CN102587198A - Functional cigarette paper - Google Patents
Functional cigarette paper Download PDFInfo
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- CN102587198A CN102587198A CN2012100648585A CN201210064858A CN102587198A CN 102587198 A CN102587198 A CN 102587198A CN 2012100648585 A CN2012100648585 A CN 2012100648585A CN 201210064858 A CN201210064858 A CN 201210064858A CN 102587198 A CN102587198 A CN 102587198A
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Abstract
The invention provides functional cigarette paper. The functional cigarette paper is mainly used for reducing the CO content and the tar content of mainstream smoke of cigarettes and does not generate negative effect on the smoking quality and the using safety of the cigarettes. The functional cigarette paper has the technical characteristics that a low temperature thermolysis polyester material is added in the production process of the cigarettes; the thermolysis polyester material is polyactic acid or polyglycolic acid; and due to the low temperature thermolysis action in the combustion process of the cigarettes, the air permeability of the cigarette paper in the region near the cigarette carbonizing line is improved, diffusion of oxygen and carbon monoxide is promoted, and the CO content and the tar content of mainstream smoke of cigarettes are reduced by 8 to 15 percent. The functional cigarette paper is implemented without changing the conventional process and equipment of the cigarette paper and industrial production is realized easily.
Description
Technical field
The present invention relates to a kind of cigarette paper, more particularly, relate to a kind of cigarette paper that falls CO and fall burnt function that has.
Background technology
Contain harmful substances such as nitrosamines, condensed-nuclei aromatics class, phenol, low molecule aldehydes in the coke tar in cigarette; This type of material can bring out a plurality of organ generation of human body canceration; Healthy very harmful to the cigarette consumer; So reduce the cigarette mainstream flue gas tar content, just reduce the harmfulness of smoking cigarette.
CO is a kind of gas of insalubrity, also is one of main harmful components of cigarette smoke, in the cigarette smoking process, produces, and every content can reach tens milligrams.In a single day CO is inhaled into just and combines with hemoglobin, forms highly stable carbonyl haemoglobin, and the chemical affinity of itself and hemoglobin is itself and O
2More than 200 times.The formation of carbonyl haemoglobin makes hemoglobin lose the ability of delivery of oxygen, makes histanoxia, causes tissue hypoxia disease.In addition, CO can also influence the permeability that blood fat sees through blood vessel, and the generation and the development of chronic obstructive pulmonary disease also had facilitation.Therefore, how reducing CO in smoke of cigarettes is the huge challenge that tobacco science and technology faces.
At present both at home and abroad cigarette paper falls CO and falls the burnt method that adopts and mainly contain: 1) improve air permeance for cigarette paper, to reduce cigarette paper quantitative, to play the effect of dilution and diffusion; 2) adopt pyrolysis filler particles or expanded material as cigarette paper part filler, improve the air permeability in cigarette paper carbonization line zone, increase the diffusion of micro-molecular gas, promote the pipe tobacco burning; 3) through adding the sylvite combustion adjuvant, increase the cigarette paper burning velocity, reduce cigarette smoking mouth number.
These three kinds of modes all can reduce CO and the tar content in the cigarette mainstream flue gas effectively, but also can produce some negative effects to cigarette.First kind of mode can not satisfy the requirement of state inner wrap strip consumer to cigarette bag ash performance and cigarette paper outward appearance, and also can desalinate cigarette flavor; The second way not only can produce special assorted gas, influences the suction quality of Chinese style cigarette, and its employed material also possibly produce poisonous and hazardous chemical composition in the cigarette paper combustion process; The third mode is easy to generate cigarette burning and bores the phenomenon that turns around, and cigarette burning is too fast, and the consumer also is not easy to accept.
Summary of the invention
The present invention is directed to cigarette paper and fall Jiao and the weak point of falling the CO prior art; Through in cigarette paper, adding the low temperature thermal decomposition polyester material; Reduced CO and the tar content in the cigarette mainstream flue gas effectively; And the suction quality to cigarette does not have a negative impact, and in the cigarette burning process, does not produce the poisonous and harmful chemical composition simultaneously yet, has security preferably.
The present invention is achieved through following technical scheme.
Invention provides a kind of functional cigarette paper, and main component is made up of softwood pulp, hardwood pulp and pearl filler, it is characterized in that, also comprises polyester material.Softwood pulp accounts for 15% ~ 30% of cigarette paper dry weight, and hardwood pulp accounts for 25% ~ 40% of cigarette paper dry weight, and pearl filler accounts for 15% ~ 30% of cigarette paper dry weight, and polyester material accounts for 1% ~ 15% of cigarette paper dry weight.
Polyester material is PLA or polyglycolic acid or the mixture of the two.PLA is a particle size range at 600 ~ 800 purpose PLA powder or the fibre length polylactic acid short-fiber at 0.8 ~ 2mm, and described polyglycolic acid is a particle size range at 600 ~ 800 purpose PLA powder or the fibre length polylactic acid short-fiber at 0.8 ~ 2mm.
In cigarette paper production technology tankman section; PLA or polyglycolic acid powder are substituted part calcium carbonate filler (its account for cigarette paper dry weight 1 ~ 15%) with the mode of filler; Or PLA or polyglycolic acid staple fibre substituted part needle slurry (its dry weight account for cigarette paper dry weight 1 ~ 15%) with the mode of fiber; Make itself and wood pulp and pearl filler join slurry, homogenate, afterwards, produce functional cigarette paper through cigarette tissue machine.
Preferably, polyester material is the mixture of PLA and polyglycolic acid, and both mass ratioes are 10:1 ~ 1:10.
When the cigarette that uses this functional cigarette paper during in burning; (decomposition temperature is about about 200 ℃ because the PLA, the polyglycolic acid heat decomposition temperature that add in the cigarette paper are lower; Decomposition temperature than wood pulp fibre is little more than 100 ℃), stay a large amount of holes after its decomposes, so the air permeability of cigarette carbonization line near zone cigarette paper very easily changes; Thereby promote the CO diffusion in airborne oxygen and the cigarette smoke; Improved the fired state of cigarette paper periphery pipe tobacco to a certain extent, reduced tar and the CO content in the cigarette mainstream flue gas, the carbon monoxide and the tar range of decrease are 8 ~ 15%.
Fall CO and fall burnt compared with techniques with existing cigarette paper, the present invention has following advantage:
1) this kind functional cigarette paper does not have negative effect to cigarette smoking quality and style and features at least, even the effect that improves the cigarette smoking mouthfeel is arranged;
2) the cigarette paper thermal decomposition product is safer, compares generation toxic and harmful substance useless in the cigarette burning process with conventional cigarette paper;
3) cigarette burning speed is moderate, and the burning velocity matching of cigarette paper and pipe tobacco is better, does not have burning and bores the phenomenon that turns around.
The specific embodiment
Below in conjunction with embodiment the present invention is described further, but they are not to qualification of the present invention that weight in following examples is dry weight.
Embodiment 1: carry out the narration of implementation process by producing 1 ton of cigarette paper: adding average fiber length in tankman's section is the acid fiber by polylactic (Jiaxing Puli's Lay new material Co., Ltd) 76 kilograms (percentage by weight is 7.6%) of 1.4mm; 224 kilograms (percentage by weight is 22.4%) of needle slurry; 400 kilograms in broad-leaved slurry (percentage by weight for be 40%); 300 kilograms in calcium carbonate (percentage by weight is 30%), and in joining stock tank, it is mixed, manufacture paper with pulp by the cigarette paper conventional production process.After the cigarette paper dry forming first time, add 20 kilograms of citrates (weight ratio is potassium citrate and the natrium citricum of 1:1) in applying glue workshop section again.This cigarette paper quantitatively, air permeability and air permeability amplification sees table 1 and table 2.
Embodiment 2: carry out the narration of implementation process by producing 1 ton of cigarette paper: add the polyglycolic acid acid fiber (Changchun Shengboma Biological Materials Co., Ltd) 10 kilograms (percentage by weight is 1%) that average fiber length is 0.8mm in tankman's section; 300 kilograms (percentage by weight is 30%) of needle slurry; 390 kilograms (percentage by weight is 39%) of broad-leaved slurry; 300 kilograms in calcium carbonate (percentage by weight is 30%), and in joining stock tank, it is mixed, manufacture paper with pulp by the cigarette paper conventional production process.After the cigarette paper dry forming first time, add 20 kilograms of citrates (weight ratio is potassium citrate and the natrium citricum of 1:1) in applying glue workshop section again.This cigarette paper quantitatively, air permeability and air permeability amplification sees table 1 and table 2.
Embodiment 3: carry out the narration of implementation process by producing 1 ton of cigarette paper: adding particle mean size in tankman's section is 600 ~ 800 purpose PLA powder (Shenzhen is prone to give birth to new material Co., Ltd) 150 kilograms (percentage by weight is 15%); 284 kilograms (percentage by weight is 28.4%) of needle slurry; 390 kilograms (percentage by weight is 39%) of broad-leaved slurry; 176 kilograms in calcium carbonate (percentage by weight is 17.6%), and in joining stock tank, it is mixed, manufacture paper with pulp by the cigarette paper conventional production process.After the cigarette paper dry forming first time, add 20 kilograms of citrates (weight ratio is potassium citrate and the natrium citricum of 1:1) in applying glue workshop section again.This cigarette paper quantitatively, air permeability and air permeability amplification sees table 1 and table 2.
Embodiment 4:Carry out the narration of implementation process by producing 1 ton of cigarette paper: adding particle mean size in tankman's section is 600 ~ 800 purpose polyglycolic acid powder (the chemical Co., Ltd of Vad, Jintan City, Jiangsu Province dragon) 80 kilograms (percentage by weight is 8%); Average fiber length is the PLA acid fiber (Jiaxing Puli's Lay new material Co., Ltd) 64 kilograms (percentage by weight is 6.4%) of 1.4mm; 290 kilograms (percentage by weight is 29%) of needle slurry; 336 kilograms (percentage by weight is 33.6%) of broad-leaved slurry; 230 kilograms in calcium carbonate (percentage by weight is 23%), and in joining stock tank, it is mixed, manufacture paper with pulp by the cigarette paper conventional production process.After the cigarette paper dry forming first time, add 20 kilograms of citrates (weight ratio is potassium citrate and the natrium citricum of 1:1) in applying glue workshop section again.This cigarette paper quantitatively, air permeability and air permeability amplification sees table 1 and table 2.
Embodiment 5:Carry out the narration of implementation process by producing 1 ton of cigarette paper: adding average fiber length in tankman's section is 150 kilograms of the polyglycolic acid fibers (Changchun Shengboma Biological Materials Co., Ltd) (percentage by weight is 15%) of 2.0mm; 166 kilograms (percentage by weight is 16.6%) of needle slurry; 390 kilograms (percentage by weight is 39%) of broad-leaved slurry; 294 kilograms in calcium carbonate (percentage by weight is 29.4%), and in joining stock tank, it is mixed, manufacture paper with pulp by the cigarette paper conventional production process.After the cigarette paper dry forming first time, add 20 kilograms of citrates (weight ratio is potassium citrate and the natrium citricum of 1:1) in applying glue workshop section again.This cigarette paper quantitatively, air permeability and air permeability amplification sees table 1 and table 2.
Embodiment 6:Carry out the narration of implementation process by producing 1 ton of cigarette paper: adding average fiber length in tankman's section is 150 kilograms of the polyglycolic acid fibers (Changchun Shengboma Biological Materials Co., Ltd) (percentage by weight is 15%) of 1.0mm; 290 kilograms (percentage by weight is 29%) of needle slurry; 260 kilograms (percentage by weight is 26%) of broad-leaved slurry; 300 kilograms in calcium carbonate (percentage by weight is 30%), and in joining stock tank, it is mixed, manufacture paper with pulp by the cigarette paper conventional production process.After the cigarette paper dry forming first time, add 20 kilograms of citrates (weight ratio is potassium citrate and the natrium citricum of 1:1) in applying glue workshop section again.This cigarette paper quantitatively, air permeability and air permeability amplification sees table 1 and table 2.
To the requirement of cigarette paper physical property, the present invention is according to standard GB/T 12655-2007 to equipment in the rolled cigarette process, several important indicators of above-mentioned six embodiment cigarette paper detected, to characterize the last machine performance of cigarette paper of the present invention.Testing result is seen table 1.
The The performance test results of table 1 cigarette paper
Remarks: the main component of the regular-size cigarette paper in the table 1 is wood pulp fibre, pearl filler and potassium citrate, sodium combustion adjuvant.
Be to characterize the influence of low temperature thermal decomposition polyester material to air permeance for cigarette paper, the cigarette paper of six embodiment of the present invention and regular-size cigarette paper were toasted 30 seconds in the environment of 220 ℃ and 250 ℃, carry out the detection of air permeance for cigarette paper then, the result sees table 2.
Baking is to the influence of air permeance for cigarette paper in table 2 varying environment
Remarks: the 1) air permeability before amplification=100* (air permeability before the air permeability-baking after the baking)/baking; 2) remarks: the main component of the regular-size cigarette paper in the table 2 is wood pulp fibre, pearl filler and potassium citrate, sodium combustion adjuvant.
Claims (6)
1. functional cigarette paper, main component is made up of softwood pulp, hardwood pulp and pearl filler, it is characterized in that, also comprises polyester material.
2. according to claims 1 described functional cigarette paper; It is characterized in that softwood pulp accounts for 15% ~ 30% of cigarette paper dry weight, hardwood pulp accounts for 25% ~ 40% of cigarette paper dry weight; Pearl filler accounts for 15% ~ 30% of cigarette paper dry weight, and polyester material accounts for 1% ~ 15% of cigarette paper dry weight.
3. according to claims 1 or 2 described functional cigarette papers, it is characterized in that described polyester material is PLA or polyglycolic acid or the mixture of the two.
4. according to claims 3 described functional cigarette papers, it is characterized in that described PLA be particle size range at 600 orders ~ 800 purpose PLA powder, or fibre length is at the polylactic acid short-fiber of 0.8mm ~ 2mm.
5. according to claims 3 described functional cigarette papers, it is characterized in that described polyglycolic acid is a particle size range at 600 orders ~ 800 purpose polyglycolic acid powder or the fibre length polyglycolic acid staple fibre at 0.8mm ~ 2mm.
6. according to claims 3 described functional cigarette papers, it is characterized in that described polyester material is the mixture of PLA and polyglycolic acid, both mass ratioes are 10:1 ~ 1:10.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210064858.5A CN102587198B (en) | 2012-03-13 | 2012-03-13 | Functional cigarette paper |
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| CN201210064858.5A CN102587198B (en) | 2012-03-13 | 2012-03-13 | Functional cigarette paper |
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| CN102587198A true CN102587198A (en) | 2012-07-18 |
| CN102587198B CN102587198B (en) | 2014-06-04 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104018391A (en) * | 2014-06-27 | 2014-09-03 | 福建省晋江优兰发纸业有限公司 | Craft knitting paper and preparation method thereof |
| CN105019299A (en) * | 2015-08-12 | 2015-11-04 | 湖南中烟工业有限责任公司 | Application of cigarette paper with thermal cracking pore forming function in preparation of cigarettes with low hydrocyanic acid release amount |
| CN105064119A (en) * | 2015-08-12 | 2015-11-18 | 湖南中烟工业有限责任公司 | Cigarette with low CO and tar release amount |
| CN105064120A (en) * | 2015-08-12 | 2015-11-18 | 湖南中烟工业有限责任公司 | Application of renewable plant fiber, cigarette paper with hole forming function through thermal cracking, and preparation method and application of cigarette paper |
| WO2021139512A1 (en) * | 2020-01-07 | 2021-07-15 | 华南理工大学 | Cooling and filtering material, preparation method therefor, and use thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275656A (en) * | 1999-05-26 | 2000-12-06 | 牡丹江恒丰纸业股份有限公司 | High air permeability cigarette paper |
| CN101798772A (en) * | 2010-04-02 | 2010-08-11 | 云南瑞升烟草技术（集团）有限公司 | Color cotton fiber cigarette paper |
| CN102334751A (en) * | 2010-07-28 | 2012-02-01 | 南通烟滤嘴有限责任公司 | Paper-core filter rod for cigarettes and manufacturing method thereof |
-
2012
- 2012-03-13 CN CN201210064858.5A patent/CN102587198B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275656A (en) * | 1999-05-26 | 2000-12-06 | 牡丹江恒丰纸业股份有限公司 | High air permeability cigarette paper |
| CN101798772A (en) * | 2010-04-02 | 2010-08-11 | 云南瑞升烟草技术（集团）有限公司 | Color cotton fiber cigarette paper |
| CN102334751A (en) * | 2010-07-28 | 2012-02-01 | 南通烟滤嘴有限责任公司 | Paper-core filter rod for cigarettes and manufacturing method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104018391A (en) * | 2014-06-27 | 2014-09-03 | 福建省晋江优兰发纸业有限公司 | Craft knitting paper and preparation method thereof |
| CN105019299A (en) * | 2015-08-12 | 2015-11-04 | 湖南中烟工业有限责任公司 | Application of cigarette paper with thermal cracking pore forming function in preparation of cigarettes with low hydrocyanic acid release amount |
| CN105064119A (en) * | 2015-08-12 | 2015-11-18 | 湖南中烟工业有限责任公司 | Cigarette with low CO and tar release amount |
| CN105064120A (en) * | 2015-08-12 | 2015-11-18 | 湖南中烟工业有限责任公司 | Application of renewable plant fiber, cigarette paper with hole forming function through thermal cracking, and preparation method and application of cigarette paper |
| WO2021139512A1 (en) * | 2020-01-07 | 2021-07-15 | 华南理工大学 | Cooling and filtering material, preparation method therefor, and use thereof |
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| Publication number | Publication date |
|---|---|
| CN102587198B (en) | 2014-06-04 |
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