CN107628751B - Apple green crystalline glaze and method for firing apple green crystalline glaze - Google Patents
Apple green crystalline glaze and method for firing apple green crystalline glaze Download PDFInfo
- Publication number
- CN107628751B CN107628751B CN201710938293.1A CN201710938293A CN107628751B CN 107628751 B CN107628751 B CN 107628751B CN 201710938293 A CN201710938293 A CN 201710938293A CN 107628751 B CN107628751 B CN 107628751B
- Authority
- CN
- China
- Prior art keywords
- apple green
- parts
- glaze
- firing
- crystalline glaze
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000010304 firing Methods 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000000919 ceramic Substances 0.000 claims abstract description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000013078 crystal Substances 0.000 claims abstract description 10
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229910052808 lithium carbonate Inorganic materials 0.000 claims abstract description 8
- 239000010453 quartz Substances 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 7
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000005751 Copper oxide Substances 0.000 claims abstract description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 7
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 7
- 239000010433 feldspar Substances 0.000 claims abstract description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940072033 potash Drugs 0.000 claims abstract description 7
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 7
- 235000015320 potassium carbonate Nutrition 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 239000011259 mixed solution Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 235000015895 biscuits Nutrition 0.000 claims abstract description 4
- 238000007873 sieving Methods 0.000 claims abstract description 4
- 238000000498 ball milling Methods 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims abstract description 3
- 238000002791 soaking Methods 0.000 claims abstract description 3
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000005303 weighing Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 20
- 238000002425 crystallisation Methods 0.000 abstract description 4
- 230000008025 crystallization Effects 0.000 abstract description 4
- 238000007667 floating Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000003086 colorant Substances 0.000 description 2
- 241000581835 Monodora junodii Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses an apple green crystalline glaze, which comprises the following raw materials in parts by mass: 20-30 parts of potash feldspar, 5-10 parts of calcite, 1-5 parts of zinc oxide, 2-6 parts of kaolin, 0.01-1 part of copper oxide, 0.1-1 part of lithium carbonate and 0.1-1 part of quartz. The invention also discloses a method for firing the apple green crystal glaze by using the apple green crystal glaze, which comprises the following steps: mixing the obtained apple green crystalline glaze with water, precipitating and floating, and then ball-milling for 12-24 hours and sieving with a 100-200 mesh sieve to obtain a mixed solution; firstly, firing a ceramic body for 5 hours to 800 ℃, then soaking the biscuit fired ceramic body into the obtained mixed liquid for 2-3 seconds, taking out, firing in an electric kiln for 12 hours, and cooling to obtain the ceramic product with the apple green crystal glaze on the surface. The invention has simple formula, convenient operation and low cost; the apple green ceramic product with the apple green crystallization effect can be obtained, and is exquisite, beautiful and strong in artistic effect; more porcelains with special artistic effects can be obtained by superposing the glaze materials.
Description
(I) technical field
The invention relates to an apple green crystalline glaze and a method for firing the apple green crystalline glaze by using the glaze.
(II) background of the invention
Coloring and glazing on the surface of the ceramic product is an effective means for increasing the texture and aesthetic feeling of the ceramic product, and the artistic effect of each glaze color or design color is different, so that various glaze colors, design colors or the combination thereof are on the market at present. The glaze on the market has a plurality of varieties, but has strong artistic effect, but has little poor glossiness, water resistance, pollution resistance, friction resistance and weak performance. The patent provides an apple green crystalline glaze, the artistic effect is strong, and the object surface is very clean, and natural film forming time is long, and waterproof, antifouling performance is good.
Disclosure of the invention
In order to solve the defects of the prior art, the invention aims to provide the glaze which has strong artistic effect, stable glaze effect and obvious decorative effect, and can be used for creating the special artistic effect of light green crystals generated by oxidizing and firing matte glaze.
In order to achieve the purpose, the invention adopts the technical scheme that:
an apple green crystalline glaze comprises the following components in parts by mass: 20-30 parts of potash feldspar, 5-10 parts of calcite, 1-5 parts of zinc oxide, 2-6 parts of kaolin, 0.01-1 part of copper oxide, 0.1-1 part of lithium carbonate and 0.1-1 part of quartz.
Further, preferably, the mass ratio of each component is as follows: 21.78 parts of potash feldspar, 6.73 parts of calcite, 1.95 parts of zinc oxide, 2.99 parts of kaolin, 0.40 part of copper oxide, 0.30 part of lithium carbonate and 0.20 part of quartz.
The invention also relates to a method for firing an apple green crystalline glaze by using the apple green crystalline glaze, which comprises the following steps:
(1) weighing the components according to the using amounts to prepare an apple green crystalline glaze;
(2) mixing the apple green crystalline glaze obtained in the step (1) with water, settling, and then ball-milling for 12-24 hours and sieving with a 100-200-mesh sieve to obtain a mixed solution; the mass ratio of the apple green crystalline glaze to water is 100: 70-80 parts;
(3) and (3) firstly, firing the ceramic body for 5 hours to 800 ℃, then soaking the biscuit fired ceramic body into the mixed liquid obtained in the step (2), taking out after 2-3 seconds, firing for 12 hours in an electric kiln, and cooling to obtain the ceramic product with the apple green crystal glaze on the surface.
Further, preferably, the electric kiln firing procedure is as follows:
the first stage is as follows: heating from 20 deg.C to 150 deg.C for 150 min;
and a second stage: heating from 150 deg.C to 300 deg.C for 100 min;
and a third stage: heating from 300 deg.C to 800 deg.C for 200 min;
a fourth stage: heating from 800 deg.C to 1240 deg.C for 240 min;
the fifth stage: raising the temperature from 1240 ℃ to 1250 ℃ for 20 min;
the sixth stage: keeping the temperature at 1250 ℃ for 10 min.
In order to achieve specific artistic effect, the ceramic blank is biscuit-fired at 800 ℃, then apple green crystal glaze with the thickness of 1-2 mm is coated, and the apple green crystal glaze with the special effect of matt and slightly green apple crystal can be obtained after the blank is fired for 12 hours at 1250 ℃.
Compared with the prior art, the invention has the following beneficial effects:
the invention has simple formula, convenient operation and low cost; the apple green ceramic product with the apple green crystallization effect can be obtained, and is exquisite, beautiful and strong in artistic effect; more porcelains with special artistic effects can be obtained by superposing the glaze materials.
(IV) detailed description of the preferred embodiments
The invention will be further described with reference to specific examples, but the scope of the invention is not limited thereto:
example 1:
the formula of the apple green crystalline glaze comprises the following components in parts by mass: 21.78 parts of potash feldspar, 6.73 parts of calcite, 1.95 parts of zinc oxide, 2.99 parts of kaolin, 0.40 part of copper oxide, 0.30 part of lithium carbonate and 0.20 part of quartz.
The firing method comprises the following steps: mixing the apple green crystalline glaze with water according to the mass ratio of 100: 75 mixing, floating and sieving by a 120-mesh sieve to obtain a mixed solution;
firstly, firing the ceramic body for 5h to 800 ℃, then immersing the biscuit fired body into the obtained mixed solution, taking out after 2-3 s, firing for 12 h in an electric kiln at 1250 ℃, and cooling to obtain the ceramic product with strong artistic sense and apple green crystallization effect.
Firing temperature profile:
and (3) electric kiln sintering: putting the green body into a kiln, and burning the green body from 20 ℃ to 150 ℃ in 150 minutes in the first stage to remove the moisture in the green body; in the second stage, the temperature is heated to 300 ℃ from 150 ℃ in 100 minutes, and the moisture is removed; in the third stage, the temperature is increased from 300 ℃ to 800 ℃ through 200 minutes, so that the blank is stable; the fourth stage is to burn from 800 ℃ to 1240 ℃ through 240 minutes to fully melt the glaze; the fifth stage is to burn from 1240 ℃ to 1250 ℃ through 20 minutes and keep the temperature for 10 minutes to fully finish the glaze crystallization. Then naturally cooling, and discharging from the kiln when the temperature reaches 100 ℃.
Example 2:
the formula of the apple green crystalline glaze comprises the following components in parts by mass: 21.78 parts of potash feldspar, 6.73 parts of calcite, 1.95 parts of zinc oxide, 2.99 parts of kaolin, 0.40 part of copper oxide, 0.10 part of lithium carbonate and 0.20 part of quartz. The firing method and firing profile were the same as in example 1.
As titanium oxide is in the glaze, when the dosage of lithium carbonate is reduced from 0.3 part to 0.1 part, the color development is affected, the opacifying effect becomes strong, and the glaze color becomes opaque green. The glaze effect of the apple green crystal of example 1 was not obtained in the glaze of example 2, but only the glaze effect of the matte translucent green alone was obtained, and the lightness was weakened.
Example 3:
the formula of the apple green crystalline glaze comprises the following components in parts by mass: 21.78 parts of potash feldspar, 6.73 parts of calcite, 1.95 parts of zinc oxide, 2.99 parts of kaolin, 0.40 part of copper oxide, 0.30 part of lithium carbonate and 1 part of quartz. The firing method and firing profile were the same as in example 1.
Example 3 the amount of quartz is increased to 1 part, and the glaze effect is clear light green glaze color, the fluidity is enhanced, and the glaze accumulation phenomenon appears under the glaze.
Claims (3)
1. An apple green crystalline glaze, characterized in that: the apple green crystalline glaze comprises the following components in parts by mass: 21.78 parts of potash feldspar, 6.73 parts of calcite, 1.95 parts of zinc oxide, 2.99 parts of kaolin, 0.40 part of copper oxide, 0.30 part of lithium carbonate and 0.20 part of quartz.
2. A method of firing an apple green crystalline glaze according to claim 1 wherein: the method comprises the following steps:
(1) preparing apple green crystalline glaze by weighing the components according to the amount of the claim 1;
(2) mixing the apple green crystalline glaze obtained in the step (1) with water, settling, and then ball-milling for 12-24 hours and sieving with a 100-200-mesh sieve to obtain a mixed solution; the mass ratio of the apple green crystalline glaze to water is 100: 70-80 parts;
(3) and (3) firstly, firing the ceramic body for 5 hours to 800 ℃, then soaking the biscuit fired ceramic body into the mixed liquid obtained in the step (2), taking out after 2-3 seconds, firing for 12 hours in an electric kiln, and cooling to obtain the ceramic product with the apple green crystal glaze on the surface.
3. The method of claim 2, wherein: the electric kiln firing procedure is as follows:
the first stage is as follows: heating from 20 deg.C to 150 deg.C for 150 min;
and a second stage: heating from 150 deg.C to 300 deg.C for 100 min;
and a third stage: heating from 300 deg.C to 800 deg.C for 200 min;
a fourth stage: heating from 800 deg.C to 1240 deg.C for 240 min;
the fifth stage: raising the temperature from 1240 ℃ to 1250 ℃ for 20 min;
the sixth stage: keeping the temperature at 1250 ℃ for 10 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710938293.1A CN107628751B (en) | 2017-09-30 | 2017-09-30 | Apple green crystalline glaze and method for firing apple green crystalline glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710938293.1A CN107628751B (en) | 2017-09-30 | 2017-09-30 | Apple green crystalline glaze and method for firing apple green crystalline glaze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107628751A CN107628751A (en) | 2018-01-26 |
| CN107628751B true CN107628751B (en) | 2020-10-09 |
Family
ID=61104184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710938293.1A Active CN107628751B (en) | 2017-09-30 | 2017-09-30 | Apple green crystalline glaze and method for firing apple green crystalline glaze |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107628751B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109020212A (en) * | 2018-09-20 | 2018-12-18 | 河南省钧艺照明灯具有限公司 | It is a kind of to watch lamps and lanterns and preparation method thereof suitable for outdoor ceramics |
| CN109354409A (en) * | 2018-12-15 | 2019-02-19 | 醴陵陶润实业发展有限公司 | Verdigris transmutation is revealed the exact details glaze and preparation method thereof |
| CN109942188A (en) * | 2019-04-16 | 2019-06-28 | 福建省德化问瓷阁陶瓷有限公司 | A kind of green temmoku glaze ceramics of matt and its manufacture craft |
| CN113800951A (en) * | 2021-09-01 | 2021-12-17 | 湖南泉湘陶瓷有限公司 | Matte antique crystal glaze and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103304273A (en) * | 2013-06-08 | 2013-09-18 | 浙江工业大学之江学院工业研究院 | Black crystal glaze material and firing method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6025379B2 (en) * | 1980-09-29 | 1985-06-18 | 日本碍子株式会社 | Lower glaze frit composition for steel plate enameling |
| ATE82234T1 (en) * | 1988-09-13 | 1992-11-15 | Bayer Ag | ENAMEL FRIES FOR ACID-RESISTANT SINGLE LAYER ENAMELING ON UNPICKLED STEEL. |
| CN105948495A (en) * | 2016-04-28 | 2016-09-21 | 浙江开尔新材料股份有限公司 | Low-temperature corrosion-resistant glaze material used for enamel pipe |
| CN106495482A (en) * | 2016-09-20 | 2017-03-15 | 崔松伟 | A kind of ceramic glaze and preparation method thereof |
-
2017
- 2017-09-30 CN CN201710938293.1A patent/CN107628751B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103304273A (en) * | 2013-06-08 | 2013-09-18 | 浙江工业大学之江学院工业研究院 | Black crystal glaze material and firing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107628751A (en) | 2018-01-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104193416B (en) | The fast firing method of dark fund star glaze ceramic roller kiln | |
| CN107628751B (en) | Apple green crystalline glaze and method for firing apple green crystalline glaze | |
| CN102249739B (en) | Preparation method of carbon-golden metallic luster crystalline glaze | |
| CN102173875B (en) | Preparation method of B2O3-TiO2 series fambe ceramic crystalline glaze | |
| CN107540218B (en) | Matte pink crystal glaze and method for firing matte pink crystal glaze | |
| CN101643368B (en) | Method for manufacturing crystal glaze color paintings | |
| CN103601534A (en) | High-whiteness under-glaze colorful low-temperature ceramic and preparation method thereof | |
| CN104030732A (en) | Bone-china exquisite glaze and method for fabricating bone-china exquisite products by using bone-china exquisite glaze | |
| CN104016719A (en) | Reactive crystalline glaze with sagging effect and preparation method of reactive crystalline glaze | |
| CN105776866B (en) | Longquan celadon jasper green glaze, the green Longquan celadon of jasper and preparation method thereof | |
| CN106495742A (en) | Anti- wax stone bonding glaze, anti-wax stone bonding pottery and its preparation technology | |
| CN104496554A (en) | Jun red glaze and preparation method thereof | |
| CN105601110A (en) | Black silver drop reduced transmutation glaze, black silver drop reduced transmutation glaze ceramic product prepared using same and preparation method | |
| CN107673614B (en) | Matte blue crystalline glaze and method for firing same | |
| CN103992140B (en) | A kind of copper iron look sunlight becomes gold ring temmoku glaze and makes the method for household china of it | |
| CN107586038B (en) | Process for preparing jun porcelain from green and white glaze for jun porcelain | |
| CN105152684B (en) | Lightweight porcelain low temperature transmutation erythema glaze, method of preparation and use | |
| CN107572789A (en) | A kind of matt light green color crystalline glaze material and the method for firing matt light green color crystalline glaze | |
| CN107663022B (en) | Celeste jun porcelain glaze and preparation method thereof | |
| CN107601898B (en) | Preparation method of Jun porcelain blue glaze | |
| CN113896422B (en) | Kiln transition blue glaze, preparation method thereof and glaze firing method | |
| CN105330147A (en) | Preparation method of zinc silicate crystal glaze for bone china | |
| CN109052946A (en) | A kind of light blue furnace chun glaze and preparation method thereof | |
| CN107540216B (en) | Brown glaze and method for firing brown glaze | |
| CN105130191B (en) | Lightweight porcelain low temperature transmutation covellite colour glaze, method of preparation and use |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |