CN107760136A - A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint and preparation method thereof - Google Patents

A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint and preparation method thereof Download PDF

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Publication number
CN107760136A
CN107760136A CN201711158996.9A CN201711158996A CN107760136A CN 107760136 A CN107760136 A CN 107760136A CN 201711158996 A CN201711158996 A CN 201711158996A CN 107760136 A CN107760136 A CN 107760136A
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parts
exterior wall
nano
negative ion
weather resisteant
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汤谏好
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New Mstar Technology Ltd In Qingyuan
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New Mstar Technology Ltd In Qingyuan
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint, and its raw material includes following components by weight:50 60 parts of silicone acrylic emulsion, 5 10 parts of pearl powder, 13 parts of anionic additive, 36 parts of nano silicon, 8 12 parts of nano titanium oxide, 10 20 parts of modified alta-mud, 0.3 0.5 parts of bactericide, 0.5 0.8 parts of mould inhibitor, 0.4 0.8 parts of coupling agent, 0.1 0.3 parts of pH adjusting agent, 0.5 1.0 parts of dispersant, 0.2 0.5 parts of defoamer, 1.0 2.5 parts of coalescents, 0.5 0.8 parts of complex thickener, 13 parts of antifreezing agent, 20 50 parts of deionized water.The present invention also provides its preparation method, the weather resisteant exterior wall negative ion paint not only has good low-temperature stability, water resistance, alkali resistance, abrasion resistance, weather resisteant, polluting proofing property and ageing resistance, and has the advantages that static sustained release anion, dispels the pernicious gases such as formaldehyde, ammonia, benzene, antibacterial bacteriostatic.

Description

A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint and preparation method thereof
Technical field
The present invention relates to a kind of exterior coating, and in particular to a kind of nano modification silicon the third weather resisteant exterior wall negative ion paint and Its preparation method.
Background technology
Anion can not only facilitate human body synthesis and vitamin storage, strengthen the physiological activity with human activin, therefore it It is otherwise known as " air vitamin ", it is believed that it has as the vitamin of food to the vital movement of human body and other biological Highly important influence, after thunderstorm, the anion of air increases, and people feel happy.And in air-conditioned room, because of sky Anion almost all after a series of processing of air conditioning purges and very long ventilation shaft disappears in gas, and people stop for a long time wherein Staying can feel that uncomfortable in chest, dizzy, weak, operating efficiency and health status decline, and be referred to as " air conditioner comprehensive disease ".In medical field, It is the effective means with germ and purification air is killed that anion, which is identified,.Its mechanism essentially consists in anion and combined with bacterium Afterwards, bacterium is produced the change of structure or the transfer of energy, cause bacterial death, most final decline is sunken to ground.Medical research shows, Electronegative particulate makes oxygen content increase in blood in air, is advantageous to blood oxygen conveying, absorbs and utilize, has and promote human body newly old Metabolism, human immunological competence is improved, strengthen human body flesh energy, the effect of regulation body function balance.According to textual criticism, anion is to human body 7 systems, nearly more than 30 kinds of diseases have suppression, alleviation and auxiliary therapeutic action, especially more bright to the health-care effect of human body It is aobvious.
Building coating is widely applied in inner-outer wall, mainly there is the reason for following several respects, when economic aspect, Using coating more than construction materials such as glass or metal curtain wall, TERRAZZO, wallpapers cheaply and conveniently;Second, the kind of coating It is more, there is the advantage such as durable, anti-pollution, easy for construction, the needs of different building decorations can be met;Third, good decorating effect, with painting Expect that the interior wall of decoration is rich in color, it is bright-coloured lucid and lively, and, using color is converted after a period of time, can be kept according to the hobby of people Indoor feeling of freshness;Fourth, the light safety of coating, and can waterproof it is mould proof compared with other ornament materials, more protectiveness, safety Property.Traditional solvent based coating brings pollution to environment due to containing organic solvent, damages the health of people, and exploitation is new The environment-friendly coating of type is following paint development trend.Coating type is various, is widely used in many fields. In existing coating it is most of be all single effect coating it is relatively more, also it is a it is qualified, security performance is high, existing resistance to Marquis's property exterior wall also has the sale of negative ion paint.
The content of the invention
The purpose of the present invention is aiming at existing issue, there is provided a kind of nano modification silicon the third weather resisteant exterior wall anion applies Material, a kind of nano modification silicon the third weather resisteant exterior wall negative ion paint is using silicone acrylic emulsion as film forming matter, the pearl powder of addition, bears Ionic additive, nano silicon, nano titanium oxide, modified alta-mud, and part of auxiliary is added, one be prepared Kind nano modification silicon the third weather resisteant exterior wall negative ion paint.A kind of this kind of nano modification silicon the third weather resisteant exterior wall negative ion paint is not But there is good low-temperature stability, water resistance, alkali resistance, abrasion resistance, weather resisteant, polluting proofing property and ageing resistance, and There is static sustained release anion, dispel the pernicious gases such as formaldehyde, ammonia, benzene, antibacterial bacteriostatic.
Another object of the present invention is to provide a kind of preparation side of the third weather resisteant of nano modification silicon exterior wall negative ion paint Method, it is simple to operate, can extensive use.
The technical solution adopted in the present invention is as follows to achieve the above object:A kind of the third weather resisteant of nano modification silicon exterior wall is born Ion coating, it is characterised in that its raw material includes following components by weight:Silicone acrylic emulsion 50-60 parts, pearl powder 5-10 Part, anionic additive 1-3 parts, nano silicon 3-6 parts, nano titanium oxide 8-12 parts, modified alta-mud 10-20 parts, Bactericide 0.3-0.5 parts, mould inhibitor 0.5-0.8 parts, coupling agent 0.4-0.8 parts, pH conditioning agent 0.1-0.3 parts, dispersant 0.5- 1.0 parts, defoamer 0.2-0.5 parts, coalescents 1.0-2.5 parts, complex thickener 0.5-0.8 parts, antifreezing agent 1-3 parts, Deionized water 20-50 parts.
Further, described anionic additive is the tourmaline powder that granularity is 80-150nm.
Further, described pearl powder is 50~150 μm of particle diameter.
Further, described nano titanium oxide is nano rutile-type titanium dioxide, and particle diameter is 100~150 μm.
Further, described dispersant be sodium tripolyphosphate, calgon, sodium pyrophosphate, lauryl sodium sulfate, One or more in neopelex, methyl anyl alcohol, polyacrylamide.
Further, described complex thickener is matching somebody with somebody by certain weight for cellulose thickener and alkali swollen thickener Than the mixture mixed, ratio of weight and number both it is 1:3.
Further, the antifreezing agent is ethylene glycol.
Further, its preparation method comprises the following steps:
S10, deionized water is added in the retort with dispersion machine, starts dispersion machine;
S11, stirring while, sequentially by dispersant, bactericide, mould inhibitor, antifreezing agent, coalescents, half defoamer
It is added in retort, the speed of stirring turns/min for 400-500, and mixing time is 5-10 minutes;
S12 and then pearl powder, anionic additive, nano silicon, nano titanium oxide, modified alta-mud etc. press density Big order is slowly added to after first small, and mixing speed, which is improved to 1000-1200, turns/min, stirs 10-20min, and speed stirring terminates Afterwards, proper quantity of defoaming agent while is according to circumstances added, to reduce caused bubble in whipping process, is then slowly added into coalescents And part complex thickener, high-speed stirred dispersion machine is moved on to after stirring at low speed is uniform again, adds remaining part complex thickener, Scattered about 20-30min produces slurry at a high speed;
S13, emulsion is slowly added in the slurry that modulates, stirring at low speed 30-40min, adjusts viscosity and pH value, both obtained institute Need a kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint.
It is compared with the prior art, the invention has the advantages that:
1st, it is strong that the effect of nano titanium oxide shielding ultraviolet rays is added in the present invention, the infringement of ultraviolet is prevented, improves coating Service life.Meanwhile its higher hardness, density, dielectric constant and refractive index, be favorably improved coating covering power and Color power, and have good reflex to the heat radiation in sunlight;
2nd, nano titanium oxide, the pearl powder added in the present invention, anionic additive, nano silicon, nanometer titanium dioxide Titanium, in sunshine(Especially ultraviolet)The lower generation OH- of irradiation, can effectively remove the benzene of indoor and outdoor, formaldehyde, sulfide, ammonia and Stink substance, and there is sterilizing function, it is green environmental friendly coatingses.And energy sustained release anion per minute, can effectively improve IAQ, dispel the harmful pollutants such as formaldehyde in indoor air, toluene, ammonia;The coating can also be rapidly in decontamination chamber Cigarette, oil fume, air pollution and electronic pollution caused by household electrical appliance;Substantially reduce electromagnetic radiation intensity etc. it is multi-functional in One, up to more than 90%, its health shows as, by improving air quality, reaching enhancing for its 24 hours sterilizations, sterilization rates The booster action of body immunity, prevention of various diseases, meet people to environmental protection and the double requirements of health;
3rd, a kind of nano modification silicon the third weather resisteant exterior wall negative ion paint of the invention not only has good low-temperature stability, resistance to Water-based, alkali resistance, abrasion resistance, weather resisteant, polluting proofing property and ageing resistance, and there is static sustained release anion, dispel The advantages that except the pernicious gases such as formaldehyde, ammonia, benzene, antibacterial bacteriostatic.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.The specific embodiments described herein are merely illustrative of the present invention, is not used to limit The present invention.
Embodiment 1
A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint, it is characterised in that its raw material includes with the following group by weight Point:50 parts of silicone acrylic emulsion, 5 parts of pearl powder, 1 part of anionic additive, 3 parts of nano silicon, 8 parts of nano titanium oxide, change 10 parts of bentonite of property, 0.3 part of bactericide, 0.5 part of mould inhibitor, 0.4 part of coupling agent, 0.1 part of pH conditioning agents, 0.5 part of dispersant, 0.2 part of defoamer, 1.0 parts of coalescents, 0.5 part of complex thickener, 1 part of antifreezing agent, 20 parts of deionized water.
Described anionic additive is the tourmaline powder that granularity is 80nm.
Described pearl powder is 50 μm of particle diameter.
Described nano titanium oxide is nano rutile-type titanium dioxide, and particle diameter is 100 μm.
Described dispersant is sodium tripolyphosphate.
Described complex thickener is being blended in by certain weight proportion for cellulose thickener and alkali swollen thickener Mixture together, ratio of weight and number both it are 1:3.
The antifreezing agent is ethylene glycol.
Its preparation method comprises the following steps:
S10, deionized water is added in the retort with dispersion machine, starts dispersion machine;
S11, stirring while, sequentially by dispersant, bactericide, mould inhibitor, antifreezing agent, coalescents, half defoamer
It is added in retort, the speed of stirring is 400 turns/min, and mixing time is 5 minutes;
S12 and then pearl powder, anionic additive, nano silicon, nano titanium oxide, modified alta-mud etc. press density Big order is slowly added to after first small, and mixing speed is improved to 1000 turns/min, stirs 10min, after speed stirring terminates, while root Proper quantity of defoaming agent is added according to situation, to reduce caused bubble in whipping process, coalescents is then slowly added into and part is multiple Thickener is closed, moves on to high-speed stirred dispersion machine after stirring at low speed is uniform again, adds remaining part complex thickener, it is scattered at a high speed About 20min produces slurry;
S13, emulsion is slowly added in the slurry that modulates, stirring at low speed 30min, adjusts viscosity and pH value, both obtained needed for A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint.
Embodiment 2
A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint, it is characterised in that its raw material includes with the following group by weight Point:60 parts of silicone acrylic emulsion, 10 parts of pearl powder, 3 parts of anionic additive, 6 parts of nano silicon, nano titanium oxide 12 Part, 20 parts of modified alta-mud, 0.5 part of bactericide, 0.8 part of mould inhibitor, 0.8 part of coupling agent, 0.3 part of pH conditioning agents, dispersant 1.0 parts, 0.5 part of defoamer, 2.5 parts of coalescents, 0.8 part of complex thickener, 3 parts of antifreezing agent, 50 parts of deionized water.
Described anionic additive is the tourmaline powder that granularity is 150nm.
Described pearl powder is 150 μm of particle diameter.
Described nano titanium oxide is nano rutile-type titanium dioxide, and particle diameter is 150 μm.
The mixture that described dispersant is sodium tripolyphosphate, calgon, sodium pyrophosphate arbitrarily match.
Described complex thickener is being blended in by certain weight proportion for cellulose thickener and alkali swollen thickener Mixture together, ratio of weight and number both it are 1:3.
The antifreezing agent is ethylene glycol.
Its preparation method comprises the following steps:
S10, deionized water is added in the retort with dispersion machine, starts dispersion machine;
S11, stirring while, sequentially by dispersant, bactericide, mould inhibitor, antifreezing agent, coalescents, half defoamer
It is added in retort, the speed of stirring is 500 turns/min, and mixing time is 10 minutes;
S12 and then pearl powder, anionic additive, nano silicon, nano titanium oxide, modified alta-mud etc. press density Big order is slowly added to after first small, and mixing speed is improved to 1200 turns/min, stirs 20min, after speed stirring terminates, simultaneously Proper quantity of defoaming agent is according to circumstances added, to reduce caused bubble in whipping process, is then slowly added into coalescents and part Complex thickener, high-speed stirred dispersion machine is moved on to after stirring at low speed is uniform again, add remaining part complex thickener, divide at a high speed Dissipate about 30min and produce slurry;
S13, emulsion is slowly added in the slurry that modulates, stirring at low speed 40min, adjusts viscosity and pH value, both obtained needed for A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint.
Embodiment 3
A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint, it is characterised in that its raw material includes with the following group by weight Point:55 parts of silicone acrylic emulsion, 8 parts of pearl powder, 2 parts of anionic additive, 5 parts of nano silicon, 10 parts of nano titanium oxide, 16 parts of modified alta-mud, 0.4 part of bactericide, 0.7 part of mould inhibitor, 0.6 part of coupling agent, 0.2 part of pH conditioning agents, dispersant 0.60 Part, 0.3 part of defoamer, 1.5 parts of coalescents, 0.6 part of complex thickener, 2 parts of antifreezing agent, 25 parts of deionized water.
Described anionic additive is the tourmaline powder that granularity is 120nm.
Described pearl powder is 75 μm of particle diameter.
Described nano titanium oxide is nano rutile-type titanium dioxide, and particle diameter is 120 μm.
It is mixed that described dispersant is that calgon, sodium pyrophosphate, lauryl sodium sulfate many kinds of substance arbitrarily match Compound.
Described complex thickener is being blended in by certain weight proportion for cellulose thickener and alkali swollen thickener Mixture together, ratio of weight and number both it are 1:3.
The antifreezing agent is ethylene glycol.
Its preparation method comprises the following steps:
S10, deionized water is added in the retort with dispersion machine, starts dispersion machine;
S11, stirring while, sequentially by dispersant, bactericide, mould inhibitor, antifreezing agent, coalescents, half defoamer
It is added in retort, the speed of stirring is 450 turns/min, and mixing time is 9 minutes;
S12 and then pearl powder, anionic additive, nano silicon, nano titanium oxide, modified alta-mud etc. press density Big order is slowly added to after first small, and mixing speed is improved to 1100 turns/min, stirs 15min, after speed stirring terminates, simultaneously Proper quantity of defoaming agent is according to circumstances added, to reduce caused bubble in whipping process, is then slowly added into coalescents and part Complex thickener, high-speed stirred dispersion machine is moved on to after stirring at low speed is uniform again, add remaining part complex thickener, divide at a high speed Dissipate about 26min and produce slurry;
S13, emulsion is slowly added in the slurry that modulates, stirring at low speed 35min, adjusts viscosity and pH value, both obtained needed for A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint.
Performance detection:
Nano modification silicon the third weather resisteant exterior wall negative ion paint prepared by 1-3 of the embodiment of the present invention is by detecting the negative of its release Ion is 3000/more than m3, and according to a kind of weathering of nano modification silicon third of GB/T9755-2014 technical requirements standard detections The performance of property exterior wall negative ion paint, performance index are shown in Table 1
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to limits the scope of protection of the invention, ability with this The change and replacement for any unsubstantiality that the technical staff in domain is done on the basis of the present invention are belonged to required by the present invention The scope of protection.

Claims (8)

1. a kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint, it is characterised in that its raw material includes following by weight Component:Silicone acrylic emulsion 50-60 parts, pearl powder 5-10 parts, anionic additive 1-3 parts, nano silicon 3-6 parts, nanometer Titanium dioxide 8-12 parts, modified alta-mud 10-20 parts, bactericide 0.3-0.5 parts, mould inhibitor 0.5-0.8 parts, coupling agent 0.4- 0.8 part, pH conditioning agent 0.1-0.3 parts, dispersant 0.5-1.0 parts, defoamer 0.2-0.5 parts, coalescents 1.0-2.5 Part, complex thickener 0.5-0.8 parts, antifreezing agent 1-3 parts, deionized water 20-50 parts.
A kind of 2. the third weather resisteant of nano modification silicon exterior wall negative ion paint according to claim 1, it is characterised in that:Institute The anionic additive stated is the tourmaline powder that granularity is 80-150nm.
A kind of 3. the third weather resisteant of nano modification silicon exterior wall negative ion paint according to claim 1, it is characterised in that:Institute The pearl powder stated is 50~150 μm of particle diameter.
A kind of 4. the third weather resisteant of nano modification silicon exterior wall negative ion paint according to claim 1, it is characterised in that:Institute The nano titanium oxide stated is nano rutile-type titanium dioxide, and particle diameter is 100~150 μm.
A kind of 5. the third weather resisteant of nano modification silicon exterior wall negative ion paint according to claim 1, it is characterised in that:Institute The dispersant stated is sodium tripolyphosphate, calgon, sodium pyrophosphate, lauryl sodium sulfate, neopelex, first One or more in base amylalcohol, polyacrylamide.
A kind of 6. the third weather resisteant of nano modification silicon exterior wall negative ion paint according to claim 1, it is characterised in that:Institute The complex thickener stated is the mixing mixed by certain weight proportion of cellulose thickener and alkali swollen thickener Thing, ratio of weight and number both it are 1:3.
A kind of 7. the third weather resisteant of nano modification silicon exterior wall negative ion paint according to claim 1, it is characterised in that:Institute It is ethylene glycol to state antifreezing agent.
A kind of 8. the third weather resisteant of nano modification silicon exterior wall negative ion paint according to claim 1, it is characterised in that:Its Preparation method comprises the following steps:
S10, deionized water is added in the retort with dispersion machine, starts dispersion machine;
S11, stirring while, sequentially by dispersant, bactericide, mould inhibitor, antifreezing agent, coalescents, half defoamer
It is added in retort, the speed of stirring turns/min for 400-500, and mixing time is 5-10 minutes;
S12 and then pearl powder, anionic additive, nano silicon, nano titanium oxide, modified alta-mud etc. press density Big order is slowly added to after first small, and mixing speed, which is improved to 1000-1200, turns/min, stirs 10-20min, and speed stirring terminates Afterwards, proper quantity of defoaming agent while is according to circumstances added, to reduce caused bubble in whipping process, is then slowly added into coalescents And part complex thickener, high-speed stirred dispersion machine is moved on to after stirring at low speed is uniform again, adds remaining part complex thickener, Scattered about 20-30min produces slurry at a high speed;
S13, emulsion is slowly added in the slurry that modulates, stirring at low speed 30-40min, adjusts viscosity and pH value, both obtained institute Need a kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint.
CN201711158996.9A 2017-11-21 2017-11-21 A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint and preparation method thereof Pending CN107760136A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109021734A (en) * 2018-07-03 2018-12-18 兰州科天环保节能科技有限公司 A kind of Economic Function type aqueous, environmental protective interiro wall latex paint
CN110643248A (en) * 2019-10-29 2020-01-03 西洞庭凯兴建材有限公司 Nano emulsion paint and preparation method thereof
CN110713762A (en) * 2019-10-22 2020-01-21 孙斌 All-round odor-free high-decorative color particle water paint
CN110724419A (en) * 2019-10-22 2020-01-24 孙斌 Production process of omnipotent odorless high-decorative colored particle water paint

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109021734A (en) * 2018-07-03 2018-12-18 兰州科天环保节能科技有限公司 A kind of Economic Function type aqueous, environmental protective interiro wall latex paint
CN109021734B (en) * 2018-07-03 2021-05-11 兰州科天环保节能科技有限公司 Economic functional water-based environment-friendly interior wall latex paint
CN110713762A (en) * 2019-10-22 2020-01-21 孙斌 All-round odor-free high-decorative color particle water paint
CN110724419A (en) * 2019-10-22 2020-01-24 孙斌 Production process of omnipotent odorless high-decorative colored particle water paint
CN110643248A (en) * 2019-10-29 2020-01-03 西洞庭凯兴建材有限公司 Nano emulsion paint and preparation method thereof

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Application publication date: 20180306