CN105297528A - Air-permeable temperature-resistant composite raw paper and making method thereof - Google Patents

Air-permeable temperature-resistant composite raw paper and making method thereof Download PDF

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Publication number
CN105297528A
CN105297528A CN201510575733.2A CN201510575733A CN105297528A CN 105297528 A CN105297528 A CN 105297528A CN 201510575733 A CN201510575733 A CN 201510575733A CN 105297528 A CN105297528 A CN 105297528A
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add
fiber
stir
hour
dry
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CN201510575733.2A
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姚志宏
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Li Wengang
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Abstract

The invention discloses air-permeable temperature-resistant composite raw paper. Hybrid antimicrobial slurry prepared from an antimicrobial agent is added into raw materials; the raw paper disclosed by the invention is durable in antimicrobial property, environment-friendly and free of environmental pollution compared with that obtained by traditional methods, such as spraying, glue application, coating, dipping and the like; wollastonite fiber and mucilage glue fiber are modified and spun again to prepare novel composite fiber, and the tenacity and the strength of the paper are remarkably improved by mutually compounding the wollastonite fiber and the mucilage glue fiber and adding into the raw materials; vinyl trimethoxy silane and other effective auxiliaries are added, an Si-C bond can form a chemical bond with hydroxyl in cellulose, and therefore the special surface property is endowed to the fiber; the composite raw paper disclosed by the invention is promoted in instantaneous high temperature resistance, good in air permeability and moisture conductivity, flexible and resistant to fold, and not easy to curl and resurgence and lays a foundation for producing high-quality wallpaper finished-products.

Description

A kind of ventilative heatproof composite base paper and preparation method thereof
Technical field
The present invention relates to pulp technology for making paper, particularly relate to a kind of ventilative heatproof composite base paper and preparation method thereof.
Background technology
Paper writes, prints, paints or the sheet-like fiber goods of packaging etc., generally by the water slurry of the string through slurrying process, in online staggered combination, preliminary hydro-extraction, more compressed, dry and form.Along with the need of development and progress people to paper of society are growing, in order to meet people to the demand paper-making industry development of paper rapidly, thus also bring a series of problem, due to the more string of needs, a large amount of trees are cut down, area of woods is reducing gradually, although take some safeguard measures, such as concede the land to forestry, but its plantation speed is far smaller than by felling speed, vegetation coverage sharply declines, thus be necessary to improve prior art, increase inorfil or other beneficiating ingredients are with substituted plant fiber, not only can save a large amount of strings also to reduction papermaking cost, conserve forests and ecological environment etc. significant, realize the target of sustainable development brought benefit to the next generation truly.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of ventilative heatproof composite base paper and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of ventilative heatproof composite base paper, is made up of the raw material of following weight portion: bleaching straw pulp 22-25, palm shell fiber pulp 11-13, expanded perlite 3-4, wollastonite fibre 19-21, viscose 15-17, carboxymethyl cellulose 2-4, water hyacinth 40-42, scouring rush 1-2, soy meal 2-3, corncob dry powder 12-14, sea-tangle liquid 10-12, vinyltrimethoxy silane 6-8, sodium borohydride 1.3-2.1,1-butyl-3-N-Methylimidazoleacetic salt 125-135, suitable quantity of water.
The preparation method of described a kind of ventilative heatproof composite base paper, comprises the following steps:
(1) water hyacinth, scouring rush are broken into juice, add corncob dry powder and stir evenly, add the sodium hydrate aqueous solution boiling 5-8 hour of appropriate 1-2%, use flowing water rinsed clean, add carboxymethyl cellulose and grind to form the antibacterial slurry of mixing;
(2) wollastonite fibre, viscose are put into 105 DEG C dry for baking oven about 3-4 hour and ground 40-50 minute, be cooled to room temperature and add sea-tangle liquid in 50-60 DEG C of grinding 2-4 hour, spraying dry, add 1-butyl-3-N-Methylimidazoleacetic salt and be heated to 90-95 DEG C, stir 40-60 minute, spinning;
(3) expanded perlite, soy meal are mixed and pulverize, add vinyltrimethoxy silane and stir 20-30 minute, dry 2-3 hour in 60-70 DEG C;
(4) bleaching straw pulp, palm shell fiber pulp and step (1), (2) material are added in beater, add suitable quantity of water making beating, then step (3) material is added and other residual componentss stir and evenly mix, being heated to 50-55 DEG C keeps temperature to stir 1-2 hour, finally starches mixing through copy paper, squeezing, oven dry, curling discharging.
Advantage of the present invention is: antiseptic is made the antibacterial slurry of mixing and added in raw material by the present invention, and traditional sprinkling of comparing, applying glue, coating, impregnating method antibiotic property are lasting, environment friendly and pollution-free environment; Wollastonite fibre, viscose modification again spinning are obtained novel composite fibre, and both mutual compounds add in raw material the toughness and intensity that significantly improve paper to; Add vinyltrimethoxy silane and other effective auxiliary agents, Si-C key can form chemical bond with the hydroxyl in cellulose, thus give fiber special surface nature, the composite base paper intensity utilizing the present invention to obtain, resistance to TRANSIENT HIGH TEMPERATURE performance boost, ventilative good, the pliable and tough folding of wet guilding, not easily crimping moisture regain, lay a good foundation for producing high-quality wallpaper finished product.
Detailed description of the invention
A kind of ventilative heatproof composite base paper, is made up of the raw material of following weight portion: bleaching straw pulp 22, palm shell fiber pulp 11, expanded perlite 3, wollastonite fibre 19, viscose 15, carboxymethyl cellulose 2, water hyacinth 40, scouring rush 1, soy meal 2, corncob dry powder 12, sea-tangle liquid 10, vinyltrimethoxy silane 6, sodium borohydride 1.3,1 butyl methyl imidazoleacetic acid salt 125, suitable quantity of water.
The preparation method of described a kind of ventilative heatproof composite base paper, comprises the following steps:
(1) water hyacinth, scouring rush are broken into juice, add corncob dry powder and stir evenly, add the sodium hydrate aqueous solution boiling 5 hours of appropriate 1%, use flowing water rinsed clean, add carboxymethyl cellulose and grind to form the antibacterial slurry of mixing;
(2) baking oven wollastonite fibre, viscose being put into 105 DEG C dries grinding 40 minutes in about 3 hours, be cooled to room temperature and add sea-tangle liquid in 50 DEG C of grindings 2 hours, spraying dry, adds 1 butyl methyl imidazoleacetic acid salt and is heated to 90 DEG C, stir 40 minutes, spinning;
(3) expanded perlite, soy meal are mixed and pulverize, add vinyltrimethoxy silane and stir 20 minutes, dry 2 hours in 60 DEG C;
(4) bleaching straw pulp, palm shell fiber pulp and step (1), (2) material are added in beater, add suitable quantity of water making beating, then step (3) material is added and other residual componentss stir and evenly mix, being heated to 50 DEG C keeps temperature to stir 1 hour, finally starches mixing through copy paper, squeezing, oven dry, curling discharging.
The technical parameter index of the composite base paper using the present invention to produce is as follows:
(1) all 99% is greater than to the inhibiting rate of mixed cell, yeast and mold;
(2) tensile index improves 112.6%;
(3) ring crush index improves 62.6%.

Claims (2)

1. a ventilative heatproof composite base paper, it is characterized in that, be made up of the raw material of following weight portion: bleaching straw pulp 22-25, palm shell fiber pulp 11-13, expanded perlite 3-4, wollastonite fibre 19-21, viscose 15-17, carboxymethyl cellulose 2-4, water hyacinth 40-42, scouring rush 1-2, soy meal 2-3, corncob dry powder 12-14, sea-tangle liquid 10-12, vinyltrimethoxy silane 6-8, sodium borohydride 1.3-2.1,1-butyl-3-N-Methylimidazoleacetic salt 125-135, suitable quantity of water.
2. the preparation method of a kind of ventilative heatproof composite base paper according to claim 1, is characterized in that comprising the following steps:
(1) water hyacinth, scouring rush are broken into juice, add corncob dry powder and stir evenly, add the sodium hydrate aqueous solution boiling 5-8 hour of appropriate 1-2%, use flowing water rinsed clean, add carboxymethyl cellulose and grind to form the antibacterial slurry of mixing;
(2) wollastonite fibre, viscose are put into 105 DEG C dry for baking oven about 3-4 hour and ground 40-50 minute, be cooled to room temperature and add sea-tangle liquid in 50-60 DEG C of grinding 2-4 hour, spraying dry, add 1-butyl-3-N-Methylimidazoleacetic salt and be heated to 90-95 DEG C, stir 40-60 minute, spinning;
(3) expanded perlite, soy meal are mixed and pulverize, add vinyltrimethoxy silane and stir 20-30 minute, dry 2-3 hour in 60-70 DEG C;
(4) bleaching straw pulp, palm shell fiber pulp and step (1), (2) material are added in beater, add suitable quantity of water making beating, then step (3) material is added and other residual componentss stir and evenly mix, being heated to 50-55 DEG C keeps temperature to stir 1-2 hour, finally starches mixing through copy paper, squeezing, oven dry, curling discharging.
CN201510575733.2A 2015-09-11 2015-09-11 Air-permeable temperature-resistant composite raw paper and making method thereof Pending CN105297528A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510575733.2A CN105297528A (en) 2015-09-11 2015-09-11 Air-permeable temperature-resistant composite raw paper and making method thereof

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Application Number Priority Date Filing Date Title
CN201510575733.2A CN105297528A (en) 2015-09-11 2015-09-11 Air-permeable temperature-resistant composite raw paper and making method thereof

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CN105297528A true CN105297528A (en) 2016-02-03

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106758489A (en) * 2016-12-08 2017-05-31 佛山市秸和科技有限公司 A kind of aroma type Anti-moth-eating composite base paper and preparation method thereof
CN108071049A (en) * 2017-11-28 2018-05-25 安徽比伦生活用纸有限公司 A kind of super-strong moisture absorbing paper handkerchief with antibiotic property

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1515739A (en) * 2003-01-08 2004-07-28 云南省非金属矿产应用研究所 Modified wollastonite mineral composite fibre for making paper and its paper-making process
CN1920167A (en) * 2005-08-24 2007-02-28 边静 Pulping method of non-wood-fiber enzymatic slurry
CN102444048A (en) * 2011-10-22 2012-05-09 富阳市金源纸业有限公司 Writing and painting paper capable of preventing water, breakage, oxidation and moth eating
CN103469672A (en) * 2013-09-07 2013-12-25 郴州四方立投资有限公司 Preparation method of wollastonite long fiber for papermaking industry
CN103911910A (en) * 2014-03-20 2014-07-09 杭州特种纸业有限公司 Plant oil filter paper
CN104005257A (en) * 2014-05-30 2014-08-27 滁州卷烟材料厂 Waterproof and degradable tipping base paper and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1515739A (en) * 2003-01-08 2004-07-28 云南省非金属矿产应用研究所 Modified wollastonite mineral composite fibre for making paper and its paper-making process
CN1920167A (en) * 2005-08-24 2007-02-28 边静 Pulping method of non-wood-fiber enzymatic slurry
CN102444048A (en) * 2011-10-22 2012-05-09 富阳市金源纸业有限公司 Writing and painting paper capable of preventing water, breakage, oxidation and moth eating
CN103469672A (en) * 2013-09-07 2013-12-25 郴州四方立投资有限公司 Preparation method of wollastonite long fiber for papermaking industry
CN103911910A (en) * 2014-03-20 2014-07-09 杭州特种纸业有限公司 Plant oil filter paper
CN104005257A (en) * 2014-05-30 2014-08-27 滁州卷烟材料厂 Waterproof and degradable tipping base paper and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106758489A (en) * 2016-12-08 2017-05-31 佛山市秸和科技有限公司 A kind of aroma type Anti-moth-eating composite base paper and preparation method thereof
CN108071049A (en) * 2017-11-28 2018-05-25 安徽比伦生活用纸有限公司 A kind of super-strong moisture absorbing paper handkerchief with antibiotic property

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Inventor after: Li Wengang

Inventor before: Yao Zhihong

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Effective date of registration: 20161208

Address after: Langya District of Anhui city in Chuzhou province 239000 Tianchang Road No. 136 building 11 room 206

Applicant after: Li Wengang

Address before: Dingyuan County in Anhui province Chuzhou city 233200 town rich Lane 20, room 4

Applicant before: Yao Zhihong

RJ01 Rejection of invention patent application after publication
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Application publication date: 20160203