CN107868522A - A kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating - Google Patents

A kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating Download PDF

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Publication number
CN107868522A
CN107868522A CN201711211851.0A CN201711211851A CN107868522A CN 107868522 A CN107868522 A CN 107868522A CN 201711211851 A CN201711211851 A CN 201711211851A CN 107868522 A CN107868522 A CN 107868522A
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China
Prior art keywords
parts
vinylacetate
negative ion
inexpensive
saving coating
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Pending
Application number
CN201711211851.0A
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Chinese (zh)
Inventor
邹伟国
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Guangdong Ju Ting Energy Saving Equipment Co Ltd
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Guangdong Ju Ting Energy Saving Equipment Co Ltd
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Priority to CN201711211851.0A priority Critical patent/CN107868522A/en
Publication of CN107868522A publication Critical patent/CN107868522A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/08Copolymers of ethene
    • C09D123/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09D123/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating, and its raw material includes following components by weight:40 80 parts of ethylene vinyl acetate emulsion, 50 80 parts of styrene-acrylic emulsion, 13 parts of anionic additive, 8 12 parts of nano titanium oxide, 30 50 parts of titanium dioxide, 20 50 parts of lithopone, 5 10 parts of bentonite, 10 20 parts of calcium carbonate, 45 60 parts of wollastonite in powder, 35 50 parts of kaolin, 20% 48 parts of hydroxyethyl cellulose solution, 0.3 0.5 parts of bactericide, 0.5 0.8 parts of mould inhibitor, 0.1 0.3 parts of crosslinking agent, 0.5 1.0 parts of dispersant, 0.2 0.5 parts of defoamer, 1.0 2.5 parts of coalescents, 0.5 0.8 parts of thickener, 13 parts of levelling agent, 100 300 parts of deionized water.The coating has the advantages that static sustained release anion, dispels the pernicious gases such as formaldehyde, ammonia, benzene, antibacterial bacteriostatic, pollution-free, environment protecting and power-saving and inexpensive high-decoration.

Description

A kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating
Technical field
The present invention relates to decorative paint, and in particular to a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving Coating.
Background technology
Anion can not only facilitate human body synthesis and vitamin storage, strengthen the physiological activity with human activin, therefore it It is otherwise known as " air vitamin ", it is believed that it has as the vitamin of food to the vital movement of human body and other biological Highly important influence, after thunderstorm, the anion of air increases, and people feel happy.And in air-conditioned room, because of sky Anion almost all after a series of processing of air conditioning purges and very long ventilation shaft disappears in gas, and people stop for a long time wherein Staying can feel that uncomfortable in chest, dizzy, weak, operating efficiency and health status decline, and be referred to as " air conditioner comprehensive disease ".In medical field, It is the effective means with germ and purification air is killed that anion, which is identified,.Its mechanism essentially consists in anion and combined with bacterium Afterwards, bacterium is produced the change of structure or the transfer of energy, cause bacterial death, most final decline is sunken to ground.Medical research shows, Electronegative particulate makes oxygen content increase in blood in air, is advantageous to blood oxygen conveying, absorbs and utilize, has and promote human body newly old Metabolism, human immunological competence is improved, strengthen human body flesh energy, the effect of regulation body function balance.According to textual criticism, anion is to human body 7 systems, nearly more than 30 kinds of diseases have suppression, alleviation and auxiliary therapeutic action, especially more bright to the health-care effect of human body It is aobvious.
The content of the invention
It is an object of the invention to provide a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating, this one The multifunction negative ion vinylacetate decorative energy-saving coating of kind of low cost using styrene-acrylic emulsion and ethylene vinyl acetate emulsion as Film forming matter, the anionic additive of addition, nano titanium oxide, titanium dioxide, lithopone, bentonite, calcium carbonate, wollastonite A variety of multi-functional face such as powder, kaolin, filler, and add part of auxiliary, what is be prepared is a kind of inexpensive multi-functional Anion vinylacetate decorative energy-saving coating.A kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating Not only there is good low-temperature stability, water resistance, alkali resistance, abrasion resistance, weather resisteant, polluting proofing property and ageing resistance, and And also there is static sustained release anion, dispel the pernicious gases such as formaldehyde, ammonia, benzene, be antibacterial bacteriostatic, pollution-free, green The advantages that energy-conservation and inexpensive high-decoration.
The technical solution adopted in the present invention is as follows to achieve the above object:A kind of inexpensive multifunction negative ion acetic acid Vinyl acetate decorative energy-saving coating, its raw material include following components by weight:Ethylene-vinyl acetate emulsion 40-80 parts, benzene Acrylic emulsion 50-80 parts, anionic additive 1-3 parts, nano titanium oxide 8-12 parts, titanium dioxide 30-50 parts, lithopone 20- 50 parts, bentonite 5-10 parts, calcium carbonate 10-20 parts, wollastonite in powder 45-60 parts, kaolin 35-50 parts, 20% hydroxyethyl cellulose Solution 4-8 parts, bactericide 0.3-0.5 parts, mould inhibitor 0.5-0.8 parts, crosslinking agent 0.1-0.3 parts, dispersant 0.5-1.0 parts, disappear Infusion 0.2-0.5 parts, coalescents 1.0-2.5 parts, thickener 0.5-0.8 parts, levelling agent 1-3 parts, deionized water 100- 300 parts.
Further, described anionic additive is the tourmaline powder that granularity is 80-150nm.
Further, described titanium dioxide rutile type titanium white.
Further, described dispersant is sodium pyrophosphate.
Further, described coalescents are propane diols.
Further, described complex thickener is matching somebody with somebody by certain weight for cellulose thickener and alkali swollen thickener Than the mixture mixed, ratio of weight and number both it is 1:3.
It is compared with the prior art, the invention has the advantages that:
1st, it is resistance to give full play to styrene-acrylic emulsion using styrene-acrylic emulsion and ethylene-vinyl acetate emulsion as main glutinous agent by the present invention The advantage that water alkali resistance is good, ethylene-vinyl acetate emulsion film forming temperature is low, mutually learns from other's strong points to offset one's weaknesses, and is advantageous to improve coating Can, reduce cost;Using bentonite as auxiliary adhesive, emulsion dosage is reduced, reduces cost;In formula add wollastonite in powder, The pigment filling substitute such as kaolin, the higher titanium dioxide of part price, lithopone can be replaced, but its coating covering power does not drop It is low;
2nd, the anionic additive added in the present invention is in sunshine(Especially ultraviolet)The lower generation OH- of irradiation, can effectively be removed Benzene, formaldehyde, sulfide, ammonia and the stink substance of indoor and outdoor are removed, and there is sterilizing function, is green environmental friendly coatingses.And can be every Minute sustained release anion, can effectively improve IAQ, dispels harmful dirt such as formaldehyde in indoor air, toluene, ammonia Contaminate material;The coating can also cigarette in decontamination chamber, oil fume, air pollution and electronic pollution caused by household electrical appliance rapidly; It is multi-functional in one to substantially reduce electromagnetic radiation intensity etc., sterilization in its 24 hours, sterilization rate are up to more than 90%, its health table It is now by improving air quality, reaching enhancing body immunity, the booster action of prevention of various diseases, meet people to ring Protect the double requirements with health;
3rd, it is strong that the effect of nano titanium oxide shielding ultraviolet rays is added in the present invention, the infringement of ultraviolet is prevented, improves coating Service life.Meanwhile its higher hardness, density, dielectric constant and refractive index, be favorably improved coating covering power and Color power, and have good reflex to the heat radiation in sunlight;The nano titanium oxide has efficiency light caloytic action so that The coating has the functions such as good armaticity, scrub resistance and sterilization;
4th, a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating of the invention not only has well low Temperature stability, water resistance, alkali resistance, abrasion resistance, weather resisteant, polluting proofing property and ageing resistance, but also continue with static Release anion, dispel the pernicious gases such as formaldehyde, ammonia, benzene, antibacterial bacteriostatic, pollution-free, environment protecting and power-saving and the high dress of low cost The advantages that decorations property.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.The specific embodiments described herein are merely illustrative of the present invention, is not used to limit The present invention.
Embodiment 1
A kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating, its raw material include with the following group by weight Point:40 parts of ethylene-vinyl acetate emulsion, 50 parts of styrene-acrylic emulsion, 1 part of anionic additive, 8 parts of nano titanium oxide, titanium white 30 parts of powder, 20 parts of lithopone, 5 parts of bentonite, 10 parts of calcium carbonate, 45 parts of wollastonite in powder, 35 parts of kaolin, 20% hydroxy ethyl fiber Plain 4 parts of solution, 0.3 part of bactericide, 0.5 part of mould inhibitor, 0.1 part of crosslinking agent, 0.5 part of dispersant, 0.2 part of defoamer, film forming help 1.0 parts of agent, 0.5 part of thickener, 1 part of levelling agent, 100 parts of deionized water.
Described anionic additive is the tourmaline powder that granularity is 80nm.
Described titanium dioxide rutile type titanium white.
Described dispersant is sodium pyrophosphate.
Described coalescents are propane diols.
Described complex thickener is being blended in by certain weight proportion for cellulose thickener and alkali swollen thickener Mixture together, ratio of weight and number both it are 1:3.
Embodiment 2
A kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating, its raw material include with the following group by weight Point:80 parts of ethylene-vinyl acetate emulsion, 80 parts of styrene-acrylic emulsion, 3 parts of anionic additive, 12 parts of nano titanium oxide, 50 parts of titanium dioxide, 50 parts of lithopone, 10 parts of bentonite, 20 parts of calcium carbonate, 60 parts of wollastonite in powder, 50 parts of kaolin, 20% ethoxy 8 parts of cellulose solution, 0.5 part of bactericide, 0.8 part of mould inhibitor, 0.3 part of crosslinking agent, 1.0 parts of dispersant, 0.5 part of defoamer, 2.5 parts of coalescents, 0.8 part of thickener, 3 parts of levelling agent, 300 parts of deionized water.
Described anionic additive is the tourmaline powder that granularity is 150nm.
Described titanium dioxide rutile type titanium white.
Described dispersant is sodium pyrophosphate.
Described coalescents are propane diols.
Described complex thickener is being blended in by certain weight proportion for cellulose thickener and alkali swollen thickener Mixture together, ratio of weight and number both it are 1:3.
Embodiment 3
A kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating, its raw material include with the following group by weight Point:70 parts of ethylene-vinyl acetate emulsion, 60 parts of styrene-acrylic emulsion, 2 parts of anionic additive, 10 parts of nano titanium oxide, 40 parts of titanium dioxide, 30 parts of lithopone, 8 parts of bentonite, 15 parts of calcium carbonate, 50 parts of wollastonite in powder, 40 parts of kaolin, 20% ethoxy 6 parts of cellulose solution, 0.4 part of bactericide, 0.6 part of mould inhibitor, 0.2 part of crosslinking agent, 0.6 part of dispersant, 0.3 part of defoamer, into Film auxiliary agent 1..5 parts, 0.6 part of thickener, 2 parts of levelling agent, 200 parts of deionized water.
Described anionic additive is the tourmaline powder that granularity is 100nm.
Described titanium dioxide rutile type titanium white.
Described dispersant is sodium pyrophosphate.
Described coalescents are propane diols.
Described complex thickener is being blended in by certain weight proportion for cellulose thickener and alkali swollen thickener Mixture together, ratio of weight and number both it are 1:3.
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this, The change and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention Claimed scope.

Claims (6)

1. a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating, it is characterised in that its raw material is by weight Part includes following components:Ethylene-vinyl acetate emulsion 40-80 parts, styrene-acrylic emulsion 50-80 parts, anionic additive 1-3 Part, nano titanium oxide 8-12 parts, titanium dioxide 30-50 parts, lithopone 20-50 parts, bentonite 5-10 parts, calcium carbonate 10-20 parts, Wollastonite in powder 45-60 parts, kaolin 35-50 parts, 20% hydroxyethyl cellulose solution 4-8 parts, bactericide 0.3-0.5 parts, mould inhibitor 0.5-0.8 parts, crosslinking agent 0.1-0.3 parts, dispersant 0.5-1.0 parts, defoamer 0.2-0.5 parts, coalescents 1.0-2.5 Part, thickener 0.5-0.8 parts, levelling agent 1-3 parts, deionized water 100-300 parts.
2. a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating according to claim 1, it is special Sign is:Described anionic additive is the tourmaline powder that granularity is 80-150nm.
3. a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating according to claim 1, it is special Sign is:Described titanium dioxide rutile type titanium white.
4. a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating according to claim 1, described Dispersant be sodium pyrophosphate.
5. a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating according to claim 1, it is special Sign is:Described coalescents are propane diols.
6. a kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating according to claim 1, it is special Sign is:Described complex thickener is that cellulose thickener and alkali swollen thickener are blended in one by certain weight proportion The mixture risen, ratio of weight and number both it are 1:3.
CN201711211851.0A 2017-11-28 2017-11-28 A kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating Pending CN107868522A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294404A (en) * 2018-10-31 2019-02-01 陈赞 A kind of preparation method of novel plastering coating
CN110123630A (en) * 2019-05-10 2019-08-16 常州市第一人民医院 A kind of intelligence Enteral nutrition transfusion bag
CN112457727A (en) * 2020-12-11 2021-03-09 北京氧道纳米科技有限公司 Nano negative ion latex paint and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294404A (en) * 2018-10-31 2019-02-01 陈赞 A kind of preparation method of novel plastering coating
CN110123630A (en) * 2019-05-10 2019-08-16 常州市第一人民医院 A kind of intelligence Enteral nutrition transfusion bag
CN110123630B (en) * 2019-05-10 2021-10-19 常州市第一人民医院 Nutrition infusion bag in intelligence intestines
CN112457727A (en) * 2020-12-11 2021-03-09 北京氧道纳米科技有限公司 Nano negative ion latex paint and preparation method thereof

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Application publication date: 20180403