CN107641284A - A kind of ABS composite material with long-acting mosquito-driving effect and preparation method thereof - Google Patents
A kind of ABS composite material with long-acting mosquito-driving effect and preparation method thereof Download PDFInfo
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- CN107641284A CN107641284A CN201710838078.4A CN201710838078A CN107641284A CN 107641284 A CN107641284 A CN 107641284A CN 201710838078 A CN201710838078 A CN 201710838078A CN 107641284 A CN107641284 A CN 107641284A
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Abstract
The present invention provides a kind of ABS composite material with long-acting mosquito-driving effect and preparation method thereof.Acrylonitrile butadient styrene resin composite materials with long-acting mosquito-driving effect are made up of 5 10 parts of 70 80 parts of emulsion polymerization ABS, 5 10 parts of ABS high glue powders, 5 10 parts of mineral powder, repellant or natural plant essential oils, 35 parts of coupling agent, 23 parts of lubricant, 0.2 0.3 parts of antioxidant.The obtained ABS composite material with long-acting mosquito-driving effect of the inventive method, it is tasteless or have light fragrance, meet masses and receive requirement, at the same have to the Common Mosquitoes such as yellow-fever mosquito, culex kind it is good expel effect, and there is good long-term effect.The functional application ability of material in use has been promoted, has improved the synthesis performance of product.Good mechanical property meets the use condition of daily material, improves resistant to damage ability of the product during impacting, fall, colliding with etc..
Description
Technical field
The present invention relates to technical field of macromolecules, and in particular to a kind of ABS composite material and its system of long-acting mosquito-driving effect
Preparation Method
Background technology
Mosquito is a kind of summer and autumn very common harmful insect, can propagate many diseases, influence health.Mosquito
There are three kinds of anopheles, culex and yellow-fever mosquito, different types of mosquito can propagate different diseases.Wherein, male mosquito is not sucked blood, and is planted with sucking
Thing juice is nutrition；Female mosquito typically starts to bite animal in more than 16 DEG C of temperature sucks blood.Harm of the mosquito to human body is, when
Pathogen can be transmitted to Healthy People by it after biting ill animal or human body.The disease of mosquitoes spread mainly has malaria, B-mode
Encephalitis, filariasis, dengue fever and yellow fever etc..For example, plasmodium falciparum, a kind of mosquito parasite, are caused more than 25%
The reason for children are dead after neonatal period.In some areas in Africa, by the World Bank, loss life years are adjusted in disability
Number aspect, malaria have ranked first.Therefore, in daily life, how effectively to carry out mosquito-prevention mosquito-repellent turns at present urgently
The problem of to be solved.
The content of the invention
Have that usage is single, and lasting effect is poor for existing mosquito repellent material, one of technical problems to be solved by the invention
It is to provide a kind of ABS composite material with long-acting mosquito-driving effect and preparation method thereof.
The technical scheme is that：A kind of ABS composite material with long-acting mosquito-driving effect, by following raw materials according by weight
Part composition：
Further scheme, described ABS resin are the high stir-in resin of emulsion method.
Further scheme, described ABS high glue powder glue content is 55-70%.
Further scheme, described mineral powder are porous material.
Further scheme, described mineral powder are mesoporous material (aperture is in 5-50nm).
Further scheme, described mineral powder particle diameter is at least more than 325 mesh.
Further scheme, described repellant are 1 octene -3- alcohol (Metadelphene (DEET)) or butyl acetylamino propionic acid second
At least one of ester (dimethyl phthalate (BAAPE)).
Further scheme, described natural plant essential oils are citronella oil, Lavender, yesterday at least one in essential oil
Kind.
Further scheme, described coupling agent are common commercially available silane coupler.
Further scheme, described lubricant are ethylene bis stearamide (EBS).
Further scheme, described antioxidant are that Hinered phenols master resists and the auxiliary anti-compounding of phosphorous acid esters.
A kind of preparation method of ABS composite material with long-acting mosquito-driving effect of the present invention, processing include following
Step：
(1) mineral powder is added in high-speed mixer, opens high-speed mixer；
(2) coupling agent is proportionally added to high-speed mixer by the atomizing sprayer above high-speed mixer
In, 60-80 DEG C of mixing 3-5 minute, open high-speed mixer deflation and be cooled to room temperature；
(3) by repellant or natural plants plants essential oil by the atomizing sprayer above high-speed mixer proportionally
It is added in high-speed mixer, mixes 3-5 minutes；
(4) ABS resin, ABS high glue powders, lubricant, antioxidant are proportionally added in mixer, stirring at low speed 2-
5 minutes；
(5) by the mixture obtained by (4) in double screw extruder extruding pelletization, wherein screw combinations are weak group in being
Close, 200-220 DEG C of temperature, screw speed 350-400RPM, vacuum ＜ -0.06MPa.
The present invention has the advantages that：
1st, compared with traditional ABS and its alloy, the composite can obtain the mosquito-proof effect of good mosquito repellent.
2nd, the processing characteristics of alloy is substantially improved using high efficiency composition heat stabilizer, composite antioxidant and lubricant.
3rd, using porous material and suitable coupling agent, intermolecular force is enhanced, obtains good long-term effect.
The obtained ABS composite material with long-acting mosquito-driving effect of the inventive method, it is tasteless or have light fragrance, accord with
Close masses and receive requirement, while there is the good effect that expels to the Common Mosquitoes such as yellow-fever mosquito, culex kind, and with well long-acting
Property.The functional application ability of material in use has been promoted, has improved the synthesis performance of product.Good mechanics
Performance meets the use condition of daily material, improves resistant to damage ability of the product during impacting, fall, colliding with etc..
Embodiment
To be best understood from the present invention, with reference to embodiment, the invention will be further described, and following examples are only pair
The present invention illustrates rather than it is limited.
Embodiment one：
A kind of ABS composite material with long-acting mosquito-driving effect is made up of by weight following raw materials according in the present embodiment：
Embodiment two
Embodiment three
Above-mentioned formula is prepared as follows respectively：
(1) mineral powder is added in high-speed mixer, opens high-speed mixer；
(2) coupling agent is proportionally added to high-speed mixer by the atomizing sprayer above high-speed mixer
In, 60-80 DEG C of mixing 3-5 minute, open high-speed mixer deflation and be cooled to room temperature；
(3) by repellant or natural plants plants essential oil by the atomizing sprayer above high-speed mixer proportionally
It is added in high-speed mixer, mixes 3-5 minutes；
(4) ABS resin, ABS high glue powders, lubricant, antioxidant are proportionally added in mixer, stirring at low speed 2-
5 minutes；
(5) by the mixture obtained by (4) in double screw extruder extruding pelletization, wherein screw combinations are weak group in being
Close, 200-220 DEG C of temperature, screw speed 350-400RPM, vacuum ＜ -0.06MPa.
By the phase of above-described embodiment one, two obtained ABS composite material and common ABS material with long-acting mosquito-driving effect
Closing physical index, according to relevant examination criteria to test its mechanical property as shown in table 1：
Table 1：The performance test results of ABS composite material and ABS-8391 with long-acting mosquito-driving effect
From above table, composite has good mechanical property, especially impact property, improves product and exists
Resistant to damage ability during impacting, fall, colliding with etc..
In addition, embodiment one and comparative example by test one, embodiment two, embodiment three and comparative example by test two,
The long-acting mosquito-driving effect of ABS composite material of the present invention is separately verified.
Test an evaluation method：
(1) laboratory temperature should be adjusted before testing as 28-30 DEG C, and whole process is tested under this temperature conditions, to carry
The activity of high mosquito.
(2) before testing, enough samples are heated into 15min in 80 DEG C of baking oven using closed bottle, to accelerate sample
The volatilization of middle anophelifuge substance.
(3) sample is taken out, is positioned in culture dish that (diameter is as big as possible, facilitates sample drawout, beneficial to waving for smell
Hair).It is placed in experiment square chest, volatilizees naturally as early as possible.Meanwhile some mosquitoes are added to experiment glass or plastics square chest
In.
(4) after adding mosquito 20min, arm is extend into experiment square chest by experimenter, observes after 3min
Mosquito populations and statistics on experimenter's arm, each experiment statisticses number are 6 times.
Test two evaluation methods：
(1) laboratory temperature should be adjusted before testing as 28-30 DEG C, and whole process is tested under this temperature conditions, to carry
The activity of high mosquito.
(2) before testing, sample is heated into 15min in 80 DEG C of baking oven using closed bottle, to accelerate mosquito repellent in sample
The volatilization of material.
(3) sample is taken out, is placed on 100g or so samples in the culture dish of suitable size as early as possible, and be positioned over pipe just
It is middle.
(4) vavuum pump is opened, (air velocity is controlled regulation air velocity by ball valve made of plastic, not influence mosquito just
Often fly and be defined and record ball valve switch position.Subsequent experimental is carried out with identical air velocity), after being evacuated 10min, from remote
One end from bleeding point adds some mosquitoes.
(5) every the mosquito populations and statistics in 10min, observation sample both sides plastic tube, experiment statisticses number is 6 times
(60min)。
Test a result：
Test two results：
Blank sample (ABS-8391)
Embodiment two
Embodiment three
Test a result to show, under same experimental conditions, fall in the composite unit interval of the present invention in tester
Mosquito populations on arm significantly reduce, and illustrate that material has to mosquito and significantly walk quickly and keep away effect.
Test two results to show, under same experimental conditions, mosquito populations distribution in blank sample both sides is essentially identical, and this hair
The mosquito distribution of bright two kinds of composite both sides has obvious orientation, illustrates that material has to mosquito and significantly walks quickly and keeps away effect.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the model of the present invention
Enclose and be defined, on the premise of design spirit of the present invention is not departed from, technical side of the those of ordinary skill in the art to the present invention
The various modifications and improvement that case is made, it all should fall into the protection domain of claims of the present invention determination.
Claims (12)
- A kind of 1. ABS composite material with long-acting mosquito-driving effect, it is characterised in that：It is made up of by weight following raw materials：ABS resin 70-80 parts,ABS high glue powder 5-10 parts,Mineral powder 5-10 parts,Repellant or natural plant essential oils 5-10 parts,Coupling agent 3-5 parts,Lubricant 2-3 parts,Antioxidant 0.2-0.3 parts.
- 2. the ABS composite material according to claim 1 with long-acting mosquito-driving effect, it is characterised in that：Described ABS trees Fat is the high stir-in resin of emulsion method.
- 3. the ABS composite material according to claim 1 with long-acting mosquito-driving effect, it is characterised in that：Described ABS is high Rubber powder glue content is 55-70%wt.
- 4. the ABS composite material according to claim 1 with long-acting mosquito-driving effect, it is characterised in that：Described mineral Powder is porous material.
- 5. the ABS composite material according to claim 4 with long-acting mosquito-driving effect, it is characterised in that：Described mineral Powder is mesoporous material.
- 6. the ABS composite material according to claim 4 with long-acting mosquito-driving effect, it is characterised in that：Described mineral Powder footpath is at least more than 325 mesh.
- 7. the ABS composite material according to claim 1 with long-acting mosquito-driving effect, it is characterised in that：Described repellent Agent is at least one of 1 octene -3- alcohol or butyl acetylamino ethyl propionate.
- 8. the ABS composite material according to claim 1 with long-acting mosquito-driving effect, it is characterised in that：Described is natural Plants essential oil is citronella oil, yesterday Lavender, at least one of essential oil.
- 9. the ABS composite material according to claim 1 with long-acting mosquito-driving effect, it is characterised in that：Described coupling Agent is common commercially available silane coupler.
- 10. the ABS composite material according to claim 1 with long-acting mosquito-driving effect, it is characterised in that：Described lubrication Agent is ethylene bis stearamide.
- 11. the ABS composite material according to claim 1 with long-acting mosquito-driving effect, it is characterised in that：Described antioxygen Agent is that Hinered phenols master resists and the auxiliary anti-compounding of phosphorous acid esters.
- 12. prepare the method for the ABS composite material with long-acting mosquito-driving effect described in any one of claim 1 ~ 11, its feature It is：Processing comprises the following steps：（1）Mineral powder is added in high-speed mixer, opens high-speed mixer；（2）Coupling agent is proportionally added in high-speed mixer by the atomizing sprayer above high-speed mixer, 60- 80 DEG C of mixing 3-5 minutes, open high-speed mixer deflation and be cooled to room temperature；（3）Repellant or natural plants plants essential oil are proportionally added by the atomizing sprayer above high-speed mixer Into high-speed mixer, 3-5 minutes are mixed；（4）ABS resin, ABS high glue powders, lubricant, antioxidant are proportionally added in mixer, 2-5 points of stirring at low speed Clock；（5）Will（4）The weak combination in being of resulting mixture extruding pelletization in double screw extruder, wherein screw combinations, temperature Spend 200-220 DEG C, screw speed 350-400RPM, vacuum ＜ -0.06MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710838078.4A CN107641284A (en) | 2017-09-18 | 2017-09-18 | A kind of ABS composite material with long-acting mosquito-driving effect and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710838078.4A CN107641284A (en) | 2017-09-18 | 2017-09-18 | A kind of ABS composite material with long-acting mosquito-driving effect and preparation method thereof |
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| CN107641284A true CN107641284A (en) | 2018-01-30 |
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| CN201710838078.4A Pending CN107641284A (en) | 2017-09-18 | 2017-09-18 | A kind of ABS composite material with long-acting mosquito-driving effect and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110540697A (en) * | 2018-05-28 | 2019-12-06 | 佛山市顺德区美的电热电器制造有限公司 | Household appliance component and preparation method thereof |
| CN112063044A (en) * | 2020-08-19 | 2020-12-11 | 上海金发科技发展有限公司 | Flame-retardant polypropylene composition capable of preventing pet from biting and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747582A (en) * | 2008-11-27 | 2010-06-23 | 中国第一汽车集团公司 | Modified ABS automobile special material and production method thereof |
| CN103524887A (en) * | 2013-09-27 | 2014-01-22 | 广东聚石化学股份有限公司 | Flame-retardant air conditioner filter screen material with long-acting antibacterial and mosquito repelling effects |
-
2017
- 2017-09-18 CN CN201710838078.4A patent/CN107641284A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747582A (en) * | 2008-11-27 | 2010-06-23 | 中国第一汽车集团公司 | Modified ABS automobile special material and production method thereof |
| CN103524887A (en) * | 2013-09-27 | 2014-01-22 | 广东聚石化学股份有限公司 | Flame-retardant air conditioner filter screen material with long-acting antibacterial and mosquito repelling effects |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110540697A (en) * | 2018-05-28 | 2019-12-06 | 佛山市顺德区美的电热电器制造有限公司 | Household appliance component and preparation method thereof |
| CN112063044A (en) * | 2020-08-19 | 2020-12-11 | 上海金发科技发展有限公司 | Flame-retardant polypropylene composition capable of preventing pet from biting and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: High tech Zone Hefei city Anhui province 230088 City Road No. 2 Applicant after: New material Limited by Share Ltd Address before: High tech Zone Hefei city Anhui province 230088 City Road No. 2 Applicant before: Hefei Orinko Plastics Group Co., Ltd. |
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| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180130 |