CN102444048A - Writing and painting paper capable of preventing water, breakage, oxidation and moth eating - Google Patents
Writing and painting paper capable of preventing water, breakage, oxidation and moth eating Download PDFInfo
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- CN102444048A CN102444048A CN2011103231998A CN201110323199A CN102444048A CN 102444048 A CN102444048 A CN 102444048A CN 2011103231998 A CN2011103231998 A CN 2011103231998A CN 201110323199 A CN201110323199 A CN 201110323199A CN 102444048 A CN102444048 A CN 102444048A
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Abstract
The invention relates to the field of manufacture of writing and painting paper, in particular to writing and painting paper capable of preventing water, breakage, oxidation and moth eating, which is prepared from raw and auxiliary materials through a pulping process and a papermaking process. The writing and painting paper comprises the following raw materials in parts by weight: 45-80 parts of bamboo pulp fiber, 10-30 parts of straw pulp fiber, 5-25 parts of wood pulp fiber and 5-25 parts of viscose fiber; and counted by tons of paper, the writing and painting paper comprises the following auxiliary materials in percent by weight: 0.5-2% of antibacterial agent, 3-15% of PVA (polyvinyl acetate), 0.5-5% of shrubby sophora extract, 1-3% of wormwood leaf extract and 1-5% of artemisia frigida P.E. The writing and printing paper has excellent functions of preventing water, breakage and oxidation, and especially, the functions of preventing water and burst are better than the wet-tensile strength index of national standard of GB/T18739-2008 rice paper by more than 10 times. In addition, matrine, chamaejasmine and wormwood leaf extract are uniformly adhered on the fiber by a dipping and spraying method, so that the function of preventing moth eating of the writing and printing paper is enhanced.
Description
Technical field
The present invention relates to china picture-character paper and make the field, be specifically related to the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water.
Background technology
The long preservation of painting and calligraphy pieces and ancient costume books always is the problem that the expert explores.But generally speaking have two deciding factors about its durability.The firstth, the environment of preserving and the technology of preservation; The secondth, the factor of paper own.With regard to the paper factor, can be divided into two factors of fibre property and manufacturing technique.As paper industry,, be the pursuit of all innovating in the successive dynasties in research to can in paper is preserved, improving its anti-oxidation function and anti-mould and anti-moth function.
A kind of writing paper, bamboo paper a kind of anciently claims red booth paper, and main product is in Fuyang City, and production history is long.Characteristics are, and are pure white pliable and tough, little bamboo delicate fragrance that contains, falling into water is prone to dissolve, inking is not oozed, for a long time the Tibetan do not eat into, nondiscolouring.Be used for painting and calligraphy in ancient times, write official document, make books for taking notes or keeping accounts or the like; After the foundation of new China, mainly as student's block letters book, mount painted scroll etc.In addition, also can make first-class wrapping paper.China picture-character paper is innovation and come on the basis of Fuyang a kind of writing paper notion.Fuyang " a kind of writing paper " is to be raw material with the bamboo fibre, and the cultural paper with traditional handicraft is produced once had the good reputation of " champion Fuyang, capital of a country paper, ten pass first book is admitted to the scholar " in ancient times.But since 20 middle of century; Social development is maked rapid progress; Hard-tipped writing instrument has replaced writing brush, and machine-made paper has replaced traditional handicraft to copy the paper of system, in the last thirty years again with high and new technology electronic products such as computer, USB flash disk, CD, duplicator, scanners; These products have formed the absolute market advantage in the character calligraph field.The cultural paper that traditional handicraft is produced has withdrawed from market basically, has calligraphy, the drawing culture field of China only, is also keeping national cultural feature and market.Originally accounted for traditional handmade paper output of national total amount 25% share as Fuyang; Also abandoned by history, and peasant households solely struggle against because of singles, lack the exploitation input of new technology new product because of technology falls behind, the matter residual quantity is few; Add that the original product labour has high input, takes in less, and change one's profession one after another.
The bamboo paper manufacture skill of current ecosystem has been put into national non-material cultural heritage representative items, has become the object of rescue property protection.Common machine-processed china picture-character paper on the present market, generally as the usefulness of mounting holder of painting and calligraphy pieces, it uses white secondary stock to be the master; The straw pulp and the wood pulp that add a little quantity are as raw material; Form with the cylinder mould machine of the single cylinder list net system of copying then, technology is simple, and the physical and chemical index data are unstable; Though cost is low, the application market scope is little.Therefore, china picture-character paper must be reformed and innovate.Publication number be CN1456744A Chinese disclosure of the Invention a kind of be the paper that is used for the write by hand painting and calligraphy that main raw material(s) is processed with the Chinese alpine rush; Its constituent comprises Chinese alpine rush, mulberry skin, fiber crops, burning cash; Weight proportion is following: Chinese alpine rush 15-70, mulberry skin 15-40, numb 5-30, burn cash 15-30, through getting the raw materials ready, feeding, boiling, bleaching, making beating, preparing burden, copy operation such as system, drying, finished product, packing and process.And for example publication number is that the Chinese invention patent of CN1384242A provides a kind of water written Xuan paper, water written Xuan paper by the black rice paper and on black rice paper surface evenly the macromolecule composite coating layer of coating constitute.These all are different with the present invention, also do not relate to anti-oxidant and mothproof content.
Summary of the invention
The inventor is in line with " making the part serve the present, conscientiously excavate cultural heritage; Weed out the old and bring forth the new, actively reform skill innovation " thought, be intended to adopt modernized machinery and advanced technical recipe, be main body with the bamboo fibre, develop and have the china picture-character paper new product that resists anti-broken, the anti-oxidant and mothproof function of water mutually, with rich cultural market.
" writing brush, ink stick, ink slab and paper " in the Chinese traditional culture, paper are treasured wherein, but no matter are " rice paper ", " Jiajiang china picture-character paper ", or Fuyang " a kind of writing paper " etc. of traditional handicraft; When the user creates; All have a large amount of prepared Chinese ink and pigment to be coated with and write on the paper, and the paper of absorption ink, pigment is easy to breakage, the works of the especially big chi width of cloth; More need take a long time, and can't move it after the works completion at once.This traditional culture is used paper, touches to be prone to broken weakness behind the water, and since the papermaking technology invention, be a difficult problem that never solves.Common china picture-character paper will remedy this shortcoming, need capture a lot of difficult problems, and the most important is exactly under dry and moistening state, to improve strength of paper simultaneously, so just needs scientific and reasonable prescription of design and pulping process.Therefore, first purpose of the present invention is to address this problem, thereby can provide the wet tensile (strength) index of the anti-broken function ratio GB/T18739-2008 rice paper national standard of a kind of anti-water to surpass the china picture-character paper more than 10 times in the painting creation process.
Traditional culture is used paper; No matter make by hand or the product that mechanization is made, all exist in various degree the problem of " oxidation (wearing out) ", people are to their preservation; Need a cover " specific preservation environment and methods "; If but can improve the anti-oxidation function of paper itself, can make things convenient for the preservation of common people masses greatly to calligraphy and painting, ancient book nationality, can alleviate the workload of specialty collected books again.Therefore, second purpose of the present invention is to improve the paper anti-oxidation function.
Traditional culture with the word of paper, picture, books works in long-time the preservation; Situation about can damage by worms; Influenced the holding time of word, picture, books, therefore at present main word, picture, books are preserved unit, not only particular environment will be arranged; Also will make regular check on and regularly ted, the libliotheca that has also carries out expelling parasite by the fragrance of plant.Though praising of " thousand bamboo paper longevity " arranged,, obviously,, depends merely on the mothproof performance inadequate natural endowment of paper itself in the china picture-character paper field because of specific environment and above measure all can only be played the certain protection effect.Therefore, the 3rd purpose of the present invention is to the raising mothproof effect of adopting new technology behind the paper dryer.
The objective of the invention is to be able to implement through following technical scheme:
The anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water is prepared through pulping process and machine hand's skill by following raw and auxiliary material, wherein:
Raw-material component and weight portion are:
Bamboo pulp fiber 45-80 part, straw pulp fiber 10-30 part, wood pulp fibre 5-25 part and viscose 5-25 part;
In ton paper, the component of auxiliary material and percentage by weight are:
Antiseptic 0.5-2%, PVA 3-15%, shrubby sophora extract 0.5-5%, Folium Artemisiae Argyi extract 1-3% and root of langdu extract 1-5%.
The present invention is made up of two parts, at first is a scientific and reasonable prescription, secondly is a manufacture craft that the advanced person is complete.Because china picture-character paper product of the present invention is to be main raw material with the bamboo pulp fiber; Though the water imbibition of bamboo pulp fiber is fine; But bamboo pulp fiber is shorter, and increase acquires a certain degree of difficulty to intensity, therefore needs to adopt the prescription of multiple fiber combinations to realize improving strength of paper.
The present invention adopts the prescription of four kinds of different fiber combinations, its objective is: should keep the original good water absorption of china picture-character paper, characteristics that ink wetting capability is good, improve the paper strength under dry, the wet different conditions again.But, be faced with two groups of contradictions: 1. from the paper water imbibition with to the explanation on the fibre structure principle, the paper of a good water absorption, its surface fiber require liquid promptly to permeate and with the moistening of fiber.The arrangement architecture of fiber just needs the environment that appropriateness is loose like this, but fibre structure is loose, and strength of paper just reduces; And paper strength is high, and fibre structure is on the contrary, needs closely; And tightr intensity is high more; Therefore fibre structure is loose and tight, and water imbibition and intensity have become " negative and positive " contradiction of opposition each other.2. the principle of contradiction is explained between ink wetting capability and the fiber length: the ink wetting capability of china picture-character paper is that expert of calligraphy and paintings' long-felt is approved with common over the past thousands of years, and has got a friendly name " ink wetting capability ".Explain from the principles of science: the china picture-character paper that ink wetting capability is good; In the slit of its surface fiber framework; Need tiny staple fibre to fill up, with the transition reposefully of help prepared Chinese ink, and paper is under the situation of the loose structure of appropriateness; Keep the measured value of satisfied " tearability " (GB/T 455-2002), " tensile strength " (GB/T 453-2002), " bursting strength " (GB/T 454-2002), just need long fiber to support as framework.So how to handle the layout of fiber alignment framework well, take into account the functional requirement of long and short two kind fiber, just tackle different fibers and take rational proportion.Simultaneously, how can the characteristic and the function of various fibers be brought into play, also need the pulping process of a science to accomplish.
The present invention at first considers the ink wetting capability of paper, so adopt the straw pulp fiber of certain proportioning and be worked into the requirement that beating degree is 40oSR ~ 65oSR when the prescription design.In principle, straw pulp fiber impurity cell content is many, and fragile, very easily broken; Therefore after arriving the beating degree requirement, actual fibers is very tiny, fills up in the slit of other fiber frameworks with such fiber fines; Can help prepared Chinese ink transition evenly; Moisture spreads in advance in the minimizing prepared Chinese ink, causes the situation of lint shape, thereby reaches good ink wetting capability effect.
In the present invention's prescription, consider the water imbibition requirement of paper, the bamboo pulp fiber that has adopted 45-80 weight portion proportioning is as main body.Because the bamboo pulp fiber surface has multilayer, fragility, random secondary wall to be wrapped in, therefore reach 35oSR ~ 55oSR through the slurrying beating degree after, the water imbibition of fiber and the fineness of paper can both effectively be improved.
Consider bursting strength, the tensile strength of paper, the requirement of tearability in the present invention prescription; Adopted the softwood pulp fiber of 5-25 weight portion and the viscose of identical proportioning, and through different carding process, on the basis of not destroying fibre length; Give fiber decomposes as far as possible; Make the fiber of decomposition become the trunk skeleton in the paper fibre arrangement, the support strength of reinforcing fibre, thereby bursting strength, tensile strength and the tearability of raising paper.
In the present invention's prescription, consider the requirement of paper wet strength, adopted the PVA of 3-15% (in ton paper).After discongesting stirring through cold water; It is dissolved in the liquid, and these liquid can make various fiber surface all bond through stirring and (draw) the very thin film of one deck after getting into and joining stock tank; This tunic; Do not influencing under the preceding topic of water imbibition, ink wetting capability, can make the intertwined point that contacts between fiber get into drying cylinder again after, become " pad " of polyvinyl alcohol one by one.The existence of the polyvinyl alcohol " pad " of several hundred million ten thousand fiber handing-over has improved the wet strength of paper greatly like this, thereby has reached the anti-broken function of anti-water.Secondly; Because each root fiber fines; All drawn the composition of an amount of polyvinyl alcohol, so after the baking and curing, weakened paper and produced the weakness of oxidative degradation because of effects such as moisture, humidity, light enzyme, humidity cause paper down; Improve the oxidation resistance of paper, reached anti-oxidation purpose.PVA among the present invention is meant paper grade (stock) PVA, such as the commercially available prod of adopting among the embodiment, and the PVA that PVA0588, PVA1788, PVA1799, PVA T-350, PVA2199, PVA2299 or the like papermaking is special-purpose.
As preferably, prevent broken anti-oxidant mothproof china picture-character paper according to a kind of anti-water of the present invention, wherein said wood pulp fibre is the softwood pulp fiber; The specification of viscose meets Φ 14-16D (D representes the fiber number of fiber, claims " dawn number " again), and length is the 10-12 millimeter.
As preferably, prevent broken anti-oxidant mothproof china picture-character paper according to a kind of anti-water of the present invention, wherein said shrubby sophora extract is the shrubby sophora extract of 5% kushenin content; Folium Artemisiae Argyi extract is the Folium Artemisiae Argyi extract of 0.8% mugwort leaf extract content; Root of langdu extract is the root of langdu extract of 0.8% chamaejasmine content.
As preferably; According to the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water of the present invention; Wherein said pulping process comprises: with straw pulp fiber pulping and defibrination handle to beating degree (also be beating degree, represent) with a ° SR be 40 ° of SR-65 ° SR, get into and join stock tank; With bamboo pulp fiber pulping and defibrination handle to beating degree be 35 ° of SR-55 ° of SR, get into and join stock tank; With the wood pulp fibre pulping and discongest handle to beating degree at 30 ° below the SR, get into and join stock tank; With viscose and PVA pulping together and discongest, the retention time got into and joins stock tank more than 30 minutes, and unified the stirring obtains paper pulp, and be subsequent use.
As preferably, prevent broken anti-oxidant mothproof china picture-character paper according to a kind of anti-water of the present invention, wherein said machine hand's skill comprises: paper pulp is delivered to paper machine; It is dewatered on papermaking wire-cloth be interweaved, bond together in the fiber filter moisture process of online, get into drying cylinder then and carry out dried;, paper gets into impregnation technology after drying for the first time immediately; Maceration extract is the solution that contains antiseptic, shrubby sophora extract and root of langdu extract, presses the branch entering drying cylinder that anhydrates to carry out the drying second time after the impregnation process, sprays processing with the solution that contains Folium Artemisiae Argyi extract behind the paper dryer; Spray is handled back entering drying cylinder and is carried out dry for the third time; Get into web inspection system behind the paper dryer and detect, get into reel cylinder then, carry out size at last and cut and check and approve the back with quantity and pack with the detection by quantitative system.Antiseptic among the present invention selects for use the special-purpose antiseptic of papermaking to get final product, such as the RZ-4 antiseptic of selecting for use among the embodiment (extensively contain in Nantong).
For satisfying requirement of the present invention; The paper pulp that pulping process obtains is delivered to paper machine; Its papermaking wire-cloth need adopt two various flows to, scalable in length and breadth to the then streaming net cage (patent No. is ZL200920199569.X) of pulling force, to dwindle the error of vertical, horizontal intensity.(outer net is the bamboo curtain splint silk screen to add two dissimilar cylinder moulds; An outer net is 90 order stainless steel plain nets); Fiber bonds together the fiber of online through the online slurry of two difference in functionalitys in filtering moisture process, get into drying cylinder then and carry out drying program.
Carried out dry run three times in machine hand's skill, dried is all accomplished one or several special functions each time.Dry for the first time back gets into impregnation technology; With suppressing vegetative antiseptic and preventing to eat into kushenin, the chamaejasmine that erosion Jia 、 Du fish, booklice and termite nibble and be immersed on the paper uniformly; The drying back sprays mugwort leaf extract on paper with the method for spray uniformly for the second time, has further strengthened mothproof function with the fragrance of plant.Antiseptic among the present invention selects for use the special-purpose antiseptic of papermaking to get final product, such as the RZ-4 antiseptic of selecting for use among the embodiment (extensively contain in Nantong).
As more preferably, according to the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water of the present invention, the wherein said oven dry first time and the drying cylinder that adopts in the drying second time meet 2.5 ~ 3 meters of Φ; Drying cylinder in the drying meets 1.5 ~ 2 meters of Φ for the third time.
As more preferably, according to the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water of the present invention, it is formulated that wherein said maceration extract adds water by the 120-150% of antiseptic, shrubby sophora extract and root of langdu extract gross weight.Antiseptic among the present invention selects for use the special-purpose antiseptic of papermaking to get final product, such as the RZ-4 antiseptic of selecting for use among the embodiment (extensively contain in Nantong).
As more preferably, according to the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water of the present invention, the wherein said solution that contains Folium Artemisiae Argyi extract carries out many shower nozzle sprays by the concentration of per hundred kg paper waters, 50 ~ 60kg.
The present invention has following advantage:
The present invention is through scientific and reasonable prescription and pulping process, and the slurry that obtains (paper pulp) is after the paper moulding, and the arrangement architecture of fiber is main skeleton with viscose; Wood pulp fibre is an assist architecture, and bamboo pulp fiber is a basal layer, three kinds of fiber support the fundamental strength of paper; And the straw pulp fiber fines fiberfill fibers in the framework slit as a whole; Increased the ink wetting capability of paper, last with the PVA after dissolving, help above fiber when integrated arrangement; Increased cementation on the mutual contact point face; After the baking and curing, weakened paper and produced, so just accomplished the anti-broken oxidation resistant purpose of the anti-water of china picture-character paper because of effects such as moisture, humidity, light enzyme, humidity cause the problem of oxidative degradation down.
The present invention prevents that with antiseptic the chamaejasmine and the kushenin of damaging by worms are uniformly impregnated within on the paper through impregnation technology, through spray mugwort leaf extract is evenly sprayed on the paper again, has further strengthened the mothproof function of paper with plant fragrance.The mode of dipping and spray is adsorbed in the fiber medicament uniformly, has guaranteed the stability of paper quality, thereby has reached the purpose of anti-mould and anti-moth.Improve the anti-mould and anti-moth function of paper fibre itself, also can reduce in the paper preservation the dependence of environment with technology.
The china picture-character paper product that the present invention obtains; Detect in the physical and chemical index: bursting strength, tensile strength (vertical, horizontal stroke), tearability (vertical, horizontal stroke), water imbibition (vertical, horizontal stroke), wet strength (vertical, horizontal stroke) and ink wetting capability; The anti-aging geographical sign product that all reached; Wet bursting strength after the quality requirement of rice paper standard GB/T18739-2008, especially the paper immersion, the index of wet tensile (strength) are particularly outstanding.And paper of whiteness, vertical, the horizontal quantitative error of paper, the fiber alignment uniformity of paper, the surface impurity of paper, surface quality such as fiber knotting have all obtained promoting significantly.Also paper has been carried out the processing of technologies such as anti-oxidant, anti-mould and anti-moth simultaneously, made the inside and outside quality of paper all obtain further raising.
The specific embodiment
Below in conjunction with embodiment, content of the present invention is described more specifically.Should be appreciated that enforcement of the present invention is not limited to following embodiment, all will fall into protection domain of the present invention any pro forma accommodation and/or the change that the present invention made.
In the present invention, if not refer in particular to, all part, percentages are unit of weight, and all equipment and raw material etc. all can be buied from market or the industry is commonly used.Method among the following embodiment if no special instructions, is the conventional method of this area.
Embodiment 1:
The anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water, preparation as follows:
1, get the raw materials ready, steps of raw and auxiliary material proportioning is following:
(1) raw-material component and weight portion are:
80 parts of bamboo pulp fibers,
30 parts of straw pulp fibers,
25 parts of softwood pulp fibers,
25 parts of viscoses (Φ 14-16D, length is 10 millimeters);
(2) in ton paper, the component of auxiliary material and percentage by weight are:
RZ-4 antiseptic (extensively contain in Nantong) 2%,
PVA0588 (Suzhou Yongsheng Chemical Industry Science Co., Ltd) 15%,
The shrubby sophora extract 5% of 5% kushenin content,
The Folium Artemisiae Argyi extract 3% of 0.8% mugwort leaf extract content
The root of langdu extract 5% of 0.8% chamaejasmine content.
2, slurrying
1. at first the straw pulp fiber is got into the hydrabrusher pulping by proportioning, get into disc mill then and carry out defibrination, stock tank was joined in entering after beating degree reached 65oSR.
2. bamboo pulp fiber carries out pulping by proportioning, gets into disc mill then and carries out defibrination, and stock tank was joined in entering after beating degree reached 55oSR.
3. the softwood pulp fiber carries out pulping by proportioning, gets into fluffer then and discongests, and beating degree remains on below the 30oSR, gets into to join stock tank.
4. viscose and PVA0588 carry out pulping by proportioning entering pulper together, get into swing fluffer then and discongest, and the retention time after range estimation, sampling pulp fiber disperse, got into and joins stock tank more than 30 minutes.
The unified stirring obtains paper pulp, and be subsequent use.
Detect: slurry is seated in the container, adds water and release and separate concentration when 1-1.5 ‰ concentration, the overall dispersion effect of range estimation fiber reaches no tiny lumps, fiber is not tied a knot, and it is qualified to detect.
3, copy paper
Paper pulp is delivered to paper machine; It is dewatered on papermaking wire-cloth is interweaved; Bond together in the fiber filter moisture process of online; The drying cylinder that gets into 2.5 meters of Φ then carries out dried, after paper is dried for the first time, gets into impregnation technology immediately, and maceration extract is the solution (it is formulated that described maceration extract adds water by 150% of RZ-4 antiseptic, shrubby sophora extract and root of langdu extract gross weight) that contains RZ-4 antiseptic, shrubby sophora extract and root of langdu extract; It is dry that the drying cylinder of pressing the branch that anhydrates to get into 2.5 meters of Φ after the impregnation process carries out the second time; Spray processing (the described solution that contains Folium Artemisiae Argyi extract carries out many shower nozzles by the concentration of per hundred kg paper water 50kg and sprays) with the solution that contains Folium Artemisiae Argyi extract behind the paper dryer, spray the drying cylinder that gets into 1.5 meters of Φ after handling and carry out drying for the third time, entering web inspection system and detection by quantitative system detect behind the paper dryer; Get into reel cylinder then, carry out size at last and cut with quantity and check and approve back packing.
For satisfying requirement of the present invention; The paper pulp that pulping process obtains is delivered to paper machine; Its papermaking wire-cloth need adopt two various flows to, scalable in length and breadth to the then streaming net cage (patent No. is ZL200920199569.X) of pulling force, to dwindle the error of vertical, horizontal intensity.(outer net is the bamboo curtain splint silk screen to add two dissimilar cylinder moulds; An outer net is 90 order stainless steel plain nets); Fiber bonds together the fiber of online through the online slurry of two difference in functionalitys in filtering moisture process, get into drying cylinder then and carry out drying program.
Carried out dry run three times in machine hand's skill, dried is all accomplished one or several special functions each time.Dry for the first time back gets into impregnation technology; With suppressing vegetative RZ-4 antiseptic and preventing to eat into kushenin, the chamaejasmine that erosion Jia 、 Du fish, booklice and termite nibble and be immersed on the paper uniformly; The drying back sprays the tarragon vanilla on paper with the method for spray uniformly for the second time, has further strengthened mothproof function with the fragrance of plant.
Embodiment 2
The anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water, preparation as follows:
1, get the raw materials ready, steps of raw and auxiliary material proportioning is following:
(1) raw-material component and weight portion are:
45 parts of bamboo pulp fibers,
20 parts of straw pulp fibers,
15 parts of softwood pulp fibers,
15 parts of viscoses (Φ 14-16D, length is 12 millimeters);
(2) in ton paper, the component of auxiliary material and percentage by weight are:
RZ-4 antiseptic (extensively contain in Nantong) 0.5%,
PVA1788 (sharpening worker Co., Ltd is thought in Shanghai) 3%,
The shrubby sophora extract 0.5% of 5% kushenin content,
The Folium Artemisiae Argyi extract 1% of 0.8% mugwort leaf extract content
The root of langdu extract 1% of 0.8% chamaejasmine content.
2, slurrying
1. at first the straw pulp fiber is got into the hydrabrusher pulping by proportioning, get into disc mill then and carry out defibrination, stock tank was joined in entering after beating degree reached 40oSR.
2. bamboo pulp fiber carries out pulping by proportioning, gets into disc mill then and carries out defibrination, and stock tank was joined in entering after beating degree reached 35oSR.
3. the softwood pulp fiber carries out pulping by proportioning, gets into fluffer then and discongests, and beating degree remains on below the 30oSR, gets into to join stock tank.
4. viscose and PVA1788 carry out pulping by proportioning entering pulper together, get into swing fluffer then and discongest, and the retention time after range estimation, sampling pulp fiber disperse, got into and joins stock tank more than 30 minutes.
The unified stirring obtains paper pulp, and be subsequent use.
Detect: slurry is seated in the container, adds water and release and separate concentration when 1-1.5 ‰ concentration, the overall dispersion effect of range estimation fiber reaches no tiny lumps, fiber is not tied a knot, and it is qualified to detect.
3, copy paper
Paper pulp is delivered to paper machine; It is dewatered on papermaking wire-cloth is interweaved; Bond together in the fiber filter moisture process of online; The drying cylinder that gets into 3 meters of Φ then carries out dried, after paper is dried for the first time, gets into impregnation technology immediately, and maceration extract is the solution (it is formulated that described maceration extract adds water by 120% of RZ-4 antiseptic, shrubby sophora extract and root of langdu extract gross weight) that contains RZ-4 antiseptic, shrubby sophora extract and root of langdu extract; It is dry that the drying cylinder of pressing the branch that anhydrates to get into 3 meters of Φ after the impregnation process carries out the second time; Spray processing (the described solution that contains Folium Artemisiae Argyi extract carries out many shower nozzles by the concentration of per hundred kg paper water 60kg and sprays) with the solution that contains Folium Artemisiae Argyi extract behind the paper dryer, spray the drying cylinder that gets into 2 meters of Φ after handling and carry out drying for the third time, entering web inspection system and detection by quantitative system detect behind the paper dryer; Get into reel cylinder then, carry out size at last and cut with quantity and check and approve back packing.
For satisfying requirement of the present invention; The paper pulp that pulping process obtains is delivered to paper machine; Its papermaking wire-cloth need adopt two various flows to, scalable in length and breadth to the then streaming net cage (patent No. is ZL200920199569.X) of pulling force, to dwindle the error of vertical, horizontal intensity.(outer net is the bamboo curtain splint silk screen to add two dissimilar cylinder moulds; An outer net is 90 order stainless steel plain nets); Fiber bonds together the fiber of online through the online slurry of two difference in functionalitys in filtering moisture process, get into drying cylinder then and carry out drying program.
Carried out dry run three times in machine hand's skill, dried is all accomplished one or several special functions each time.Dry for the first time back gets into impregnation technology; With suppressing vegetative RZ-4 antiseptic and preventing to eat into kushenin, the chamaejasmine that erosion Jia 、 Du fish, booklice and termite nibble and be immersed on the paper uniformly; The drying back sprays the tarragon vanilla on paper with the method for spray uniformly for the second time, has further strengthened mothproof function with the fragrance of plant.
Embodiment 3
The anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water, preparation as follows:
1, get the raw materials ready, steps of raw and auxiliary material proportioning is following:
(1) raw-material component and weight portion are:
70 parts of bamboo pulp fibers,
10 parts of straw pulp fibers,
5 parts of softwood pulp fibers,
5 parts of viscoses (Φ 14-16D, length is 10 millimeters);
(2) in ton paper, the component of auxiliary material and percentage by weight are:
RZ-4 antiseptic (extensively contain in Nantong) 1%,
PVA T-350 (The Nippon Synthetic Chemical Industry Co., Ltd) 10%,
The shrubby sophora extract 3% of 5% kushenin content,
The Folium Artemisiae Argyi extract 3% of 0.8% mugwort leaf extract content
The root of langdu extract 2% of 0.8% chamaejasmine content.
2, slurrying
1. at first the straw pulp fiber is got into the hydrabrusher pulping by proportioning, get into disc mill then and carry out defibrination, stock tank was joined in entering after beating degree reached 60oSR.
2. bamboo pulp fiber carries out pulping by proportioning, gets into disc mill then and carries out defibrination, and stock tank was joined in entering after beating degree reached 45oSR.
3. the softwood pulp fiber carries out pulping by proportioning, gets into fluffer then and discongests, and beating degree remains on below the 30oSR, gets into to join stock tank.
4. viscose and PVA T-350 carry out pulping by proportioning entering pulper together, get into swing fluffer then and discongest, and the retention time after range estimation, sampling pulp fiber disperse, got into and joins stock tank more than 30 minutes.
The unified stirring obtains paper pulp, and be subsequent use.
Detect: slurry is seated in the container, adds water and release and separate concentration when 1-1.5 ‰ concentration, the overall dispersion effect of range estimation fiber reaches no tiny lumps, fiber is not tied a knot, and it is qualified to detect.
3, copy paper
Paper pulp is delivered to paper machine; It is dewatered on papermaking wire-cloth is interweaved; Bond together in the fiber filter moisture process of online; The drying cylinder that gets into 3 meters of Φ then carries out dried, after paper is dried for the first time, gets into impregnation technology immediately, and maceration extract is the solution (it is formulated that described maceration extract adds water by 140% of RZ-4 antiseptic, shrubby sophora extract and root of langdu extract gross weight) that contains RZ-4 antiseptic, shrubby sophora extract and root of langdu extract; It is dry that the drying cylinder of pressing the branch that anhydrates to get into 3 meters of Φ after the impregnation process carries out the second time; Spray processing (the described solution that contains Folium Artemisiae Argyi extract carries out many shower nozzles by the concentration of per hundred kg paper water 54kg and sprays) with the solution that contains Folium Artemisiae Argyi extract behind the paper dryer, spray the drying cylinder that gets into 2 meters of Φ after handling and carry out drying for the third time, entering web inspection system and detection by quantitative system detect behind the paper dryer; Get into reel cylinder then, carry out size at last and cut with quantity and check and approve back packing.
For satisfying requirement of the present invention; The paper pulp that pulping process obtains is delivered to paper machine; Its papermaking wire-cloth need adopt two various flows to, scalable in length and breadth to the then streaming net cage (patent No. is ZL200920199569.X) of pulling force, to dwindle the error of vertical, horizontal intensity.(outer net is the bamboo curtain splint silk screen to add two dissimilar cylinder moulds; An outer net is 90 order stainless steel plain nets); Fiber bonds together the fiber of online through the online slurry of two difference in functionalitys in filtering moisture process, get into drying cylinder then and carry out drying program.
Carried out dry run three times in machine hand's skill, dried is all accomplished one or several special functions each time.Dry for the first time back gets into impregnation technology; With suppressing vegetative RZ-4 antiseptic and preventing to eat into kushenin, the chamaejasmine that erosion Jia 、 Du fish, booklice and termite nibble and be immersed on the paper uniformly; The drying back sprays the tarragon vanilla on paper with the method for spray uniformly for the second time, has further strengthened mothproof function with the fragrance of plant.
Embodiment 4
The anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water, preparation as follows:
1, get the raw materials ready, steps of raw and auxiliary material proportioning is following:
(1) raw-material component and weight portion are:
50 parts of bamboo pulp fibers,
15 parts of straw pulp fibers,
20 parts of softwood pulp fibers,
20 parts of viscoses (Φ 14-16D, length is 12 millimeters);
(2) in ton paper, the component of auxiliary material and percentage by weight are:
RZ-4 antiseptic (extensively contain in Nantong) 1.5%,
PVA2199 (river, Jiangxi Wei Gaoke limited company) 12%,
The shrubby sophora extract 2% of 5% kushenin content,
The Folium Artemisiae Argyi extract 3% of 0.8% mugwort leaf extract content
The root of langdu extract 4% of 0.8% chamaejasmine content.
2, slurrying
1. at first the straw pulp fiber is got into the hydrabrusher pulping by proportioning, get into disc mill then and carry out defibrination, stock tank was joined in entering after beating degree reached 58oSR.
2. bamboo pulp fiber carries out pulping by proportioning, gets into disc mill then and carries out defibrination, and stock tank was joined in entering after beating degree reached 42oSR.
3. the softwood pulp fiber carries out pulping by proportioning, gets into fluffer then and discongests, and beating degree remains on below the 30oSR, gets into to join stock tank.
4. viscose and PVA2199 carry out pulping by proportioning entering pulper together, get into swing fluffer then and discongest, and the retention time after range estimation, sampling pulp fiber disperse, got into and joins stock tank more than 30 minutes.
The unified stirring obtains paper pulp, and be subsequent use.
Detect: slurry is seated in the container, adds water and release and separate concentration when 1-1.5 ‰ concentration, the overall dispersion effect of range estimation fiber reaches no tiny lumps, fiber is not tied a knot, and it is qualified to detect.
3, copy paper
Paper pulp is delivered to paper machine; It is dewatered on papermaking wire-cloth is interweaved; Bond together in the fiber filter moisture process of online; The drying cylinder that gets into 2.5 meters of Φ then carries out dried, after paper is dried for the first time, gets into impregnation technology immediately, and maceration extract is the solution (it is formulated that described maceration extract adds water by 135% of RZ-4 antiseptic, shrubby sophora extract and root of langdu extract gross weight) that contains RZ-4 antiseptic, shrubby sophora extract and root of langdu extract; It is dry that the drying cylinder of pressing the branch that anhydrates to get into 2.5 meters of Φ after the impregnation process carries out the second time; Spray processing (the described solution that contains Folium Artemisiae Argyi extract carries out many shower nozzles by the concentration of per hundred kg paper water 56kg and sprays) with the solution that contains Folium Artemisiae Argyi extract behind the paper dryer, spray the drying cylinder that gets into 1.5 meters of Φ after handling and carry out drying for the third time, entering web inspection system and detection by quantitative system detect behind the paper dryer; Get into reel cylinder then, carry out size at last and cut with quantity and check and approve back packing.
For satisfying requirement of the present invention; The paper pulp that pulping process obtains is delivered to paper machine; Its papermaking wire-cloth need adopt two various flows to, scalable in length and breadth to the then streaming net cage (patent No. is ZL200920199569.X) of pulling force, to dwindle the error of vertical, horizontal intensity.(outer net is the bamboo curtain splint silk screen to add two dissimilar cylinder moulds; An outer net is 90 order stainless steel plain nets); Fiber bonds together the fiber of online through the online slurry of two difference in functionalitys in filtering moisture process, get into drying cylinder then and carry out drying program.
Carried out dry run three times in machine hand's skill, dried is all accomplished one or several special functions each time.Dry for the first time back gets into impregnation technology; With suppressing vegetative RZ-4 antiseptic and preventing to eat into kushenin, the chamaejasmine that erosion Jia 、 Du fish, booklice and termite nibble and be immersed on the paper uniformly; The drying back sprays the tarragon vanilla on paper with the method for spray uniformly for the second time, has further strengthened mothproof function with the fragrance of plant.
Table 1 present disclosure drawing paper and GB/T18739-2008 geographical sign product, rice paper national standard are relatively
Can find out by table 1; China picture-character paper of the present invention can both meet or exceed the rice paper national standard aspect the degradation under tightness, tensile strength, breaking length, tear index, water imbibition and ageing-resistant whiteness, particularly outstanding is that wet tensile (strength) has improved more than 18 times than rice paper.Therefore, china picture-character paper of the present invention has possessed the anti-broken antioxygenic property of strong relatively anti-water.
In addition, suppress vegetative RZ-4 antiseptic owing to added in the machine hand of the present disclosure drawing paper skill, prevent to eat into kushenin, the chamaejasmine that erosion Jia 、 Du fish, booklice and termite are nibbled, the plant fragrance of mugwort leaf extract has further been strengthened the mothproof function of china picture-character paper.Therefore, the present disclosure drawing paper has also possessed strong relatively mildew-resistant and mothproof performance.
Above-mentioned preferred embodiment just is used for explanation and explains content of the present invention not constituting the restriction to content of the present invention.Although the inventor has done in more detail the present invention and has enumerated; But; The content that those skilled in the art is disclosed according to summary of the invention part and embodiment can be made various modifications or/and additional or to adopt similar mode to substitute be obvious to described specific embodiment, and can realize technique effect of the present invention; Therefore, give unnecessary details no longer one by one here.The term that occurs among the present invention is used for the elaboration of technical scheme of the present invention and understanding are not construed as limiting the invention.
Claims (8)
1. the anti-broken anti-oxidant mothproof china picture-character paper of anti-water is characterized in that described china picture-character paper is prepared through pulping process and machine hand's skill by following raw and auxiliary material, wherein:
Raw-material component and weight portion are:
Bamboo pulp fiber 45-80 part, straw pulp fiber 10-30 part, wood pulp fibre 5-25 part and viscose 5-25 part;
In ton paper, the component of auxiliary material and percentage by weight are:
Antiseptic 0.5-2%, PVA 3-15%, shrubby sophora extract 0.5-5%, Folium Artemisiae Argyi extract 1-3% and root of langdu extract 1-5%.
2. the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water according to claim 1, its characteristic is being that described wood pulp fibre is the softwood pulp fiber; The specification of viscose meets Φ 14-16D, and length is the 10-12 millimeter.
3. the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water according to claim 1 is characterized in that described shrubby sophora extract is the shrubby sophora extract of 5% kushenin content; Folium Artemisiae Argyi extract is the Folium Artemisiae Argyi extract of 0.8% mugwort leaf extract content; Root of langdu extract is the root of langdu extract of 0.8% chamaejasmine content.
4. the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water according to claim 1 is characterized in that described pulping process comprises: with straw pulp fiber pulping and defibrination handle to beating degree be 40 ° of SR-65 ° SR, get into and join stock tank; With bamboo pulp fiber pulping and defibrination handle to beating degree be 35 ° of SR-55 ° of SR, get into and join stock tank; With the wood pulp fibre pulping and discongest handle to beating degree at 30 ° below the SR, get into and join stock tank; With viscose and PVA pulping together and discongest, the retention time got into and joins stock tank more than 30 minutes, and unified the stirring obtains paper pulp, and be subsequent use.
5. the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water according to claim 1 is characterized in that described machine hand's skill comprises: paper pulp is delivered to paper machine, it is dewatered be interweaved on papermaking wire-cloth; Bond together in the fiber filter moisture process of online; Get into drying cylinder then and carry out dried, after paper is dried for the first time, get into impregnation technology immediately, maceration extract is the solution that contains antiseptic, shrubby sophora extract and root of langdu extract; Press the branch entering drying cylinder that anhydrates to carry out the drying second time after the impregnation process; Use the solution that contains Folium Artemisiae Argyi extract to spray processing behind the paper dryer, spray processing back entering drying cylinder and carry out drying for the third time, entering web inspection system and detection by quantitative system detect behind the paper dryer; Get into reel cylinder then, carry out size at last and cut with quantity and check and approve back packing.
6. the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water according to claim 5 is characterized in that the described oven dry first time meets 2.5 ~ 3 meters of Φ with the drying cylinder that adopts in the drying second time; Drying cylinder in the drying meets 1.5 ~ 2 meters of Φ for the third time.
7. the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water according to claim 5, it is formulated to it is characterized in that described maceration extract adds water by the 120-150% of antiseptic, shrubby sophora extract and root of langdu extract gross weight.
8. the anti-broken anti-oxidant mothproof china picture-character paper of a kind of anti-water according to claim 5 is characterized in that the described solution that contains Folium Artemisiae Argyi extract carries out many shower nozzle sprays by the concentration of per hundred kg paper waters, 50 ~ 60kg.
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| CN102677526A (en) * | 2012-06-13 | 2012-09-19 | 何卷舒 | Environmental-friendly rice paper and preparation method thereof |
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| CN104963233B (en) * | 2015-07-30 | 2017-03-01 | 四川理工学院 | The china picture-character paper of a kind of interpolation bleached bamboo pulp dregs of rice and fibre grafting agent and preparation method |
| CN105297528A (en) * | 2015-09-11 | 2016-02-03 | 姚志宏 | Air-permeable temperature-resistant composite raw paper and making method thereof |
| CN105780580A (en) * | 2016-05-05 | 2016-07-20 | 潘小英 | Bamboo paper making process |
| CN107338673A (en) * | 2017-07-21 | 2017-11-10 | 华南理工大学 | Controllable antibacterial china picture-character paper of a kind of ink wetting capability and preparation method thereof |
| CN107447585B (en) * | 2017-08-09 | 2019-10-18 | 华南理工大学 | A kind of high performance machine imperial decree drawing paper and preparation method thereof |
| CN107447585A (en) * | 2017-08-09 | 2017-12-08 | 华南理工大学 | A kind of high performance machine imperial decree drawing paper and preparation method thereof |
| CN108411700A (en) * | 2017-10-07 | 2018-08-17 | 谷文 | A kind of painting and calligraphy carrier material |
| CN108589392A (en) * | 2017-12-20 | 2018-09-28 | 新乡学院 | A kind of special drawing drawing paper of gouache |
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