 parts of decentralized medium, 7 parts of adhesive are poured into retort, then into retort add 15 parts of atlapulgite,
0.3 part of N hydroxymethyl acrylamide, 2 parts of nano medical stone powder, are uniformly mixed, and stand 4h；
(5) 2 parts of sodium gluconate, 0.2 part of carboxymethyl chitosan, calligraphy and painting protection against the tide rice paper matrix are added in retort again,
It is uniformly mixed；
(6) be placed in after retort is sealed in water-bath, heating water bath to constant temperature underwater curing 3h after 80 DEG C, after will solidification
Material adds rice paper paper making equipment afterwards, prepares calligraphy and painting protection against the tide rice paper.
The decentralized medium is absolute ethyl alcohol.
The adhesive is epoxy resin adhesive；Specially epoxy resin E-51.
Embodiment 2：The preparation method of calligraphy and painting protection against the tide rice paper：
The technical problems to be solved by the invention are realized using following technical scheme：
The preparation method of calligraphy and painting protection against the tide rice paper：
The calligraphy and painting protection against the tide rice paper includes each component of following parts by weight：31 parts of Chu's bark powder, 30 parts of decentralized medium, Tan Shu
24 parts of skin powder, 8 parts of reed straw powder, 9 parts of adhesive, 17 parts of atlapulgite, 8 parts of chitosan oligosaccharide-ceramic, modified meerschaum
3 parts of grain, 2 parts of polyvinyl alcohol resin, 1 part of sepiolite fibre, 0.5 part of N hydroxymethyl acrylamide, 0.3 part of asbestos wool, mica powder
25 parts, 22 parts of land plaster, 4 parts of nano medical stone powder, 5 parts of Tissuemat E, 0.5 part of lauric monoglyceride, Glycerin, mixed triester with caprylic acid capric acid
0.5 part, 13 parts of modified polyvinyl chloride emulsion, 2 parts of sodium gluconate, 0.4 part of carboxymethyl chitosan.
Wherein described modified polyvinyl chloride emulsion is made from the following raw materials in parts by weight：13 parts of vinyl chloride, 5 parts of acrylic acid,
1 part of carboxymethyl cellulose, 0.5 part of trifluoro propyl methyl cyclotrisiloxane, 0.02 part of potassium peroxydisulfate, 2 parts of nano titanium oxide, ten
0.1 part of sodium dialkyl sulfate, 20 parts of water；The preparation method of modified polyvinyl chloride emulsion is first by lauryl sodium sulfate and carboxylic first
Base cellulose is added to the water stirring until being completely dissolved, and then adds vinyl chloride, acrylic acid, nano titanium oxide and trifluoro propyl
Methyl cyclotrisiloxane 1000r/min stirs 1h, is eventually adding 80 DEG C of reaction 4h of remaining raw material, is produced after cooling.
Chitosan oligosaccharide-the ceramic is made up of the raw material of following parts by weight：12 parts of chitosan oligosaccharide, 4 parts of ceramic,
2 parts of hydroxyethyl cellulose, 1 part of PVPP, 0.3 part of poly-aspartate, 0.05 part of HPMA, 6 parts of water, it is made
Preparation Method is：PVPP and poly-aspartate are added into chitosan oligosaccharide, 115-120 DEG C of insulation grinding is warming up under grinding
15min, ceramic, hydroxyethyl cellulose and HPMA are added, continued in 118-120 DEG C of insulation grinding
15min, sealing and standing 1h in 0-5 DEG C of environment is then transferred to, and adds 50-55 DEG C of water, be sufficiently mixed and stood after 55 DEG C of insulations
30min, gained mixed liquor are sent into spray dryer, are dried gained particle and are made micro mist through micronizer, as chitosan oligosaccharide-
Ceramic.
Chu's bark, wingceltis bark, reed straw processing and preparation method are：
(1) choose without rotten, the high-quality Chu's bark of quality, wingceltis bark, reed straw, first by Chu's bark, wingceltis bark, reed straw
Stalk, which is positioned in 6% aqueous slkali, soaks 6h；
(2) Chu's bark after immersion, wingceltis bark, reed straw are taken out and are placed in drying frame and drain away the water, after by Chu's bark, wingceltis
Bark, reed straw allow in dryer, 45 DEG C of baking 7h, until Chu's bark, wingceltis bark, reed straw moisture are within 20%；
(3) by Chu's bark, wingceltis bark, reed straw input pulverizer after, comminuted powder can be treated within 200 mesh
With.
The aqueous slkali is sodium acid carbonate.
The preparation method of calligraphy and painting protection against the tide rice paper, step are as follows：
(1) 2 parts of polyvinyl alcohol resin, 1 part of sepiolite fibre are added into 40 DEG C of heating for dissolving in 9 parts of water completely, then will
PH is adjusted to 7.0, adds 0.5 part of 25 parts of mica powder, 22 parts of land plaster and Glycerin, mixed triester with caprylic acid capric acid and mixed at high speed is uniform, obtain polyethylene
Alcohol resin mixed liquor；
(2) by 31 parts of Chu's bark powder, 24 parts of wingceltis bark powder, 8 parts of reed straw powder, 8 parts of chitosan oligosaccharide-ceramic, modification
3 parts of sepiolite particle is common to add 80 DEG C of reaction 3h in container, adds the polyvinyl alcohol resin that 8 parts by weight steps (1) obtain
Mixed liquor is stirred at same temperature, and 5 parts of Tissuemat E, 0.5 part of lauric monoglyceride, modified polychlorostyrene are added after cooling
13 parts of vac emulsion, and 0.3 part of stirring 15min of asbestos wool, obtain calligraphy and painting protection against the tide rice paper matrix, standby；
(3) each component is prepared according to foregoing parts by weight, it is standby；
(4) 30 parts of decentralized medium, 9 parts of adhesive are poured into retort, then into retort add 17 parts of atlapulgite,
0.5 part of N hydroxymethyl acrylamide, 4 parts of nano medical stone powder, are uniformly mixed, and stand 5h；
(5) 2 parts of sodium gluconate, 0.4 part of carboxymethyl chitosan, calligraphy and painting protection against the tide rice paper matrix are added in retort again,
It is uniformly mixed；
(6) be placed in after retort is sealed in water-bath, heating water bath to constant temperature underwater curing 3h after 80 DEG C, after will solidification
Material adds rice paper paper making equipment afterwards, prepares calligraphy and painting protection against the tide rice paper.
The decentralized medium is absolute ethyl alcohol.
The adhesive is epoxy resin adhesive；Specially epoxy resin E-44.
To carrying out experiment investigation respectively in embodiment provided by the invention, by the calligraphy and painting prepared by embodiment 1 and embodiment 2
Moistureproof rice paper is investigated, with reference to GB/T10739；GB/T 4688；GB/T451；GB/T7974；GB/T 453；GB/T 455；
GB/T 465；GB/T 464；GB/T 459；GB/T 1541；GB/T 462 is detected, and reference standard and the results are shown in Table 1 institute
Show；
The performance reference standard and result (physical and chemical index) of the rice paper of table 1
Shown by result above：Calligraphy and painting protection against the tide rice paper prepared by the embodiment of the present invention, moistureproof performance are better than common standard,
And can be ageing-resistant, corrosion-resistant, oil resistivity, by the calligraphy and painting protection against the tide rice paper moisture effect of the invention prepared more preferably；Moistureproof a surname of the calligraphy and painting
Paper brings convenience for gallery protection against the tide, effective practical effect, and price is low, and practicality is good, reduces production and maintenance cost.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (4)
1. the preparation method of calligraphy and painting protection against the tide rice paper, it is characterised in that：Calligraphy and painting protection against the tide rice paper includes each component of following parts by weight：Chu
Bark powder 25-40 parts, decentralized medium 26-50 parts, wingceltis bark powder 23-35 parts, reed straw powder 5-12 parts, adhesive 5-11 parts,
Atlapulgite 15-20 parts, chitosan oligosaccharide-ceramic 5-10 parts, modified meerschaum particle 2-3 parts, polyvinyl alcohol resin 1-2 parts,
Sepiolite fibre 0.5-1 parts, N hydroxymethyl acrylamide 0.3-0.5 parts, asbestos wool 0.1-0.3 parts, mica powder 25-35 parts, stone
Cream powder 20-25 parts, nano medical stone powder 2-4 parts, Tissuemat E 3-5 parts, lauric monoglyceride 0.3-0.5 parts, pungent capric acid are sweet
Grease 0.3-0.5 parts, modified polyvinyl chloride emulsion 10-15 parts, sodium gluconate 1-2 parts, carboxymethyl chitosan 0.2-0.4 parts.
2. the preparation method of calligraphy and painting protection against the tide rice paper according to claim 1, it is characterised in that：The modified polyvinyl chloride breast
Liquid is made from the following raw materials in parts by weight：Vinyl chloride 10-15 parts, acrylic acid 3-5 parts, carboxymethyl cellulose 0.5-1 parts, trifluoropropyl
Ylmethyl cyclotrisiloxane 0.3-0.5 parts, potassium peroxydisulfate 0.01-0.02 parts, nano titanium oxide 1-2 parts, dodecyl sulphate
Sodium 0.05-0.1 parts, water 20-30 parts；The preparation method of modified polyvinyl chloride emulsion is first by lauryl sodium sulfate and carboxymethyl
Cellulose is added to the water stirring until being completely dissolved, and then adds vinyl chloride, acrylic acid, nano titanium oxide and trifluoro propyl first
Basic ring trisiloxanes 800-1000r/min stirs 0.5-1h, is eventually adding 70-80 DEG C of reaction 2-4h of remaining raw material, after cooling i.e.
.
3. the preparation method of calligraphy and painting protection against the tide rice paper according to claim 2, it is characterised in that：Chitosan oligosaccharide-the ceramics are micro-
Powder is made up of the raw material of following parts by weight：Chitosan oligosaccharide 10-15 parts, ceramic 3-5 parts, hydroxyethyl cellulose 1-2 parts, friendship
Join PVP 0.5-1 parts, poly-aspartate 0.1-0.3 parts, HPMA 0.05-0.1 parts, water 5-8 parts, its preparation side
Method is：PVPP and poly-aspartate are added into chitosan oligosaccharide, 115-120 DEG C of insulation grinding 15min is warming up under grinding,
Ceramic, hydroxyethyl cellulose and HPMA are added, continues to grind 15min in 115-120 DEG C of insulation, then
Sealing and standing 1h in 0-5 DEG C of environment is transferred to, and adds 50-55 DEG C of water, is sufficiently mixed and stands 30min, institute after 50-55 DEG C of insulation
Obtain mixed liquor to be sent into spray dryer, dry gained particle and micro mist is made through micronizer, as chitosan oligosaccharide-ceramics are micro-
Powder.
4. the preparation method of calligraphy and painting protection against the tide rice paper according to claim 3, it is characterised in that：Calligraphy and painting protection against the tide rice paper preparation side
Method, step are as follows：
(1) 35-40 DEG C in polyvinyl alcohol resin 1-2 parts, sepiolite fibre 0.5-1 parts addition 8-10 part water has been dissolved by heating
Entirely, pH is then adjusted to 6.5-7.5, adds mica powder 25-35 parts, land plaster 20-25 parts and Glycerin, mixed triester with caprylic acid capric acid 0.3-0.5 parts
And mixed at high speed is uniform, polyvinyl alcohol resin mixed liquor is obtained；
(2) by Chu bark powder 25-40 parts, wingceltis bark powder 23-35 parts, reed straw powder 5-12 parts, chitosan oligosaccharide-ceramic 5-10
Part, modified meerschaum particle 2-3 parts add 70-80 DEG C of reaction 3-5h in container jointly, add 2-13 parts by weight step (1) and obtain
To polyvinyl alcohol resin mixed liquor stirred at same temperature, it is sweet that Tissuemat E 3-5 parts, laurate list are added after cooling
Grease 0.3-0.5 parts, modified polyvinyl chloride emulsion 10-15 parts, and asbestos wool 0.1-0.3 parts stirring 10-15min, obtain calligraphy and painting
Moistureproof rice paper matrix, it is standby；
(3) each component is prepared according to foregoing parts by weight, it is standby；
(4) decentralized medium 26-50 parts, adhesive 50-80 parts are poured into retort, then atlapulgite is added into retort
15-20 parts, N hydroxymethyl acrylamide 0.3-0.5 parts, nano medical stone powder 2-4 parts, are uniformly mixed, and stand 3-5h；
(5) sodium gluconate 1-2 parts, carboxymethyl chitosan 0.2-0.4 parts, calligraphy and painting protection against the tide rice paper matrix are added into retort again
In, it is uniformly mixed；
(6) be placed in after retort is sealed in water-bath, heating water bath to constant temperature underwater curing 1-3h after 80 DEG C, after will solidification after
Material adds rice paper paper making equipment, prepares the calligraphy and painting protection against the tide rice paper of different model.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111041888A (en) * | 2019-12-26 | 2020-04-21 | 同曦集团有限公司 | Antibacterial, mildew-proof and moth-proof rice paper pulp, rice paper and preparation method |
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| CN104164804A (en) * | 2013-05-16 | 2014-11-26 | 中央民族大学 | Handmade calligraphy paper using crofton weed root powder as new filling material and preparation method thereof |
| CN106182279A (en) * | 2016-08-25 | 2016-12-07 | 阜南县永兴工艺品有限公司 | A kind of antibacterial deodouring straw treatment fluid and preparation method thereof |
| CN106962461A (en) * | 2017-04-17 | 2017-07-21 | 安徽省佳康食用菌科技开发有限责任公司 | A kind of preparation method of the moistureproof bag of edible mushroom dried food and nuts storage |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101333783A (en) * | 2008-07-16 | 2008-12-31 | 安徽泾县千年古宣宣纸有限公司 | Processing method of leather slurry for producing ancient xuan paper |
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| CN104164804A (en) * | 2013-05-16 | 2014-11-26 | 中央民族大学 | Handmade calligraphy paper using crofton weed root powder as new filling material and preparation method thereof |
| CN106182279A (en) * | 2016-08-25 | 2016-12-07 | 阜南县永兴工艺品有限公司 | A kind of antibacterial deodouring straw treatment fluid and preparation method thereof |
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