CN107709601A - Metal substrate and the deposition mask using the metal substrate - Google Patents
Metal substrate and the deposition mask using the metal substrate Download PDFInfo
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- CN107709601A CN107709601A CN201580080724.4A CN201580080724A CN107709601A CN 107709601 A CN107709601 A CN 107709601A CN 201580080724 A CN201580080724 A CN 201580080724A CN 107709601 A CN107709601 A CN 107709601A
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- hole
- deposition mask
- metallic plate
- surface hole
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/12—Organic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
- C23C14/042—Coating on selected surface areas, e.g. using masks using masks
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/042—Coating on selected surface areas, e.g. using masks using masks
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/02—Local etching
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/164—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using vacuum deposition
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/166—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using selective deposition, e.g. using a mask
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Electroluminescent Light Sources (AREA)
- Physical Vapour Deposition (AREA)
Abstract
Embodiments of the present invention are related to a kind of mask structure for the depositing operation for being applicable to organic luminescent device etc., and allow to provide a kind of deposition mask, and the deposition mask includes:First surface and second surface, the first surface and second surface are orthogonal and facing with each other in the thickness direction of metallic plate;And multiple unit holes, multiple unit holes have through first surface and second surface and the first surface hole and second surface hole that communicate with each other, wherein, the change in size in the first surface hole between adjacent cells hole or second surface hole is controlled within 2% to 10% based on the change in size between optional unit hole, or the center in first surface hole and second surface hole are centrally disposed on by center misaligned position each other based on the surface of first surface.
Description
Technical field
Embodiments of the present invention, which are related to the metallic plate for the depositing operation for being applicable to organic luminescent device and used, is somebody's turn to do
The mask structure of metallic plate.
Background technology
In the manufacturing process of organic electroluminescent (EL) color monitor including organic EL luminescent devices, pass through vacuum
Depositing operation forms the organic layer including organic material.In this case, it is used for the pattern with organic layer
The deposition mask in multiple holes for penetration material of matching.Generally, can by metallic film apply photoresistance film come
By performing the lithography solution of etch process or by after sheet glass is electroplated with desired pattern after exposing patterns
The electrical forming scheme of execution hierarchical process forms the hole of deposition mask to be formed.
Conventional deposition mask is embodied as the form of common metal mask.However, the side for common metal mask
Case concentrates merely on the open area accurately realized for deposition.However, by such scheme, do not improve deposition efficiency and
The effect in the dead band for being not subjected to deposition is reduced without significantly generation.
The content of the invention
[technical problem]
Embodiments of the present invention be in order to solving the above problems and make and a kind of deposition mask can be provided, should
Deposition mask have adjust unit adjacent to each other it is deposited microporous between uniformity and perform can after depositing operation
Prevent the color spot of organic luminescent device (OLED) panel and the structure of moire fringes (Moire).
In addition, another embodiment of the present invention can provide a kind of deposition mask, the deposition mask can be by by structure
It is arranged so that center and second table in first surface hole into the first surface hole in the unit hole for deposition and second surface hole
The center of face is mismatched to improve deposition efficiency, and can minimize the dead band for being not subjected to depositing operation in deposition,
So as to can also improve the uniformity of deposition in the deposition target of large area.
Especially, a kind of metal substrate can be provided, the metal substrate makes in the gold to that will be manufactured into deposition mask
Category plate is occurred minimizing twisting when being etched.Furthermore, it is possible to being realized based on metal substrate is included for the multiple of deposition
The deposition mask in unit hole.In addition, by controlling the roughness in the unit hole of deposition mask to increase deposition efficiency.
[technical scheme]
In order to solve these problems, can provide according to the embodiment of the present invention a kind of including the metallic plate with thickness
Deposition mask.The metallic plate can include first surface and second surface and multiple unit holes, wherein, first surface and
Perpendicular to the direction of thickness and opposite each other, multiple unit holes have a first surface hole and second surface hole on two surfaces, and first
Surface holes and second surface hole are formed through first surface and second surface to be connected to each other.In unit adjacent to each other
The dimension difference in first surface hole or second surface hole between hole can be in the dimension difference between arbitrary unit hole
Within 10%.
In addition, a kind of the heavy of metallic plate for including there is thickness (t) can be provided according to another embodiment of the present invention
Product mask.Metallic plate can include first surface and second surface and multiple unit holes, wherein, first surface and second surface
Perpendicular to the direction of thickness and opposite each other, multiple unit holes have be formed through first surface and second surface with
The first surface hole and second surface hole being connected to each other.Metallic plate can include at least one unit hole, wherein, first surface hole
The center in center and second surface hole mismatched on the surface of first surface.
In addition, a kind of gold for including the base metal plate with thickness can be provided according to another embodiment of the invention
Belong to substrate.Base metal plate is included perpendicular to thickness direction and reciprocal first surface and second surface.From base metal
At the specified point of plate extract size be 30mm × 180mm (width × length) sample substrate, and to sample substrate except
Inside beyond two inside 10mm in end (part 220) of sample substrate 200 is etched so that forms thickness pair
Should be in the etching area of the 2/3 to 1/2 of sample substrate thickness.Then, when sample substrate is arranged on horizontal target surface, sample
The distortion index (Hr) of product substrate meets following relation.
[formula 1]
Hr={ (H1-Ha) 2+ (H2-Ha) 2+ (H3-Ha) 2+ (H4-Ha) 2 } 1/2
[formula 2]
Ha=(H1+H2+H3+H4)/4
(Ha refers to distance H1, H2, H3 and the H4's at four angles from horizontal target surface to the sample substrate etched
Average value).In addition, it can be provided by using the metallic plate for meeting above-mentioned distortion index (Hr) a kind of including more for what is deposited
The deposition mask in individual unit hole.
[advantageous effects]
According to the embodiment of the present invention, the uniformity between the regulation unit hole for being used to deposit adjacent to each other and
After performing depositing operation, the color spot and moire fringes of oled panel can be prevented.
In addition, according to another embodiment of the present invention, by the way that the first surface hole in the unit hole for depositing will be formed
It is arranged so that the center in first surface hole mismatches with the center in second surface hole with second surface hole, it is heavy so as to improve
Product efficiency.Furthermore it is possible to minimize the dead band for being not subjected to depositing operation in deposition process, so as to even in the deposition of large area
The uniformity of deposition can also be improved in target.
In addition, according to the embodiment of the present invention, a kind of metal substrate can be provided so as to deposition will be manufactured into
What is occurred when the metallic plate of mask is etched is minimizing twisting.
Especially, realized when based on metal substrate according to the embodiment of the present invention including multiple units for depositing
During the deposition mask in hole, the distortion of deposition mask can be substantially reduced so that deposition uniformity and deposition efficiency can be maximum
Change.
In addition, according to another embodiment of the present invention, when can based on metal substrate according to the embodiment of the present invention
When including the deposition mask for the multiple unit holes deposited to realize, the table for the inner circumferential surface for controlling unit hole can be passed through
Surface roughness increases deposition efficiency and deposition uniformity.
Brief description of the drawings
Fig. 1 is the schematic diagram for the mode of operation for showing the deposition mask according to embodiment of the present invention.Fig. 2 is schematically
The sectional view of the major part of deposition mask according to embodiment of the present invention is shown.
Fig. 3 is the plan for the second surface for showing the deposition mask in the structure according to Fig. 2 of embodiment of the present invention.
Fig. 4 is the plan for the first surface for showing the deposition mask in the structure according to Fig. 2 of embodiment of the present invention.
Fig. 5 is the plane for showing first surface hole and second surface hole when from the second surface in Fig. 4 structure
Figure.
Fig. 6 is shown in the central axis and second surface hole according to the arrangement first surface hole of embodiment of the present invention
The schematic diagram of the mode of mandrel line.
Fig. 7 is the schematic diagram for showing to determine the mode at the center in Fig. 6 first surface hole.
Fig. 8 is the deposition for schematically showing multiple unit holes including Fig. 2 according to third embodiment of the present invention
The sectional view of mask.
Fig. 9 is the sectional view for schematically showing the deposition mask according to another embodiment of the present invention.
Figure 10 is to schematically show wherein to have Fig. 9 first surface hole being connected to each other and the unit in second surface hole
The sectional view in hole.
Figure 11 is the partial view for showing wherein to have a part for the first surface in the first surface hole for realizing Figure 10.
Figure 12 is the view for showing arithmetic average roughness (Ra).Figure 13, which is shown, explains 10 points of height of nao-and micro relief
(Rz) image.
Figure 14 to Figure 16 is the view of the measurement and the definition that show the linearity according to the present invention.
Figure 17 and Figure 18 is the schematic diagram for the feature for showing metal substrate according to the embodiment of the present invention.
Embodiment
Hereinafter, the configuration according to the present invention and operation be will be described in detail with reference to the accompanying drawings.Referring to the drawings carry out with
In lower description, regardless of figure number, identical element will omit allocated identical reference to similar elements
Repeated description.Term " first " and " second " are used to explain various elements.Element can not be limited by term.Term is only used for area
Divide an element and another element.
1. first embodiment
Fig. 1 is the schematic diagram for the mode of operation for showing the deposition mask according to embodiment of the present invention.Fig. 2 is schematically
The sectional view of the major part of deposition mask according to embodiment of the present invention is shown.
Referring to Figures 1 and 2, can be in the base portion of such as sedimentary origin S glass according to the deposition mask of embodiment of the present invention
Deposition target T is realized on material G, wherein, deposition mask is used as the organic layer for being embodied as being formed Organic Light Emitting Diode (OLED)
Mask structure.In this case, deposition mask (M) 100 is realized as the structure with multiple unit holes.Unit hole can
To be realized as the first surface hole 110 and second surface hole 130 that there is mutually different width, be connected to each other.
Specifically, similar to Fig. 2 structure, metallic plate, the gold are included according to the deposition mask 100 of embodiment of the present invention
Category plate has predetermined thickness and including vertical with thickness direction while reciprocal first surface and second surface.Deposition is covered
Film 100 includes multiple unit holes, and unit hole has the first surface hole being connected to each other simultaneously through first surface and second surface
110 and second surface hole 120.In this case, first surface hole 110 and second surface hole 130 share boundary member 120,
First surface hole 110 and second surface hole 130 are connected to each other by boundary member 120.Provide multiple unit holes.Especially,
According to the embodiment of the present invention, the size between unit hole adjacent to each other in terms of first surface hole or second surface hole is poor
Value can be implemented as within the 10% of the size difference being between arbitrary unit hole.In other words, the of adjacent unit hole
Dimension difference between one surface holes or second surface hole can have the first surface in a unit hole at arbitrfary point
Larger value or less value within the 1% to 10% of the size in hole or second surface hole.Size between adjacent cells hole
Difference can be realized more preferably in the range of 2% to 8%.
In such a case, it is possible to based between first surface hole adjacent to each other or second surface hole adjacent to each other
Difference in diameter contrasts the dimension difference between unit hole adjacent to each other.
In other words, Fig. 3 is the second surface for showing the deposition mask in the structure according to Fig. 2 of embodiment of the present invention
Plan.Fig. 4 is the plane for the first surface for showing the deposition mask in the structure according to Fig. 2 of embodiment of the present invention
Figure.
Reference picture 3, when any entity of the realization to multiple unit holes in the second surface hole of second surface (below
In, be referred to as " datum hole ") vertical direction diameter Cy and horizontal direction diameter Cx when measuring, the hole adjacent with datum hole
(total of six hole as depicted) in terms of the vertical direction diameter Cy between difference be embodied as being within 10%.
In addition, datum hole and another hole adjacent with datum hole in the horizontal direction in terms of diameter Cx between difference can be with
It is implemented as being less than 10%.In other words, when the dimension difference between the hole adjacent with a datum hole is realized as being less than 10%
When, it can be ensured that deposition uniformity.If the dimension difference between datum hole and adjacent holes is in heavy to improve within 10%
Long-pending uniformity, then difference or datum hole between datum hole and another adjacent holes are in terms of the vertical direction diameter Cx with it is another
Adjacent holes in the horizontal direction in terms of diameter Cx between deviation can be preferably in the range of 1% to 10% or 2% to 8%
In the range of, so as to improve deposition uniformity.On the contrary, when all holes are realized as identical size, it is being subjected to depositing
In the oled panel of technique, moire fringes may be occurred with higher possibility.When the size difference between hole adjacent to each other exceedes
The size of datum hole 10% when, can make to be subjected to cause the possibility of color spot to increase in the oled panel of deposition mask.
First surface hole of the above-mentioned standard similarly suitable for Fig. 4 realization the first surface of metallic plate.First
Difference between surface holes and adjacent holes in terms of the vertical direction diameter By and in terms of horizontal direction diameter Bx can be implemented as
Within 10%, wherein, first surface hole is used as arbitrary datum hole.In addition, it is highly preferred that dimension difference can be implemented as 1%
Bigger value or smaller value in the range of to 10%.It is highly preferred that the dimension difference between datum hole and adjacent holes can be real
Now be 2% to 8% in the range of.
In addition, according to the embodiment of the present invention, the dimension difference between datum hole and adjacent holes can be realized at ± 3 μm
Within.
For example, in figure 3, the vertical direction diameter Cy of datum hole can be 36 μm, and the diameter of adjacent holes can be
33 μm or 39 μm, it is ± 3 μm to represent difference.In this case, the diameter deviation percentage between datum hole and adjacent holes becomes
For 8.3%, i.e. the dimension difference between datum hole and adjacent holes is embodied as within 10% of the size in datum hole, so as to
Improve deposition efficiency.
In another example in figure 3, the horizontal diameter Cx of datum hole is 125 μm, the diameter of adjacent holes can be at 122 μm or 128
In the range of μm.In this case, deviation percent is changed into 2.4%.Therefore, the dimension difference between adjacent holes and reference bore
It is embodied as within 10% in datum hole size, so as to improve deposition efficiency.
Fig. 5 is the first surface hole 110 and second surface hole 130 for showing Fig. 4 structure when from second surface
Plan.When the dimension difference between above-mentioned hole be any projection of the outer surface based on hole to calculate when, from second surface
Outer surface towards second surface hole center protrude the width Y1 of projection or the height X1 of projection be preferably implemented
It is less than 20 μm into maximum.The projection corresponds to the defects of occurring substantially in depositing operation structure.According to the reality of the present invention
Mode is applied, projection is realized as, with 20 μm of size, therefore ensuring that deposition uniformity.Especially, according to the implementation of the present invention
Mode, above-mentioned projection can be realized as the size with 11 μm or smaller of size, further 6 μm or smaller.
2. second embodiment
Hereinafter, by the structure referring to figs. 1 to Fig. 5 descriptions according to the deposition mask of another embodiment of the present invention.
Fig. 6 is central axis and the second surface hole for showing arrangement first surface hole according to the embodiment of the present invention
The schematic diagram of the mode of central axis.
There can be the feature of first embodiment according to the structure of second embodiment.However, in the following description, it is
The purpose of explanation, the structure with the feature of second embodiment are implemented separately.
According to second embodiment, as illustrated in fig 2 and fig.Deposition mask is with including with specific thicknesses and multiple
The structure of the metallic plate in unit hole, wherein, multiple unit holes have the first surface and second for being formed through metallic plate
Surface and the first surface hole and second surface hole being connected to each other.In this regard, deposition mask has and first embodiment
Structure identical structure.
In this case, deposition mask has following feature:The center F in first surface hole 110 and second surface hole 130
Center E can be mismatched each other in the surface observation on first surface 110.In other words, the center in first surface hole
Mismatched each other with the center in second surface hole so that the center in first surface hole and the center in second surface hole do not weigh each other
Close.
When in the center and second surface hole such as the first surface hole described in second embodiment of the present invention
When the heart mismatches to cause the center in the center in first surface hole and second surface hole misaligned each other each other, as it ensure that more
High deposition uniformity and obtain superior benefit.
As shown in Figure 6, when in view of the spoke from the sedimentary origin (S) separated with the deposition mask with multiple unit holes
During firing angle, the deposition materials of sedimentary origin (S) are applied in the unit hole of opening position different from each other.Therefore, deposition materials may
Unevenly transmitted.Therefore, according to the present invention, in order to improve deposition uniformity, each hole is implemented so that second surface
The central axis in hole and the central axis in first surface hole mismatch each other.Therefore, even in throughout the base with larger area
In the depositing operation performed in the whole surface of plate, deposition materials can also be transmitted equably, so as to improve deposition uniformity.This
Outside, even if when needing to increase deposit thickness, the structure also allows in the regional area or whole region throughout deposition target
Inside effectively adjust deposit thickness.
Wherein misaligned arrangement can be as follows each other at the center in the center in first surface hole and second surface hole
Structure, in the structure, when establishing the first table perpendicular to metallic plate at the center at the center in first surface hole or second surface
During the imaginary vertical line of face or second surface, imaginary vertical line extends only through the two of the center of first surface and the center of second surface
One of person.Therefore, the central axis of the central axis in first surface hole or second surface can mismatch each other.
In addition, in the center and second surface hole in the first surface hole limited second embodiment of the invention
The heart can refer to when the outer surface in first surface hole and second surface hole is circular or oval in circular or ellipse
The heart.The center of first surface and the center of second surface represent polygon in the outer surface in first surface hole and second surface hole
When can represent center of gravity.
Alternatively, as shown in Fig. 6 structure, even if plane hole has a case that the warp architecture of rounding in its corner
Under, when center of gravity is determined, center of gravity also serves as the center in plane hole.
In addition, on realizing the angle for having bending (according to the embodiment of the present invention, when tip being present in the outside of plane hole
When, tip is used as angle, and when the marginal portion with bending be present, the part with the curvature smaller than the curvature of surrounding is used as
Angle) in the case of plane hole center for, when being provided with the n angle with curvature and n is even number, by relative
The quantity of angle setting-out and line is changed into K.In this case, if the quantity K of line is three or two, three can be surrounded
The point-rendering circle that bar line or two lines intersect each other.Round center may be used as the center in plane hole.
Alternatively, if the quantity (n) at angle is odd number, angle and the side setting-out towards angle are passed through.Assuming that the quantity of line
For " k ", setting-out is untill the quantity (k) of line is 3 or 2.Then, the point that line intersects each other is used as the center in plane hole.
For example, Fig. 7 is the view for showing to determine the center F in Fig. 6 first surface hole 110 mode, wherein, the number of fillet
Amount is 4 (even numbers) altogether.Therefore, when another on the direction at another angle from a central point of curvature to being positioned at
When individual angle setting-out b1 and b2, the quantity (K) of line is two, and center F of the point as first surface hole that two lines are intersecting.
In addition, the center E in second surface hole 130 is determined in an identical manner, and unit hole is implemented so that center E
Mismatched each other with F.Especially, as shown in Figure 6, between the center F in first surface hole and the center E in second surface hole away from
From at least the 90% of the length A for the diameter that d can be realized as second surface hole, i.e. 0.9A.
In addition, the center F in first surface hole can be realized in this scope with the distance between the center E in second surface hole d
It is interior:Preferably the 50% or smaller of the length A of the diameter in second surface hole, more preferably 0.1%~10% scope, 0.2%
~8% scope or 0.2% or 5% scope.When the mismatch degree of the distance between central axis is realized as second
The length A of the diameter of surface holes at least 90% when, can further improve the uniformity of deposition efficiency.
In other words, when the length A of the diameter in second surface hole is 125 μm, the center (F) and second in first surface hole
The distance between the center (E) of surface holes (d) can be realized as at least 112.5 μm.
As described above, using deposition mask depositing operation in, due to all unit holes of sedimentary origin and mask not by
It is arranged on the bottom of vertical direction.Therefore, angle and bottom level more than special angle are needed to carry for each unit hole
Height is used for OLED deposition uniformity.
In this case, when using deposition mask according to the embodiment of the present invention, first surface hole and second
Surface holes are arranged to be mismatched each other, thus improves deposition efficiency.Further, since arrangement, it is possible to reduce performing
Dead band during depositing operation, and can also be obtained in depositing operation by increasing deposit thickness or the thick material of coating
Higher utilization rate.When depositing bigger area by OLED depositing devices, tensile force may increase.In this case,
When the position using first surface hole second embodiment of the invention and the position in second surface hole that
During this unmatched unit sectional hole patterns, tensile force is equally distributed.Thereby it can be assured that OLED deposition uniformity.
3. the 3rd embodiment
Hereinafter, another embodiment of the invention will be described.
Current 3rd embodiment can use the deposition described above by reference to first embodiment and second embodiment
Whole features of mask.However, in the following description, there is the structure quilt of the feature of the 3rd embodiment for illustrative purposes
Independently implement.
Fig. 8 is the deposition for schematically showing multiple unit holes including Fig. 2 according to third embodiment of the present invention
The profile of mask.
Reference picture 2 and Fig. 8, the metal with specific thicknesses is included according to the deposition mask of third embodiment of the present invention
Plate and metallic plate can include perpendicular to thickness direction and reciprocal first surface and second surface.In such case
Under, metallic plate includes multiple unit holes, and the plurality of unit hole has by being each passed through first surface and second surface to pass through side
The first surface hole 110 and second surface hole 130 that boundary part 120 is connected to each other and formed, wherein, boundary member 120 is through the
One surface holes 110 and second surface hole 130 are connected to each other.
Especially, unit hole can be realized in the following manner:The depth that first surface hole is formed on the thickness direction of metallic plate
Degree is different from the depth that second surface hole is formed on the thickness direction of metallic plate.In this case, based on boundary member 120
Outermost protruding point A1 to A21, by with second surface hole 130 and be subjected to depositing operation region be referred to as " effective coverage
(AC) ", wherein, first surface hole 110 and second surface hole 130 are connected to each other by boundary member 120.In addition, it will be not subjected to
The region of depositing operation is defined as non-active area (NC), wherein, the region is without second surface hole and is included in border
In the outermost protruding point A1 to A21 of part 120 Outboard Sections, first surface hole 110 and second surface hole 130 pass through side
Boundary part 120 is connected to each other.
In other words, reference picture 2 and Fig. 8, the unit hole in the AC of effective coverage can be implemented as structure described above, made
Obtain first surface hole 110 and be more than the depth " a " for arriving boundary member 120 in second surface hole 130 to the depth " b " of boundary member 120.
In addition, as entirety, unit hole can be implemented so as to the depth " a " in second surface hole and the integral thickness " c " of metallic plate
Between relation meet 1:3 to 30 scope.
According to the embodiment of the present invention, when the unit hole in structure is realized as different width and depth, second
An important factor for depth " a " of surface holes 130 is with deposit thickness is made adjustments.When the depth " a " in second surface hole 130 excessively increases
When, the depth in second surface hole 130 can exceed that above-mentioned thickness ratio model for the thickness " c " of whole base material
Enclose.In this case, the change of organic material thickness may increase, and thereby resulting in wherein can not deposit and cause the cause in dead band
Life problem.Dead band reduces the area of organic material in whole OLED, thus shortens the life-span.
Therefore, according to third embodiment of the present invention, the depth " a " in second surface hole 130 and the thickness " c " of metallic plate
Between ratio can meet 1 while above range is met:The ratio of (3.5 to 12.5).More specifically, can be by second
Ratio between the depth " a " of surface holes 130 and the thickness " c " of metallic plate is implemented as satisfaction 1:The ratio of (4.5 to 10.5).Root
According to embodiments of the present invention, meet that the thickness " c " of the metallic plate of above-mentioned ratio range can be implemented as being in 10 μm to 50 μm
In the range of.If the thickness of metallic plate is implemented as to be less than 10 μm, the degreeof tortuosity of base material increases, therefore excessively program control
System is difficult.If the thickness of base material, more than 50 μm, dead band increase is so that it may not be possible to real in subsequent deposition process
Existing OLED fine pattern.Especially, the thickness " c " of above-mentioned base material within the above range can be implemented as meeting
15 μm to the thickness in 40 μ ms.In addition, it is highly preferred that the thickness of base material can realize into the model in 20 μm to 30 μm
In enclosing.
Furthermore it is possible to the depth " a " corresponding to the second surface hole of the thickness of metallic plate " c " is preferably implemented into satisfaction
0.1 μm to 7 μm of scope.If the depth " a " in second surface hole is implemented as to be less than 0.1 μm, possibly hole can not be realized.Such as
The depth " a " in fruit second surface hole, due to the dead band in subsequent deposition process, it is fine possibly can not to form OLED more than 7 μm
Pattern, and the area of organic material may reduce so that and the OLED life-spans are likely to reduced.Especially, the depth in second surface hole
" a " can be implemented as in the range of within the above range 1 μm to 6 μm.It is highly preferred that the depth " a " in second surface hole can
To be embodied as being in the range of 2 μm to 4.5 μm.
It is contemplated that the inclination angle for the inner surface that deposition materials are introduced to first surface hole 110 as shown in Figure 2 is to enter one
Step improves deposition efficiency.
Due to using inclination angle theta when, inclination angle theta meets above range, therefore ensures that deposition uniformity, wherein, inclination angle theta pass through by
It is positioned at the outermost of first surface holes 110 of the outermost arbitrfary point A1 of boundary member 120 with being positioned at first surface
Arbitrfary point B1 connections and formed.If inclination angle exceedes or crossed the scope, the possibility increase in dead band is formed wherein, so as to
Make it difficult to ensure that the reliability of uniform deposition.According to the embodiment of the present invention, realized as in the range of inclination angle (θ)
Preferred embodiment, angle of inclination (θ) can be implemented as meeting 30 ° to 60 ° of scope, it is highly preferred that meeting 32 ° extremely
38 ° of scope or 52 ° to 58 ° of scope.
According to a kind of embodiment, make first by sharing the border surface between first surface hole and second surface hole
Surface holes and the structure that second surface hole is connected have the width in each hole towards in metallic plate in the structure in first surface hole
It is favourable to deposition efficiency during the feature that centre partly reduces.It is highly preferred that can be by the inner surface in the second hole or the first hole
It is implemented as the structure with curvature.Compared with simple incline structure, the structure with curvature can adjust introducing deposition materials
Density and deposition uniformity can be improved.
In addition, according to the embodiment of the present invention, the width C of the opening in a surface in second surface hole, border
The partial width A and width B of the open pore in apparent surface of first surface can have B>C>A ratio.This can
The density of deposition materials is introduced with regulation and deposition uniformity can be improved.Furthermore it is possible to by the one of second surface hole
Length difference (d=C-A) between the width " C " of opening in surface and the width " A " of boundary member is implemented as meeting 0.2 μm
To 14 μm of scope.
In other words, vertical distance d1 can meet to be in the range of 0.1 μm to 7 μm, wherein, vertical distance d1 is by fixed
Position the most external office on a surface in second surface hole arbitrfary point C1 and be positioned at the most external office of boundary member
Formed between the A1 of arbitrfary point.If vertical range d1 is less than 0.1 μm, possibly hole can not be realized.If vertical distance d1 is more than 7
μm, OLED fine patterns may not be formed due to the dead band in subsequent process, the area of organic material may reduce, from
And cause the OLED losts of life.In addition, according to the preferred embodiment in the number range of vertical distance d1 realizations, vertical distance
D1 is realized can be in the range of 1 μm to 6 μm, and more specifically, it is possible to achieve in the range of 2 μm to 4.5 μm.
In addition, according to the embodiment of the present invention, can be by second surface hole (or first surface hole) in a surface
The corner of opening be implemented as the structure with curvature.
As shown in Fig. 5 or Fig. 6, when consideration is exposed to the top surface in second surface hole 110 --- i.e., the one of base material
Individual surface --- open area horizontal cross sectional geometry when, horizontal cross sectional geometry can be implemented as to rectangular configuration or square
Structure.In that case it is preferable that the rounded feature for being embodied as there is specific curvature in each corner portion.
If the curvature of the rounded portion by extending corner is embodied as being in 5 μm and the virtual diameter of a circle R formed
To in the range of 20 μm, then it can further widen deposition region.Having the shape of angular bore portion may make it difficult to put down
Deposition process is performed suitablely and essentially forms dead band.Deposition efficiency increase in rounded feature.Especially, can be above-mentioned
Curvature in number range represents highest sedimentation rate and realizes uniform deposition.If diameter is less than 5 μm, deposition efficiency
May be with the structure without curvature without very big difference.More than 20 μm, if sedimentation rate may reduce diameter.Especially
Ground, according to the preferred embodiment in the range of diameter R, diameter R can be implemented as being in the range of 7 μm to 15 μm, and
More specifically, in the range of 8 μm to 12 μm.
Especially, according to the embodiment of the present invention, can be preferably by base material surface or opposite table
Surface roughness Ra on face realizes to be at most 2 μm, wherein, surface roughness Ra is used as the deposition quality for improving organic material
One factor.If surface roughness increases, the resistance moved for preventing mounting material along hole is produced.If surface roughness
Reach at least 2 μm, be then difficult to the deposition smoothed out, so as to produce the increase of the ratio in dead band.
4. the 4th embodiment
Hereinafter, it is proposed that according to the deposition mask of another embodiment of the present invention.According to first embodiment to
The technical characteristic of three embodiments can apply to current 4th embodiment.However, in the following description, for the mesh of explanation
The feature according to the 4th embodiment be performed individually.
According to the 4th embodiment, deposition mask includes the metallic plate with specific thicknesses and metallic plate can include hanging down
Directly in thickness direction and reciprocal first surface and second surface.In this case, metallic plate includes multiple unit holes,
Multiple unit holes have by be formed through first surface and second surface to be connected to each other by boundary member 120 the
One surface holes 110 and second surface hole 130, wherein, boundary member 120 by first surface hole 110 and second surface hole 130 that
This connection.
However, reference picture 9, the difference of Fig. 9 structure and the structure of the 3rd embodiment of the description of reference picture 8 exists
In:In the structure of deposition mask, the plate thickness in the AC of effective coverage is different from non-active area NC plate thickness,
Wherein, the structure of deposition mask includes the effective coverage AC with unit hole and the non-active area being arranged on outside the AC of effective coverage
Domain NC.
Especially, reference picture 9, according to the 4th embodiment, when metal of the consideration in the effective coverage with unit hole
During the maximum gauge h2 of the maximum gauge h1 of plate and the metallic plate in the non-active area outside effective coverage, by effective coverage
In the maximum gauge h1 of metallic plate be implemented as that there is the value smaller than the maximum gauge H2 of the metallic plate in non-active area.
In this case, the maximum gauge h1 of the metallic plate in effective coverage is defined as to the thickness direction along metallic plate of metallic plate
Prominent most long projection (hereinafter referred to as " projection ";G1 the maximum in thickness).
In such a case, it is possible to make the maximum gauge h2 of the metallic plate in non-active area and the metal in effective coverage
The maximum gauge h1 of plate relation meets 0.2h1<h2<1.0h1.Furthermore, it is possible to maximum gauge h2 is implemented as meeting to include
0.2h1 in above range<h2<0.9h1.
The maximum gauge h1 of metallic plate in effective coverage can be implemented as to the maximum of the metallic plate in non-active area
The 20% to 100% of thickness h 2.In addition, within the above range, maximum gauge h1 can be formed as to have maximum gauge h2's
25% to 85% thickness, it is further 30% to 60% thickness with maximum gauge h2.For example, when in non-active area
Maximum gauge h2 when being 30 μm, the maximum gauge h1 of the metallic plate in effective coverage can be implemented as 6 μm to 27 μm, 7.5 μm
To 25.5 μm or 9 μm to 18 μm.
Above-mentioned number range can increase deposition efficiency by adjusting the slope (inclination angle) in first surface hole.If drop
The height of low effective coverage, then angle of deposit is can easily be ensured that and controls, so that realizing high-resolution sink
Product mask.
Figure 10 is to schematically show the unit hole that wherein there is Fig. 9 first surface hole and second surface hole to be connected to each other
Sectional view.Reference picture 9 and Figure 10, as described above, in order to especially ensure angle of deposit, it may be considered that from being arranged on metallic plate table
The inclination for the line that one point of the opening in first surface hole or second surface hole in face extends to the predetermined point on boundary member
Angle.In such a case, it is possible to the slope realized from a point on the long axis of opening to boundary member is implemented as difference
In the slope from a point on minor axis to boundary member.
Specifically, the first tiltangleθ 1 is implemented as it is different from the second tiltangleθ 2, wherein, the first tiltangleθ 1 is from sudden and violent
A point being exposed on the long axis of the first surface hole 110 on the surface of metallic plate or the opening in second surface hole 130 extends to
The angle of the line of the predetermined point on boundary member 120 between first surface hole and second surface hole, the second tiltangleθ 2
It is to be extended to from a point on the minor axis of the first surface hole on the surface of metallic plate or the opening in second surface hole
The angle of the line of a point on boundary member 120 between first surface hole and second surface hole.In other words, can be with
Different slopes can be realized on the same inner surface in first surface hole or second surface hole.According to present embodiment, especially
Ground, the first tiltangleθ 1 is implemented as to be less than the second tiltangleθ 2.In this case, the first tiltangleθ 1 can be realized
In the range of 20 ° to 80 °.When realizing different inclination angles in the same interior section in second surface hole (or first surface hole)
When, the uniformity of depositing member can be improved.
In addition, in the structure according to current 4th embodiment, can be in the effective coverage described towards reference picture 9
The structure with curvature is formed at the projection g1 of tip.If as discussed above, at the projection g1 of the tip towards effective coverage
Realization has curvature, then can effectively disperse the deposition materials introduced by first surface hole and introduce adjacent not same district
Domain.It is thus possible to improve deposition efficiency and deposition uniformity.Therefore, at projection g1 formed with curvature in the case of, by curvature
Radius R is embodied as 0.5 μm or bigger.If realizing that radius of curvature R is less than 0.5 μm, dispersion efficiency may reduce.
Additionally, in the structure according to current 4th embodiment, tension adjustment pattern HF can be by along metallic plate
Thickness direction etch figures(s) 9 shown in non-active area NC realize.Tension adjustment pattern HF can be implemented as having recessed
Groove pattern structure, wherein, the groove pattern structure is realized in the structure that metallic plate is not pierced.
Half-etched regions can be implemented as to have the thickness thinner than the thickness h 1 of metallic plate.This is in OLED deposition process
In be required when applying tension to the deposition mask in equipment for by making will focus on the tension force on effective coverage point
Dissipate to efficiently perform depositing operation, so that deposition materials have uniformity.
Especially, half-etched regions can be implemented as to 10% to 100% scope with the thickness h 1 in metallic plate
Interior thickness.In other words, the thickness h 3 of half-etched regions can be implemented as relative to the metallic plate in non-active area
Thickness h 1 and meet 0.1h1<h3<1.0h1 relation.The thickness of half-etched regions can be implemented as to the thickness in metallic plate
In the range of the 20% to 80% or 30% to 70% of the thickness h 1 of metallic plate in the thickness range of the 10% to 100% of h1.
For example, when metallic plate has 30 μm of thickness, the thickness of half-etched regions can be in the range of 3 μm to 27 μm
(in 10% to 90% thickness range of the thickness h 1 of metallic plate).In addition, in order to pass through the realization in thinner structure
Half-etched regions produce the effect of scattered tension force, can be implemented as half-etched regions in the range of 6 μm to 24 μm, it is
The 20% to 80% of the thickness of metallic plate, or be implemented as in the range of 9 μm to 21 μm, it is the 30% of the thickness of metallic plate
To 70%.
Figure 11 is the partial view for showing to realize a part for the first surface in the first surface hole for having Figure 10.Reference picture 10
And Figure 11, in the structure according to current 4th embodiment, multiple first surfaces are realized, wherein, first surface is and face
Surface relative raised g1 to the tip of above-mentioned effective coverage.Therefore, by the way that first surface to be implemented as to have different height
Degree, deposition spacing can be reduced in deposition process.In other words, can be by point Z1, Z2 and Z3 in Figure 11 structure
Highly it is implemented as different from each other.
5. the 5th embodiment
Hereinafter, the structure by description according to the deposition mask of another embodiment of the present invention.It is real according to the current 5th
Whole features of first to fourth embodiment can be had by applying the structure of mode.However, it will focus on independent realize according to the
The example for the structure that five embodiments are characterized carries out following description.
It will be retouched below by using the profile for the major part for showing the deposition mask according to embodiment of the present invention
State the feature of the 5th embodiment.
Specifically, metallic plate is included similar to Fig. 4 structure, deposition mask 100 according to the embodiment of the present invention, should
Metallic plate has predetermined thickness and including perpendicular to thickness direction while reciprocal first surface and second surface.Deposition
Mask 100 is included with the table of first surface hole 110 and second being connected to each other while through first surface and second surface
Multiple unit holes of face 130.In this case, first surface hole 110 and second surface hole 130 share boundary member 120,
First surface hole 110 and second surface hole 130 are connected to each other by boundary member 120.Unit hole is realized as being provided with multiple.
It is equal to or less than the 3rd roughness in such a case, it is possible to be implemented as having by unit hole in deposition mask
The roughness value of Ra3 roughness value, wherein, the 3rd roughness Ra 3 is the surface roughness of first surface 112.In other words,
The value of the value of first roughness Ra 1 of the first inner surface or the second roughness Ra 2 of the second inner surface 131 can be formed as
Value with less than the 3rd roughness Ra 3, wherein, the second inner surface 131 is the inner surface in second surface hole.[Ra3=(Ra2 or
Ra1)]
It is equal to or more than the first inner surface furthermore, it is possible to which the second roughness Ra 2 of the second inner surface 131 is formed as having
The value of 111 the first roughness Ra 1, wherein, the second inner surface 131 is the inner surface in second surface hole, and the first inner surface 111 is
The inner surface in first surface hole 110.[Ra2=Ra1].
If reference quantity or bigger is formed on the surface of this deposition mask realized with metal material (metal mask)
Roughness, then the linearity (Fig. 7 line roughness) in unit hole is exerted one's influence, the unit hole is to use when forming deposition mask
In the hole of deposition.Therefore, organic material can not be deposited smoothly.In addition, ought such as OLED organic material be deposited and so
When being cleaned afterwards, the cleaning capacity of organic material reduces so that may shorten the life-span of deposition mask.
, can be by the arithmetic average roughness Ra1 of the first inner surface and the arithmetic of the second inner surface according to present embodiment
Average roughness Ra 2 is implemented as 1.0 μm or smaller.If 0.08 μm within the above range is to 0.5 μm or 0.15 μm to 0.3
The mean roughness (Ra) of the first inner surface, the second inner surface and first surface is realized in the range of μm, then it is heavy to realize
Accumulate efficiency and increase reliability.
In this case, as shown in Figure 12, arithmetic average roughness Ra is expressed as roughness average (Ra), center
Line average value (CLA), arithmetic mean of instantaneous value (AA) and arithmetic average roughness Ra are by calculating the surface in the range of datum line
The height at peak and being obtained relative to the depth of datum line for paddy.In other words, as shown in Fig. 5 curve, relative to
The datum line (center line) for making the benchmark on the surface of measurement roughness represents roughness and calculated by arithmetic mean of instantaneous value.
In addition, in the another aspect of embodiments of the present invention, can be by the first inner surface of deposition mask, second
The value of 10 points of height (Rz) of nao-and micro relief of at least one of surface and first surface is implemented as 3.0 μm or smaller.In addition,
Can be 10 points high by the nao-and micro relief of at least one of the first inner surface, the second inner surface and first surface of deposition mask
The value of degree (Rz) is embodied as 2.5 or smaller, specifically, the scope 1.5 to 2.5 is embodied as while above range is met
It is interior, so as to improve deposition efficiency and increase reliability.
In this case, as shown in Figure 13,10 points of height (Rz) of nao-and micro relief can refer to be measured coarse
The surface roughness at 10 points around the datum line of the reference surface of the target surface of degree.
In addition, in deposition mask according to the embodiment of the present invention, can be by the outer of the unit hole that reference picture 2 describes
The line roughness (linearity for being referred to as unit hole) in footpath is implemented as 1.5 μm.Line roughness --- the i.e. straight line of the external diameter in unit hole
Degree --- as the index represented from datum line (center line) to the inclined degree of either side, wherein, the datum line is by drawing
The straight line extended from the central point of the external diameter in hole is formed.The farthest distance of distance center line is represented with linearity.
According to the embodiment of the present invention, measurement linearity is described into reference picture 14 to Figure 16.Figure 14 and Figure 15 are shown
The image of the true outward appearance in Fig. 2 first surface hole.Reference picture 14 and Figure 15, it is assumed that the minor axis of the opening in first surface hole and
Long axis are known respectively as " x " and " y ", can be by the total length of the y-axis measured only about the y-axis as long axis point
Into two, and the center of y-axis can be referred to as " y2 ".In this case, measured along the circumference of the external diameter of opening thick
Rugosity, while meet the scope from the distance of leftward or rightward 1.5 μm of center " y2 ", i.e. 3 μm of scope altogether.In such case
Under, measurement range is no more than 3 μm of scope.While 3 μm of scope is met, deposition according to the embodiment of the present invention
The linearity of mask can be realized as 1.5 μm or smaller.In other words, while 3 μm of measurement range is met, linearity
1.5 μm or smaller can be realized as.
6. the 6th embodiment
Hereinafter, description is being manufactured according to institute in the deposition mask of above-mentioned first embodiment to the 5th embodiment
The example of the metal substrate used.
Figure 17 and 18 is the schematic diagram for the feature for showing the metal substrate according to embodiment of the present invention.
Reference picture 17 and Figure 18, it can be enough to pass through etching by being implemented as having according to the metallic plate of embodiment of the present invention
Base metal plate with predetermined thickness manufactures the thickness of deposition mask.Furthermore it is possible to metallic plate is implemented as to make local torsion
It is bent or overall minimizing twisting.
Therefore, as shown in Figure 17, in the case of metallic plate according to the first embodiment of the invention, from base portion gold
Category plate extraction sample substrate 200 and etched sample substrate 200 realizes etching area 210 and non-etched areas 220, wherein,
Base metal plate has predetermined thickness in the whole part of metallic plate.(hereinafter, it is used for what is extracted from base metal plate
The substrate of etching be referred to as " sample substrate ", and by it is being extracted from base substrate and be not subjected to etching substrate be referred to as " unit base
Plate ").
In this case, base metal plate is included perpendicular to thickness direction and reciprocal first surface and the second table
Face.On base metal plate, the sample for being 30mm × 180mm (width × length) from the arbitrfary point of base metal plate extraction size
Substrate 200 and to the inside in addition to two inside 10mm in end (part 220) from sample substrate 200 of sample substrate
Perform etch process so that etching area 210 is implemented as 2/3 to 1/2 thickness with the thickness corresponding to sample substrate 200
Degree.Then, when sample substrate is arranged on horizontal target surface, the distortion index (Hr) for being subjected to the sample substrate of etching is full
It is enough lower relation.
Formula 1
Hr={ (H1-Ha) 2+ (H2-Ha) 2+ (H3-Ha) 2+ (H4-Ha) 2 } 1/2
Formula 2
Ha=(H1+H2+H3+H4)/4
(Ha refers to being averaged for distance H1, H2, H3 and H4 from horizontal target surface to four angles of institute's etched sample substrate
Value.)
Specifically, described below with reference to Fig. 1, Figure 17 and Figure 18 according to the metal substrate of embodiment of the present invention
Feature.
Generally, as shown in fig. 1, the deposition manufactured by using metal substrate according to the embodiment of the present invention is covered
Film is used as mask structure to realize OLED organic layer.Deposition mask is to be realized on the base portion G of such as sedimentary origin glass
Target T is deposited to provide deposition materials.In this case, deposition mask (M) 100 is implemented as to the knot with multiple unit holes
Structure.Generally, in order to improve the deposition uniformity in OLED depositions, deposition mask must keep uniform shape during deposition process
State.
However, substantially, in the case where metallic plate is etched away to manufacture deposition mask, the thickness of metallic plate significantly subtracts
It is small.If realizing multiple deposition holes in the metallic plate that thickness is substantially reduced, manufactured deposition mask easily distorts.Cause
This, in arrangement as shown in Figure 1,1, deposition uniformity can not be ensured.
Therefore, embodiments of the present invention, which can provide, can make the distortion as caused by metallic plate or in etching metal plate
Caused minimizing twisting metal substrate.
According to the manufacturing process of the metal substrate of the present invention, the sample that size is 30mm × 180mm is extracted from base substrate
Product substrate.
Hereafter, length be 180mm sample substrate in addition to the both sides 10mm of long axis, 1/2 to 2/3 sample base
Plate is subjected to etching.Then, the sample substrate for being subjected to etching is arranged on the i.e. such as surface plate in surface for ensuring flatness
When in target, height H1, H2, H3, the H4 at four angles of the sample substrate being spaced apart with reference plane are measured, wherein, reference plane is
The horizontal target surface of surface plate.
In this case, when height H1, H2, H3 and the H4 at four angles of the sample substrate being spaced apart with reference plane are equal to
Or during more than " 0 ", sample substrate is confirmed as distortion.Pass through the index represented with exponential form as shown in formula 1
(Hr) this degreeof tortuosity is represented.
Therefore, with the increase for distorting index Hr of sample substrate, the torsion resistance increase of substrate.According to the implementation of the present invention
Mode, when the non-etched sample substrate extracted to the predetermined point from base metal plate with 30mm × 180mm equidimensions (below
In, be referred to as " unit substrate ") with contrasted by the distortion index of the sample substrate etched when, by the sample base etched
The distortion index of plate is more than the distortion index of non-etched sample substrate.
In other words, it is the predetermined point from above-mentioned base metal plate having been described above is (wide with 30mm × 180mm
Degree × length) size extraction non-etched sample substrate (unit substrate) be arranged on horizontal target surface so that by for
The distortion index Hr (T1) of formula 1 and formula 2 extraction at substrate T1 four angles is equal to or less than from the extraction of base metal plate
And by the sample substrate T2 etched distortion index Hr (T2).This can be represented with below equation.
Formula 3
Hr (T1)=Hr (T2)
Especially, according to the embodiment of the present invention, the distortion index of sample substrate can be implemented as being equal to or less than
10.Therefore, if the thickness of base substrate is 20 μm, and if extraction and is etched sample substrate, then by etching
The thickness of sample substrate is implemented as 10 μm or smaller at four angles of sample substrate.
In other words, 10 or smaller will can be implemented as by the distortion index of the sample substrate etched, it is preferable that realize
Into the value in the range of 0.2 to 7 or 0.5 to 5., can be with if the distortion index of sample substrate is implemented as into 10 or smaller
Reduce the twisted phenomena when manufacturing final deposition mask.In addition, OLED lateral deviation reduces in OLED depositions, so as to
Improve deposition uniformity.
According to the embodiment of the present invention, in order to which the distortion index of sample substrate is implemented as into 10 or smaller, by base portion
Material, which is realized, can perform cooling technique and rolling mill practice during metallic plate.Once to base material at a temperature of 10 DEG C to 20 DEG C
After performing cooling technique, rolling mill practice can be performed.Rolling mill practice is performed to realize the metallic plate with desired thickness.
In this case, rolling degree is a key factor.In addition, relative to the unit volume at the predetermined point of base material
(1mm3), reduction ratio can be implemented as 2/3 to 1/5.
Figure 18 is shown when extracting sample substrate from metallic plate 200 according to the embodiment of the present invention and being etched
Distortion index view.As it is shown in the figures, four angles of sample substrate are spaced apart and away from water with horizontal target surface ST
At least one of distance H1 to H4 of flat target surface has the value different from Distance Remaining.In addition, in the short of sample substrate
The distance H1 and H2 or distance H3 and H4 of adjacent part on axis can be with different from each other.
In the case of metal substrate according to the embodiment of the present invention, deposition mask can be implemented as including having
First surface hole and multiple unit holes in second surface hole, wherein, first surface hole and second surface hole are formed through metal
The first surface and second surface of the etching area of plate are to be connected to each other.Especially, the deposition mask realized by this way can
To significantly decrease distortion so that deposition reliability can be realized.
Although the preferred embodiment of the present invention has been described for illustrative purposes, those skilled in the art will
It will be appreciated that in the case where not departing from the scope and spirit of the present invention as disclosed in appended claim, can carry out
Various remodeling, addition and replacement.
Claims (28)
1. a kind of deposition mask, including:
Metallic plate with thickness,
Wherein, the metallic plate includes:First surface and second surface, the first surface and the second surface are perpendicular to institute
State the direction of thickness and opposite each other;And multiple unit holes, the unit hole have first surface hole and second surface hole,
The first surface hole and the second surface hole are formed through the first surface and the second surface with each other
Connection, and
Wherein, the dimension difference in the first surface hole between unit hole adjacent to each other or the second surface hole, which is in, appoints
Within the 10% of the dimension difference anticipated between unit hole.
2. deposition mask according to claim 1, wherein, the dimension difference between the unit hole is formed so that
Dimension difference between this adjacent first surface hole or second surface hole adjacent to each other is within ± 3 μm.
3. deposition mask according to claim 2, wherein, between the first surface hole or between the second surface hole
Dimension difference be the first surface hole or the second surface hole the diameter formed in a first direction and described first
Surface holes or the diameter between the diameter being upwardly formed perpendicular to the second party of the first direction in the second surface hole
Difference.
4. deposition mask according to claim 1, wherein, the projection protruded from the outer surface in the second surface hole
Width or height have 20 μm of maximum.
5. a kind of deposition mask, including:
Metallic plate with thickness,
Wherein, the metallic plate is included perpendicular to the direction of the thickness and reciprocal first surface and second surface,
And multiple unit holes, the unit hole, which has, is formed through the first surface and the second surface to connect each other
The first surface hole and second surface hole connect, and
Wherein, the metallic plate includes at least one unit hole, at least one unit hole, the first surface hole
The center at center and the second surface hole mismatches on the surface of the first surface.
6. deposition mask according to claim 5, wherein, the center and the second surface in the first surface hole
The unmatched structure in the center in hole is by described from the center in the first surface hole and the second surface hole
Draw one of in the heart perpendicular to the metallic plate the first surface or the second surface surface it is virtual vertical
Line causes the virtual vertical line to be not passed through in the center in the first surface hole and the described of the second surface hole
The remaining one of the heart and formed.
7. deposition mask according to claim 5, wherein, the center and the second surface in the first surface hole
The distance between the center in hole (b) is equal to or less than the 0.9a of the length (a) of the diameter in the second surface hole.
8. deposition mask according to claim 5, wherein, the first surface hole between unit hole adjacent to each other or
The dimension difference in the second surface hole is within 10% of the dimension difference between arbitrary unit hole.
9. deposition mask according to claim 5, wherein, the direction constriction of the width in the unit hole along the thickness is extremely
Border surface as the tie point between the first surface hole and the second surface hole.
10. deposition mask according to claim 7, wherein, the first surface hole exposed to the first surface
The width of opening is more than the width of the opening exposed to the second surface in the second surface hole.
11. a kind of deposition mask, including:
Metallic plate with thickness,
Wherein, the metallic plate includes:First surface and second surface, the first surface and the second surface are perpendicular to institute
State the direction of thickness and opposite each other;And multiple unit holes, the unit hole, which has, is formed through described first
The first surface hole and second surface hole of surface and the second surface to be connected to each other, and
Wherein, the maximum gauge (h1) in the effective coverage with the unit hole of the metallic plate and the metallic plate
The maximum gauge (h2) being arranged in the non-active area of the outside of the effective coverage is different.
12. deposition mask according to claim 11, wherein, the metallic plate described in the effective coverage most
Big thickness (h1) is thinner than the maximum gauge (h2) in the non-active area of the metallic plate.
13. deposition mask according to claim 12, wherein, described in the non-active area of the metallic plate
The relation of maximum gauge (h2) and the maximum gauge (h1) in the effective coverage of the metallic plate meets 0.2h1<
h2<1.0h1。
14. deposition mask according to claim 12, wherein, by being lost on the direction of the thickness of the metallic plate
Carve and tension adjustment pattern is set in the non-active area.
15. deposition mask according to claim 14, wherein, the tension adjustment pattern is that metallic plate exists described in thickness ratio
The thin half-etched regions of the thickness (h1) in the non-active area.
16. deposition mask according to claim 15, wherein, thickness (h3) and the metallic plate of the half-etched areas
The relation of the thickness (h1) in the non-active area meets 0.1h1<h3<1.0h1.
17. deposition mask according to claim 11, wherein, from first table exposed to the surface of the metallic plate
A point on the long axis of the opening in face or the second surface hole is extended to positioned at the first surface hole and described the
First inclination angle of the line of a point on the boundary member between two surface holes with from exposed to the surface of the metallic plate
A point on the minor axis of the opening in the first surface hole or the second surface hole is extended to positioned at the first surface
Second inclination angle of the line of the point on the boundary member between hole and the second surface hole is different.
18. deposition mask according to claim 17, wherein, first inclination angle is less than second inclination angle.
19. deposition mask according to claim 18, wherein, first inclination angle is in the range of 20 ° to 80 °.
20. deposition mask according to claim 17, wherein, it is in the effective coverage of the metallic plate and from
Realize there is curvature at the first surface jut prominent to the second surface.
21. deposition mask according to claim 20, wherein, the curvature of the jut is equal to or more than 0.5 μm.
22. deposition mask according to claim 20, wherein, in each unit hole, in the first surface and institute
State and at least one different height is provided with the relative part of jut.
23. a kind of deposition mask, including:
Metallic plate including etching area and non-etched areas;
First surface hole, depth direction shape of the first surface hole from the first surface of the etching area along the metallic plate
Into;
Second surface hole, the depth side of the second surface hole from the second surface of the etching area along the metallic plate
It is connected to formation and the second surface hole relative to boundary member with the first surface hole;And
Each of multiple unit holes, the multiple unit hole have a pair of first surface holes being connected to each other and described
Second surface hole.
24. deposition mask according to claim 23, wherein, in the unit hole, the table as the first surface
The surface that the value of 3rd roughness (Ra3) of surface roughness is equal to or more than the first inner surface as the first surface hole is thick
Second roughness of the first roughness (Ra1) of rugosity and the surface roughness of the second inner surface as the second surface hole
(Ra2) (Ra represents the mean roughness of target surface).
25. deposition mask according to claim 24, wherein, second roughness (Ra2) is equal to or more than described the
One roughness (Ra1).
26. deposition mask according to claim 25, wherein, first inner surface, second inner surface and institute
(Ra) for stating first surface is equal to or less than 1.0.
27. deposition mask according to claim 26, wherein, first inner surface, second inner surface and institute
Stating first surface has the 10 points of height (Rz) of nao-and micro relief for being equal to or less than 3.0.
28. deposition mask according to claim 23, wherein, the first surface hole in the unit hole or described second
The opening of surface holes is with 1.5 μm of linearity.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911112607.8A CN110760793A (en) | 2015-04-24 | 2015-08-25 | Deposition mask |
CN201911112620.3A CN110923622B (en) | 2015-04-24 | 2015-08-25 | Deposition mask |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020150058346A KR102528582B1 (en) | 2015-04-24 | 2015-04-24 | Metal substrate and Mask using the same |
KR10-2015-0058346 | 2015-04-24 | ||
KR10-2015-0062137 | 2015-04-30 | ||
KR1020150062137A KR102590892B1 (en) | 2015-04-30 | 2015-04-30 | Mask for oled |
PCT/KR2015/008894 WO2016171337A1 (en) | 2015-04-24 | 2015-08-25 | Metal substrate, and deposition mask using same |
Related Child Applications (2)
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CN201911112620.3A Division CN110923622B (en) | 2015-04-24 | 2015-08-25 | Deposition mask |
CN201911112607.8A Division CN110760793A (en) | 2015-04-24 | 2015-08-25 | Deposition mask |
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CN107709601A true CN107709601A (en) | 2018-02-16 |
CN107709601B CN107709601B (en) | 2019-12-13 |
Family
ID=57144656
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CN201580080724.4A Active CN107709601B (en) | 2015-04-24 | 2015-08-25 | Metal substrate and deposition mask using the same |
CN201911112620.3A Active CN110923622B (en) | 2015-04-24 | 2015-08-25 | Deposition mask |
CN201911112607.8A Pending CN110760793A (en) | 2015-04-24 | 2015-08-25 | Deposition mask |
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CN201911112620.3A Active CN110923622B (en) | 2015-04-24 | 2015-08-25 | Deposition mask |
CN201911112607.8A Pending CN110760793A (en) | 2015-04-24 | 2015-08-25 | Deposition mask |
Country Status (4)
Country | Link |
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EP (2) | EP3993075A1 (en) |
JP (2) | JP7075214B2 (en) |
CN (3) | CN107709601B (en) |
WO (1) | WO2016171337A1 (en) |
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Also Published As
Publication number | Publication date |
---|---|
EP3993075A1 (en) | 2022-05-04 |
JP2018513918A (en) | 2018-05-31 |
EP3288097A1 (en) | 2018-02-28 |
CN110923622B (en) | 2021-12-03 |
CN110923622A (en) | 2020-03-27 |
CN107709601B (en) | 2019-12-13 |
EP3288097A4 (en) | 2019-05-15 |
JP7075214B2 (en) | 2022-05-25 |
JP2022068330A (en) | 2022-05-09 |
WO2016171337A1 (en) | 2016-10-27 |
CN110760793A (en) | 2020-02-07 |
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