CN103233391B - A kind of cigarette Acidic flame-retardant additive and application thereof - Google Patents
A kind of cigarette Acidic flame-retardant additive and application thereof Download PDFInfo
- Publication number
- CN103233391B CN103233391B CN201310116018.3A CN201310116018A CN103233391B CN 103233391 B CN103233391 B CN 103233391B CN 201310116018 A CN201310116018 A CN 201310116018A CN 103233391 B CN103233391 B CN 103233391B
- Authority
- CN
- China
- Prior art keywords
- cigarette
- acid
- flame
- retardant additive
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses a kind of cigarette Acidic flame-retardant additive and application thereof, this flame-retardant additive is one or more in oxalic acid, malic acid, caffeic acid, citric acid, tartaric acid, ascorbic acid or aluminum sulfate; Application one or more in above-mentioned flame-retardant additive is connect after mouth glue mixes as flame-retardant additive and cigarette to be coated in cigarette tipping paper position; This additive raw material is cheap and easy to get, safety non-toxic evil, proterties are stablized when using, free from extraneous odour and keep the original suction quality of cigarette, has and stub can be made to have fast from the function put out; This additive application is fire-retardant in cigarette, and the cigarette combustion do not extinguished is to when having a position of tipping paper, and stub self-extinguish in 1 ~ 2 minute, certainly puts out rate and can reach 100%, can effectively prevent and reduce because of the fire caused by non-extingushing cigarette tip.
Description
Technical field
The present invention relates to a kind of cigarette Acidic flame-retardant additive and application thereof, belong to technical field of cigarettes.
Background technology
China is cigarette producing country maximum in the world, is also tobacco consumption state maximum in the world.Along with the development of tobacco science and technology, " smoking is with healthy ", " smoking and safety " become the main trend that tobacco business develops gradually.This mainly considers from two aspects: the infringement that is the flue gas that produces of cigarette burning produces human body and surrounding environment and pollution, two refer to the fire caused by smoking.
Lighted cigarette butt surface temperature is 200 DEG C ~ 300 DEG C, and central temperature is 700 DEG C ~ 800 DEG C, apparently higher than the burning-point of other combustible materials.If paper is 130 DEG C, cotton-wadded quilt, numb suede are 150 degree, and pine is 250 DEG C.It is 4 ~ 15 minutes that Linear Leaf Speedwell cigarette prolongs the burning time, and inhale surplus cigarette end and generally can continue to ignite 1 ~ 4 minute, within this time, many inflammability article all can be lighted.Sometimes cigarette end is thrown away in cotton-wadded quilt, wood shavings, wood chip or thick grass, dozens of minutes of glowing, and be not easy to be noted by people, danger is larger.
According to statistics, what in Japanese family fire, smoking caused accounts for 26%, and what in American family fire, smoking caused accounts for 29.1%.These countries have every year many people to die from smoking or the fire throwing out cigarette end without care and cause due to carelessness.The fire that cigarette end causes in some cities of China accounts for 1/7th of fire sum, causes the news report of personnel and property loss to happen occasionally by the house or forest fire throwing out cigarette end initiation without care.
Summary of the invention
The present invention is directed to and inhale surplus stub and there is very conflagration hidden danger, object is to provide a kind of cheaper starting materials to be easy to get, safety non-toxic evil, proterties are stablized when using, free from extraneous odour and keep the original suction quality of cigarette, stub can be made to have fast from the additive putting out function.
Another object of the present invention is the application being to additionally provide a kind of cigarette Acidic flame-retardant additive, and this additive application is fire-retardant in cigarette, can effective fire-retarded butt fast, and keeps the original suction quality of cigarette, the disaster hidden-trouble that can effectively prevent stub from bringing.
The invention provides a kind of cigarette flame-retardant additive, this additive comprises one or more in oxalic acid, malic acid, caffeic acid, citric acid, tartaric acid, ascorbic acid or aluminum sulfate.
Preferred Acidic flame-retardant additive is tartaric acid and caffeinic composite, or oxalic acid, malic acid and ascorbic acid is composite, or citric acid and caffeinic composite, or citric acid and aluminum sulfate is composite.
Described tartaric acid and caffeic acid are that 1:0.5 ~ 2 are composite in mass ratio; Described oxalic acid, malic acid and ascorbic acid are that 1:0.5 ~ 2:0.5 ~ 2 are composite in mass ratio; Described citric acid and caffeic acid are that 1:0.5 ~ 2 are composite in mass ratio; Described citric acid and aluminum sulfate are that 1:0.5 ~ 2 are composite in mass ratio.
Present invention also offers a kind of application of cigarette flame-retardant additive, this application is that one or more in oxalic acid, malic acid, caffeic acid, citric acid, tartaric acid, ascorbic acid or aluminum sulfate are applied to cigarette as flame-retardant additive is fire-retardant.
Described being applied as mass ratio is that the tartaric acid of 1:0.5 ~ 2 and caffeic acid are composite, or mass ratio is that the oxalic acid of 1:0.5 ~ 2:0.5 ~ 2, malic acid and ascorbic acid are composite, or mass ratio is that the citric acid of 1:0.5 ~ 2 and caffeic acid are composite, or mass ratio is that the citric acid of 1:0.5 ~ 2 and aluminum sulfate are composite, connects after mouth glue mixes be coated in cigarette tipping paper position as flame-retardant additive and cigarette.
Described flame-retardant additive is 5 ~ 15wt% at the content that cigarette connects in mouth glue.
The pH that described cigarette connects mouth glue is 4 ~ 6.
Described cigarette connects mouth glue primarily of one or more compositions in the polyvinyl acetate of acidity, vinyl acetate copolymer, polyvinyl alcohol.
The purity requirement of oxalic acid of the present invention, malic acid, caffeic acid, citric acid, tartaric acid, ascorbic acid, aluminum sulfate is that food adds level or more.
The remarkable advantage that the present invention has:
A, the present invention from numerous material through repetition test, the Acidic flame-retardant additive filtered out is more cheap and easy to get relative to other flame-retardant additive, safer environmental protection, totally nontoxic, meets the requirement of " food additives use sanitary standard " (GB2760-2007) and " food containers, packaging material additive use sanitary standard " (GB9685-2008) and " tobacco additive agent license register " etc. completely;
During b, additive application of the present invention are fire-retardant to cigarette, when cigarette combustion is to when having a position of tipping paper, in 1 ~ 2 minute, stub can self-extinguish, certainly puts out rate and can reach 100%, therefore can effectively prevent and reduce because of the fire caused by non-extingushing cigarette tip;
C, additive proterties of the present invention are stable, and can keep the original suction quality of cigarette and taste, smoke chemistry index is substantially unchanged.
Detailed description of the invention
Now further illustrate in conjunction with the embodiments, and restriction can not be formed to the present invention:
Embodiment 1
Connect in mouth glue at 440 grams of regular-size cigarettes and slowly add 30 grams of tartaric acid and 30 grams of caffeic acids while stirring to dissolving completely, mixing.
Adopt the above-mentioned tartaric acid that with the addition of to connect mouth glue, identical pipe tobacco and other auxiliary material with the caffeinic mouth glue that connects with regular-size cigarette respectively, production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, excitant, pleasant impression etc.) are evaluated; By standard method, analyzing and testing is carried out to two kinds of cigarette sample main flume conventional chemical indexs simultaneously;
Cigarette sample quality evaluation result shows: by with the addition of tartaric acid and the caffeinic cigarette connecing mouth film can keep the original suction quality of cigarette and taste substantially, and cigarette sample main flume conventional chemical index analysis testing result shows both basic indifferences.
End extinguishing is tested:
D, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, self-burning, when firing the position to tipping paper, observe it from putting out rate;
E, two kinds of cigarette samples are divided into two groups, respectively getting 20 and light rear vertical placement (combustion head-up), self-burning, when firing the position to tipping paper, observing it from putting out rate;
Test result shows: the sample connecing mouth film with regular-size cigarette from putting out rate≤10%, with the addition of tartaric acid and the caffeinic sample connecing mouth film is 100% from putting out rate.
Embodiment 2
Connect in mouth glue at 440 grams of regular-size cigarettes and add 30 grams of citric acids and 30 grams of aluminum sulfate while stirring respectively to dissolving completely, mixing.
Adopt the above-mentioned mouth glue that connects that with the addition of aluminum sulfate to connect mouth glue, identical pipe tobacco and other auxiliary material with regular-size cigarette respectively, production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, excitant, pleasant impression etc.) are evaluated; By standard method, analyzing and testing is carried out to two kinds of cigarette sample main flume conventional chemical indexs simultaneously;
Cigarette sample quality evaluation result shows: substantially can keep the original suction quality of cigarette and taste by the cigarette connecing mouth film that with the addition of citric acid and aluminum sulfate, and cigarette sample main flume conventional chemical index analysis testing result shows both basic indifferences.
End extinguishing is tested:
F, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, self-burning, when firing the position to tipping paper, observe it from putting out rate;
G, two kinds of cigarette samples are divided into two groups, respectively getting 20 and light rear vertical placement (combustion head-up), self-burning, when firing the position to tipping paper, observing it from putting out rate;
Test result shows, the sample connecing mouth film with regular-size cigarette, from putting out rate≤10%, is 100% with the sample connecing mouth film that with the addition of aluminum sulfate from putting out rate.
Embodiment 3
Connect in mouth glue at 440 grams of regular-size cigarettes and slowly add 20 grams of oxalic acid, 20 grams of malic acid and 20 grams of ascorbic acid while stirring to dissolving completely, mixing.
Adopt respectively and above-mentionedly with the addition of oxalic acid, malic acid connects mouth glue, identical pipe tobacco and other auxiliary material with the mouth glue that connects of ascorbic acid with regular-size cigarette, production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, excitant, pleasant impression etc.) are evaluated; By standard method, analyzing and testing is carried out to two kinds of cigarette sample main flume conventional chemical indexs simultaneously;
Cigarette sample quality evaluation result shows: substantially can keep the original suction quality of cigarette and taste by the cigarette connecing mouth film that with the addition of oxalic acid, malic acid and ascorbic acid, and cigarette sample main flume conventional chemical index analysis testing result shows both basic indifferences.
End extinguishing is tested:
H, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, self-burning, when firing the position to tipping paper, observe it from putting out rate;
I, two kinds of cigarette samples are divided into two groups, respectively getting 20 and light rear vertical placement (combustion head-up), self-burning, when firing the position to tipping paper, observing it from putting out rate;
Test result shows: the sample connecing mouth film with regular-size cigarette, from putting out rate≤10%, is 100% with the sample connecing mouth film that with the addition of oxalic acid, malic acid and ascorbic acid from putting out rate.
Embodiment 4
Connect in mouth glue at 450 grams of regular-size cigarettes and slowly add 50 grams of oxalic acid while stirring to dissolving completely, mixing.
Adopt the above-mentioned mouth glue that connects that with the addition of oxalic acid to connect mouth glue, identical pipe tobacco and other auxiliary material with regular-size cigarette respectively, production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, excitant, pleasant impression etc.) are evaluated; By standard method, analyzing and testing is carried out to two kinds of cigarette sample main flume conventional chemical indexs simultaneously;
Cigarette sample quality evaluation result shows: when being aspirated by the cigarette connecing mouth film that with the addition of oxalic acid, pungent taste mouthfeel is described and strengthened, but cigarette sample main flume conventional chemical index analysis testing result shows both basic indifferences.
End extinguishing is tested:
J, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, self-burning, when firing the position to tipping paper, observe it from putting out rate;
K, two kinds of cigarette samples are divided into two groups, respectively getting 20 and light rear vertical placement (combustion head-up), self-burning, when firing the position to tipping paper, observing it from putting out rate;
Test result shows: the sample connecing mouth film with regular-size cigarette is from putting out rate≤10%, and certainly putting out rate with the sample connecing mouth film that with the addition of oxalic acid is 60%.
Embodiment 5
Connect in mouth glue at 440 grams of regular-size cigarettes and add 30 grams of citric acids and 30 grams of caffeic acids while stirring respectively to dissolving completely, mixing.
Adopt the above-mentioned citric acid that with the addition of to connect mouth glue, identical pipe tobacco and other auxiliary material with the caffeinic mouth glue that connects with regular-size cigarette respectively, production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, excitant, pleasant impression etc.) are evaluated; By standard method, analyzing and testing is carried out to two kinds of cigarette sample main flume conventional chemical indexs simultaneously;
Cigarette sample quality evaluation result shows: with the addition of citric acid and the caffeinic cigarette connecing mouth film can keep the original suction quality of cigarette and taste substantially, and cigarette sample main flume conventional chemical index analysis testing result shows both basic indifferences.
End extinguishing is tested:
L, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, self-burning, when firing the position to tipping paper, observe it from putting out rate;
M, two kinds of cigarette samples are divided into two groups, respectively getting 20 and light rear vertical placement (combustion head-up), self-burning, when firing the position to tipping paper, observing it from putting out rate;
Test result shows: the sample connecing mouth film with regular-size cigarette from putting out rate≤5%, with the addition of citric acid and the caffeinic sample connecing mouth film from putting out rate 100%.
Comparative example 1
Connect in mouth glue at 440 grams of regular-size cigarettes and add 30 grams of salicylic acids and 30 grams of benzoic acid while stirring respectively to dissolving completely, mixing.
Adopt the above-mentioned salicylic acid that with the addition of to connect mouth glue, identical pipe tobacco and other auxiliary material with the benzoic mouth glue that connects with regular-size cigarette respectively, production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, excitant, pleasant impression etc.) are evaluated; By standard method, analyzing and testing is carried out to two kinds of cigarette sample main flume conventional chemical indexs simultaneously;
Cigarette sample quality evaluation result shows: describe strengthen by with the addition of pungent taste mouthfeel when salicylic acid and the benzoic cigarette connecing mouth film are aspirated, pleasant impression is impure, but cigarette sample main flume conventional chemical index analysis testing result shows both basic indifferences.
End extinguishing is tested:
O, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, self-burning, when firing the position to tipping paper, observe it from putting out rate;
P, two kinds of cigarette samples are divided into two groups, respectively getting 20 and light rear vertical placement (combustion head-up), self-burning, when firing the position to tipping paper, observing it from putting out rate;
Test result shows: the sample connecing mouth film with regular-size cigarette from putting out rate≤10%, with the addition of salicylic acid and the benzoic sample connecing mouth film from putting out rate≤40%.
Claims (5)
1. a cigarette flame-retardant additive, is characterized in that, described flame-retardant additive is tartaric acid and caffeic acid is that 1:0.5 ~ 2 are composite in mass ratio; Or be that oxalic acid, malic acid and ascorbic acid are in mass ratio for 1:0.5 ~ 2:0.5 ~ 2 are composite; Or be that citric acid and caffeic acid are in mass ratio for 1:0.5 ~ 2 are composite; Or be that citric acid and aluminum sulfate are in mass ratio for 1:0.5 ~ 2 are composite.
2. the application of a cigarette flame-retardant additive, it is characterized in that, the tartaric acid and the caffeic acid that by mass ratio are 1:0.5 ~ 2 are composite, or mass ratio is that the oxalic acid of 1:0.5 ~ 2:0.5 ~ 2, malic acid and ascorbic acid are composite, or mass ratio is that the citric acid of 1:0.5 ~ 2 and caffeic acid are composite, or mass ratio is that the citric acid of 1:0.5 ~ 2 and aluminum sulfate are composite, connects as flame-retardant additive and cigarette and to be coated in cigarette tipping paper position after mouth glue mixes to be applied to cigarette fire-retardant.
3. apply as claimed in claim 2, it is characterized in that, described flame-retardant additive is 5 ~ 15wt% at the content that cigarette connects in mouth glue.
4. apply as claimed in claim 3, it is characterized in that, the pH that described cigarette connects mouth glue is 4 ~ 6.
5. apply as claimed in claim 2, it is characterized in that, described cigarette connects mouth glue primarily of one or more compositions in the polyvinyl acetate of acidity, vinyl acetate copolymer, polyvinyl alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310116018.3A CN103233391B (en) | 2013-04-03 | 2013-04-03 | A kind of cigarette Acidic flame-retardant additive and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310116018.3A CN103233391B (en) | 2013-04-03 | 2013-04-03 | A kind of cigarette Acidic flame-retardant additive and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103233391A CN103233391A (en) | 2013-08-07 |
| CN103233391B true CN103233391B (en) | 2015-10-07 |
Family
ID=48881455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310116018.3A Active CN103233391B (en) | 2013-04-03 | 2013-04-03 | A kind of cigarette Acidic flame-retardant additive and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103233391B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107821402A (en) * | 2017-10-19 | 2018-03-23 | 鄄城康泰化工有限公司 | A kind of sym-closene aerosol disinfectant |
| CN110698115B (en) * | 2019-09-05 | 2021-11-23 | 中南林业科技大学 | Phosphotungstic acid intercalated hydrotalcite-like light foam heat insulation material and preparation method thereof |
| CN113215859B (en) * | 2021-05-11 | 2023-11-10 | 安徽工程大学 | Simple, efficient and environment-friendly preparation method of flame-retardant office paper |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031793A (en) * | 1987-09-03 | 1989-03-22 | 英美烟草公司 | The improvement of smoking article |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5105837A (en) * | 1990-08-28 | 1992-04-21 | R. J. Reynolds Tobacco Company | Smoking article with improved wrapper |
| CN1795771A (en) * | 2004-12-24 | 2006-07-05 | 长沙卷烟厂 | Fireproof self-extinguishing safe type cigarette and preparation method |
| JP5493991B2 (en) * | 2010-02-24 | 2014-05-14 | 富士ゼロックス株式会社 | Polylactic acid-based resin composition, method for producing polylactic acid-based resin composition, and polylactic acid-based resin molded article |
| CN102321438A (en) * | 2011-08-04 | 2012-01-18 | 湖南中烟工业有限责任公司 | Flame-retardant adhesive additive, and flame-retardant adhesive and application method thereof |
| CN102391795A (en) * | 2011-09-26 | 2012-03-28 | 湖南中烟工业有限责任公司 | Acidic flame-retardant adhesive for automatically extinguishing cigarettes and application method |
-
2013
- 2013-04-03 CN CN201310116018.3A patent/CN103233391B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031793A (en) * | 1987-09-03 | 1989-03-22 | 英美烟草公司 | The improvement of smoking article |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103233391A (en) | 2013-08-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102199902B (en) | Cigarette paper with low ignition tendency and preparation method | |
| CA2729564C (en) | Cigarette paper coated with coating materials for low ignition propensity and a fire-safe cigarette covered by the same | |
| CN102321438A (en) | Flame-retardant adhesive additive, and flame-retardant adhesive and application method thereof | |
| CN103233391B (en) | A kind of cigarette Acidic flame-retardant additive and application thereof | |
| CN101781867B (en) | Low ignition tendency cigarette paper and preparation method thereof | |
| CN103173162B (en) | Acidic flame-retardant holder adhesive for cigarettes | |
| CN107898001A (en) | Leaf group raw material and its application in terms of cigarette is not burnt in preparation heating | |
| CN102839565A (en) | Cigarette paper additive for reducing harmful ingredients of cigarette mainstream smoke and application thereof | |
| CN101775759A (en) | Cigarette paper additive, preparation method and application thereof | |
| CN102587198B (en) | Functional cigarette paper | |
| CN102345247A (en) | Application method of flame retardant paint, as well as flame-retardant cigarette tipping paper and cigarette | |
| CN204707984U (en) | A kind of ternary composite rod | |
| CN104188105A (en) | Preparation method and device for slow release spice sheets and adsorbing sheets for cigarettes | |
| CN202072983U (en) | Lower ignition propensity cigarette paper | |
| CN105064119A (en) | Cigarette with low CO and tar release amount | |
| CN109288127A (en) | A kind of composition and application thereof of adjustable cigarette mainstream flue gas pH value | |
| PH12014502651B1 (en) | Cigarette paper comprising a lamellar filler | |
| JP2006217820A (en) | Cigarette | |
| CN107927904A (en) | Cigarette filter rod curing agent and its preparation and application | |
| CN1795770A (en) | Fireproof self-extinguishing cigarette, preparation device and preparation method | |
| CN1795771A (en) | Fireproof self-extinguishing safe type cigarette and preparation method | |
| JP2006187260A (en) | Cigarette | |
| CN101408014A (en) | Acetate fiber coating paper and paper filter stick for preparing cigarette filter stick and preparing method thereof | |
| CN201242541Y (en) | Apparatus for observing cigarette burning performance | |
| CN209768965U (en) | Cooling slice for cigarette |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |