CN102391705A - Electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating capable of releasing trace element negative ions - Google Patents
Electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating capable of releasing trace element negative ions Download PDFInfo
- Publication number
- CN102391705A CN102391705A CN2011102618363A CN201110261836A CN102391705A CN 102391705 A CN102391705 A CN 102391705A CN 2011102618363 A CN2011102618363 A CN 2011102618363A CN 201110261836 A CN201110261836 A CN 201110261836A CN 102391705 A CN102391705 A CN 102391705A
- Authority
- CN
- China
- Prior art keywords
- nanometer
- wall coating
- coating
- nano
- electromagnetic wave
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating capable of releasing trace element negative ions, which belongs to the technical field of the preparation and the production of the modified coating of construction decoration nanometer material. The coating is an engineering material matched with the national economy industrial sector. Along with the development of the high-technology industry, economic takeoff and improvement in the living standard, people have higher requirements on room conditions, working space and air quality, and therefore the requirement on the multifunction of the interior wall coating used for constructions for accelerating human health is higher. In the electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating, the porosity of a medical stone is utilized, various tract elements can be dissolved out and released, and especially the content of magnetic ferrous oxide Fe2O3 is high; the electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating has a high magnet adsorption property and contains elements, such as TiO2, SiO2 and the like which have magic water-purification and sterilization action; and nano silver, acetofenate, natural negative ion generators and copolymers, such as nanometer tourmalines and the like are added to mix to prepare the nanometer interior wall coating. The electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating not only can continuously release trace element negative ions beneficial for the human health and adsorb electromagnetic pollution but also can kill insects, sterilize and purify air.
Description
Technical field:
The porcelain nano inner wall coating is imitated in release of trace elements negative ion anti electromagnetic wave deinsectization sterilization of the present invention, is to belong to the nano-material modified coating preparation and production of building decoration field.
Background technology:
Coating is and the supporting engineering materials of national economy branch of industry.The exploitation of universe and ocean, aerospace, new forms of energy and renewable resources, life and work, studying space, shipbuilding industry, information novel material etc. are the development of master's high-tech industry; Economic rapid development; Improving constantly of people's living standard proposes higher performance requriements to coating.Although the coating worker tackles challenge by persistence, the improvement speed of coating property lags far behind demands of social development.Before decades; Coating scholar and formulator just know that the size of particles of coating material is influential to film performance; Performance, material particle to filming are more little good more; Little like size of particles is film forming matter preferably to the emulsion below the 100mm, for trade sales coating provides good pigment-dispersing and sticking power, is used for water-borne coatings like polyurethane dispersions and just obtains satisfied performance; The nano material that modified paint is used is more, is the functional silicon-dioxide SiO through colloidal sol, gel technique preparation like nano silicon
2, colloidal sol is a kind of single dispersion, non-state of aggregation, low viscous transparent material, it is produced by alkoxyl silicone or its hydrolyzate.It becomes the line step following:
Step 1: hydrolysis M (OR)
x+ nH
2O---M (OR)
4---n (OH)
n+ nROH.Here, the M representation metal ion can be Si, Ti, Zr etc.
Step 2: polycondensation, with tetraethylorthosilicise (alkoxyl silicone) as parent material.
(RO)
3-Si-OH+HO-Si-(OH)
3——(RO)
3-Si-O-Si-(OR)
3+H
2O；
(RO)
3-Si-OR+HO-Si-(OR)
3——(RO)
3-Si-O-Si-(OR)
3+ROH。
Above step: use colloidal sol---gel technique, synthetic and other the suitable functionality oligopolymer of the original position pyrocondensation of these colloidal sols own, the macromole condensation forms siloxane network, can give coating many new performance effects, nano silicon SiO
2If, to introduce in the coating system through suitable way, this protects light to improving the hardness of film of coating, improving, protects colourity, and reduces gas permeability, wear-resistant consumption, scratch resistance, anti-performance of staiing, and can reach 10 times of traditional parquet floor.
Use titanium dioxide nano-particle TiO
2In coating,, reduce the porosity of filming, thereby increase the weather resistance of filming, simultaneously TiO because their superfine size and higher surface area can block film cracking effectively and help improving the flexible effect of filming
2Coating can make the surface produce the oxygenizement of peroxylradicals and hydroxyl radical free radical, can be with the pollutent of air (like CO and NO
x) be converted into harmless object, with TiO
2The favourable rainwash of composite photocatalyst coating for the basis has self-cleaning, antibiotic, bacteriostatic action.
Summary of the invention:
Infiltrate coating with nano_scale particle, use organic to process convergent improvement property coating and push a new stage for producing coating, will for the performance effectiveness of coating bring up to several times or tens times maybe.Because nanosecond science and technology can realize the compound of organic on molecular level, can the peculiar effect of nano material be introduced in the molecule of coating, thereby produce unexpected fancy effect.Nano material and organic polymer composite methods: comprise physical blending, intercalation and in-situ polymerization, colloidal sol---gel method.The physical blending method generally be with nano-powder through surface treatment or be prefabricated into the slurry of stable dispersion, directly be scattered in the organic binder, be that the surface tissue material is introduced in the multicomponent system coating, each component synergy is improved the performance effectiveness of coating.TiO and for example
2, SiO
2, ZnO, Fe
2O
3, Fe
3O
4, Al
2O
3Deng all extremely strong absorption ultraviolet ray and the function of electromagnetic wave shielding.The high speed development that present Along with people's high-tech makes rapid progress, sci-tech product miscellaneous, household electrical appliance have been come in people's life, and everything has improved people's work efficient greatly; Improved people's life, but also brought injury to health of people, even serious injury; Caused the fourth-largest pollution after water pollution, atmospheric pollution, sound pollution, promptly electromagenetic wave radiation pollutes, or cries the pollution of electrons cluster; Hi-line, substation, radio station, television station, radar station, electromagnetic field platform, electronic machine, medical facilities, CT, X line, office equipment robotization, computer, duplicating machine, microwave oven, receiving set, televisor, air-conditioning or the like, their all can produce the hertzian wave of various frequencies when working, be flooded with the space and the room of your life; Colourless, tasteless, invisible again, can not touch, can't see; It can penetrate any material that comprises human body; Human body is polluted, HUMAN HEALTH is damaged, be exposed to for a long time above the human body under the radiation dose of the safety of national regulation; Cells in vivo can large-arealy kill and wound, kill; Cause human body sick, in addition dead, prevent that therefore electromagenetic wave radiation from polluting is the key subjects that the numerous scientific workers of China are eager to solve.
Medical stone and tourmalinite all are that a kind of composition and very complicated natural crystal, the medical stone of structure are major ingredient with silicic acid, aluminum oxide; Also have the necessary gallium Ga of human body, germanium Ge, selenium Se, strontium Sr, vanadium V, zinc Zn, copper Cu, molybdenum Mo, chromium Cr, nickel, niobium Nb, tantalum Ta, cobalt Co, tin Sn, europium Fu, nobelium Zr, tungsten W etc.; And the harmful element arsenic As, mercury Hg, plumbous Pb, uranium U, the thorium Th equal size that produce are extremely low, can not constitute the injury to human body.Experimental result shows; The medical stone dissolving out capability is good; Meet water and can discharge element and mineral substance such as calcium Ca, magnesium Mg, potassium K, sodium Na, strontium Sr, selenium Se, zinc Zn, iodine I, metasilicic acid very soon; And in can planar water to odorous gas such as the deleterious heavy metal lead Pb of animal, arsenic As, mercury Hg, cadmium Cd and hydrogen sulfide; Adsorb mikrobe and other organic substances such as intestinal bacteria, virus simultaneously, can get rid of the intravital toxicant of people effectively, have strengthening the spleen and stomach, protect the liver dirty, antifatigue, adjusting metabolism, strengthen blood circulation, improve the biological effects such as ability of immunizing power and resist the disease; Simultaneously diuresis, hypertension, hyperglycemia, cardiovascular disorder, arteriosclerosis, coronary heart disease all there is good therapeutic action; The more important thing is that nano medical stone adds in the coating, can well absorb ultraviolet ray, absorb hertzian wave, because the major ingredient in the medical stone is silicon-dioxide SiO
2, titanium oxide TiO
2, aluminium sesquioxide Al
2O
3, red oxide of iron Fe
2O
3Deng all being good electromagnetic shielding material, the electromagnetic ability of very strong absorption is all arranged, tourmalinite is a kind of natural anion generator simultaneously; It has two important characteristics; Be pyroelectricity and piezoelectricity, after coating infiltrates the tourmalinite nano ultrafine powders, at certain temperature, sunlight, pressure, gentle breeze; Or even very under the minor effect, can cause between the negative ion crystal up to 1.0 * 10
6Ev static electric heating is poor; Thereby form electric field, high-voltage, make the ionization of air in the electric field, the permanent positive and negative polarity that the electronics that is hit is had through tourmalinite nanometer fines two ends; With common water, airborne water molecules; Or after the contact of the water molecules of skin surface, will produce the sudden discharge ionisation effect, be H with the water molecules electrolysis
+And OH
-H
+The electronics that discharges with tourmalinite nano powder end combines, and is neutralized into the H atom, and OH
-With other water molecules, can generate hydroxyl negative ion H continuously
3O
2 -
Now because environmental pollution produces a large amount of positive ions; Airborne negative ion is obviously reduced; People hope to improve the Air quality in residence, chamber and the Working environment; Enjoying the Nature concentration is negative aeroion, and the natural defence of human body can only tackle oarse-grained flue dust, and just powerless for the nanometer microparticle that is lower than 1～2 μ m.Because getting into alveolar smoothly, these small-particles cause the human body various diseases.Negative ion is " Z " font and moves in the coating in air; Be easy to carry negative charge to bacterium, virus, dust, smoke particles and airborne water droplet etc.; With materials such as airborne micronic dust dusts, bacterium, virus, smog, fall earthward after agglomerating in the charge energy, make polluted air be converted into the air of fresh cleaning with these particles agglomerate; Thereby purify air, improve the Air quality of residence, chamber and Working environment.Negative aeroion is the material that HUMAN HEALTH is highly profitable, and is called as " airborne VITAMINs ", " long-lived plain ", and when human body sucked lung with the negative ion of air, the system that can excite nerve produced good effect.Carry these negative ions in each tissue of whole body through the blood circulation, can improve myocardial function, strengthen myocardial nutrition and cellular metabolism; Improve immunizing power, strengthen the ability of resist the disease, promote healthy; When the people sucks certain density negative aeroion, can mediator's somatic nervous system function, promote the blood of human body circulation; Make the people energetic, good health and a long life are so above old man at the age of one hundred years old lives in high mountain, field, rural area, seashore; Be exactly that negative ion is many, seashore, forest waterfall limit anion concentration: 50000～20000/cm because air there is pollution-free
3, 5000～50000/cm in field, countryside
3Green 800～2000/cm in park
320～50/cm in Urban House room
30～10/cm of air-conditioned room of sealing
3If people life by the sea, forest, waterfall district, field, countryside, make the people can suck the negative aeroion of a great deal of, also can drive away multiple person in middle and old age's property diseases such as treatment asthma, hypertension, hyperglycemia, coronary heart disease.
Below in conjunction with examples of implementation the present invention is further specified:
Embodiment 1: the 1. chlorine vinegar third wheat stone nanoemulsions formulation weight proportioning %
1. vinylchlorid 13.6%;
2. vinyl acetate between to for plastic 13.6%;
3. Bing Xisuandingzhi 7.8%;
4. the medical stone nano powder 1.9%;
5. the tourmalinite nano powder 1.9%;
6. Sodium palmityl sulfate 1.6%;
7. alkylphenol-polyethenoxy (10) ether 0.2%;
8. sodium polymethacrylate 0.2%;
9. ammonium persulphate 0.2%;
10. sodium hydrogencarbonate 0.1%;
Embodiment 2: the chlorine vinegar third wheat stone copolymer nano emulsion coatings formulation weight proportioning %
1. the chlorine vinegar third wheat stone nanoemulsions, promptly embodiment 1 56.7%;
2. Z 150PH 11.3%;
3. titanic oxide nano TiO
28.5%;
4. silica nanometer powder SiO
28.5%;
5. the mica nano powder 4.5%;
6. the medical stone nano powder 1.5%;
7. the tourmalinite nano powder 1.3%;
8. talcum powder 1.7%;
9. Sodium hexametaphosphate 99 0.2%;
10. tributyl phosphate 0.06%;
tsp 0.04%;
The preparation method:
(1) chlorine vinegar third wheat stone nanoemulsions preparation:
The preparation emulsion must be carried out in stainless steel or enamel reaction still, because vinylchlorid is gas, adding before the monomer should first closed reactor; Through going into the nitrogen pressure testing, the inspection stopping property adds water by prescription in reaction kettle; PH value to 7.5～8.0 that add a small amount of sodium hydrogencarbonate levelling water simultaneously; Add sodium polymethacrylate and alkylphenol-polyethenoxy (10) ether again, the off-response still feeds the nitrogen pressure testing.4 * 10
5Pressure testing 15min vacuumizes under the pressure of Pa, adds vinyl acetate between to for plastic, Bing Xisuandingzhi, medical stone, tourmalinite nano powder, Sodium palmityl sulfate then; Add 2/3 ammonium persulphate simultaneously; Feed monochloroethane gas, start stirrer and stir 30min, the available decrement method of the control of monochloroethane add-on is carried out; Mixed solution uniformly emulsify in the still, at this moment reacting kettle inner pressure is controlled at 2 * 10
5About Pa, feed steam-heated cal(l)andria, begin to be heated to 40 ℃ to the still intraformational bed; Promptly stop the supple of gas or steam, reaction beginning when mixed solution leans on still wall waste heat to continue to be warming up to 60 ℃ in the still, reaction can be very fierce; Emit a large amount of hot gas, use instead this moment to the still intraformational bed and send the cold water cooling, the control temperature in the kettle is 70～75 ℃; Prevent that reaction is too fierce, the still internal pressure raises with Yin Wendu, reaches 5 * 10
5Pa, initiator have the ammonium persulphate of powerful oxidation agent to begin only to add 2/3, also are in order to control reaction, and be too not fierce, keeps said temperature to continue reaction 2～3h, because vinylchlorid gas progressively consumes, the still internal pressure drops to 1.5 * 10
5When Pa is following, add 1/3 remaining ammonium persulphate this moment, feed steam-heated cal(l)andria to interlayer again, make the interior feed temperature of still rise to 80 ℃, continue reaction 1～1.5h, temperature in the kettle raise with temperature before this, dropped to 1.5 * 10 gradually afterwards
5Below the Pa, reaction is accomplished basically.Open the valve exhaust at last, treat that temperature in the kettle drops to below 40 ℃ to emit copolymer emulsion, emulsion is a white liquid, and solids content is about 36%～39%, barrelling 50kg/ bucket, and deposit at shady and cool place, and pH value is 5～6.
(2) with the chlorine vinegar third wheat stone copolymer nano emulsion coatings formulation:
The emulsion pH value that the preparation emulsion coatings is equipped with coating must be 5～6, with tsp levelling its pH value to 7～8, again by filling a prescription titanic oxide nano TiO
2, silica nanometer powder SiO
2, mica nano powder, medical stone nano powder, tourmalinite nano powder, talcum powder, Sodium hexametaphosphate 99 and water heating sand mill stir, and adds the chlorine vinegar third wheat stone copolymer nano emulsion then, stirring and evenly mixing; Add polyvinyl alcohol solution (10% concentration) again, fully agitation grinding adds the tributyl phosphate froth breaking at last; And get product after sieving; Coating is used the plastic tank barrelling, the 50kg/ bucket, and deposit at shady and cool place.
It is extensive to be suitable for this application of paints, is used for the application of metal, plastics and architectural interior exterior wall.
Embodiment 3: Pesticidal and sterilizing nanometer silver porcelain-imitated coating weight proportion %
1. Z 150PH 2.0%;
2. SEPIGEL 305 0.2%;
3. Gadolinium sesquisulfate 10%;
4. calcium hydroxide 0.3%;
5. titanium oxide TiO
21.0%;
6. silicon-dioxide SiO
21.5%;
7. talcum powder 35%;
8. nanometer Ag 0.2%;
9. acetofenate 15%;
10. water 34.8%.
The preparation method:
(1) water and Z 150PH are added in the reaction kettle, are heated to 90 ℃, behind the stirring 30min, add SEPIGEL 305 again and stir back for use;
(2) with Gadolinium sesquisulfate, calcium hydroxide, titanium oxide TiO
2, silicon-dioxide SiO
2, nanometer Ag with less water stir the back for use;
(3) solution that step (1) is made is put into stirrer; The solution that again step (2) is made is poured in the above-mentioned stirrer, behind the stirring reaction 30min, adds acetofenate, talcum powder in the stirrer together; Mixed together restir 30min promptly makes whitewash.If need the coating of the imitative wallpaper of color pocerlain-like, can add various mill bases as required.
Effect: this coating adds nanometer silver; It can both kill any germ known today, virus; Do not find as yet that in the laboratory any mikrobe, bacterium, virus can not be killed by silver in 6min, and silver can kill 650 kinds of pathogenic organisms bacterium, nanometer silver infiltrates coating; Its element molecule is very little, is released in through weathering and gives sterilizing air, purification in the air; Acetofenate name ethyl acetic ester has good killing action to mosquitos and flies, be suitable for hotel, restaurant, family expenses chamber occupy in, be coated with usefulness in decoration and the work office.
Experimentation on animals:
1, animal: healthy Chinese rabbit, body weight 1.5kg～2.0kg; Healthy wistar rat, body weight 200g～300g; Healthy guinea pig, body weight 200g～300g, above animal male and female half and half provide by Nantong University experimentation on animals field.
2, emulsion coatings:
1. the chlorine vinegar third wheat stone nanoemulsions;
2. the chlorine vinegar third wheat stone copolymer nano emulsion coatings;
3. Pesticidal and sterilizing nanometer silver porcelain-imitated coating.
3, experimental technique:
(1) skin irritation test: get 12 of healthy rabbits, each 3 of half and half, three group of coating of male and female, 3 of control groups, 24h sloughs rabbit spring ridge both sides hair with 8% sodium sulfate starch paste, the about 100cm of every side depilatory solution before the experiment
2, divide cage feeding, each is with 1., 2., 3. emulsion coatings is smeared; Control group is smeared with 70% alcohol; With two layers of gauze of one deck oilcloth cover comprise fixing 6 hours after, repeat to smear once, take off fixing behind the 24h; With wet gauze flush away emulsion, whether coating is observed emulsion or coating after respectively at 0h, 1h, 24h, 48h, 72h and is smeared the position and have redness, erythema, bubble, oedema phenomenon to occur.
Result: do not see that rabbit vertebra both sides erythema, bubble, phenomenon occur, and prove that this emulsion coatings is to the skin vacuum response after observing 72h.
(2) skin acute toxicity test: get 20 of healthy wistar rats, male and female half and half are divided into four groups, and 5 every group, to smear preceding 24h with method and slough rat vertebra both sides hair with aforesaid method, the depilation scope is 2cm * 3cm
2, respectively with 1., 2., 3. emulsion 2ml smears, control group is smeared with 70% alcohol; Fixedly take off fixingly behind the 24h,, have any problem like washing with wet gauze flush away emulsion or coating; Available 75% alcohol is cleaned, and respectively at the body weight of observing animal behind 0h, 1h, 24h, 48h, the 72h, gets head, gets face and take out each internal organs then; Put and make the pathology result in the formalin solution, reaction of section no abnormality seen and pathology.
In experimentation, the active animal situation is good, and feed is normal, even body weight also increased, and removes mouse that Pesticidal and sterilizing nanometer silver porcelain-imitated coating uses and begins 24h movable some is slow, still very active later on.
(3) allergic experiment: get 20 of the cavys that healthy no skin decreases, male and female half and half, method is the same, after contact is smeared in three groups of experiments, does not see any reaction behind 24h, 48h, the 72h, the back hair bears very soon, do not see yet any unusually.
The result: emulsion and three kinds of coating do not have pathogenic characteristic of disease reaction to animal.
The temporary building that inner room is scribbled the chlorine vinegar third wheat stone nanoemulsions, the chlorine vinegar third wheat stone copolymer nano emulsion coatings and Pesticidal and sterilizing nanometer silver porcelain-imitated coating is with totally 10 in room, area 23m
2/, each is coated with 5 at interior wall two kinds of coating, lives in 6 people altogether for every, totally 60 people, and at 21～63 years old age, 45 years old mean age, all the male sex wherein has asthma person 8 people, accounts for 13.3%; Hyperpietic 15 people account for 25%; Hyperglycemia person 5 people account for 8.3%; Early rich palpitaition 4 people account for 6.7%; Immunocompromised often has flu person 8 people, accounts for 13.3%, and patient totally 40 people are arranged, and accounts for 66.7%.Stay in the temporary building room that scribbles above-mentioned two kinds of coating, after four months again 8 philtrums of asthma have 5 people not send out, all the other 3 people only send out 2 times, and lighter than in the past; Hyperpietic's 15 philtrums have 11 people's blood pressure that decline is in various degree arranged, the dizzy sx of all the other 4 people; It is not big in the past that hyperglycemia 5 philtrums have 3 people's blood sugar to float, and all the other 2 people are not obvious; Early rich palpitaition 4 people here lived 4 months, and palpitaition, rich generation early feel happy at heart; Immunocompromised often has flu person's 8 people's times of common cold to reduce, and feels strong, unlike just catching a cold with last enduring cold; The trace-element anion that possible interior wall discharges has strengthened the immunizing power of human body; The absorption hertzian wave makes hertzian wave reduce the human injury, the in-vivo element balance; The ability of resist the disease has improved, and this adds up whole world subhealth state with the World Health Organization is to account for 75% among the crowd to conform to.Use this ooze trace element is arranged, the decoration of the inner wall of building of nanopowder particles mixed copolymer coating such as medical stone, tourmalinite, can promote health really, improve, improve the body quality of sub-health population, be worthy to be popularized.
Claims (3)
1. porcelain nano inner wall coating, its characteristic: the chlorine vinegar third wheat stone nanoemulsions formulation weight proportioning % are imitated in release of trace elements negative ion anti electromagnetic wave deinsectization sterilization
1. vinylchlorid 10～17%;
2. vinyl acetate between to for plastic 10～17%;
3. Bing Xisuandingzhi 5～10%;
4. the medical stone nano powder 0.5～3.5%;
5. the tourmalinite nano powder 0.5～3.5%;
6. Sodium palmityl sulfate 1～3%;
7. alkylphenol-polyethenoxy (10) 0.1～0.3%;
8. sodium polymethacrylate 0.1～0.3%;
9. ammonium persulphate 0.1～0.3%;
10. sodium hydrogencarbonate 0.05～0.15%;
Fe
2O
3 0.9～2.7％；
2. according to claim 1, the porcelain nano inner wall coating is imitated in release of trace elements negative ion anti electromagnetic wave deinsectization sterilization, it is characterized in that: the chlorine vinegar third wheat stone copolymer nano emulsion coatings formulation weight proportioning %
1. the chlorine vinegar third wheat stone nanoemulsions, promptly embodiment 1 50～63%;
2. Z 150PH 8～14%;
3. titanic oxide nano TiO
25～13%;
4. silica nanometer powder SiO
25～13%;
5. the mica nano powder 2～7%;
6. the medical stone nano powder 1～2%;
7. the tourmalinite nano powder 1～1.6%;
8. talcum powder 0.8～2.5%;
9. Sodium hexametaphosphate 99 0.1～0.3%;
10. tributyl phosphate 0.04～0.08%;
3. according to claim 2, the porcelain nano inner wall coating is imitated in release of trace elements negative ion anti electromagnetic wave deinsectization sterilization, it is characterized in that: Pesticidal and sterilizing nanometer silver porcelain-imitated coating weight proportion %
1. Z 150PH 1～3%;
2. SEPIGEL 305 0.1～0.3%;
3. Gadolinium sesquisulfate 5～15%;
4. calcium hydroxide 0.2～0.4%;
5. titanium oxide TiO
20.5～1.5%;
6. silicon-dioxide SiO
21～2%;
7. talcum powder 30～40%;
8. nanometer Ag 0.1～0.3%;
9. acetofenate 10～20%;
10. water 30～40%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102618363A CN102391705A (en) | 2011-09-01 | 2011-09-01 | Electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating capable of releasing trace element negative ions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102618363A CN102391705A (en) | 2011-09-01 | 2011-09-01 | Electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating capable of releasing trace element negative ions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102391705A true CN102391705A (en) | 2012-03-28 |
Family
ID=45859096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102618363A Pending CN102391705A (en) | 2011-09-01 | 2011-09-01 | Electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating capable of releasing trace element negative ions |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102391705A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305067A (en) * | 2013-06-26 | 2013-09-18 | 关锦池 | Multifunctional coating capable of releasing trace element anions |
| CN106977997A (en) * | 2017-05-02 | 2017-07-25 | 南通蛇类治疗研究所 | The both effectiveness nano paint of disease-prevention health |
| CN107163657A (en) * | 2017-06-01 | 2017-09-15 | 中山市丽莎涂料有限公司 | A kind of radiation-preventing composition and a kind of coating additive and radiation shielding coating |
| CN107227081A (en) * | 2017-06-15 | 2017-10-03 | 南通蛇类治疗研究所 | Nano-element anion composite efficacy coating |
| CN110479052A (en) * | 2019-08-27 | 2019-11-22 | 徐玲军 | A kind of anion removes the air cleaning decorative adhesive film and preparation method of formaldehyde |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1473883A (en) * | 2003-07-01 | 2004-02-11 | 上海华明高技术（集团）有限公司 | Method for increasing dispersiveness of inorganic oxide powder in organic medium |
| CN101098896A (en) * | 2005-01-06 | 2008-01-02 | 巴斯福股份公司 | Method for producing aqueous composite particle dispersions |
| CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
| CN102093791A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Formula process for nano negative ion compound functional coating |
| CN102140284A (en) * | 2011-02-16 | 2011-08-03 | 张震红 | Medicinal stone coating and preparation method thereof |
-
2011
- 2011-09-01 CN CN2011102618363A patent/CN102391705A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1473883A (en) * | 2003-07-01 | 2004-02-11 | 上海华明高技术（集团）有限公司 | Method for increasing dispersiveness of inorganic oxide powder in organic medium |
| CN101098896A (en) * | 2005-01-06 | 2008-01-02 | 巴斯福股份公司 | Method for producing aqueous composite particle dispersions |
| CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
| CN102093791A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Formula process for nano negative ion compound functional coating |
| CN102140284A (en) * | 2011-02-16 | 2011-08-03 | 张震红 | Medicinal stone coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 陈三斌: "《180种实用化工产品配方与制造》", 31 December 2002, article "氯-醋-丙共聚乳液涂料", pages: 196-197 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305067A (en) * | 2013-06-26 | 2013-09-18 | 关锦池 | Multifunctional coating capable of releasing trace element anions |
| CN106977997A (en) * | 2017-05-02 | 2017-07-25 | 南通蛇类治疗研究所 | The both effectiveness nano paint of disease-prevention health |
| CN107163657A (en) * | 2017-06-01 | 2017-09-15 | 中山市丽莎涂料有限公司 | A kind of radiation-preventing composition and a kind of coating additive and radiation shielding coating |
| CN107227081A (en) * | 2017-06-15 | 2017-10-03 | 南通蛇类治疗研究所 | Nano-element anion composite efficacy coating |
| CN110479052A (en) * | 2019-08-27 | 2019-11-22 | 徐玲军 | A kind of anion removes the air cleaning decorative adhesive film and preparation method of formaldehyde |
| CN110479052B (en) * | 2019-08-27 | 2021-01-26 | 北京优氧朗芬莱环保科技有限公司 | Air purification decoration film capable of removing formaldehyde through negative ions and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102391705A (en) | Electromagnetic wave-proof disinsection and sterilizing imitation ceramic nanometer interior wall coating capable of releasing trace element negative ions | |
| Jiang et al. | Effective E. coli inactivation of core-shell ZnO@ ZIF-8 photocatalysis under visible light synergize with peroxymonosulfate: Efficiency and mechanism | |
| Zhang et al. | Light-assisted rapid sterilization by a hydrogel incorporated with Ag3PO4/MoS2 composites for efficient wound disinfection | |
| CN105315727B (en) | The environmental multifunctional inorganic dry powder paint of releasable negative oxygen ion | |
| CN108610817A (en) | Nana intelligent health powdery paints | |
| CN102093791A (en) | Formula process for nano negative ion compound functional coating | |
| CN104422018B (en) | Device for improving indoor air quality | |
| CN107236351A (en) | A kind of releasable negative aeroion additive | |
| CN101857408A (en) | Interior wall decoration mortar and construction method thereof | |
| CN105368223B (en) | A kind of mercerising photocatalyst emulsion paint finish paint and its production technology | |
| CN108864907A (en) | A kind of aqueous inner wall paint and preparation method thereof | |
| CN107555843A (en) | A kind of artificial quartz stone plate | |
| CN105585955A (en) | Water-based coating with self-cleaning, anti-mildew, sterilization and air purification functions | |
| CN101433209A (en) | High-temperature resistant negative ion antibiotic material and preparation method | |
| CN106904979A (en) | Additive of releasable negative oxygen ion and preparation method thereof | |
| CN107760136A (en) | A kind of the third weather resisteant of nano modification silicon exterior wall negative ion paint and preparation method thereof | |
| CN107793866A (en) | A kind of nano-TiO2Modified pure acrylic acid exterior wall negative ion paint and preparation method thereof | |
| Zhou et al. | High metal-loaded Cu2O@ TM hybrids for melt-spun antibacterial fibers engineered towards medical protective fabrics | |
| CN108976848A (en) | Nano rare earth zeolite coating | |
| CN109082160A (en) | A kind of release anion quick-dry type environmental protection coating material and preparation method | |
| CN104046156A (en) | Nano multicolor interior wall environment-friendly paint | |
| CN103820492A (en) | Functional nano catechin gene-introduction material and preparation method thereof | |
| CN108300055A (en) | Coating formula application based on the efficient anion material of Low emissivity and its preparation process | |
| CN102417793A (en) | Electromagnetic wave shielding nanometer fragrant brightener capable of releasing trace element negative ions | |
| CN102863834A (en) | Modified nano-cuprous oxide coating additive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120328 |