CN107638343A - A kind of sunscreen spray composition of the component of antiallergic containing plant - Google Patents

A kind of sunscreen spray composition of the component of antiallergic containing plant Download PDF

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Publication number
CN107638343A
CN107638343A CN201710846269.5A CN201710846269A CN107638343A CN 107638343 A CN107638343 A CN 107638343A CN 201710846269 A CN201710846269 A CN 201710846269A CN 107638343 A CN107638343 A CN 107638343A
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composition
component
antiallergic
sunscreen spray
spray composition
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CN201710846269.5A
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CN107638343B (en
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练英铎
杜送英
陶叶强
雷楚屏
彭春燕
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Opal Cosmetics Huizhou Co Ltd
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Opal Cosmetics Huizhou Co Ltd
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Abstract

The present invention relates to cosmetic field, discloses a kind of sunscreen spray composition of the component of antiallergic containing plant, comprises the following raw materials by weight percent and form:The ethanol 53 65% of 280 20 32%, 330 400nm wavelength UV absorbers of 330nm wavelength UV absorbers 3 7%, acrylic acid(Ester)/ octylacrylamido 1.3 2.3%, volatility grease 4 8%, Genes For Plant Tolerance sensitive composition 0.1 2.5%, deionized water 1 6%.Said composition overcomes the defects of prior art, and skin-friendly is not stimulated while having reached high sun-proof value.

Description

A kind of sunscreen spray composition of the component of antiallergic containing plant
Technical field
The present invention relates to cosmetic field, and in particular to a kind of sunscreen spray composition of the component of antiallergic containing plant.
Background technology
As atmosphere pollution causes depletion of the ozone layer, the ultraviolet increase on ground is reached;People's living standard improves simultaneously, Particularly Asia consumer is rung with Bai Weimei traditional aesthetic viewing, sun-proof pay attention to day by day of the people to skin.Investigation result shows Show, consumer is to sun-proof class cosmetics demand growth, to sun-proof value(Spf value and PA values)It is expected to increase.Special outdoor exercises and The sun-proof value of swimming crowd trend selection is higher, has the anti-sweat function of waterproof, uses more easily spray-type products.In order to meet The market demand, prior art generally have following several method:First, the chemically or physically UV absorbents of high content are added, to carry High sun-proof result.However, the chemical UV absorbing agent of high content generally increases skin irritatin or allergy risk, and it is easily caused skin Feel greasy.The usual skin sense of high content physical UV filters is hardened dry and astringent.2nd, patent " 201010002536.9 a kind of sun-proof gas Mist agent and its device, method " has the effect of increase film forming agent is to reach anti-MJPZ, but its spreadability and quality of forming film do not have Being optimal, to skin sense, the anti-sweat of waterproof, sun-proof result lifting not being optimal, the kinds of ingredients used is to sensitive flesh Skin is unfriendly.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of sunscreen spray composition of the component of antiallergic containing plant, overcome The defects of above-mentioned prior art, while having reached high sun-proof value skin-friendly is not stimulated.
The technical problems to be solved by the invention are achieved by the following technical programs:
A kind of sunscreen spray composition of the component of antiallergic containing plant, including following components in percentage by weight:
280-330nm wavelength UV absorber 20-32%,
330-400nm wavelength UV absorbers 3-7%
Ethanol 53-65%,
Acrylic acid(Ester)/ octylacrylamido 1.3-2.3%,
Volatility grease 4-8%,
Genes For Plant Tolerance sensitive composition 0.1-2.5%,
Deionized water 1-6%.
The proportion of ethanol 53-65% can have an appropriate film forming speed, and film forming is more uniformly distributed and stably.
The acrylic acid(Ester)/ octylacrylamido is 1.3-2.3% as film forming agent ratio, present invention combination Thing uses the lysotype system more relaxed and comfortable compared with emulsification system, while also needs the requirement for meeting the anti-sweat of waterproof, thus exclude water decide it is molten The selection of agent, exclude water-soluble film forming agent.By being screened to oil-soluble film forming agent, alcohol-soluble film forming agent, alcohol-soluble film forming is found Agent to alcohol solution system spray-type products performance more preferably.Described acrylic acid(Ester)Class/octylacrylamido dissolves for alcohol Film forming agent, ratio 1.3-2.3%.In this proportion into film hardness will not too high while uniformity it is preferable, film is in skin Surface is firmly, persistently.It can cause into that film hardness is too high, and film-forming flexibility is poor more than 2.5% dosage.Consumer is when skin body moves Film rupture can be caused, bits are played, come off, so as to cause the reduction of design function or forfeiture;It is simultaneously high into film hardness, film-forming flexibility Difference, a bits, feeling of grittiness can be experienced with poor skin sense.Film forming agent dosage is less than 1%, causes film forming imperfect, equally reduces film forming Quality.
The volatility grease is poor less than 4% spreadability, good higher than 8% spreadability, but film forming uniformity can't be after Continuous increase.
Described deionized water ratio 1-6%, the skin sense that this can be simultaneously with water profit.
Further, described 280-330nm wavelength UV absorbers are selected from ethylhexyl methoxy cinnamate, Losec is stood Woods, ethylhexyl salicylate, Homosalate, p- methoxycinnamates isoamyl valerate, PARSOL 500, ethylhexyl three At least three kinds in piperazine ketone, OXYBENZONE.
Further, described 330-400nm wavelength UV absorbers be selected from double ethyl hexyl oxy phenol anisyl triazines, At least one of di-2-ethylhexylphosphine oxide BTA base tetramethyl butyl phenol, Uvinul A Plus.As UV absorbents are supplemented, strengthen the absorption to the ultraviolet of different wave length, improve the sun-proof result of the present invention.
Further, described volatility grease is selected from trisiloxanes, the poly- trimethicone of methyl, boiling point 200- 250 DEG C of cyclomethicone, boiling point are 180-240 DEG C of dimethyl silicone polymer, and boiling point is 170-240 DEG C of hydrogenation At least one of polyisobutene, the isoparaffin of 170-240 DEG C of boiling point.
Further, the sunscreen spray composition of the component of antiallergic containing plant also includes emollient, NMF, perfume (or spice) At least one of essence, preservative, conditioner, account for the 0.2-5% of composition total weight.It is conventional other this areas can also to be contained Additive such as chelating agent etc..
Further, this contains the sunscreen spray composition of plant antiallergic component using normal pressure spray packaging or pressure volume pot Packaging.
Further, when being packed using pressure volume pot, gas-filling is less than 67 saturated alkane using relative molecular weight Gas, gas weight:The ratio of this composition weight is 20-60:40-80.
Further, described Genes For Plant Tolerance sensitive composition is made up of following weight percent composition:Radix scutellariae root extract 20%th, windproof root extract 8%, purple common perilla seed 6%, peony root extractive 6%, glycyrrhiza glabra root extract 6%, centella carry Take thing 5%, ginger-root extract 4%, butanediol 45%.Using the Chinese medicine antiallergic composition of special proportioning, to human body, close friend is non-stimulated, Sensitive skin can be improved.
A kind of preparation technology of described Genes For Plant Tolerance sensitive composition, using microwave radiation heating means carry plant Take, Extraction solvent used is butanediol, microwave frequency is 3 × 105~3 × 106Hz, microwave power are 650W~850W.
The preparation method of the sunscreen spray composition of the component of antiallergic containing plant of the present invention, which is that this area is conventional, matches somebody with somebody Put and hybrid technology, do not elaborate herein.
After applying above-mentioned technical proposal, the present invention has the advantages that:
UV absorbent molecular polarities are larger, and molecule is inclined to form cluster because of strong polarization.Cluster molecular arrangement is applying it Cloth surface easily forms isolated island, causes to sprawl uneven, and molecule absorbs effective area to UV to be reduced, and absorption efficiency reduces.By The technology of skin surface film forming brings following benefit:When film forming agent can fix smearing under friction force drawout UV molecules, Reduce the effect of molecule cluster.Reflection, scattering of the film to light simultaneously adds the light path of light in the film, causes film layer pair The increase of UV light absorbs dosage, the UV light dosages of skin surface are reached through film to be reduced.Pass through skin so as to reach reduction UV light Skin absorptivity, improve sun-proof result.The present invention can cross screen and optimize UV absorbents in spray-type, grease and different categories into Film matches, and not only improves quality of forming film, and find that fast filming can band additional benefit by contrasting.By optimizing each component Proportioning, reach optimal film forming speed and quality of forming film to lift sun-proof result, be embodied as:
1. one kind of the present invention contains acrylic acid(Ester)The component of antiallergic containing plant of class/octylacrylamido it is sun-proof Spray composite, by limiting UV absorbents, volatility grease, ethanol, acrylic acid(Ester)Class/octylacrylamido, Deionized water portfolio ratio, fast filming effect can be provided, film forming is uniform, and fastness is good, and persistence is good.
2. the sunscreen spray composition of the component of antiallergic containing plant of the present invention, optimized by the selection to film forming agent, Effectively increase sun-proof value(Spf value and PA values).
3. the present invention with the addition of the plant antiallergic composition of uniqueness, influence of the composition system to skin condition is reduced, is not drawn Rise allergic, while synergy has been carried out to sun-proof result.
Embodiment
The present invention is described in further detail with reference to test example and embodiment.But this should not be understood Following embodiment is only limitted to for the scope of the above-mentioned theme of the present invention, it is all that this is belonged to based on the technology that present invention is realized The scope of invention.
Except as otherwise noted, all percentage, number and ratio are based on the content weight meter related to ingredients listed.
By being screened to oil-soluble film forming agent, alcohol-soluble film forming agent, find alcohol-soluble film forming agent to alcohol solution system aerosol type Properties of product are more preferably.When product is sprayed on skin, body temperature quickly volatilizees by ethanol causes the quick conjunctiva of alcohol-soluble film forming agent.Alcohol UV absorbent of the soluble film layer under by water and residual is influenceed smaller, therefore can reach preferable effect.Pass through the embodiment of table 1 Illustrate with comparative example.
Table 1:The percentage of weight formula of embodiment and comparative example
Above-described embodiment and comparative example are used《Cosmetics safety technical specification》(Version in 2015)Middle method carries out human body SPF surveys Examination, test result are as follows:
Embodiment 1 Comparative example 1 Comparative example 2
Human body SPF test results 32 16 12
The present invention reaches good by screening and optimizing ethereal oil lipid species and dosage, the dosage of film forming agent, ethanol consumption Spreadability and quality of forming film, so as to lift skin sense, the anti-sweat effect of waterproof, sun-proof result.Said by the embodiment and comparative example of table 2 It is bright.
Table 2:The percentage of weight formula of embodiment and comparative example
The quality of forming film and skin appraisal method of product are as follows:
Sample pretreatment:3 square centimeters of PMMA are dipped vertically into sample 5 seconds, then taken out, lie against 30 ± 1 DEG C, humidity 55 5 minutes are separately dried in ± 5% environment
Film forming Evaluation for Uniformity:By pretreatment sample, with Optometrics 290, sun-proof tester test sample is ultraviolet in vitro Light(290-400nm)Every plate of absorbance takes 9 test points, and each test point produces an absorption curve, according to 9 curves Degree of fitting it is better, then it is more preferable to be judged as into film uniformity.5 grades are divided to be scored in an experiment.The best person of degree of fitting is 5 Point.
Film layer firmness is evaluated:Pretreatment sample is put on shake frost sieve, is shaken 40 minutes.With the bodies of Optometrics 290 Outer tester test sample shakes ultraviolet light after preceding and vibrations(290-400nm)Trap and calculate the spf value of sample And PA values.Spf value and the front and rear less person of reduction of PA values vibrations, then be judged as that film layer firmness is more preferable.In an experiment by spf value and PA values reduce percentage 5 grades of score and scored, and it is 5 points to reduce percentage those at least.
Film layer water-resistance is evaluated:Pretreatment sample is put into 28 ± 2 DEG C of water-baths, shakes 40 points on water-bath shake frost sieve Clock, take out sample and lie against 30 ± 1 DEG C, be separately dried in the environment of humidity 55 ± 5% 5 minutes.It is external with Optometrics 290 Before tester test sample water-bath and water-bath after ultraviolet light(290-400nm)Trap and calculate sample spf value and PA values.Spf value and the front and rear less person of reduction of PA values water-bath, then be judged as that film layer water-resistance is more preferable.Spf value and PA are pressed in an experiment Value reduces percentage 5 grades of score and scored, and it is 5 points to reduce percentage those at least.
Skin sense is evaluated:Organize 50 consumers(Women, 20-40 year)It is on probation, carry out preference degree scoring, preference degree soprano For 5 points.
Quality of forming film is carried out to embodiment in table 2 and comparative example in aforementioned manners and skin sense is evaluated, is drawn as shown in table 3 As a result.
Table 3:The filming performance and skin sense evaluation result of embodiment and comparative example in table 2
Assessment item Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Comparative example 3 Comparative example 4 Comparative example 5 Comparative example 6
Into film uniformity 5 5 5 5 3 4 3 4
Film layer firmness 5 5 5 5 3 4 3 4
Film layer water-resistance 4 5 5 5 4 4 3 4
Skin sense is evaluated 5 5 5 5 3 3 4 4
Above items total score 19 20 20 20 13 15 13 16
Sun-proof function is tested:SPF and PA test values in being tested using film layer water-resistance before and after water-bath, the result as shown in table 4.
Table 4:The sun-proof result of embodiment and comparative example is tested in table 2
Assessment item Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Comparative example 3 Comparative example 4 Comparative example 5 Comparative example 6
SPF before water-bath 40 42 35 35 35 35 32 35
SPF after water-bath 32.2 36 30.6 31 23 25 20 26
PA before water-bath 11 11 10.5 11 5 5 9.5 10
PA after water-bath 8.8 9.4 9.5 10 3.4 3.8 6 7.5
The present invention has chemiluminescence by adding Genes For Plant Tolerance sensitive composition to sun-proof value.Following table embodiment 6 is in embodiment 1 On the basis of with the addition of 0.8% Genes For Plant Tolerance sensitive composition of the present invention.
The embodiment 1 of table 5 and the percentage of weight formula of embodiment 6
Embodiment 1 and embodiment 6 are used《Cosmetics safety technical specification》(Version in 2015)Middle method carries out human body SPF and PA Test, test result are as follows:
Assessment item Embodiment 1 Embodiment 6
Internal test SPF 32 36
Internal test PA 9 11
Skin sense evaluation is carried out to embodiment 1 and embodiment 6:Organize 50 sensitive skin consumers(Women, 20-40 year)It is on probation, Preference degree scoring is carried out, preference degree soprano is 5 points.Test result is as follows:
Assessment item Embodiment 1 Embodiment 6
Skin sense is evaluated 3 5
The present composition can use normal pressure spray packaging and two kinds of manner of packings of pressure volume pot.The present composition uses When pressure volume pot is packed, gas-filling uses low molecule(Relative molecular weight is less than 67)Saturated alkane gas, due to compressed Saturated alkane gas liquefaction mixes with the present composition, can change the compatibility between composition.When the present composition is adopted When being packed with pressure volume pot, saturated alkane gas weight:This composition weight≤60:40.
By the above, contrast experiment has found, the spreading property of the present composition is good, and filming performance is good, improve skin sense, Water-resistance, sun-proof result;And by adding Genes For Plant Tolerance sensitive composition synergy sun-proof result.

Claims (9)

1. a kind of sunscreen spray composition of the component of antiallergic containing plant, it is characterised in that including following components in percentage by weight:
280-330nm wavelength UV absorber 20-32%,
330-400nm wavelength UV absorbers 3-7%
Ethanol 53-65%,
Acrylic acid(Ester)/ octylacrylamido 1.3-2.3%,
Volatility grease 4-8%,
Genes For Plant Tolerance sensitive composition 0.1-2.5%,
Deionized water 1-6%.
2. the sunscreen spray composition of the component of antiallergic containing plant according to claim 1, it is characterised in that described 280- 330nm wavelength UV absorbers be selected from ethylhexyl methoxy cinnamate, Octocrilene, ethylhexyl salicylate, Homosalate, At least three kinds in p- methoxycinnamates isoamyl valerate, PARSOL 500, Uvinul T 150, OXYBENZONE.
3. the sunscreen spray composition of the component of antiallergic containing plant according to claim 1, it is characterised in that described 330- 400nm wavelength UV absorbers are selected from double ethyl hexyl oxy phenol anisyl triazines, di-2-ethylhexylphosphine oxide BTA base tetramethyl fourth At least one of base phenol, Uvinul A Plus.
4. the sunscreen spray composition of the component of antiallergic containing plant according to claim 1, it is characterised in that described volatilization Property grease be selected from trisiloxanes, the poly- trimethicone of methyl, boiling point be 200-250 DEG C cyclomethicone, boiling point The Parleam for being 170-240 DEG C for 180-240 DEG C of dimethyl silicone polymer, boiling point, the isomery of 170-240 DEG C of boiling point At least one of alkane.
5. the sunscreen spray composition of the component of antiallergic containing plant according to claim 1, it is characterised in that described containing is planted The sunscreen spray composition of thing antiallergic component also includes at least one of emollient, NMF, essence, preservative, conditioner, Account for the 0.2-5% of composition total weight.
6. the sunscreen spray composition of the component of antiallergic containing plant according to claim 1, it is characterised in that this contains Genes For Plant Tolerance The sunscreen spray composition of quick component is packed using normal pressure spray or pressure volume pot packaging.
7. the sunscreen spray composition of the component of antiallergic containing plant according to claim 6, it is characterised in that held using pressure When device tank is packed, gas-filling is less than 67 saturated alkane gas, gas weight using relative molecular weight:This composition weight Ratio is 20-60:40-80.
8. the sunscreen spray composition of the component of antiallergic containing plant according to claim 1, it is characterised in that described plant Antiallergic composition is made up of following weight percent composition:Radix scutellariae root extract 20%, windproof root extract 8%, purple perilla seed extraction Thing 6%, peony root extractive 6%, glycyrrhiza glabra root extract 6%, Gotu Kola P.E 5%, ginger-root extract 4%, butanediol 45%.
9. the preparation technology of the Genes For Plant Tolerance sensitive composition described in a kind of claim 8, it is characterised in that heated using microwave radiation Method is carried out to plant extract, and Extraction solvent used is butanediol, microwave frequency is 3 × 105~3 × 106Hz, microwave power are 650W~850W.
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Publication number Priority date Publication date Assignee Title
CN101780014A (en) * 2010-01-14 2010-07-21 台州绿岛化妆品有限公司 Sun-blocking aerosol and device method thereof
CN104661638A (en) * 2012-07-26 2015-05-27 里曼贸易有限责任公司 Improved high protection sunscreen composition
CN106176478A (en) * 2016-08-31 2016-12-07 广州巧巧生物科技有限公司 A kind of cosmetic composition and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101780014A (en) * 2010-01-14 2010-07-21 台州绿岛化妆品有限公司 Sun-blocking aerosol and device method thereof
CN104661638A (en) * 2012-07-26 2015-05-27 里曼贸易有限责任公司 Improved high protection sunscreen composition
CN106176478A (en) * 2016-08-31 2016-12-07 广州巧巧生物科技有限公司 A kind of cosmetic composition and preparation method thereof

Non-Patent Citations (2)

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Title
宋丽雅 等编著: "《化妆品植物功效添加剂的研究与开发》", 31 January 2011, 中国轻工业出版社 *
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