CN105064119A - Cigarette with low CO and tar release amount - Google Patents

Cigarette with low CO and tar release amount Download PDF

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Publication number
CN105064119A
CN105064119A CN201510492833.9A CN201510492833A CN105064119A CN 105064119 A CN105064119 A CN 105064119A CN 201510492833 A CN201510492833 A CN 201510492833A CN 105064119 A CN105064119 A CN 105064119A
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cigarette
paper
low
cigarette paper
tar
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CN201510492833.9A
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银董红
罗玮
黄富
丁多
黄溢清
钟科军
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China Tobacco Hunan Industrial Co Ltd
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China Tobacco Hunan Industrial Co Ltd
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Priority to CN201510492833.9A priority Critical patent/CN105064119A/en
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Abstract

The invention discloses a cigarette with a low CO and tar release amount. The cigarette is compounded through butt joint of a filter rod and a cut tobacco stick, wherein the filter rod is formed by wrapping tow with tipping paper; the cut tobacco stick is formed by wrapping cut tobacco with the cigarette paper; the tipping paper adopts non-punched tipping paper; the cigarette paper is obtained through beating and papermaking of at least one recycled plant fiber of corn fiber, soybean fiber and straw fiber and a raw material comprising wood pulp and filler. According to the cigarette, the cigarette paper with low-temperature thermal cracking hole forming performance replaces the cigarette paper in the prior art, the effect of reduction of CO and tar in main stream smoke of the cigarette can be realized, and no influence on cigarette sensory quality and no harmful substance are produced during burning of the cigarette paper. By comparison with an existing tipping paper punching technology, the cigarette paper used in the cigarette realizes the same effect of reduction of tar and harmful components as the punched tipping paper, the smoking sensory quality of the cigarette is remarkably improved through the functional tipping paper, and particularly, the preparation cost is greatly reduced.

Description

The cigarette of a kind of low CO and releasing content of coke tar
Technical field
The present invention relates to the cigarette of a kind of low CO and releasing content of coke tar, being specifically related in a kind of cigarette burning process can the cigarette paper of pore in real time, and alternative tipping paper cheesing techniques reduces main flume CO and releasing content of coke tar; Belong to cigarette preparation field.
Background technology
Reducing tar and reducing harm is the inevitable choice of the tobacco business survival and development, in recent years, along with the startup that " Framework Convention on Tobacco Control " works, society constantly strengthens the concern of smoking and health problem, reduces bitting midges and has become significant technology issues urgently to be resolved hurrily.To be formulated by WHO and " Framework Convention on Tobacco Control " of national governments' signature not only defines national governments and will take and carry out effective legislation, administration or other measure and prevent and reduce tobacco consumption, nicotine addiction and Exposure To Tobacco flue gas etc., but also requirement limits tobacco product composition.At present, world's Main Developed Countries has also made concrete limitation standard to the tar of commercial cigarettes, nicotine and CO burst size in succession, as European Union clear stipulaties, after 2004, its commercial cigarettes product must lower than the limit standard of " tar l0mg, nicotine 1mg, CO10mg ".Tobacco research worker is in order to reduce the harm of tobacco product to human health; the health of Protection of consumer better; carry out large quantifier elimination in fields such as leaf tobacco production, processing and reducing tar and reducing harm technology, developed and comprise the reducing tar and reducing harm such as biotechnology, new material technology new tool and be successfully applied in production of cigarettes.Meanwhile, also there is the new trend to low tar, the development of low harmful components release cigarette in international cigarette market.
At present, countries in the world tobacco company produces low-coke tar cigarette (6mg, 8mg) and mostly adopts tipping paper cheesing techniques to meet low tar, the requirement of low CO box target, this technology is mainly used for realizing reducing the object of CO and releasing content of coke tar in main flume by Dilution air, although it has and falls Jiao preferably and fall CO effect, but also there are some unavoidable shortcomings, as caused comparatively significantly negative effect to cigarette odor-absorbing, increase production of cigarettes cost.
Cigarette paper is the important materials in production of cigarettes, and it participates in cigarette burning directly, has important impact to the burning velocity of cigarette, smolderability, the burst size of main flume harmful components, the aspect such as cigarette odor-absorbing and presentation quality.Therefore utilizing cigarette paper on the impact of cigarette burning state, is the effective means realizing reducing cigarette mainstream flue gas harmful components.
Summary of the invention
The deficiency existed for existing Tar aspect and the demand of industry development, the object of the invention is to be to provide CO and releasing content of coke tar in a kind of low cost, main flume low and the good cigarette of cigarette sensory quality.
In order to realize technical purpose of the present invention, the invention provides the cigarette of a kind of low CO and releasing content of coke tar, being docked be composited by filter rod and tobacco rod, filter rod wraps up tow by tipping paper and forms, and tobacco rod is wrapped up pipe tobacco by cigarette paper and formed; Described tipping paper is non-perforated tipping paper; Described cigarette paper by least one aftergrowth fiber in zein fiber, fibre and soya and stalk fibre with comprise wood pulp, the raw material of filler obtained by papermaking of pulling an oar.
Traditional cigarette reduces the method mainly tipping paper cheesing techniques of tar and CO, but this method to there is cost high, and large defect is affected on the organoleptic quality of cigarette.Technical scheme of the present invention replaces the cigarette paper in existing cigarette by a kind of cigarette paper with Low Temperature Thermal cracking pore function of employing, the cigarette paper energy pore in time near line is carbonized in cigarette burning process, considerably increase the diffusion of cigarette paper to CO, too increase the inlet of air simultaneously, make CO Thorough combustion, main flume is diluted fully, realizes the reduction of CO and releasing content of coke tar in main flume.By using this functional cigarette paper, the tipping paper re-using punching can not be needed, and reach the reducing tar and reducing harm effect same with perforated tipping paper.Particularly functional cigarette paper is cheap, relative usage perforated tipping paper technology, greatly reduce production of cigarettes cost, and produce without impact and nonhazardous material cigarette sensory quality in functional cigarette paper combustion process, hinge structure has significant technological progress.
In preferred scheme, aftergrowth fiber quality accounts for 8% ~ 21% of cigarette paper quality.By regulating the ratio of aftergrowth fiber in cigarette paper, cigarette paper pore volume size and micropore number in combustion can be controlled, thus the diffusion of control CO and burnt oil dilution.In order to reduce the burst size of tar and CO in proper range, and not affecting cigarette sensory quality, preferably making aftergrowth fiber quality account for 8% ~ 21% of cigarette paper quality.
In preferred scheme, wood pulp is made up of softwood pulp and hardwood pulp.
More preferably in scheme, softwood pulp quality accounts for 18% ~ 28% of cigarette paper quality.
More preferably in scheme, hardwood pulp quality accounts for 24% ~ 38% of cigarette paper quality.
In preferred scheme, filler is calcium carbonate.
More preferably in scheme, calcium carbonate quality accounts for 27% ~ 48% of cigarette paper quality.
In preferred scheme, in cigarette paper, micro-combustion adjuvant can be added by cigarette paper requirement.
In preferred scheme, aftergrowth fiber is the fiber dust of granularity within the scope of 100 ~ 400 orders, or is the fibre bundle of length within the scope of 0.6 ~ 1.5mm.Consider that aftergrowth fiber will participate in papermaking on the one hand, must meet the cracking in time at low temperatures of aftergrowth fiber on the other hand, near realizing charing line, cigarette paper pore volume increases and micropore increased number; Preferably select the aftergrowth fiber of appropriate size.
The zein fiber that the present invention adopts, fibre and soya and stalk fibre belong to conventional commercially available raw material.Can buy in producers such as Haining Xin Neng Textile Co., Ltd., Yizheng Xing Hai chemical fibre Co., Ltd, Shandong Zheng De Food Co., Ltd, the emerging milky way Chemical Co., Ltd.s in Hubei.
Hinge structure, the Advantageous Effects that technical scheme of the present invention is brought: the present invention adopts a kind of cigarette paper with Low Temperature Thermal cracking pore performance to replace cigarette paper of the prior art and uses, can reach the effect well reducing CO and releasing content of coke tar in cigarette mainstream flue gas, and cigarette paper burns on cigarette sensory quality without affecting and not producing harmful toxic matter; Compared with existing tipping paper cheesing techniques, the present invention adopts functional cigarette paper to reach the reducing tar and reducing harm effect same with perforated tipping paper, but function tipping paper improves obviously the suction organoleptic quality of cigarette, and particularly preparation cost reduces greatly.Technical scheme of the present invention prepares cigarette cigarette paper by adopting the aftergrowth fiber of the Low Temperature Thermal cracking performances such as zein fiber, cigarette paper is made to have the characteristic of Low Temperature Thermal cracking pore, by increasing pore volume and the micropore number of cigarette paper near charing line in cigarette burning process, significantly improve cigarette paper to the diffusion of CO and focusing oil dilution effect, realize the object reducing tar and CO burst size in cigarette mainstream flue gas; And cigarette paper burning produces without impact and unharmful substance cigarette sensory quality.
The present invention prepares cigarette by real-time pore cigarette paper technical substitution tipping paper cheesing techniques, maximum advantage is: tipping paper cheesing techniques relatively, under the prerequisite greatly reducing production of cigarettes cost, significantly can improve the organoleptic quality of cigarette, and reach the effect of the reducing tar and reducing harm same with tipping paper cheesing techniques.The present invention adopts real-time pore functional cigarette paper that smoke delivery can be made to reach the level using conventional tipping paper cheesing techniques, under the condition of namely not punching at tipping paper, fall CO be used for reaching low-coke tar cigarette CO and the requirement of tar box target by using Jiao that falls with real-time pore functional cigarette paper; Shown by smoking result, the Sensory Quality of Cigarette that functional cigarette paper is made smokes panel test score all more than 91 points simultaneously.The preparation method of cigarette paper is simple in addition, the cheaper starting materials of employing, and in all meeting " tobacco additive agent license register ", allow the safe additive of use, meet laws and regulations and the relevant criterion requirement of country, both at home and abroad tobacco business cigarette additive, in actual production is used, there is higher security and practicality, be conducive to suitability for industrialized production and apply.
Detailed description of the invention
Following examples are intended to content of the present invention is described, instead of the further restriction of protection domain to the claims in the present invention.
Comparative example 1
Get 180 kilograms of softwood pulps and 230 kilograms of hardwood pulps, add 280 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 5%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 29gm -2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00gm -2.This is control sample cigarette paper (being numbered P1).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, the results are shown in Table 1.Obtained control sample cigarette paper and perforated tipping paper are combinationally used and manufacture experimently a certain trade mark cigarette (being numbered C1), the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Embodiment 1
Get 180 kilograms of softwood pulps, 230 kilograms of hardwood pulps, 70 kilograms of fibre and soyas (100 ~ 400 order), 50 kilograms of zein fibers (100 ~ 400 order), add 280 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 5%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 29gm -2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00gm -2(being numbered P2).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, the results are shown in Table 1.Obtained real-time pore cigarette paper and common non-perforated tipping paper are combinationally used and manufactures experimently a certain trade mark cigarette (being numbered C2), the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.Table 2 result shows, and compared with adopting the control sample cigarette C1 of tipping paper cheesing techniques, adopts CO in the experiment sample C2 main flume of real-time pore cigarette paper technical substitution tipping paper cheesing techniques substantially suitable with releasing content of coke tar.Table 3 result shows, and the organoleptic quality score of C2 cigarette is obviously better than C1 cigarette.
Embodiment 2
Get 180 kilograms of softwood pulps, 220 kilograms of hardwood pulps, 60 kilograms of zein fibers (100 ~ 400 order), 20 kilograms of stalk fibres (100 ~ 400 order), add 270 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 5%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 29gm -2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00gm -2(being numbered P3).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, the results are shown in Table 1.Obtained real-time pore cigarette paper and common non-perforated tipping paper are combinationally used and manufactures experimently a certain trade mark cigarette (being numbered C3), the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.Table 2 result shows, and compared with adopting the control sample cigarette C1 of tipping paper cheesing techniques, adopts CO in the experiment sample C3 main flume of real-time pore cigarette paper technical substitution tipping paper cheesing techniques substantially suitable with releasing content of coke tar.Table 3 result shows, and the organoleptic quality score of C3 cigarette is obviously better than C1 cigarette.
Embodiment 3
Get 200 kilograms of softwood pulps, 230 kilograms of hardwood pulps, 80 kilograms of fibre and soyas (long 0.6 ~ 1.5mm), 40 kilograms of stalk fibres (long 0.6 ~ 1.5mm), add 310 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 5%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 29gm -2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00gm -2(being numbered P4).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, the results are shown in Table 1.Obtained real-time pore cigarette paper and common non-perforated tipping paper are combinationally used and manufactures experimently a certain trade mark cigarette (being numbered C4), the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.Table 2 result shows, and compared with adopting the control sample cigarette C1 of tipping paper cheesing techniques, adopts CO in the experiment sample C4 main flume of real-time pore cigarette paper technical substitution tipping paper cheesing techniques substantially suitable with releasing content of coke tar.Table 3 result shows, and the organoleptic quality score of C4 cigarette is obviously better than C1 cigarette.
Embodiment 4
Get 180 kilograms of softwood pulps, 230 kilograms of hardwood pulps, 60 kilograms of zein fibers (100 ~ 400 order), 60 kilograms of fibre and soyas (100 ~ 400 order), 30 kilograms of stalk fibres (100 ~ 400 order), add 280 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 5%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, equipment controls cigarette paper parameter is: quantitatively 29gm -2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00gm -2(being numbered P5).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, the results are shown in Table 1.Obtained real-time pore cigarette paper and common non-perforated tipping paper are combinationally used and manufactures experimently a certain trade mark cigarette (being numbered C5), the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.Table 2 result shows, and compared with adopting the control sample cigarette C1 of tipping paper cheesing techniques, adopts CO in the experiment sample C5 main flume of real-time pore cigarette paper technical substitution tipping paper cheesing techniques substantially suitable with releasing content of coke tar.Table 3 result shows, and the organoleptic quality score of C5 cigarette is obviously better than C1 cigarette.
Embodiment 5
Get 180 kilograms of softwood pulps, 230 kilograms of hardwood pulps, 50 kilograms of zein fibers (100 ~ 400 order), 40 kilograms of fibre and soyas (100 ~ 400 order), 30 kilograms of stalk fibres (100 ~ 400 order), add 280 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 5%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, equipment controls cigarette paper parameter is: quantitatively 29gm -2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00gm -2(being numbered P6).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, the results are shown in Table 1.Obtained real-time pore cigarette paper and common non-perforated tipping paper are combinationally used and manufactures experimently a certain trade mark cigarette (being numbered C6), the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.Table 2 result shows, and compared with adopting the control sample cigarette C1 of tipping paper cheesing techniques, adopts CO in the experiment sample C6 main flume of real-time pore cigarette paper technical substitution tipping paper cheesing techniques substantially suitable with releasing content of coke tar.Table 3 result shows, and the organoleptic quality score of C6 cigarette is obviously better than C1 cigarette.
The change of (afterwards) diffusivity before the baking of table 1 cigarette paper
Cigarette paper sample Diffusivity (cm/s) before baking Diffusivity (cm/s) after baking Increment rate
P1 1.58 3.30 108.8%
P2 1.60 3.75 134.3%
P3 1.55 3.89 151.0%
P4 1.61 4.20 160.9%
P5 1.64 4.02 145.1%
P6 1.58 3.96 150.6%
The conventional flue gas data of table 2 cigarette mainstream flue gas
Table 3 Sensory Quality of Cigarette is smoked panel test data (judging panel's number 9 people)

Claims (8)

1. a cigarette for low CO and releasing content of coke tar, is docked by filter rod and tobacco rod and is composited, and filter rod wraps up tow by tipping paper and forms, and tobacco rod is wrapped up pipe tobacco by cigarette paper and formed, and it is characterized in that, described tipping paper is non-perforated tipping paper; Described cigarette paper by least one aftergrowth fiber in zein fiber, fibre and soya and stalk fibre with comprise wood pulp, the raw material of filler obtained by papermaking of pulling an oar.
2. the cigarette of low CO according to claim 1 and releasing content of coke tar, is characterized in that, described aftergrowth fiber quality accounts for 8% ~ 21% of cigarette paper quality.
3. the cigarette of low CO according to claim 1 and releasing content of coke tar, is characterized in that, described wood pulp is made up of softwood pulp and hardwood pulp.
4. the cigarette of low CO according to claim 3 and releasing content of coke tar, is characterized in that, described softwood pulp quality accounts for 18% ~ 28% of cigarette paper quality; Described hardwood pulp quality accounts for 24% ~ 38% of cigarette paper quality.
5. the cigarette of low CO according to claim 1 and releasing content of coke tar, is characterized in that, described filler is calcium carbonate.
6. the cigarette of low CO according to claim 5 and releasing content of coke tar, is characterized in that, described calcium carbonate quality accounts for 27% ~ 48% of cigarette paper quality.
7. the cigarette of low CO according to claim 1 and releasing content of coke tar, is characterized in that, can add micro-combustion adjuvant in described cigarette paper by cigarette paper requirement.
8. the cigarette of low CO according to claim 1 and releasing content of coke tar, is characterized in that, described aftergrowth fiber is the fiber dust of granularity within the scope of 100 ~ 400 orders, or is the fibre bundle of length within the scope of 0.6 ~ 1.5mm.
CN201510492833.9A 2015-08-12 2015-08-12 Cigarette with low CO and tar release amount Pending CN105064119A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110546322A (en) * 2017-04-27 2019-12-06 日本制纸株式会社 Method for producing inorganic particle composite fiber
CN111165871A (en) * 2020-01-17 2020-05-19 湖南中烟工业有限责任公司 Low-harm cigarette subjected to cigarette enhancement treatment

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110546322A (en) * 2017-04-27 2019-12-06 日本制纸株式会社 Method for producing inorganic particle composite fiber
CN110546322B (en) * 2017-04-27 2022-06-03 日本制纸株式会社 Method for producing inorganic particle composite fiber
CN111165871A (en) * 2020-01-17 2020-05-19 湖南中烟工业有限责任公司 Low-harm cigarette subjected to cigarette enhancement treatment

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Application publication date: 20151118