CN109021734A - A kind of Economic Function type aqueous, environmental protective interiro wall latex paint - Google Patents

A kind of Economic Function type aqueous, environmental protective interiro wall latex paint Download PDF

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Publication number
CN109021734A
CN109021734A CN201810720911.XA CN201810720911A CN109021734A CN 109021734 A CN109021734 A CN 109021734A CN 201810720911 A CN201810720911 A CN 201810720911A CN 109021734 A CN109021734 A CN 109021734A
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China
Prior art keywords
aqueous
weight
parts
wall latex
environmental protective
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Granted
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CN201810720911.XA
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CN109021734B (en
Inventor
戴家兵
田元兵
郭荣军
高雄锋
许艳
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HEFEI SCISKY TECHNOLOGY Co.,Ltd.
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Lanzhou Ke Tian Environmental Protection And Energy Saving Science And Technology Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

Abstract

The invention discloses a kind of Economic Function type aqueous, environmental protective interiro wall latex paint, which is mainly made of following raw material: water 300-400 parts by weight;Cellulose 4-5 parts by weight;Dispersing agent 5-7 parts by weight;Wetting agent 1-2 parts by weight;Defoaming agent 2-3 parts by weight;Coalescing agent 15-20 parts by weight;Titanium dioxide 0-50 parts by weight;Active pearl powder 100-400 parts by weight;Dicalcium powder 0-400 parts by weight;Aqueous acrylic emulsion 100-200 parts by weight;Thickener 4-6 parts by weight;The active pearl powder is fineness >=3000 mesh pearl powder.Interiro wall latex paint of the invention can satisfy the covering force request of product, can also purify the air of a room in formaldehyde, improve the indoor living environment of people, and the light of paint film reflection is naturally soft, people does not allow to be also easy to produce visual fatigue, can effectively protect eyesight.

Description

A kind of Economic Function type aqueous, environmental protective interiro wall latex paint
Technical field
The invention belongs to paint fields, and in particular to a kind of Economic Function type aqueous, environmental protective interiro wall latex paint.
Background technique
With the appearance successively of national environmental protection policy, reinforcement of the people to environmental consciousness, Environmental Protective Water-paint increasingly by The favor of the majority of consumers, the rapid development of water paint, demand are increasing in recent years;Titanium dioxide as water paint only One provides the white pigment covered, and titanium dioxide market demand increasingly increases, and price rises steadily, for water paint manufacturer Manufacturing cost at being also continuously improved.Used pearl powder only has a certain degree of cohesiveness energy and water resistant etch resistant properties, to film Hardness, adhesive force and metope bright property make moderate progress, without providing film covering power, absorb the pernicious gases such as formaldehyde Function.
Summary of the invention
Problem mentioned in the background art, the purpose of the present invention is reduce the dosage of titanium dioxide in water paint, drop Low cost makes up the deficiency of existing pearl powder, provides a kind of Economic Function type aqueous, environmental protective interiro wall latex paint.
To realize the above purposes, the technical scheme adopted is as follows:
A kind of Economic Function type aqueous, environmental protective interiro wall latex paint, the aqueous, environmental protective interiro wall latex paint is mainly by following original Material composition:
The active pearl powder is fineness >=3000 mesh pearl powder.
Preferably, lead to emulsion paint stability reduction etc. during production and storage to avoid growing because of microorganism, it is described Aqueous, environmental protective interiro wall latex paint can add the fungicide of 2-3 parts by weight, to inhibit the growth of microorganism.
Preferably, the pH of the aqueous, environmental protective interiro wall latex paint is 7~8.
The preparation method of above-mentioned aqueous, environmental protective interiro wall latex paint, comprising:
(1) thickener and fungicide are diluted with water respectively, spare;
(2) under stiring, cellulose is added to the water, after cellulose dissolution, sequentially add dispersing agent, wetting agent, Defoaming agent, coalescing agent, titanium dioxide, dicalcium powder and active pearl powder, then at 1000-1200r/min stirring 20~ 40min obtains mixed emulsion;
(3) under stiring, sequentially added in the mixed emulsion obtained to step (2) aqueous acrylic emulsion, thickener and Fungicide.
To control and adjusting pH value, other raw materials can be added after cellulose dissolution, first plus pH adjusting agent.
Beneficial effect
1, the present invention can satisfy the covering power of product in the interiro wall latex paint of high, normal, basic PVC value using active pearl powder It is required that while reducing cost, realization economic benefit.
2, interiro wall latex paint of the invention can purify the air of a room in formaldehyde, improve the indoor living environment of people.
3, active pearl powder color is soft, so that the metope reflection light for having brushed interiro wall latex paint of the present invention is naturally soft With people does not allow to be also easy to produce visual fatigue, can effectively protect eyesight.
Detailed description of the invention
Attached drawing is used to provide further understanding of the present invention, and constitutes part of specification, with reality of the invention It applies example to be used to explain the present invention together, not be construed as limiting the invention.In the accompanying drawings:
Fig. 1 is the electron microscopic picture of active pearl powder;
Fig. 2 is the electron microscopic picture of ordinary pearl powder.
Specific embodiment
The technical solution in the content of present invention will be clearly and completely described below, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Active pearl powder of the invention is produced by Xi'an Jia Beirui new material Co., Ltd, model: JBR005, and fineness >= 3000 mesh.As shown in Fig. 1 (11000 times of amplification), which is in spindle, hence it is evident that is different from ordinary pearl powder (such as Fig. 2 It is shown, amplify 8600 times).
250HHBR, 250H4BR, 250HBR, the 250MBR of Ya Shilan production can be selected in cellulose of the invention, One of 250HMBR, HE10K, HE3KB or a variety of;
The spy that Tao Shi production can be selected in dispersing agent of the invention dissipates wellTM1620, it is special good scatteredTM1618, it is special good scatteredTMIt is fast easy, it is special It is good to dissipateTM963, it is special good scatteredTMThe SN-DISPERSANT 2500, SN-DISPERSANT 5040, SN- of 1124, Sheng Nuopuke productions One of DISPERSANT 5020, SN-DISPERSANT 5027 or a variety of;
EMULSOGEN LCN 407, the EMULSOGEN LCN 070 of Clariant production can be selected in wetting agent of the invention, In the SN-WET 990 of TRITON BD-405, TRITON X-405, Sheng Nuopuke production, SN-WET 996, SN-WET 366 It is one or more;
The alcohol ester-12 for Yi Shiman production, OE-300, RhodiaSolv DIB, third can be selected in coalescing agent of the invention One of glycol is a variety of;
The RS-64, RS-959W, RS-5906, RS- of Ahmedabad richness production can be selected in aqueous acrylic emulsion of the invention The hundred of 5608, Tao Shi productions, which go through, to rubTMDC-450V, hundred go through and rubTMDC-420V, hundred go through and rubTMDC-423V, hundred go through and rubTMSF-157 One of or it is a variety of;
The SN-THICKENER 615, SN-THICKENER636 of Sheng Nuopuke production can be selected in thickener of the invention, The Asia pleasure of SN-THICKENER640, Tao Shi production is suitableTMASE-60, Asia pleasure are suitableTMTT-935, Asia pleasure are suitableTMRD-73, Asia pleasure are suitableTMOne of RD-72 or a variety of.
R996, R982 of Sichuan dragon boa production can be selected in titanium dioxide of the invention, climb the production of steel titanium industry R248, R258, One of R298 or a variety of.
Wide Fujian material CC-1000 can be selected in dicalcium powder of the invention, excellent to open up 1250 coarse whitings, and 1250 coarse whitings are avenged in Gongga, and hundred million is glad One of 1250 coarse whitings are a variety of.
The NOPCON NXZ, SN-DEFOAMER 345, SN- of Sheng Nuopuke production can be selected in defoaming agent of the invention DEFOAMER318, SN-DEFOAMER319, SN-DEFOAMER 154, SN-DEFOAMER 321, SN-DEFOAMER 470, One of SN-DEFOAMER 485 or a variety of.
The KATHON of Tao Shi production can be selected in fungicide of the inventionTMLX 300, ROCIMATMBT NV2, ROCIMATM 631, ROCIMATM342, ROCIMATM363, DOWICILTMQK-20, ROCIMATMCF-1100, ROCIMATM586, SKANETM One of M-8 or a variety of.
For control emulsion paint pH value 7~8, Tao Shi AMP-95 can be selected in the present invention, attains product CH27 as pH adjusting agent.
Embodiment 1
The formula of emulsion paint is as follows:
Preparation method: being added deionized water under 600-800r/min revolving speed and cellulose stirring 10 minutes complete to cellulose Fully dissolved into water, sequentially add pH adjusting agent, dispersing agent, wetting agent, defoaming agent, coalescing agent, titanium dioxide, dicalcium powder, Active pearl powder disperses 30 minutes at 1000-1200r/min, revolving speed is adjusted to 600-800r/min, sequentially adds aqueous third Olefin(e) acid lotion, thickener and fungicide (thickener, fungicide are diluted with the water of 3 times of weight respectively in advance) are to get arriving pigment body The Economic Function type aqueous, environmental protective interiro wall latex paint of product concentration (PVC)=63.97%.
Comparative example 1
The formula of emulsion paint is as follows:
Preparation method: being added deionized water under 600-800r/min revolving speed and cellulose stirring 10 minutes complete to cellulose Fully dissolved into water, sequentially add pH adjusting agent, dispersing agent, wetting agent, defoaming agent, coalescing agent, titanium dioxide, dicalcium powder, Active pearl powder disperses 30 minutes at 1000-1200r/min, revolving speed is adjusted to 600-800r/min, sequentially adds aqueous third Olefin(e) acid lotion, thickener and fungicide (thickener, fungicide are diluted with the water of 3 times of weight respectively in advance) are to get arriving pigment body The water emulsion paint for internal wall of product concentration (PVC)=64.14%.
Embodiment 2
The formula of emulsion paint is as follows:
Preparation method: being added deionized water under 600-800r/min revolving speed and cellulose stirring 10 minutes complete to cellulose Fully dissolved into water, sequentially add pH adjusting agent, dispersing agent, wetting agent, defoaming agent, coalescing agent, titanium dioxide, dicalcium powder, Active pearl powder disperses 30 minutes at 1000-1200r/min, revolving speed is adjusted to 600-800r/min, sequentially adds aqueous third Olefin(e) acid lotion, thickener and fungicide (thickener, fungicide are diluted with the water of 3 times of weight respectively in advance) are to get arriving pigment body The Economic Function type aqueous, environmental protective interiro wall latex paint of product concentration (PVC)=51.63%.
Comparative example 2
The formula of emulsion paint is as follows:
Preparation method: being added deionized water under 600-800r/min revolving speed and cellulose stirring 10 minutes complete to cellulose Fully dissolved into water, sequentially add pH adjusting agent, dispersing agent, wetting agent, defoaming agent, coalescing agent, titanium dioxide, dicalcium powder, Active pearl powder disperses 30 minutes at 1000-1200r/min, revolving speed is adjusted to 600-800r/min, sequentially adds aqueous third Olefin(e) acid lotion, thickener and fungicide (thickener, fungicide are diluted with the water of 3 times of weight respectively in advance) are to get arriving pigment body The water emulsion paint for internal wall of product concentration (PVC)=51.63%.
Embodiment 3
The formula of emulsion paint is as follows:
Preparation method: being added deionized water under 600-800r/min revolving speed and cellulose stirring 10 minutes complete to cellulose Fully dissolved into water, sequentially add pH adjusting agent, dispersing agent, wetting agent, defoaming agent, coalescing agent, titanium dioxide, dicalcium powder, Active pearl powder disperses 30 minutes at 1000-1200r/min, revolving speed is adjusted to 600-800r/min, sequentially adds aqueous third Olefin(e) acid lotion, thickener and fungicide (thickener, fungicide are diluted with the water of 3 times of weight respectively in advance) are to get arriving pigment body The Economic Function type aqueous, environmental protective interiro wall latex paint of product concentration (PVC)=39.97%.
Comparative example 3
The formula of emulsion paint is as follows:
Preparation method: being added deionized water under 600-800r/min revolving speed and cellulose stirring 10 minutes complete to cellulose Fully dissolved into water, sequentially add pH adjusting agent, dispersing agent, wetting agent, defoaming agent, coalescing agent, titanium dioxide, dicalcium powder, Active pearl powder disperses 30 minutes at 1000-1200r/min, revolving speed is adjusted to 600-800r/min, sequentially adds aqueous third Olefin(e) acid lotion, thickener and fungicide (thickener, fungicide are diluted with the water of 3 times of weight respectively in advance) are to get arriving pigment body The water emulsion paint for internal wall of product concentration (PVC)=41.12%.
Comparative example 4~6
Compared with Examples 1 to 3, difference is comparative example 4~6, substitutes activity with ordinary pearl powder (1250 mesh or so) Pearl powder.
According to " GB/T 9756-2009 resin latex dope " test comparison rate.
According to " JCT 1074-2008 function of purifying indoor air coating material purifying property " method of testing formaldehyde absorption rate.
It can satisfy in the interiro wall latex paint of high, normal, basic PVC value using active pearl powder it can be seen from above-mentioned comparison The covering force request of product, while reducing cost realizes economic benefit, and the formaldehyde in can purifying the air of a room, and improves people Indoor living environment.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (6)

1. a kind of Economic Function type aqueous, environmental protective interiro wall latex paint, the aqueous, environmental protective interiro wall latex paint is mainly by following raw material Composition:
The active pearl powder is fineness >=3000 mesh pearl powder.
2. aqueous, environmental protective interiro wall latex paint according to claim 1, which is characterized in that the aqueous, environmental protective interior wall latex Paint the fungicide containing 2-3 parts by weight.
3. aqueous, environmental protective interiro wall latex paint according to claim 2, which is characterized in that the fungicide is KATHONTM LX 300, ROCIMATMBT NV2, ROCIMATM631, ROCIMATM342, ROCIMATM363, DOWICILTMQK-20, ROCIMATMCF-1100, ROCIMATM586, SKANETMOne of M-8 or a variety of.
4. aqueous, environmental protective interiro wall latex paint according to claim 1, which is characterized in that the aqueous, environmental protective interior wall latex The pH of paint is 7~8.
5. aqueous, environmental protective interiro wall latex paint according to claim 1, which is characterized in that
The cellulose is 250HHBR, 250H4BR, 250HBR, 250MBR, 250HMBR, HE10K, one of HE3KB or more Kind;
The dispersing agent is special good scatteredTM1620, it is special good scatteredTM1618, it is special good scatteredTMIt is fast easy, it is special good scatteredTM963, it is special good scatteredTM1124, In SN-DISPERSANT 2500, SN-DISPERSANT 5040, SN-DISPERSANT 5020, SN-DISPERSANT 5027 It is one or more;
The wetting agent is EMULSOGEN LCN 407, EMULSOGEN LCN 070, TRITON BD-405, TRITON X- One of 405, SN-WET 990, SN-WET 996, SN-WET 366 or a variety of;
The coalescing agent is alcohol ester-12, OE-300, RhodiaSolv DIB, one of propylene glycol or a variety of;
The aqueous acrylic emulsion is gone through for RS-64, RS-959W, RS-5906, RS-5608, hundred and rubsTMDC-450V, hundred go through and rubTM DC-420V, hundred go through and rubTMDC-423V, hundred go through and rubTMOne of SF-157 or a variety of;
The thickener is SN-THICKENER 615, SN-THICKENER636, SN-THICKENER640, and Asia pleasure is suitableTMASE- 60, Asia pleasure is suitableTMTT-935, Asia pleasure are suitableTMRD-73, Asia pleasure are suitableTMOne of RD-72 or a variety of.
6. the preparation method of any aqueous, environmental protective interiro wall latex paint of Claims 1 to 5, comprising:
(1) thickener and fungicide are diluted with water respectively, spare;
(2) under stiring, cellulose is added to the water, after cellulose dissolution, sequentially adds dispersing agent, wetting agent, defoaming Then agent, coalescing agent, titanium dioxide, dicalcium powder and active pearl powder stir 20~40min at 1000-1200r/min, obtain To mixed emulsion;
(3) under stiring, aqueous acrylic emulsion, thickener and sterilization are sequentially added in the mixed emulsion obtained to step (2) Agent.
CN201810720911.XA 2018-07-03 2018-07-03 Economic functional water-based environment-friendly interior wall latex paint Active CN109021734B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423776A (en) * 2020-04-29 2020-07-17 广州昊特建材有限公司 Antibacterial and mildewproof wall paint and preparation method thereof
CN114456635A (en) * 2022-03-25 2022-05-10 西安前沿材料研究院有限公司 Self-cleaning self-stratifying inner wall coating and preparation method and application thereof

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CN107760136A (en) * 2017-11-21 2018-03-06 清远市思晴新材料科技有限公司 A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint and preparation method thereof
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423776A (en) * 2020-04-29 2020-07-17 广州昊特建材有限公司 Antibacterial and mildewproof wall paint and preparation method thereof
CN114456635A (en) * 2022-03-25 2022-05-10 西安前沿材料研究院有限公司 Self-cleaning self-stratifying inner wall coating and preparation method and application thereof

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Address before: 730000 Ketian water science and Technology Industrial Park, 3949 Kunlun Mountain Avenue, Lanzhou New District, Lanzhou City, Gansu Province

Patentee before: LANZHOU KETIAN ENVIRONMENTAL PROTECTION ENERGY SAVING SCIENCE & TECHNOLOGY Co.,Ltd.

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