CN1077938C - 含有甘油和季铵化合物的软薄纸 - Google Patents
含有甘油和季铵化合物的软薄纸 Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
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- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
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Abstract
公开了一种具有柔和手感的软薄纸,所述软薄纸含有包含大约20至大约98重量百分数的甘油和大约0.2至大约5重量百分数经选择的季铵化合物的软化组合物。
Description
发明背景
在薄纸的开发和生产领域,已做过相当大量努力来改进薄纸的柔软性。这可以用许多方法来达到,一般或者是通过改进薄纸的基质,或者是通过往薄纸中加入化学品来提供改进的手感。例如,加入矿物油或聚硅氧烷类是可以给薄纸表面提供更平滑手感的化学品。虽然薄纸的手感是一种重要的特性,但使用薄纸还要为用户提供其它益处的机会。
发明概要
现已发现优异的软薄纸可通过往薄纸中掺入一种含有经选择的组分的组合的水溶液软化组合物而提供柔和的手感。一般,本发明归结为这样一种薄纸,它已被加入一种包含甘油和一种或多种特定的有机季铵化合物的水溶液组合物。
更具体地说,季铵化合物可选自以下这些季铵类化合物:
具有下列结构的单烷基三甲基季铵类:其中X=氯化物或甲基硫酸盐,和R=脂族饱和或不饱和的C12-C22基团;
具有下列结构的单甲基三烷基季铵类:其中X=氯化物,和R=脂族烷基,正的或带支链的C8-C18基团;
施加的软化组合物的量为基于薄纸重量的大约3至大约30干重百分数,更具体地为大约3至大约20干重百分数,还更具体地为大约5至大约15干重百分数。更高的施加量更可能在皮肤上留下可觉察到的残留物,而更低的施加量则效果不可靠。可以将水加入制剂来减小甘油的粘度,从而使制剂更适宜于施用。
在水溶液软化组合物中季铵化合物的量按重量计为大约0.2%至大约5%,更具体地为大约0.3%至大约3%,还更具体地为大约0.5%至大约1%。
在水溶液软化组合物中甘油的量按重量计为大约20%至大约98%,更具体地为大约60%至大约80%,还更具体地为大约40%至大约60%。
此外,软化组合物中可含有大约0.5至大约50重量百分数的丙二醇,更具有地为大约5至大约30重量百分数的丙二醇。丙二醇可被用作这类制剂中甘油的部分替代物。
再有,软化组合物中可含有大约0.5至大约50重量百分数的聚乙二醇,更具体地为大约5至大约30重量百分数。这种聚乙二醇的分子量最好是在大约200至大约750的范围内。聚乙二醇可被用作这类软化组合物中甘油或丙二醇的部分替代物。
其它可供选择的组分包括芦荟、湿润剂、皮肤防护剂、防腐剂和手感改进剂。合适的湿润剂包括乳酸及其盐类、糖类、乙氧基化的甘油、乙氧基化的羊毛脂、玉米糖浆、经水解的淀粉水解物、尿素和山梨醇。合适的皮肤防护剂包括尿囊素、高岭土、氧化锌、二甲基聚硅氧烷乳状液、滑石和淀粉。合适的手感改进剂包括玉米淀粉、燕麦粉、滑石、一氮化硼和环糊精。
这种可以以水溶液或悬浮液形式存在的软化组合物可周任何合适的方法诸如喷雾法掺入薄纸中或印刷在薄纸的表面上。
施用软化组合物的薄纸可以是任何用作化妆纸、卫生纸或纸巾的薄纸。这类薄纸可通过完全干燥或湿压薄纸制造方法来生产并且可以是起绉的或未起绉的,层状的或非层状的(混合的)。
实施例
实施例1
一种由按重量计80份甘油、19份去离子水和1份芦荟组成的溶液是通过把三种组分混合直到均匀而制得的。然后把得到的溶液用喷雾装置施加到定量为每平方米大约45克的三层、经湿压的、起绉的薄纸上。施加的量基于薄纸重量分别为5、8和10干重百分数。所得的薄纸试样没有提供任何特别的益处。
实施例2
一种软化组合物由按重量计70份甘油、19份去离子水、1份Lanoquat 1751-A(Ambler,PA的Henkel公司出售的一种季铵-33(季铵化的羊毛脂)和丙二醇的掺合物)和一份芦荟组成。先把甘油和Lanoquat 1751-A混合在一起直到均匀,然后加入水和芦荟并把混合物搅拌直到形成均相溶液。得到的软化溶液用喷雾装置施加到定量为每平方米大约45克的三层、经湿压的、起绉的薄纸上。施加的量基于薄纸重量分别为大约10和大约12干重百分数。所得的薄纸试样在两种施加量的情况下都显得特别柔软。
实施例3
制备一种由按重量计60份甘油、20份丙二醇、1份Lanoquat 1751-A、19份去离子水和一份芦荟组成的软化组合物。将甘油和丙二醇混合在一起直到均匀。加入Lanoquat 1751-A并混合直到均匀。然后加入水和芦荟并把溶液搅拌直到均相。把得到的软化组合物用喷雾装置施加到定量为每平方米大约42克的两层的完全干燥的薄纸上。施加的量基于薄纸重量分别为6、9和12干重百分数。此外,把得到的软化组合物用喷雾装置施加到定量为每平方米大约45克的四层、经湿压的、起绉的薄纸上。施加的量基于薄纸的重量分别为6、9和12干重百分数。
实施例4
制备一种由按重量计60份甘油、20份丙二醇、5份Lanoquat1751-A、14份去离子水和1份芦荟组成的软化组合物。将甘油和丙二醇混合在一起直到均匀。加入Lanoquat 1751-A并混合直到均匀。然后加入水和芦荟并把溶液搅拌直到均相。把得到的软化组合物用喷雾装置施加到定量为每平方米大约42克的两层、完全干燥的、起绉的薄纸上。施加的量基于薄纸重量分别为6、9和12干重百分数。
用传感器表盘评估实施例3和实施例4的薄纸试样及未经处理过的两层、完全干燥的薄纸和用基于薄纸重量3干重百分数的硅氧烷处理过的两层、完全干燥的薄纸的性能。在柔软性方面实施例3和4的试样与经过硅氧烷处理过的试样一样好或更好,并在柔软性方面优于未经处理的对照纸样。在所有试样中,用量为12%的实施例4具有最好的柔软性,其次是用量为12%的实施例3。
实施例5
制备一种由按重量计40份丙二醇、1份硬脂基氯化铵、19份去离子水组成的软化组合物。将丙二醇和硬脂基氯化铵混合在一起并加热直到均匀。加入甘由并混合直到均匀。然后加入水,并把溶液搅拌直到成为均相。把得到的软化组合物用喷雾装置施加到定量为每平方米大约27克的两层、完全干燥的、起绉的薄纸上。施加的量基于薄纸重量为大约102重百分数。
实施例5的薄纸用传感器表盘主观评价,并发现比实施例3的试样更柔软、更柔滑、更平整。
在所有试样中,除实施例1的以外,当用量增加时,得到的薄纸也明显地更软。较低用量产生的薄纸不会在皮肤上留下显著的残留物。
应该理解,上述实施例是给出来用作说明的目的,而不是想限制由下面的权利要求及所有它的等价物来定义的本发明的范围。
Claims (14)
1.一种吸收性薄纸,往其中加入了大约3至大约30干重百分数的含水软化组合物,所说的软化组合物包含大约20至大约98重量百分数的甘油和大约0.2至大约5重量百分数的选自下列的季铵化合物:
具有下列结构的单烷基三甲基季铵类:其中X=氯化物或甲基硫酸盐,R=脂族饱和或不饱和的C12-C22基团;
具有下列结构的苄基季铵类:其中X=氯化物,R=脂族正C12-C18基团;
9.权利要求1的薄纸,其中的软化组合物还包含大约0.5至大约50重量百分数的丙二醇。
10.权利要求1的薄纸,其中的软化组合物还包含大约0.5至大约50重量百分数的聚乙二醇。
11.权利要求1的薄纸,其中还包含选自乳酸及其盐类、糖类、乙氧基化的甘油、乙氧基化的羊毛脂、玉米糖浆、经水解的淀粉水解物、尿素和山梨醇的湿润剂。
12.权利要求1的薄纸,其中还包含选自尿囊素、高岭土、氧化锌、二甲聚硅氧烷乳状液、滑石和淀粉的皮肤防护剂。
13.权利要求1的薄纸,其中还包含选自玉米淀粉、燕麦粉、滑石、一氮化硼和环糊精的手感改进剂。
14.一种包含大约5至大约30干重百分数的软化组合物的化妆纸,所说的软化组合物包含大约60至大约80重量百分数的甘油、大约0.5至大约20重量百分数的丙二醇以及大约1至大约4重量百分数的具有以下结构的季铵化的羊毛脂:其中RCO=羊毛脂酸基团。
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Application Number | Priority Date | Filing Date | Title |
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US08/400,896 | 1995-03-08 | ||
US08/400,896 US5558873A (en) | 1994-06-21 | 1995-03-08 | Soft tissue containing glycerin and quaternary ammonium compounds |
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CN1183127A CN1183127A (zh) | 1998-05-27 |
CN1077938C true CN1077938C (zh) | 2002-01-16 |
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US (1) | US5558873A (zh) |
KR (1) | KR100356878B1 (zh) |
CN (1) | CN1077938C (zh) |
AU (1) | AU4968796A (zh) |
BR (1) | BR9604773A (zh) |
PE (1) | PE53997A1 (zh) |
SV (1) | SV1996000016A (zh) |
TR (1) | TR199700912T1 (zh) |
WO (1) | WO1996027707A1 (zh) |
ZA (1) | ZA961524B (zh) |
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CN101191310B (zh) * | 2007-05-24 | 2010-05-26 | 杭州市化工研究院有限公司 | 纸用柔软剂及其制备方法 |
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1996
- 1996-02-02 CN CN96193611A patent/CN1077938C/zh not_active Expired - Fee Related
- 1996-02-02 WO PCT/US1996/001298 patent/WO1996027707A1/en active Application Filing
- 1996-02-02 AU AU49687/96A patent/AU4968796A/en not_active Abandoned
- 1996-02-02 BR BR9604773A patent/BR9604773A/pt not_active IP Right Cessation
- 1996-02-02 TR TR97/00912T patent/TR199700912T1/xx unknown
- 1996-02-26 ZA ZA961524A patent/ZA961524B/xx unknown
- 1996-03-07 PE PE00015696A patent/PE53997A1/es not_active Application Discontinuation
- 1996-03-08 SV SV1996000016A patent/SV1996000016A/es unknown
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CN101191310B (zh) * | 2007-05-24 | 2010-05-26 | 杭州市化工研究院有限公司 | 纸用柔软剂及其制备方法 |
Also Published As
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---|---|
TR199700912T1 (en) | 1998-02-21 |
AU4968796A (en) | 1996-09-23 |
CN1183127A (zh) | 1998-05-27 |
PE53997A1 (es) | 1998-01-06 |
BR9604773A (pt) | 1998-06-23 |
KR100356878B1 (ko) | 2003-02-05 |
SV1996000016A (es) | 1997-02-19 |
US5558873A (en) | 1996-09-24 |
KR960001338A (ko) | 1996-01-25 |
WO1996027707A1 (en) | 1996-09-12 |
ZA961524B (en) | 1996-09-03 |
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