CN107587382A - A kind of cigarette paper with the inflammable function that eliminates smoke - Google Patents

A kind of cigarette paper with the inflammable function that eliminates smoke Download PDF

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Publication number
CN107587382A
CN107587382A CN201710798680.XA CN201710798680A CN107587382A CN 107587382 A CN107587382 A CN 107587382A CN 201710798680 A CN201710798680 A CN 201710798680A CN 107587382 A CN107587382 A CN 107587382A
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China
Prior art keywords
cigarette paper
cigarette
weight
inflammable
function
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Pending
Application number
CN201710798680.XA
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Chinese (zh)
Inventor
李勇
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Chuzhou City Guang Wei Chemical Co Ltd
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Chuzhou City Guang Wei Chemical Co Ltd
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Application filed by Chuzhou City Guang Wei Chemical Co Ltd filed Critical Chuzhou City Guang Wei Chemical Co Ltd
Priority to CN201710798680.XA priority Critical patent/CN107587382A/en
Publication of CN107587382A publication Critical patent/CN107587382A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of cigarette paper with the inflammable function that eliminates smoke, the present invention will be calcium carbonate modified rear as filler, combustion adjuvant is used as using potassium citrate and sodium potassium tartrate tetrahydrate mixed powder, reduce activation energy when wood pulp cellulose is pyrolyzed in cigarette paper, make it that pyrolytic reaction occur at a lower temperature, promote the air permeability of the cigarette paper after cigarette charing line in the range of 1cm that significant change occurs, promote the pipe tobacco burning of cigarette paper periphery, so that the tar and volatile carbonyl compound in cigarette mainstream flue gas are minimized;Addition n-trimethyl chitosan chloride and suction taste regulator improve air permeability, tensile strength and the suction taste of cigarette paper, the cigarette burning speed that obtained cigarette paper is produced is fast, the bag ash performance of the cigarette ash during burning and sucking can be improved, solve the cigarette paper ash phenomenon that dissipates, float, falling, and improve cigarette when cigarette is burnt and sucked to hold grey length, safety in utilization higher.

Description

A kind of cigarette paper with the inflammable function that eliminates smoke
Technical field
The present invention relates to cigarette paper technical field, and in particular to a kind of cigarette paper with the inflammable function that eliminates smoke.
Background technology
Unhealthful harmful substance is primarily present in cigarette smoke, and the chemical composition in cigarette smoke is by one What sequence of chemical and physical process were formed, including the evaporation of volatile ingredient and still-process, the heat of non-volatile component in tobacco Solution preocess, pyrolysis form the imperfect combustion of coke and the secondary response process of initial product, in addition to glow and puffing regimenses Under transmittance process(Quality, heat and momentum)Deng change.Thus in order to reduce the discharge of harmful substances from flue gases, except to cigarette It is also very high to the quality requirement of the major auxiliary burden cigarette paper of cigarette beyond yarn quality requires high.
Major auxiliary burden of the cigarette paper as cigarette, burning is directly participated in during cigarette burning, the static state of cigarette is fired Burning speed, degree of ventilation, puff number, main flow and side-stream smoke composition has considerable influence.Thus develop a kind of with smoke elimination It is inflammable, bag is grey, water-fast etc., and function is determined to win in the cigarette paper of one.
The content of the invention
It is an object of the invention to provide a kind of cigarette paper with the inflammable function that eliminates smoke, to overcome prior art not Foot.
The object of the present invention is achieved like this:
A kind of cigarette paper with the inflammable function that eliminates smoke, it is characterised in that auxiliary agent is added during cigarette paper production technology, institute Auxiliary agent is stated as filler, combustion adjuvant, n-trimethyl chitosan chloride and inhales taste regulator composition, it is described to fill out on the basis of the weight of finished paper The percentage by weight of material is 30-35%;The percentage by weight of the combustion adjuvant is 1.5-2.5%;The weight of the n-trimethyl chitosan chloride Amount percentage is 0.7-0.9%;The percentage by weight for inhaling taste regulator is 0.3-0.5%.
Described filler is modified calcium carbonate, and its preparation method is:
(1)The scattered ultrasonic grinding in deionized water of calcium carbonate is made into the slurries that mass concentration is 20-30%, adds calcium carbonate Absolute dry mass 2-4% brown sugar powder is warming up to 75-85 DEG C and continues ultrasonic disperse 30min;
(2)Calcium carbonate absolute dry mass 0.6-0.8% Low Molecular Weight Cationic Polyacrylamide is added into above-mentioned material, with 600-800r/min stirs 1-2 hours, is spray-dried to obtain modified calcium carbonate;Described PAMC molecular weight is 100-200 ten thousand.
Described combustion adjuvant is is combined by potassium citrate and sodium potassium tartrate tetrahydrate, wherein potassium sodium ratio in described combustion adjuvant For 7: 3.
The preparation method of described n-trimethyl chitosan chloride is:
(1)Weigh and stirred and evenly mixed in the chitosan of 2-3 parts by weight and the isopropanol input reactor of 45-50 parts by weight, in 60-65 Constant temperature swelling 40min in DEG C water-bath;
(2)The 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride aqueous solution of 8-9 parts by weight is slowly added dropwise into above-mentioned material, slowly rises Temperature constant temperature stirring 5-7h, cooling, precipitating, filtering, is washed 3-5 times with ethanol, acetone, is drying to obtain to 85 DEG C successively;Wherein institute The mass fraction for the 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride aqueous solution stated is 65-70%.
Described taste regulator of inhaling is the one or more in xylitol, D-sorbite, lactose, maltose, glucose.
Beating degree is 20-22 ° of SR in the cigarette paper production technology.
The present invention has following beneficial effect:The present invention will be calcium carbonate modified rear as filler, improve calcium carbonate in cigarette Retention in paper;Using potassium citrate and sodium potassium tartrate tetrahydrate mixed powder as combustion adjuvant, wood pulp cellulose in cigarette paper is reduced Activation energy during pyrolysis, makes it that pyrolytic reaction occur at a lower temperature, promotes the cigarette paper in the range of 1cm after cigarette charing line Air permeability significant change occurs, not only strengthen the dilution and diffusion of cigarette smoke, while when cigarette is burnt and sucked, also improve outer The diffusion of small-molecule substance in boundary's air and cigarette, promote the pipe tobacco burning of cigarette paper periphery, so that in cigarette mainstream flue gas Tar and volatile carbonyl compound are minimized;Addition n-trimethyl chitosan chloride and suction taste regulator improve the ventilative of cigarette paper Degree, tensile strength and suction taste, the cigarette burning speed produced using cigarette paper produced by the present invention is fast, can improve and burn and suck The bag ash performance of cigarette ash in journey, solves the cigarette paper ash phenomenon that dissipates, float, falling, and that improves cigarette when cigarette is burnt and sucked holds ash Length, safety in utilization are higher.
Embodiment
A kind of cigarette paper with the inflammable function that eliminates smoke, it is characterised in that add and help during cigarette paper production technology Agent, the auxiliary agent are filler, combustion adjuvant, n-trimethyl chitosan chloride and inhale taste regulator composition, on the basis of the weight of finished paper, institute The percentage by weight for stating filler is 30%;The percentage by weight of the combustion adjuvant is 1.5%;The weight hundred of the n-trimethyl chitosan chloride Divide than being 0.9%;The percentage by weight for inhaling taste regulator is 0.3%.
Described filler is modified calcium carbonate, and its preparation method is:
(1)The scattered ultrasonic grinding in deionized water of calcium carbonate is made into the slurries that mass concentration is 20-30%, adds calcium carbonate The brown sugar powder of absolute dry mass 3% is warming up to 75-85 DEG C and continues ultrasonic disperse 30min;
(2)The Low Molecular Weight Cationic Polyacrylamide of calcium carbonate absolute dry mass 0.8% is added into above-mentioned material, with 600- 800r/min stirs 1-2 hours, is spray-dried to obtain modified calcium carbonate;Described PAMC molecular weight is 100- 2000000.
Described combustion adjuvant is is combined by potassium citrate and sodium potassium tartrate tetrahydrate, wherein potassium sodium ratio in described combustion adjuvant For 7: 3.
The preparation method of described n-trimethyl chitosan chloride is:
(1)Weigh and stirred and evenly mixed in the chitosan of 3 parts by weight and the isopropanol input reactor of 50 parts by weight, in 60-65 DEG C of water Constant temperature is swelled 40min in bath;
(2)The 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride aqueous solution of 8 parts by weight is slowly added dropwise into above-mentioned material, slowly heating To 85 DEG C, constant temperature stirring 5-7h, cooling, precipitating, filtering, washed 3-5 times, be drying to obtain with ethanol, acetone successively;It is wherein described The mass fraction of the 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride aqueous solution be 65-70%.
Described taste regulator of inhaling is the one or more in xylitol, D-sorbite, lactose, maltose, glucose.
Beating degree is 20-22 ° of SR in the cigarette paper production technology.

Claims (6)

  1. A kind of 1. cigarette paper with the inflammable function that eliminates smoke, it is characterised in that auxiliary agent is added during cigarette paper production technology, The auxiliary agent is filler, combustion adjuvant, n-trimethyl chitosan chloride and inhales taste regulator composition, described on the basis of the weight of finished paper The percentage by weight of filler is 30-35%;The percentage by weight of the combustion adjuvant is 1.5-2.5%;The n-trimethyl chitosan chloride Percentage by weight is 0.7-0.9%;The percentage by weight for inhaling taste regulator is 0.3-0.5%.
  2. 2. a kind of cigarette paper with the inflammable function of eliminating smoke according to claim 1, it is characterised in that described filler is Modified calcium carbonate, its preparation method are:
    (1)The scattered ultrasonic grinding in deionized water of calcium carbonate is made into the slurries that mass concentration is 20-30%, adds calcium carbonate Absolute dry mass 2-4% brown sugar powder is warming up to 75-85 DEG C and continues ultrasonic disperse 30min;
    (2)Calcium carbonate absolute dry mass 0.6-0.8% Low Molecular Weight Cationic Polyacrylamide is added into above-mentioned material, with 600-800r/min stirs 1-2 hours, is spray-dried to obtain modified calcium carbonate;Described PAMC molecular weight is 100-200 ten thousand.
  3. A kind of 3. cigarette paper with the inflammable function that eliminates smoke according to claim 1, it is characterised in that described combustion adjuvant To be combined by potassium citrate and sodium potassium tartrate tetrahydrate, wherein potassium sodium ratio is 7: 3 in described combustion adjuvant.
  4. 4. a kind of cigarette paper with the inflammable function that eliminates smoke according to claim 1, it is characterised in that described is quaternized The preparation method of chitosan is:
    (1)Weigh and stirred and evenly mixed in the chitosan of 2-3 parts by weight and the isopropanol input reactor of 45-50 parts by weight, in 60-65 Constant temperature swelling 40min in DEG C water-bath;
    (2)The 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride aqueous solution of 8-9 parts by weight is slowly added dropwise into above-mentioned material, slowly rises Temperature constant temperature stirring 5-7h, cooling, precipitating, filtering, is washed 3-5 times with ethanol, acetone, is drying to obtain to 85 DEG C successively;Wherein institute The mass fraction for the 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride aqueous solution stated is 65-70%.
  5. 5. a kind of cigarette paper with the inflammable function that eliminates smoke according to claim 1, it is characterised in that described suction taste is adjusted Whole dose is the one or more in xylitol, D-sorbite, lactose, maltose, glucose.
  6. A kind of 6. cigarette paper with the inflammable function that eliminates smoke according to claim 1, it is characterised in that the cigarette paper life Beating degree is 20-22 ° of SR in production. art.
CN201710798680.XA 2017-09-07 2017-09-07 A kind of cigarette paper with the inflammable function that eliminates smoke Pending CN107587382A (en)

Priority Applications (1)

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CN201710798680.XA CN107587382A (en) 2017-09-07 2017-09-07 A kind of cigarette paper with the inflammable function that eliminates smoke

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Application Number Priority Date Filing Date Title
CN201710798680.XA CN107587382A (en) 2017-09-07 2017-09-07 A kind of cigarette paper with the inflammable function that eliminates smoke

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Publication Number Publication Date
CN107587382A true CN107587382A (en) 2018-01-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115369681A (en) * 2022-08-26 2022-11-22 四川中烟工业有限责任公司 Cigarette paper preparation method for improving ash wrapping performance

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1429946A (en) * 2002-12-27 2003-07-16 云南瑞升科技有限公司 Functional cigarette paper
CN101775759A (en) * 2010-02-05 2010-07-14 广东中烟工业有限责任公司 Cigarette paper additive, preparation method and application thereof
CN101781867A (en) * 2010-02-09 2010-07-21 广东中烟工业有限责任公司 Low ignition tendency cigarette paper and preparation method thereof
CN101858044A (en) * 2010-06-23 2010-10-13 牡丹江恒丰纸业股份有限公司 Preparation method of cigarette paper additive
CN102242527A (en) * 2011-05-13 2011-11-16 民丰特种纸股份有限公司 Functional cigarette paper and preparation method
CN105769177A (en) * 2016-04-01 2016-07-20 佛山市质量计量监督检测中心 Electrocardiograph signal examination record analyzing device
CN106368069A (en) * 2016-10-19 2017-02-01 中烟摩迪(江门)纸业有限公司 Heating non-combustible cigarette paper and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1429946A (en) * 2002-12-27 2003-07-16 云南瑞升科技有限公司 Functional cigarette paper
CN101775759A (en) * 2010-02-05 2010-07-14 广东中烟工业有限责任公司 Cigarette paper additive, preparation method and application thereof
CN101781867A (en) * 2010-02-09 2010-07-21 广东中烟工业有限责任公司 Low ignition tendency cigarette paper and preparation method thereof
CN101858044A (en) * 2010-06-23 2010-10-13 牡丹江恒丰纸业股份有限公司 Preparation method of cigarette paper additive
CN102242527A (en) * 2011-05-13 2011-11-16 民丰特种纸股份有限公司 Functional cigarette paper and preparation method
CN105769177A (en) * 2016-04-01 2016-07-20 佛山市质量计量监督检测中心 Electrocardiograph signal examination record analyzing device
CN106368069A (en) * 2016-10-19 2017-02-01 中烟摩迪(江门)纸业有限公司 Heating non-combustible cigarette paper and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115369681A (en) * 2022-08-26 2022-11-22 四川中烟工业有限责任公司 Cigarette paper preparation method for improving ash wrapping performance

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Application publication date: 20180116

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