CN105585955A - Water-based coating with self-cleaning, anti-mildew, sterilization and air purification functions - Google Patents
Water-based coating with self-cleaning, anti-mildew, sterilization and air purification functions Download PDFInfo
- Publication number
- CN105585955A CN105585955A CN201511000649.4A CN201511000649A CN105585955A CN 105585955 A CN105585955 A CN 105585955A CN 201511000649 A CN201511000649 A CN 201511000649A CN 105585955 A CN105585955 A CN 105585955A
- Authority
- CN
- China
- Prior art keywords
- water
- mildew
- cleaning
- self
- air purification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 238000000576 coating method Methods 0.000 title claims abstract description 49
- 239000011248 coating agent Substances 0.000 title claims abstract description 47
- 238000004140 cleaning Methods 0.000 title claims abstract description 39
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 30
- 238000004887 air purification Methods 0.000 title claims abstract description 27
- 238000004659 sterilization and disinfection Methods 0.000 title abstract description 6
- 239000000839 emulsion Substances 0.000 claims abstract description 23
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 15
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000000945 filler Substances 0.000 claims abstract description 8
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 42
- 238000002156 mixing Methods 0.000 claims description 40
- 239000003973 paint Substances 0.000 claims description 32
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 29
- 229910052799 carbon Inorganic materials 0.000 claims description 29
- 230000000694 effects Effects 0.000 claims description 29
- 239000003899 bactericide agent Substances 0.000 claims description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- 239000008367 deionised water Substances 0.000 claims description 16
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 16
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 14
- 239000004593 Epoxy Substances 0.000 claims description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 14
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 14
- 239000001023 inorganic pigment Substances 0.000 claims description 14
- 229920001296 polysiloxane Polymers 0.000 claims description 14
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical group CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 14
- 229920002050 silicone resin Polymers 0.000 claims description 14
- 235000011201 Ginkgo Nutrition 0.000 claims description 9
- 235000008100 Ginkgo biloba Nutrition 0.000 claims description 9
- 241000533293 Sesbania emerus Species 0.000 claims description 9
- 239000005539 carbonized material Substances 0.000 claims description 9
- 235000013312 flour Nutrition 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 9
- 239000012279 sodium borohydride Substances 0.000 claims description 9
- 238000013019 agitation Methods 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 8
- 239000001569 carbon dioxide Substances 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 8
- 238000003763 carbonization Methods 0.000 claims description 8
- 239000012153 distilled water Substances 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 229920000058 polyacrylate Polymers 0.000 claims description 8
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 8
- 238000000967 suction filtration Methods 0.000 claims description 8
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 6
- 244000194101 Ginkgo biloba Species 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000003206 sterilizing agent Substances 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 150000001336 alkenes Chemical class 0.000 description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 10
- 241000218628 Ginkgo Species 0.000 description 8
- 125000004122 cyclic group Chemical group 0.000 description 7
- 238000000227 grinding Methods 0.000 description 7
- 239000008236 heating water Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000003643 water by type Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000009931 harmful effect Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 241000223261 Trichoderma viride Species 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1681—Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a water-based coating with self-cleaning, anti-mildew, sterilization and air purification functions. The water-based coating is prepared from following components in parts by weight: 20-30 parts of organic silicon resin, 20-30 parts of a water-based fluorocarbon emulsion, 0.4-0.9 parts of a coalescing agent, 30-35 parts of water, 0.5-1 part of a dispersing agent, 0.1-0.6 parts of an antifoaming agent, 1-1.5 parts of a leveling agent, 10-15 parts of pigments, 8-14 parts of filler and 7-8 parts of an anti-mildew sterilizing agent. The water-based coating has better self-cleaning, anti-mildew, sterilization and air purification functions.
Description
Technical field:
The present invention relates to a kind of water paint, particularly relate to there is self-cleaning, anti-mildew, sterilizing and air purification effectWater paint.
Background technology:
Since reform and opening-up, along with the rapid growth of China's national economy, improving constantly of people's living standard, is coated withMaterial output and consumption be just with speed increment faster, and China has become second-biggest-in-the-world coating country of consumption, annual production at presentApproximately 600 tons are reached. But than developed country, the consumption structure of China's coating is also unreasonable, high pollutionCoating variety still occupies larger ratio, and environment and workmen are brought to serious harm. Along with the change of global climateThe day of change and resource, the energy is becoming tight, and countries in the world have been formulated strict environmental regulation and policy in succession, encourage and push awayThe wide new product that uses environmental protection, energy-saving material-saving. Oligosaprobic water paint, powdery paints, high solid coatingAnd radiation curable coating has become the developing direction of coating technology. Water paint is than other low Contamination Coatings, byCan realize in having that technological approaches is many, wide application, safety, construction relatively simply form headed by selection kind, more wideLarge coating scientific and technical personnel concern and coating user's favor, has recently obtained certain development in China, before being subject toNot some attention, but water paint is except building coating field is widely used, at other field particularlyIndustrial coating field, is still solvent based coating and rules all the land, and water paint also only accounts for very little ratio.
Topmost its feature of environmental protection that is characterised in that of aqueous architectural coating, water is as the decentralized medium of coating, nothing ownMalicious, tasteless, not can to human body and environment cause harmful effect (by comparison most organic solvents can be to environment andHuman health has a negative impact); Secondly, it is evident that being easy to get property and the inexpensive property of water. As for coating propertyBecause the difference of kind is different. According to different sorting techniques, can obtain different aqueous architectural coating kinds.For example, according to the difference classification of film forming matter state in water, can be divided into water soluble paint and water milk type coating; RootAccording to the difference classification of coating constituent, can be divided into organic architecture coating and inorganic architectural coatings; According to coating appearanceThe difference classification of form, can be divided into liquid building coating and powdery building coating etc.
Publication number is CN103275543B, within open day, is 2014.06.25, applies for that the China that people is Luoyang Institute Of Science And Technology is specialProfit application discloses " a kind of preparation method of the water paint that can be used for formaldehyde and toluene gas degraded ", with natural micro-Pore structure nonmetallic mineral is raw material, adopts the methods such as scouring, acidleach, calcining to purify to mineral, with what purifyMicropore nonmetallic mineral is carrier, taking inorganic titanium salt as presoma, adopts the low temperature neutralizing hydrolysis precipitation method to prepare nanometer twoTitanium oxide composite photocatalyst material, taking prepared nanometer titanic oxide composite photochemical catalyst material as filler, preparing canFor the water paint of formaldehyde and toluene gas degraded. The coating that the method is prepared, containing volatile organic compoundThe harmful substances such as thing, formaldehyde, toluene, and effectively degradation of formaldehyde and toluene gas, the degradation rate of PARA FORMALDEHYDE PRILLS(91,95) can reachMore than 80%, can reach more than 35% the degradation rate of toluene. This coating is mainly harmful to gas by nano titanium dioxide degradableBody, its defect is that nano titanium oxide need to irradiate and could produce photocatalysis in the ultraviolet ray of sunshine, at wet weatherMore difficult playing a role under weather, therefore actual degradation effect bad, and also this coating is in self-cleaning, anti-mildew, sterilizing etc.Aspect is also very undesirable.
Summary of the invention:
The technical problem to be solved in the present invention be to provide there is self-cleaning, anti-mildew, the water-based of sterilizing and air purification effect is coated withMaterial.
For solving the problems of the technologies described above, technical scheme of the present invention is:
There is the water paint of self-cleaning, anti-mildew, sterilizing and air purification effect, by weight, by following component systemBecome: 20～30 parts of organic siliconresins, 20～30 parts of water-base fluorocarbon emulsion, 0.4～0.9 part of coalescents, water 30～35 parts, 0.5～1 part of dispersant, 0.1～0.6 part of defoamer, 1～1.5 part of levelling agent, 10～15 parts of pigment,8～14 parts of fillers, 7～8 parts of anti-mildew bactericidal agents;
The described water paint with self-cleaning, anti-mildew, sterilizing and air purification effect is made by following steps:
(1) the coffee bean shell that is 3:1 by mass ratio, ginkgo shell are pulverized with pulverizer, and after grinding, obtaining particle diameter is 1mmShell powder, shell powder is added to the phosphoric acid solution that the concentration of 2 times of weight is 55%, after stirring, soak 24 hours, putEnter microwave reactor, logical nitrogen protection, microwave power is that under 800W condition, carbonization obtains carbonized material in 20 minutes, by charcoalMaterial is put into tube type resistance furnace, is warming up to 750 DEG C, passes into carbon dioxide, 40 points with the speed of 180mL/min simultaneouslyAfter clock, take out, be washed with distilled water to neutrality, after drying, grind and obtain mixed shell powdered carbon;
(2) mixed shell powdered carbon step (1) being obtained is added to the water ultrasonic agitation 2 hours, heating water bath to 50 DEG C,Adding concentration is that the liquor argenti nitratis ophthalmicus constant temperature of 1mol/L stirs 4 hours, and being added dropwise to concentration in 1 hour is 0.6mol/L'sSodium borohydride solution, continues to stir 4 hours, uses circulating water type vavuum pump suction filtration, by deionized water, anhydrous after taking outEthanol cyclic washing, is placed at 90 DEG C of thermostatic drying chambers and is dried to constant weight, obtains anti-mildew bactericidal agent, wherein, mixesThe weight ratio of shell powdered carbon, silver nitrate, sodium borohydride is 900:15:2;
(3) take each component by formula, the water of half amount is added to a mixing bowl, under linear velocity 15m/s, stir 2 pointsClock, adds a mixing bowl by dispersant, defoamer, continues to stir 10 minutes, by pigment, filler, coalescents, stepSuddenly the anti-mildew bactericidal agent that (2) obtain adds a mixing bowl, stirs 40 minutes until scraper plate fineness is under linear velocity 27m/s45-50 μ m, reduces linear velocity to 14m/s, and organic siliconresin, water-base fluorocarbon emulsion are added, and a mixing bowl stirs 5 pointsClock, adds a mixing bowl and remaining water by levelling agent, is stirred to and is uniformly dispersed, and obtains having self-cleaning, anti-mildew, goes outThe water paint of bacterium and air purification effect.
Preferably, organic siliconresin of the present invention is epoxy silicone resin.
Preferably, water-base fluorocarbon emulsion of the present invention is the copolymer emulsion of tetrafluoroethene and ethene.
Preferably, coalescents of the present invention is propandiol butyl ether.
Preferably, water of the present invention is deionized water.
Preferably, dispersant of the present invention is polyacrylate.
Preferably, defoamer of the present invention is silicone defoaming agent.
Preferably, levelling agent of the present invention is propane diols.
Preferably, pigment of the present invention is inorganic pigment.
Preferably, filler of the present invention is silica flour or barium sulfate.
Compared with prior art, the present invention has following beneficial effect:
(1) organic siliconresin has good hydrophobic property, can obtain smooth uniform film coated surface, but it adheres toProperty poor, can not be grease proofing, and water-base fluorocarbon emulsion have extremely low surface can, hydrophobicity and oleophobic property are equally very excellentDifferent, and tack is extremely strong, the present invention combines organic siliconresin and water-base fluorocarbon emulsion, and the coating obtaining canThere is good hydrophobicity, oleophobic property and tack, produce class lotus leaf effect, reach good self-cleaning property.
(2) coffee bean shell, ginkgo shell all belong to the discarded object in people's daily life, first after the present invention is pulverizedBy phosphate impregnation microwave activation, then carry out re-activation and obtained having the mixed shell of central hole structure by carbon dioxidePowdered carbon, it has good anti-mildew activity to mould, and organic siliconresin can produce dense film coated surface simultaneously,Can effectively stop entering of mould, thereby effectively improve the anti-fungi performance of water paint; In addition, mixed shell powdered carbon hasAnion active component, can produce anion when use, and pernicious gas is produced to coated sedimentation, reaction, Current DecompositionDeng effect, make water paint can produce the effect purifying air.
(3) silver ion has excellent broad-spectrum antibacterial effect, the present invention by have central hole structure mixed shell powdered carbon andSilver nitrate, sodium borohydride reduce compound, nano-Ag particles are carried in the duct of mixed shell powdered carbon, form multipleClose anti-mildew bactericidal agent, make an addition to the fungistatic effect that can give full play of silver ion in coating, be coated with thereby effectively improve water-basedThe sterilization ability of material.
Detailed description of the invention:
Describe the present invention in detail below in conjunction with specific embodiment, in this illustrative examples of the present invention and explanationBe used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1
Super self-cleaning exterior wall building organic coating, by weight, is made up of following component: epoxy silicone resin 20Part, 30 parts of the copolymer emulsions of tetrafluoroethene and ethene, 0.4 part of propandiol butyl ether, 31 parts of deionized waters, poly-third0.6 part of olefin(e) acid salt, 0.2 part of silicone defoaming agent, 1.1 parts of propane diols, 13 parts of inorganic pigments, 8 parts of silica flours,7.7 parts of anti-mildew bactericidal agents.
The preparation process of this water paint is as follows:
(1) the coffee bean shell that is 3:1 by mass ratio, ginkgo shell are pulverized with pulverizer, and after grinding, obtaining particle diameter is 1mmShell powder, shell powder is added to the phosphoric acid solution that the concentration of 2 times of weight is 55%, after stirring, soak 24 hours, putEnter microwave reactor, logical nitrogen protection, microwave power is that under 800W condition, carbonization obtains carbonized material in 20 minutes, by charcoalMaterial is put into tube type resistance furnace, is warming up to 750 DEG C, passes into carbon dioxide, 40 points with the speed of 180mL/min simultaneouslyAfter clock, take out, be washed with distilled water to neutrality, after drying, grind and obtain mixed shell powdered carbon;
(2) mixed shell powdered carbon step (1) being obtained is added to the water ultrasonic agitation 2 hours, heating water bath to 50 DEG C,Adding concentration is that the liquor argenti nitratis ophthalmicus constant temperature of 1mol/L stirs 4 hours, and being added dropwise to concentration in 1 hour is 0.6mol/L'sSodium borohydride solution, continues to stir 4 hours, uses circulating water type vavuum pump suction filtration, by deionized water, anhydrous after taking outEthanol cyclic washing, is placed at 90 DEG C of thermostatic drying chambers and is dried to constant weight, obtains anti-mildew bactericidal agent, wherein, mixesThe weight ratio of shell powdered carbon, silver nitrate, sodium borohydride is 900:15:2;
(3) take each component by formula, the deionized water of half amount is added to a mixing bowl, under linear velocity 15m/s, stir2 minutes, polyacrylate, silicone defoaming agent are added to a mixing bowl, continue stir 10 minutes, by inorganic pigment,The anti-mildew bactericidal agent that silica flour, propandiol butyl ether, step (2) obtain adds a mixing bowl, under linear velocity 27m/s, stirsWithin 40 minutes, until scraper plate fineness is 45-50 μ m, reduction linear velocity is to 14m/s, by epoxy silicone resin, tetrafluoro secondThe copolymer emulsion of alkene and ethene adds, and a mixing bowl stirs 5 minutes, and propane diols is added to a mixing bowl and remaining goingIonized water, is stirred to and is uniformly dispersed, and obtains having the water paint of self-cleaning, anti-mildew, sterilizing and air purification effect.
Embodiment 2
Super self-cleaning exterior wall building organic coating, by weight, is made up of following component: epoxy silicone resin 25Part, 24 parts of the copolymer emulsions of tetrafluoroethene and ethene, 0.6 part of propandiol butyl ether, 35 parts of deionized waters, poly-third0.5 part of olefin(e) acid salt, 0.4 part of silicone defoaming agent, 1.3 parts of propane diols, 15 parts of inorganic pigments, 10 parts, barium sulfate,7 parts of anti-mildew bactericidal agents.
The preparation process of this water paint is as follows:
(1) the coffee bean shell that is 3:1 by mass ratio, ginkgo shell are pulverized with pulverizer, and after grinding, obtaining particle diameter is 1mmShell powder, shell powder is added to the phosphoric acid solution that the concentration of 2 times of weight is 55%, after stirring, soak 24 hours, putEnter microwave reactor, logical nitrogen protection, microwave power is that under 800W condition, carbonization obtains carbonized material in 20 minutes, by charcoalMaterial is put into tube type resistance furnace, is warming up to 750 DEG C, passes into carbon dioxide, 40 points with the speed of 180mL/min simultaneouslyAfter clock, take out, be washed with distilled water to neutrality, after drying, grind and obtain mixed shell powdered carbon;
(2) mixed shell powdered carbon step (1) being obtained is added to the water ultrasonic agitation 2 hours, heating water bath to 50 DEG C,Adding concentration is that the liquor argenti nitratis ophthalmicus constant temperature of 1mol/L stirs 4 hours, and being added dropwise to concentration in 1 hour is 0.6mol/L'sSodium borohydride solution, continues to stir 4 hours, uses circulating water type vavuum pump suction filtration, by deionized water, anhydrous after taking outEthanol cyclic washing, is placed at 90 DEG C of thermostatic drying chambers and is dried to constant weight, obtains anti-mildew bactericidal agent, wherein, mixesThe weight ratio of shell powdered carbon, silver nitrate, sodium borohydride is 900:15:2;
(3) take each component by formula, the deionized water of half amount is added to a mixing bowl, under linear velocity 15m/s, stir2 minutes, polyacrylate, silicone defoaming agent are added to a mixing bowl, continue stir 10 minutes, by inorganic pigment,The anti-mildew bactericidal agent that barium sulfate, propandiol butyl ether, step (2) obtain adds a mixing bowl, under linear velocity 27m/s, stirsWithin 40 minutes, until scraper plate fineness is 45-50 μ m, reduction linear velocity is to 14m/s, by epoxy silicone resin, tetrafluoro secondThe copolymer emulsion of alkene and ethene adds, and a mixing bowl stirs 5 minutes, and propane diols is added to a mixing bowl and remaining goingIonized water, is stirred to and is uniformly dispersed, and obtains having the water paint of self-cleaning, anti-mildew, sterilizing and air purification effect.
Embodiment 3
Super self-cleaning exterior wall building organic coating, by weight, is made up of following component: epoxy silicone resin 24Part, 25 parts of the copolymer emulsions of tetrafluoroethene and ethene, 0.8 part of propandiol butyl ether, 33 parts of deionized waters, poly-third0.7 part of olefin(e) acid salt, 0.6 part of silicone defoaming agent, 1.5 parts of propane diols, 11 parts of inorganic pigments, 12 parts of silica flours,7.2 parts of anti-mildew bactericidal agents.
The preparation process of this water paint is as follows:
(1) the coffee bean shell that is 3:1 by mass ratio, ginkgo shell are pulverized with pulverizer, and after grinding, obtaining particle diameter is 1mmShell powder, shell powder is added to the phosphoric acid solution that the concentration of 2 times of weight is 55%, after stirring, soak 24 hours, putEnter microwave reactor, logical nitrogen protection, microwave power is that under 800W condition, carbonization obtains carbonized material in 20 minutes, by charcoalMaterial is put into tube type resistance furnace, is warming up to 750 DEG C, passes into carbon dioxide, 40 points with the speed of 180mL/min simultaneouslyAfter clock, take out, be washed with distilled water to neutrality, after drying, grind and obtain mixed shell powdered carbon;
(2) mixed shell powdered carbon step (1) being obtained is added to the water ultrasonic agitation 2 hours, heating water bath to 50 DEG C,Adding concentration is that the liquor argenti nitratis ophthalmicus constant temperature of 1mol/L stirs 4 hours, and being added dropwise to concentration in 1 hour is 0.6mol/L'sSodium borohydride solution, continues to stir 4 hours, uses circulating water type vavuum pump suction filtration, by deionized water, anhydrous after taking outEthanol cyclic washing, is placed at 90 DEG C of thermostatic drying chambers and is dried to constant weight, obtains anti-mildew bactericidal agent, wherein, mixesThe weight ratio of shell powdered carbon, silver nitrate, sodium borohydride is 900:15:2;
(3) take each component by formula, the deionized water of half amount is added to a mixing bowl, under linear velocity 15m/s, stir2 minutes, polyacrylate, silicone defoaming agent are added to a mixing bowl, continue stir 10 minutes, by inorganic pigment,The anti-mildew bactericidal agent that silica flour, propandiol butyl ether, step (2) obtain adds a mixing bowl, under linear velocity 27m/s, stirsWithin 40 minutes, until scraper plate fineness is 45-50 μ m, reduction linear velocity is to 14m/s, by epoxy silicone resin, tetrafluoro secondThe copolymer emulsion of alkene and ethene adds, and a mixing bowl stirs 5 minutes, and propane diols is added to a mixing bowl and remaining goingIonized water, is stirred to and is uniformly dispersed, and obtains having the water paint of self-cleaning, anti-mildew, sterilizing and air purification effect.
Embodiment 4
Super self-cleaning exterior wall building organic coating, by weight, is made up of following component: epoxy silicone resin 30Part, 20 parts of the copolymer emulsions of tetrafluoroethene and ethene, 0.5 part of propandiol butyl ether, 34 parts of deionized waters, poly-third0.9 part of olefin(e) acid salt, 0.1 part of silicone defoaming agent, 1.4 parts of propane diols, 14 parts of inorganic pigments, 11 parts, barium sulfate,7.5 parts of anti-mildew bactericidal agents.
The preparation process of this water paint is as follows:
(1) the coffee bean shell that is 3:1 by mass ratio, ginkgo shell are pulverized with pulverizer, and after grinding, obtaining particle diameter is 1mmShell powder, shell powder is added to the phosphoric acid solution that the concentration of 2 times of weight is 55%, after stirring, soak 24 hours, putEnter microwave reactor, logical nitrogen protection, microwave power is that under 800W condition, carbonization obtains carbonized material in 20 minutes, by charcoalMaterial is put into tube type resistance furnace, is warming up to 750 DEG C, passes into carbon dioxide, 40 points with the speed of 180mL/min simultaneouslyAfter clock, take out, be washed with distilled water to neutrality, after drying, grind and obtain mixed shell powdered carbon;
(2) mixed shell powdered carbon step (1) being obtained is added to the water ultrasonic agitation 2 hours, heating water bath to 50 DEG C,Adding concentration is that the liquor argenti nitratis ophthalmicus constant temperature of 1mol/L stirs 4 hours, and being added dropwise to concentration in 1 hour is 0.6mol/L'sSodium borohydride solution, continues to stir 4 hours, uses circulating water type vavuum pump suction filtration, by deionized water, anhydrous after taking outEthanol cyclic washing, is placed at 90 DEG C of thermostatic drying chambers and is dried to constant weight, obtains anti-mildew bactericidal agent, wherein, mixesThe weight ratio of shell powdered carbon, silver nitrate, sodium borohydride is 900:15:2;
(3) take each component by formula, the deionized water of half amount is added to a mixing bowl, under linear velocity 15m/s, stir2 minutes, polyacrylate, silicone defoaming agent are added to a mixing bowl, continue stir 10 minutes, by inorganic pigment,The anti-mildew bactericidal agent that barium sulfate, propandiol butyl ether, step (2) obtain adds a mixing bowl, under linear velocity 27m/s, stirsWithin 40 minutes, until scraper plate fineness is 45-50 μ m, reduction linear velocity is to 14m/s, by epoxy silicone resin, tetrafluoro secondThe copolymer emulsion of alkene and ethene adds, and a mixing bowl stirs 5 minutes, and propane diols is added to a mixing bowl and remaining goingIonized water, is stirred to and is uniformly dispersed, and obtains having the water paint of self-cleaning, anti-mildew, sterilizing and air purification effect.
Embodiment 5
Super self-cleaning exterior wall building organic coating, by weight, is made up of following component: epoxy silicone resin 21Part, 28 parts of the copolymer emulsions of tetrafluoroethene and ethene, 0.7 part of propandiol butyl ether, 32 parts of deionized waters, poly-third1 part of olefin(e) acid salt, 0.3 part of silicone defoaming agent, 1.2 parts of propane diols, 10 parts of inorganic pigments, 13 parts, barium sulfate,8 parts of anti-mildew bactericidal agents.
The preparation process of this water paint is as follows:
(1) the coffee bean shell that is 3:1 by mass ratio, ginkgo shell are pulverized with pulverizer, and after grinding, obtaining particle diameter is 1mmShell powder, shell powder is added to the phosphoric acid solution that the concentration of 2 times of weight is 55%, after stirring, soak 24 hours, putEnter microwave reactor, logical nitrogen protection, microwave power is that under 800W condition, carbonization obtains carbonized material in 20 minutes, by charcoalMaterial is put into tube type resistance furnace, is warming up to 750 DEG C, passes into carbon dioxide, 40 points with the speed of 180mL/min simultaneouslyAfter clock, take out, be washed with distilled water to neutrality, after drying, grind and obtain mixed shell powdered carbon;
(2) mixed shell powdered carbon step (1) being obtained is added to the water ultrasonic agitation 2 hours, heating water bath to 50 DEG C,Adding concentration is that the liquor argenti nitratis ophthalmicus constant temperature of 1mol/L stirs 4 hours, and being added dropwise to concentration in 1 hour is 0.6mol/L'sSodium borohydride solution, continues to stir 4 hours, uses circulating water type vavuum pump suction filtration, by deionized water, anhydrous after taking outEthanol cyclic washing, is placed at 90 DEG C of thermostatic drying chambers and is dried to constant weight, obtains anti-mildew bactericidal agent, wherein, mixesThe weight ratio of shell powdered carbon, silver nitrate, sodium borohydride is 900:15:2;
(3) take each component by formula, the deionized water of half amount is added to a mixing bowl, under linear velocity 15m/s, stir2 minutes, polyacrylate, silicone defoaming agent are added to a mixing bowl, continue stir 10 minutes, by inorganic pigment,The anti-mildew bactericidal agent that silica flour, propandiol butyl ether, step (2) obtain adds a mixing bowl, under linear velocity 27m/s, stirsWithin 40 minutes, until scraper plate fineness is 45-50 μ m, reduction linear velocity is to 14m/s, by epoxy silicone resin, tetrafluoro secondThe copolymer emulsion of alkene and ethene adds, and a mixing bowl stirs 5 minutes, and propane diols is added to a mixing bowl and remaining goingIonized water, is stirred to and is uniformly dispersed, and obtains having the water paint of self-cleaning, anti-mildew, sterilizing and air purification effect.
Embodiment 6
Super self-cleaning exterior wall building organic coating, by weight, is made up of following component: epoxy silicone resin 28Part, 21 parts of the copolymer emulsions of tetrafluoroethene and ethene, 0.9 part of propandiol butyl ether, 30 parts of deionized waters, poly-third0.8 part of olefin(e) acid salt, 0.5 part of silicone defoaming agent, 1 part of propane diols, 12 parts of inorganic pigments, 14 parts of silica flours,7.6 parts of anti-mildew bactericidal agents.
The preparation process of this water paint is as follows:
(1) the coffee bean shell that is 3:1 by mass ratio, ginkgo shell are pulverized with pulverizer, and after grinding, obtaining particle diameter is 1mmShell powder, shell powder is added to the phosphoric acid solution that the concentration of 2 times of weight is 55%, after stirring, soak 24 hours, putEnter microwave reactor, logical nitrogen protection, microwave power is that under 800W condition, carbonization obtains carbonized material in 20 minutes, by charcoalMaterial is put into tube type resistance furnace, is warming up to 750 DEG C, passes into carbon dioxide, 40 points with the speed of 180mL/min simultaneouslyAfter clock, take out, be washed with distilled water to neutrality, after drying, grind and obtain mixed shell powdered carbon;
(2) mixed shell powdered carbon step (1) being obtained is added to the water ultrasonic agitation 2 hours, heating water bath to 50 DEG C,Adding concentration is that the liquor argenti nitratis ophthalmicus constant temperature of 1mol/L stirs 4 hours, and being added dropwise to concentration in 1 hour is 0.6mol/L'sSodium borohydride solution, continues to stir 4 hours, uses circulating water type vavuum pump suction filtration, by deionized water, anhydrous after taking outEthanol cyclic washing, is placed at 90 DEG C of thermostatic drying chambers and is dried to constant weight, obtains anti-mildew bactericidal agent, wherein, mixesThe weight ratio of shell powdered carbon, silver nitrate, sodium borohydride is 900:15:2;
(3) take each component by formula, the deionized water of half amount is added to a mixing bowl, under linear velocity 15m/s, stir2 minutes, polyacrylate, silicone defoaming agent are added to a mixing bowl, continue stir 10 minutes, by inorganic pigment,The anti-mildew bactericidal agent that silica flour, propandiol butyl ether, step (2) obtain adds a mixing bowl, under linear velocity 27m/s, stirsWithin 40 minutes, until scraper plate fineness is 45-50 μ m, reduction linear velocity is to 14m/s, by epoxy silicone resin, tetrafluoro secondThe copolymer emulsion of alkene and ethene adds, and a mixing bowl stirs 5 minutes, and propane diols is added to a mixing bowl and remaining goingIonized water, is stirred to and is uniformly dispersed, and obtains having the water paint of self-cleaning, anti-mildew, sterilizing and air purification effect.
Self-cleaning property, anti-fungi performance, sterilization ability and the purification sky of coating prepared by embodiment 1-6 and comparative exampleGas performance is tested respectively, and wherein, comparative example is that publication number is the Chinese patent of CN103275543B.
Self-cleaning property test process is: each coating is coated on to glass surface, then glass surface is put into outdoorly, putPut after 3 days, 6 days and observe respectively glass surface situation, result as shown in Table 1:
Table 1
As can be seen from Table 1, the self-cleaning property of embodiment of the present invention 1-6 is significantly better than comparative example.
Anti-fungi performance is tested the control of mold effect of each coating with reference to GB/T18261-2000, test bacterial classification is black songMould, Trichoderma viride, test result is as shown in table 2:
Table 2
From table 2, the control of mold effect of embodiment of the present invention 1-6, apparently higher than comparative example, shows wellAnti-fungi performance.
Sterilization ability is tested the antibiotic rate of each coating with reference to HG/T3950-2007, test result is as shown in table 3:
Table 3
From table 3, the antibiotic rate of embodiment of the present invention 1-6, apparently higher than comparative example, shows good sterilizingEnergy.
The negative ion concentration that the performance that purifies air produces each coating with reference to GB/T18809-2002 is tested, testResult is as shown in table 4:
Table 4
From table 4, the negative ion concentration that embodiment of the present invention 1-6 produces, apparently higher than comparative example, shows veryGood air cleaning performance.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention. Any ripeThe personage who knows this technology all can, under spirit of the present invention and category, modify or change above-described embodiment.Therefore, have in technical field under such as and conventionally know that the knowledgeable is not departing from disclosed spirit and technological thoughtLower all completed equivalences are modified or change, and must be contained by claim of the present invention.
Claims (10)
1. the water paint with self-cleaning, anti-mildew, sterilizing and air purification effect, is characterized in that: by weight, made by following component: 20～30 parts of organic siliconresins, water-base fluorocarbon emulsion 20～30 parts, 0.4～0.9 part of coalescents, 30～35 parts, water, 0.5～1 part of dispersant, defoamer 0.1～0.6 part, 1～1.5 part of levelling agent, 10～15 parts of pigment, 8～14 parts of fillers, anti-mildew bactericidal agent 7～8 parts;
The described water paint with self-cleaning, anti-mildew, sterilizing and air purification effect is by following steps system:
(1) the coffee bean shell that is 3:1 by mass ratio, ginkgo shell are pulverized with pulverizer, after grindingThe shell powder that is 1mm to particle diameter, adds by shell powder the phosphoric acid solution that the concentration of 2 times of weight is 55%, stirsEvenly, soak 24 hours, put into microwave reactor, logical nitrogen protection, microwave power is 800W conditionLower carbonization obtains carbonized material in 20 minutes, and carbonized material is put into tube type resistance furnace, is warming up to 750 DEG C, withTime pass into carbon dioxide with the speed of 180mL/min, after 40 minutes take out, in being washed with distilled water toProperty, after drying, grind and obtain mixed shell powdered carbon;
(2) mixed shell powdered carbon step (1) being obtained is added to the water ultrasonic agitation 2 hours, water-bathBe heated to 50 DEG C, adding concentration is that the liquor argenti nitratis ophthalmicus constant temperature of 1mol/L stirs 4 hours, drips in 1 hourAdding concentration is the sodium borohydride solution of 0.6mol/L, continues to stir 4 hours, uses recirculated water after taking-upFormula vavuum pump suction filtration, with deionized water, absolute ethyl alcohol cyclic washing, is placed in 90 DEG C of thermostatic drying chambersUnder be dried to constant weight, obtain anti-mildew bactericidal agent, wherein, mixed shell powdered carbon, silver nitrate, sodium borohydrideWeight ratio be 900:15:2;
(3) take each component by formula, the water of half amount is added to a mixing bowl, under linear velocity 15m/sStir 2 minutes, dispersant, defoamer added to a mixing bowl, continue stir 10 minutes, by pigment,The anti-mildew bactericidal agent that filler, coalescents, step (2) obtain adds a mixing bowl, linear velocity 27m/sLower stirring 40 minutes, until scraper plate fineness is 45-50 μ m, reduces linear velocity to 14m/s, by organosiliconResin, water-base fluorocarbon emulsion add, a mixing bowl stir 5 minutes, by levelling agent add a mixing bowl andRemaining water, is stirred to and is uniformly dispersed, and obtains having self-cleaning, anti-mildew, sterilizing and air purification effectWater paint.
2. the water with self-cleaning, anti-mildew, sterilizing and air purification effect according to claim 1Property coating, is characterized in that: described organic siliconresin is epoxy silicone resin.
3. the water with self-cleaning, anti-mildew, sterilizing and air purification effect according to claim 1Property coating, is characterized in that: described water-base fluorocarbon emulsion is the copolymer emulsion of tetrafluoroethene and ethene。
4. the water with self-cleaning, anti-mildew, sterilizing and air purification effect according to claim 1Property coating, is characterized in that: described coalescents is propandiol butyl ether.
5. the water with self-cleaning, anti-mildew, sterilizing and air purification effect according to claim 1Property coating, is characterized in that: described water is deionized water.
6. the water with self-cleaning, anti-mildew, sterilizing and air purification effect according to claim 1Property coating, is characterized in that: described dispersant is polyacrylate.
7. the water with self-cleaning, anti-mildew, sterilizing and air purification effect according to claim 1Property coating, is characterized in that: described defoamer is silicone defoaming agent.
8. the water with self-cleaning, anti-mildew, sterilizing and air purification effect according to claim 1Property coating, is characterized in that: described levelling agent is propane diols.
9. the water with self-cleaning, anti-mildew, sterilizing and air purification effect according to claim 1Property coating, is characterized in that: described pigment is inorganic pigment.
10. according to claim 1 have self-cleaning, anti-mildew, sterilizing and an air purification effectWater paint, is characterized in that: described filler is silica flour or barium sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511000649.4A CN105585955B (en) | 2015-12-28 | 2015-12-28 | Water paint with self-cleaning, anti-mildew, sterilizing and air purification effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511000649.4A CN105585955B (en) | 2015-12-28 | 2015-12-28 | Water paint with self-cleaning, anti-mildew, sterilizing and air purification effect |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105585955A true CN105585955A (en) | 2016-05-18 |
| CN105585955B CN105585955B (en) | 2017-10-31 |
Family
ID=55925871
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511000649.4A Active CN105585955B (en) | 2015-12-28 | 2015-12-28 | Water paint with self-cleaning, anti-mildew, sterilizing and air purification effect |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105585955B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624227A (en) * | 2018-06-04 | 2018-10-09 | 合肥语林装饰工程有限公司 | A kind of environment-friendlywater-based water-based paint capable of purifying air and preparation method thereof |
| CN109897470A (en) * | 2019-04-10 | 2019-06-18 | 中建七局第二建筑有限公司 | A kind of multiple-effect building wall coating and preparation method thereof |
| CN109971225A (en) * | 2017-12-28 | 2019-07-05 | 东莞市广信知识产权服务有限公司 | A kind of novel architecture water-repellent paint |
| CN110274170A (en) * | 2018-03-12 | 2019-09-24 | 常熟卓辉光电科技股份有限公司 | A kind of toilet's lamps and lanterns with sterilizing and self-cleaning function |
| CN110760240A (en) * | 2019-11-07 | 2020-02-07 | 安徽阜南县向发工艺品有限公司 | Wooden floor surface antibacterial coating and preparation method thereof |
| CN114058265A (en) * | 2022-01-18 | 2022-02-18 | 国能投(北京)智慧能源科技有限公司 | Water-based inorganic nano-composite silicon resin anticorrosive paint and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007095454A2 (en) * | 2006-02-10 | 2007-08-23 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Carbon-encased metal nanoparticles and sponges, methods of synthesis, and methods of use |
| CN102407340A (en) * | 2011-04-18 | 2012-04-11 | 中国人民解放军总后勤部军需装备研究所 | Preparation method of micro powder with silver/carbon nuclear shell structure |
| CN102993946A (en) * | 2012-12-11 | 2013-03-27 | 天津灯塔涂料工业发展有限公司 | Waterborne fluorine silicone resin modified acrylic acid concrete protective coating |
| CN103275543A (en) * | 2013-05-02 | 2013-09-04 | 洛阳理工学院 | Preparation method of aqueous paint for degradation of formaldehyde gas and toluene gas |
| CN104725945A (en) * | 2015-03-24 | 2015-06-24 | 湖州国信物资有限公司 | Novel high-temperature-resistance waterborne fluorocarbon coating and preparation method thereof |
-
2015
- 2015-12-28 CN CN201511000649.4A patent/CN105585955B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007095454A2 (en) * | 2006-02-10 | 2007-08-23 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Carbon-encased metal nanoparticles and sponges, methods of synthesis, and methods of use |
| CN102407340A (en) * | 2011-04-18 | 2012-04-11 | 中国人民解放军总后勤部军需装备研究所 | Preparation method of micro powder with silver/carbon nuclear shell structure |
| CN102993946A (en) * | 2012-12-11 | 2013-03-27 | 天津灯塔涂料工业发展有限公司 | Waterborne fluorine silicone resin modified acrylic acid concrete protective coating |
| CN103275543A (en) * | 2013-05-02 | 2013-09-04 | 洛阳理工学院 | Preparation method of aqueous paint for degradation of formaldehyde gas and toluene gas |
| CN104725945A (en) * | 2015-03-24 | 2015-06-24 | 湖州国信物资有限公司 | Novel high-temperature-resistance waterborne fluorocarbon coating and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109971225A (en) * | 2017-12-28 | 2019-07-05 | 东莞市广信知识产权服务有限公司 | A kind of novel architecture water-repellent paint |
| CN110274170A (en) * | 2018-03-12 | 2019-09-24 | 常熟卓辉光电科技股份有限公司 | A kind of toilet's lamps and lanterns with sterilizing and self-cleaning function |
| CN108624227A (en) * | 2018-06-04 | 2018-10-09 | 合肥语林装饰工程有限公司 | A kind of environment-friendlywater-based water-based paint capable of purifying air and preparation method thereof |
| CN109897470A (en) * | 2019-04-10 | 2019-06-18 | 中建七局第二建筑有限公司 | A kind of multiple-effect building wall coating and preparation method thereof |
| CN110760240A (en) * | 2019-11-07 | 2020-02-07 | 安徽阜南县向发工艺品有限公司 | Wooden floor surface antibacterial coating and preparation method thereof |
| CN114058265A (en) * | 2022-01-18 | 2022-02-18 | 国能投(北京)智慧能源科技有限公司 | Water-based inorganic nano-composite silicon resin anticorrosive paint and preparation method thereof |
| CN114058265B (en) * | 2022-01-18 | 2022-04-01 | 国能投(北京)智慧能源科技有限公司 | Water-based inorganic nano-composite silicon resin anticorrosive paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105585955B (en) | 2017-10-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105585955A (en) | Water-based coating with self-cleaning, anti-mildew, sterilization and air purification functions | |
| CN104629548B (en) | A kind of interior wall coating and preparation method thereof with air-cleaning function | |
| CN105400239B (en) | A kind of preparation method of modifying super hydrophobicity silica | |
| CN110183880B (en) | Photocatalytic super-amphiphobic coating and preparation method and application thereof | |
| CN107141992B (en) | A kind of super-hydrophobic transparent coating liquid and preparation method thereof | |
| CN102989436A (en) | Coating with antibacterial and air-purifying functions | |
| CN102277051B (en) | A kind of TiO 2light-catalyzed zero-VOC interior wall latex coatings | |
| CN101955697A (en) | Ceramic non-stick coating with bacteriostasis action and coating method thereof | |
| CN109880470B (en) | Preparation method of water-based acrylate time-delay antibacterial coating | |
| CN110093101B (en) | Paint for cosmetic packaging bottle and preparation method and coating process thereof | |
| CN105131672A (en) | Scrubbing-resistant anti-microbial inner wall emulsion paint | |
| CN110982307A (en) | Ecological shell powder interior wall coating and preparation method thereof | |
| CN107497450B (en) | A kind of compound bismuth tantalate photochemical catalyst and its preparation method and application | |
| CN110003749B (en) | High-efficiency photocatalytic coating | |
| CN106495510B (en) | A kind of nano-TiO with photo-catalysis function2/ Zeolite modifying cement and preparation method thereof | |
| CN110437682A (en) | A kind of ordor removing is except formaldehyde composite coating and preparation method thereof | |
| CN110358437A (en) | A kind of high-performance environment-friendly water paint and preparation method thereof | |
| CN104151871B (en) | A kind of porous surface modified nano-titanium dioxide and preparation method thereof | |
| CN104028245B (en) | A kind of have modified nano-titanium dioxide of better adsorption effect and preparation method thereof | |
| CN102702798B (en) | Modified silica filler and preparation method thereof | |
| CN111040605A (en) | Multifunctional single-component water-based interior wall paint and preparation method thereof | |
| CN111808481A (en) | Monoatomic algae-killing and sterilizing water tank coating and preparation method thereof | |
| CN106957563B (en) | A kind of coating | |
| CN111073485A (en) | Single-component water-based antibacterial interior wall paint and preparation method thereof | |
| CN103865336A (en) | Photocatalyst paint doped with zinc oxide and titanium dioxide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240415 Address after: 528000 No. 101 and 201, building 7, Shunde Leliu Photoelectric Industrial Center, No. 85, Lianfu 1st Road, Chonghe village committee, Leliu sub district office, Shunde District, Foshan City, Guangdong Province Patentee after: Guangdong Longfen Chemical Co.,Ltd. Country or region after: China Address before: 310000 room 504, unit 2, building 126, Banshan sanjiatang, Gongshu District, Hangzhou City, Zhejiang Province Patentee before: HANGZHOU MINGJIANG BUILDING DECORATION ENGINEERING Co.,Ltd. Country or region before: China |
|
| TR01 | Transfer of patent right |