CN114304726A - Cigarette rod for improving ash wrapping performance, cigarette containing cigarette rod and preparation method of cigarette - Google Patents
Cigarette rod for improving ash wrapping performance, cigarette containing cigarette rod and preparation method of cigarette Download PDFInfo
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- CN114304726A CN114304726A CN202011060098.1A CN202011060098A CN114304726A CN 114304726 A CN114304726 A CN 114304726A CN 202011060098 A CN202011060098 A CN 202011060098A CN 114304726 A CN114304726 A CN 114304726A
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- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 372
- 238000002360 preparation method Methods 0.000 title claims description 9
- 239000000654 additive Substances 0.000 claims abstract description 145
- 241000208125 Nicotiana Species 0.000 claims abstract description 131
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 130
- 230000000996 additive effect Effects 0.000 claims abstract description 127
- 238000002485 combustion reaction Methods 0.000 claims abstract description 116
- 239000002245 particle Substances 0.000 claims abstract description 37
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 90
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 64
- 238000000034 method Methods 0.000 claims description 54
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 51
- 239000001488 sodium phosphate Substances 0.000 claims description 51
- 235000011008 sodium phosphates Nutrition 0.000 claims description 51
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 51
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 42
- 239000000391 magnesium silicate Substances 0.000 claims description 42
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 42
- 235000019792 magnesium silicate Nutrition 0.000 claims description 42
- 239000001508 potassium citrate Substances 0.000 claims description 34
- 229960002635 potassium citrate Drugs 0.000 claims description 34
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 34
- 235000011082 potassium citrates Nutrition 0.000 claims description 34
- 239000001509 sodium citrate Substances 0.000 claims description 34
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 34
- 239000011122 softwood Substances 0.000 claims description 34
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 32
- 239000011121 hardwood Substances 0.000 claims description 31
- 238000004537 pulping Methods 0.000 claims description 31
- 238000004519 manufacturing process Methods 0.000 claims description 29
- 238000001035 drying Methods 0.000 claims description 28
- 238000005507 spraying Methods 0.000 claims description 28
- 239000000378 calcium silicate Substances 0.000 claims description 27
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 27
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 239000000835 fiber Substances 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 12
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 12
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 11
- 241000196324 Embryophyta Species 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 8
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 7
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 7
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 6
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 6
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 6
- 238000005096 rolling process Methods 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 16
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004513 sizing Methods 0.000 description 58
- 230000035699 permeability Effects 0.000 description 31
- 238000011156 evaluation Methods 0.000 description 30
- 238000012546 transfer Methods 0.000 description 29
- 238000011056 performance test Methods 0.000 description 28
- 230000008569 process Effects 0.000 description 23
- 230000000052 comparative effect Effects 0.000 description 18
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 18
- 229910000160 potassium phosphate Inorganic materials 0.000 description 9
- 235000011009 potassium phosphates Nutrition 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- 238000011160 research Methods 0.000 description 7
- 239000011258 core-shell material Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- FLAQQSHRLBFIEZ-UHFFFAOYSA-N N-Methyl-N-nitroso-4-oxo-4-(3-pyridyl)butyl amine Chemical compound O=NN(C)CCCC(=O)C1=CC=CN=C1 FLAQQSHRLBFIEZ-UHFFFAOYSA-N 0.000 description 1
- 244000184734 Pyrus japonica Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
Images
Abstract
The invention belongs to the technical field of traditional cigarettes (combustion type cigarettes), and particularly relates to a cigarette rod for improving ash wrapping performance, which comprises a tobacco rod and cigarette paper wrapping the tobacco rod, wherein an additive A is added into the tobacco rod, and an additive B is added into the cigarette paper; wherein the additive A is at least one of alkali metal phosphate, dibasic hydrogen phosphate and monobasic hydrogen phosphate; the additive B is water-insoluble silicate particles. The invention innovatively combines the additives A and B, and further cooperates with the combined control of the addition modes of the additives A and B, and chemical reactions can be mutually generated in the combustion stage, so that the ash wrapping effect is synergistically improved, and the combustion appearance of the cigarette is improved.
Description
Technical Field
The invention belongs to the technical field of traditional cigarettes, and particularly relates to a cigarette rod capable of improving ash wrapping performance and a cigarette thereof.
Background
The cigarette paper and the tobacco shreds are main bodies of the cigarette in the combustion process, and the problems of turning around, ash falling, soot blackening and the like in the combustion process are caused by the difference of combustion performances of the cigarette paper and the tobacco shreds, so that the smoking experience of consumers is seriously influenced. In recent years, much research has been conducted at home and abroad on the improvement of cigarette ash wrapping performance by adjusting cigarette paper parameters and the influence of different tobacco shred formulas on combustion. For example, the carbon fiber cigarette paper for improving the ash wrapping property invented by the Modi company, namely, the carbon fiber which accounts for 60 percent of the total amount of the fiber and has the average length of less than 1.91cm is added into the cigarette paper, so that the ash wrapping capability of the cigarette paper can be obviously improved. The cigarette paper for inhibiting the dispersion of the cigarette ash developed by Nicotiana japonica company can obviously inhibit the splitting of the cigarette ash without increasing the total amount of the auxiliary agent. The research on the factors influencing the ash wrapping capacity of the cigarette paper by the cigarette in Hubei shows that the cigarette paper has increased air permeability, quantitatively increased air permeability, reduced citrate combustion improver content and properly increased proportion of reconstituted tobacco leaves, the ash wrapping capacity of the cigarette paper is enhanced, and the ash wrapping capacity of the cigarette paper is enhanced.
In the aspect of influence of a tobacco shred formula and a tobacco shred structure on the falling of a combustion cone, research is carried out by changing the sizes of cut stems, reconstituted tobacco shreds and cut leaves in the tobacco shred formula, and the influence factors of the tobacco shred structure on the falling rate of the cigarette combustion cone are found to be the reconstituted tobacco shred ratio, the filament ratio, the medium shred ratio and the cut stem ratio, and the ash wrapping phenomenon of the cigarette can be effectively improved by reducing the filament ratio and improving the medium and short shred ratio.
Although some techniques for improving the ash performance of cigarettes are reported in the prior art, the ash coating effect of cigarettes still needs to be further improved.
Disclosure of Invention
In view of the defects of the prior art, the invention provides a cigarette rod (also referred to as a burning rod for short) capable of improving the ash wrapping performance of cigarette, and aims to provide a cigarette rod capable of obviously improving the ash wrapping performance through the synergistic combination of a tobacco rod and cigarette paper.
The invention also provides a preparation method of the cigarette rod.
The third purpose of the invention is to provide a cigarette with the cigarette rod.
A cigarette rod for improving ash wrapping performance comprises a tobacco rod and cigarette paper wrapping the tobacco rod, wherein an additive A is added into the tobacco rod, and an additive B is added into the cigarette paper;
wherein the additive A is at least one of alkali metal phosphate, dibasic hydrogen phosphate and monobasic hydrogen phosphate;
the additive B is water-insoluble silicate particles.
The invention innovatively combines the additives A and B, and further cooperates with the combined control of the addition modes of the additives A and B, and the additives A and B can mutually and chemically react in the combustion stage, thereby synergistically improving the ash coating effect and improving the combustion appearance of cigarettes.
In the invention, the control of the components of the additives A and B and the special control of the adding mode are the key points for realizing the synergy of the additives A and B. The research of the invention finds that the required additive A and the required additive B are adopted, the additive A is further taken as a core, the additive B is taken as a shell layer, and based on the component control and the control of the special core-shell structure, good synergistic effect can be realized in the aspect of improving the ash coating.
In the present invention, the additive a is a salt containing an alkali metal and a phosphate, wherein the alkali metal is preferably sodium. Researches find that in the burning process of cigarettes, sodium phosphate is taken as a core and is further matched with the shell of the additive B, so that the ash wrapping effect is further improved.
Preferably, the additive A is at least one of sodium phosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate, potassium dihydrogen phosphate and dipotassium hydrogen phosphate.
More preferably, the additive A is a compound additive. The compound additive A contains two or more additives of additive components.
The preferable compound additive A at least comprises sodium phosphate and optionally at least one of sodium dihydrogen phosphate, disodium hydrogen phosphate, potassium dihydrogen phosphate and dipotassium hydrogen phosphate. The research of the invention finds that the additive A is adopted, and the additive B is further matched with the control of the core-shell structure, so that the ash coating performance of the material is further improved.
More preferably, the additive A at least contains sodium phosphate, and optionally at least one of sodium dihydrogen phosphate and potassium phosphate.
Still more preferably, in the formulated additive a, the content of sodium phosphate is not less than 10 wt.%; preferably 40 to 60 wt.%.
In the invention, the additive A is uniformly adsorbed in the cut tobacco of the cut tobacco rod. For example, the additive A is obtained by spraying the additive A on a tobacco shred rod in the form of solution and then drying the tobacco shred rod.
In the invention, the tobacco shred rod contains tobacco shreds and the additive A, and in addition, other auxiliary agents allowed to be added in the traditional cigarette field, such as an adhesive, an aromatizing agent and the like, can be added.
The present inventors have found that further control of the amount of additive a in the tobacco rod contributes to further improving the synergistic effect of the additives a and B and the core-shell structure. Preferably, in the tobacco rod, the mass percentage of the additive A is 0.2-2.0%; preferably 0.5-1.8%; more preferably 0.7 to 1.5%.
In the present invention, the additive B is preferably a water-insoluble solid particle, which contributes to further improvement of the effect of ash inclusion.
In the cigarette paper, the particle size of the additive B is 0.2-5.0 microns (D50 particle size).
Preferably, the additive B is at least one of magnesium silicate, calcium silicate and iron silicate.
Preferably, the additive B is a compound additive B; preferably a binary mixture or a ternary mixture of two of magnesium silicate, calcium silicate and iron silicate. The research of the invention finds that the additive B is adopted to further cooperate with the additive A and the control of the core-shell structure, which is beneficial to further improving the ash coating performance of the material.
Preferably, the additive B is a binary mixture, and the mass ratio of each component is 1-8: 8 to 1.
Preferably, the cigarette paper also comprises plant fibers, a filler and a combustion improver.
Preferably, the plant fiber may be a fiber conventional in the field of cigarettes, and more preferably, at least one of softwood fiber and hardwood fiber.
In the invention, the filler in the cigarette paper can be any material known in the field of cigarette paper, and preferably, the filler is calcium carbonate.
In the invention, the combustion improver in the cigarette paper can be any material known in the field of cigarette paper, and preferably, the combustion improver is at least one of potassium citrate and sodium citrate.
Preferably, the combustion improver is a mixture of potassium citrate and sodium citrate with the mass ratio of 5:1-1: 5.
In the invention, in the cigarette paper, the weight content of the additive B is 2-10%; the weight content of the combustion improver is 1-4%; the weight content of the filler is 20-35%; the balance being plant fiber.
In the invention, other auxiliary agents which are allowed to be added in the cigarette paper can be added into the cigarette paper.
In the cigarette, the mass ratio of the additive A to the additive B is 1: 1-1: 15; more preferably 1:2 to 1: 10.
The invention also provides a preparation method of the cigarette rod for improving ash wrapping performance, which comprises the steps of obtaining the tobacco rod added with the additive A and the cigarette paper added with the additive B, and wrapping the tobacco rod with the cigarette paper.
In the invention, the steps of obtaining the tobacco rod added with the additive A are as follows: spraying a solution in which the additive A is dissolved into the tobacco shred raw material, uniformly mixing, drying and rolling to obtain a tobacco shred rod;
or, the cigarette is made into a cigarette rod, and the solution containing the additive A is directly sprayed into the cigarette rod and then dried to obtain the cigarette.
Preferably, the solution in which the additive A is dissolved is an aqueous solution of the additive A, wherein the mass percentage concentration of the solute is 5-10%.
Preferably, the preparation process of the cigarette paper comprises the following steps:
pulping the plant fiber pulp, the filler, the combustion improver and the additive B, then papermaking and drying to obtain the cigarette paper.
A preferred method of preparation comprises the steps of:
(1) the improved ash-coated cigarette paper mainly comprises plant fiber slurry, a filler, a combustion improver and an additive B, wherein the mass fraction of the filler calcium carbonate is 25-40%, the mass fraction of the combustion improver potassium citrate and sodium citrate is 2-4%, the ratio of potassium salt to sodium salt is 5:1-1:5, and the quantitative amount of the cigarette paper is 29-40g m-2。
(2) In the plant fiber slurry, softwood pulp and hardwood pulp are mixed according to the weight ratio of 1:6-6: 1.
(3) The additive B on the cigarette paper is magnesium silicate, calcium silicate, ferric silicate powder or freshly prepared suspension. The grain diameter is 0.2-5.0 microns, and the addition amount is 2-10%.
(4) The additive A in the tobacco shreds is one or more of sodium phosphate, sodium dihydrogen phosphate and disodium hydrogen phosphate, and is added by uniformly spraying 5-10% solution, wherein the addition amount is 0.1-1.5% of the weight of the tobacco shreds.
(5) And (4) rolling the cigarette paper and the cut tobacco added with the additive A on a cigarette making machine to make cigarettes, and testing the ash wrapping performance of the cigarettes.
The cigarette rod prepared by the preparation method is based on the additive A and the additive B and the joint control of the additive positions, and can synergistically improve the adhesion effect between particles by utilizing the mutual chemical action of the additive A and the additive B, so that the tobacco shred ash and the cigarette paper ash are firmly adhered, and the combustion appearance quality of cigarettes is obviously improved.
The invention also provides a cigarette comprising the cigarette rod for improving the ash wrapping performance.
The cigarette also comprises a filter rod connected with the cigarette rod in an attached mode.
Advantageous effects
1. Based on the precise control of the components of the additives A and B and the combined control of the addition modes, the invention can unexpectedly improve the cooperativity of the additives A and B and improve the ash wrapping effect of cigarettes.
2. The additive A and the additive B are compounded, so that the additive components of the additive A and the additive B are further controlled in a combined manner, the synergy of the additive A and the additive B is further improved, and the ash coating effect is further improved.
Drawings
FIG. 1 is an appearance diagram of cigarette burning ash wrapping of examples and comparative examples of the present invention.
Example 1
Taking 100 kg of softwood pulp, 200 kg of hardwood pulp and 15 kg of magnesium silicate (additive B) with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing machine in a sizing working section of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P1). And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of the addition of sodium phosphate (additive A). The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C1), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Example 2
Compared with example 1, the difference is only that the content of the additive A is changed, specifically:
taking 100 kg of softwood pulp and 200 kg of broad woodAdding 150 kg of calcium carbonate into 15 kg of magnesium silicate with the grain diameter of 2.0-4.0 microns for pulping and papermaking, preparing a combustion improver solution of potassium citrate with the mass percent of 4% and sodium citrate with the mass percent of 2%, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing machine at a sizing section of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P2). And spraying a 10% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with the sodium phosphate addition of 2%. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C2), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 3
Compared with example 1, the difference is only that the kind of the additive A is changed, specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 15 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P3). And spraying a sodium dihydrogen phosphate solution with the concentration of 5% on the tobacco shreds, and drying to obtain the tobacco shreds with the addition of 1% of sodium dihydrogen phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C3), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 4
Compared with example 1, the difference is only that the kind of the additive A is changed, specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 15 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P4). And spraying a 5% disodium hydrogen phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with the addition of 1% disodium hydrogen phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C4), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 5
Compared with example 1, the difference is only that the kind of the additive A is changed, specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 15 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P5). And spraying 5% potassium phosphate solution on the tobacco shreds, and drying to obtain tobacco shreds with 1% of potassium phosphate. Trial-producing cigarette paper and tobacco shred into cigarette (number C5), photographing the cigarette combustion appearance with high-resolution camera, and measuring the ash wrapping performance of the obtained photographThe results of the test evaluations are shown in Table 1.
Example 6
Compared with example 1, the difference is only that the kind of the additive A is changed, specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 15 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P6). And spraying and drying the tobacco shreds by using a potassium dihydrogen phosphate solution with the concentration of 5% to obtain the tobacco shreds with the addition of 1% of potassium dihydrogen phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C6), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 7
Compared with the example 1, the difference is only that the type of the additive A is changed (the compounded additive A is adopted), and specifically the following steps are adopted:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 15 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P7). Spraying 5% sodium phosphate and sodium dihydrogen phosphate (weight ratio of 1: 1) solution on tobacco shred, and oven drying to obtain phosphoric acidThe total adding amount of sodium and sodium dihydrogen phosphate is 1%. The prepared cigarette paper and tobacco shreds are trial-manufactured into a certain brand of cigarette (serial number C7) by adopting a high-resolution camera to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 8
Compared with the example 1, the difference is only that the type of the additive A is changed (the compounded additive A is adopted), and specifically the following steps are adopted:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 15 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P8). And spraying a 5% solution of sodium phosphate and potassium phosphate (the weight ratio of the sodium phosphate to the potassium phosphate is 1: 1) on the cut tobacco, and drying to obtain the cut tobacco with the addition of the sodium phosphate and the potassium phosphate being 1%. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C8), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Example 9
Compared with the example 1, the difference is only that the type of the additive A is changed (the compounded additive A is adopted), and specifically the following steps are adopted:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp and 15 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 160 kg of calcium carbonate to carry out pulping and papermaking, preparing a mixed combustion improver solution of 4 percent by mass of potassium citrate and 2 percent by mass of sodium citrate, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing machine at a sizing working section in the production of the cigarette paper, and producing the cigarette paper according to a conventional papermaking methodThe cigarette paper comprises the following cigarette paper parameters which are controlled on equipment: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P9). And spraying 5% sodium phosphate and dipotassium hydrogen phosphate solution (the weight ratio of the sodium phosphate to the dipotassium hydrogen phosphate is 1: 1) on the tobacco shreds, and drying to obtain the tobacco shreds with the addition amount of the sodium phosphate and the dipotassium hydrogen phosphate being 1%. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C9), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 10
Compared with example 1, the difference is only that the kind of the additive B is changed, specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp and 15 kg of calcium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and calcium silicate content of 3% (numbered P10) in the cigarette paper. And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of sodium phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C10), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 11
Compared with the example 1, the difference is only that the type of the additive B and the dosage of the additive A are changed, and specifically, the following components are adopted:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp and 4 kg of calcium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate to carry out pulping and papermaking, and preparing 4% of lemon in percentage by massMixing potassium citrate and 2% sodium citrate with a combustion improver solution, uniformly adding the prepared combustion improver solution into the cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and calcium silicate added in the cigarette paper in an amount of 2% (No. P11). And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with the sodium phosphate addition of 1.5%. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C11), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 12
Compared with the example 1, the difference is only that the type and the content of the additive B are changed, and specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp and 24 kg of calcium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and calcium silicate content of 10% (numbered P12) in the cigarette paper. And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of sodium phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C12), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Example 13
Compared with example 1, the difference is only that the kind of the additive B is changed, specifically:
taking 100 kg of softwood pulp and 200 kg of softwood pulpAdding 150 kg of calcium carbonate into 15 kg of broadleaf wood pulp and 15 kg of ferric silicate with the particle size of 2.0-4.0 microns for pulping and papermaking, preparing a combustion improver solution of potassium citrate with the mass percentage of 4% and sodium citrate with the mass percentage of 2%, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing machine in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and addition amount of iron silicate in cigarette paper of 3% (number P13). And spraying a 10% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with the sodium phosphate addition of 1.5%. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C13), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 14
Compared with example 1, the difference is only that the kind of the additive B is changed, specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp and 15 kg of ferric silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing machine in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and calcium silicate content of 3% (numbered P14) in the cigarette paper. And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of sodium phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C14), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 15
Compared with the example 1, the difference is only that the type of the additive B is changed (the compound additive B is adopted), and the concrete steps are as follows:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 7.5 kg of calcium silicate with the particle size of 2.0-4.0 microns and 7.5 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4 percent of potassium citrate and 2 percent of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator at a sizing working section of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment to be: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and total addition amount of calcium silicate and magnesium silicate in the cigarette paper of 3% (numbered P15). And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of sodium phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C15), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 16
Compared with the example 1, the difference is only that the type of the additive B is changed (the compound additive B is adopted), and the concrete steps are as follows:
taking 100 kilograms of softwood pulp, 200 kilograms of hardwood pulp, 7.5 kilograms of calcium silicate with the grain diameter of 2.0-4.0 microns and 7.5 kilograms of ferric silicate with the grain diameter of 2.0-4.0 microns, adding 150 kilograms of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4 percent of potassium citrate and 2 percent of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing working section of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment to be: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and total addition amount of calcium silicate and iron silicate in the cigarette paper of 3% (numbered P16). And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of sodium phosphate. Will be prepared intoThe cigarette paper and the tobacco shreds are trial-manufactured into a certain brand of cigarette (No. C16), a high-resolution camera is used for photographing the combustion appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test and evaluation, and the result is shown in Table 1.
Example 17
Compared with the example 1, the difference is only that the type of the additive B is changed (the compound additive B is adopted), and the concrete steps are as follows:
taking 100 kilograms of softwood pulp, 200 kilograms of hardwood pulp, 7.5 kilograms of magnesium silicate with the grain diameter of 2.0-4.0 microns and 7.5 kilograms of ferric silicate with the grain diameter of 2.0-4.0 microns, adding 150 kilograms of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4 percent of potassium citrate and 2 percent of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing working section of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment to be: quantitative 29g m-2The air permeability is 60CORESTA, the content of combustion improver is 2.4 percent, and the total adding amount of magnesium silicate and ferric silicate in the cigarette paper is 3 percent (numbered as P17). And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of sodium phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C17), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 18
Compared with the example 1, the difference is only that the type of the additive B is changed (the ternary complex additive B is adopted), and the concrete steps are as follows:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 5 kg of magnesium silicate with the particle size of 2.0-4.0 microns, 5 kg of ferric silicate with the particle size of 2.0-4.0 microns and 5 kg of calcium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate to carry out pulping and papermaking, preparing a mixed combustion improver solution of 4 mass percent of potassium citrate and 2 mass percent of sodium citrate, and uniformly adding the prepared combustion improver solution to a roll by a metering rod type film transfer sizing machine in a sizing working section for producing cigarette paperIn the cigarette paper, cigarette paper is produced according to a conventional papermaking method, and the parameters of the cigarette paper are controlled on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and total addition amount of magnesium silicate, calcium silicate and iron silicate in the cigarette paper of 3% (numbered P18). And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of sodium phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C18), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Example 19
Compared with the example 1, the difference is only that the types of the additives A and B are changed (both adopt the compounded additives), specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 7.5 kg of magnesium silicate with the particle size of 2.0-4.0 microns and 7.5 kg of calcium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4 percent of potassium citrate and 2 percent of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator at a sizing working section of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment to be: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and total addition amount of magnesium silicate and calcium silicate in the cigarette paper of 3% (numbered P19). And spraying 5% sodium phosphate and potassium phosphate (weight ratio of the sodium phosphate to the potassium phosphate is 1: 1) solution on the cut tobacco, and drying to obtain the cut tobacco with the addition of 1% of sodium phosphate and potassium phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C19), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Example 20
Taking 120 kg of softwood pulp, 180 kg of hardwood pulp, 6 kg of magnesium silicate with the particle size of 2.0-4.0 microns and 9 kg of calcium silicate with the particle size of 2.0-4.0 microns, and adding calcium carbonatePulping 170 kg of the mixture for papermaking, preparing a combustion improver solution mixed by 4 percent of potassium citrate and 2 percent of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into the cigarette paper through a metering rod type film transfer sizing applicator in a sizing process for producing the cigarette paper, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2The air permeability is 60CORESTA, the content of combustion improver is 2.4 percent, and the total adding amount of magnesium silicate, calcium silicate and iron silicate in the cigarette paper is 7 percent (numbered P20). And spraying and drying the tobacco shreds by using 8% sodium dihydrogen phosphate solution to obtain the tobacco shreds with the addition of 1.5% of sodium dihydrogen phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C20), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in Table 1.
Comparative example 1
Compared with the example 1, the difference is that phosphate is not compounded in the cut tobacco and silicate is not compounded in the cigarette paper, and specifically:
taking 100 kg of softwood pulp and 200 kg of hardwood pulp, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a combustion improver solution of potassium citrate and sodium citrate with the mass percentage of 4%, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the cigarette paper parameters on equipment as follows: quantitative 29g m-2Air permeability 60CORESTA, combustion improver content 2.4% (numbered P21). The prepared cigarette paper and cut tobacco without additive A are together trial-manufactured into a certain brand of cigarette (No. C21), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Comparative example 2
Compared with the embodiment 1, the difference is that phosphate is not compounded in the cut tobacco, specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp and 15 kg of particlesMagnesium silicate with the diameter of 2.0-4.0 microns is added with 150 kilograms of calcium carbonate for pulping and papermaking, potassium citrate with the mass percent of 4 percent and sodium citrate with the mass percent of 2 percent are prepared to be mixed with combustion improver solution, the prepared combustion improver solution is evenly added into cigarette paper in a sizing process of the cigarette paper production through a metering rod type film transfer sizing machine, the cigarette paper is produced according to a conventional papermaking method, and the parameters of the cigarette paper are controlled on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P22). The prepared cigarette paper and cut tobacco without additive A are together trial-manufactured into a certain brand of cigarette (No. C22), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Comparative example 3
Compared with the example 1, the difference is that the additive B is not compounded in the cigarette paper, and specifically comprises the following components:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp and 150 kg of calcium carbonate to carry out pulping and papermaking, preparing a combustion improver solution mixed by 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the cigarette paper parameters on equipment as follows: quantitative 29g m-2Air permeability 60CORESTA, combustion improver content 2.4% (numbered P23). And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of sodium phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C23), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Comparative example 4
Compared with the example 1, the difference is mainly that other components are adopted to replace the additive A, and the concrete steps are as follows:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp and 15 kg of wood pulp with the particle size of 2.0-4Adding 150 kg of calcium carbonate into 0 micron of magnesium silicate, pulping and papermaking, preparing a combustion improver solution mixed by 4 percent of potassium citrate and 2 percent of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing machine in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the cigarette paper parameters on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and the addition amount of magnesium silicate in the cigarette paper is 3% (numbered P24). And spraying a 5% sodium alginate solution on the tobacco shreds, and drying to obtain the tobacco shreds with the sodium alginate addition of 1%. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C24), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Comparative example 5
Compared with the embodiment 1, the difference is that the additives A and B are uniformly added into the cigarette paper, specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 15 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2The air permeability is 60CORESTA, the content of combustion improver is 2.4 percent, the addition amount of magnesium silicate in the cigarette paper is 3 percent (numbered P25), and the addition amount of sodium phosphate in the cigarette paper is controlled to be 1 percent. The prepared cigarette paper and cut tobacco without additive A are together trial-manufactured into a certain brand of cigarette (No. C25), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Comparative example 6
Compared with the embodiment 1, the difference is that the additives A and B are uniformly added into the cut tobacco, specifically:
taking 100 kg of softwood pulp and 200 kg of hardwood pulp, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a combustion improver solution of potassium citrate and sodium citrate with the mass percentage of 4%, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the cigarette paper parameters on equipment as follows: quantitative 29g m-2Air permeability 60CORESTA, combustion improver content 2.4% (numbered P26). Cut tobacco with 1 percent of sodium phosphate and 3 percent of magnesium silicate (with the grain diameter of 2.0-4.0 microns) is prepared. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C26), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Comparative example 7
Compared with the example 1, the difference is mainly that the adding mode of the additive is changed, for example, the additive A is added in the cigarette paper, and the additive B is added in the cut tobacco, specifically:
taking 100 kg of softwood pulp, 200 kg of hardwood pulp, 15 kg of magnesium silicate with the particle size of 2.0-4.0 microns, adding 150 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2The air permeability is 60CORESTA, the content of combustion improver is 2.4 percent, the addition amount of magnesium silicate in the cigarette paper is 3 percent (numbered P27), and the addition amount of sodium phosphate in the cigarette paper is controlled to be 1 percent. Preparing tobacco shred containing magnesium silicate (particle size of 2.0-4.0 μm) with addition amount of 3%. Trial-producing the cigarette paper and tobacco shred into a certain brand of cigarette (serial number C27), photographing the burning appearance of the cigarette by a high-resolution camera, and performing ash wrapping performance test evaluation on the obtained photograph, wherein the result is shown in figure 1 and a table1 is shown.
Comparative example 8
The difference from the examples is mainly that the amount of calcium silicate added is not controlled within a preferred range, specifically:
taking 120 kg of softwood pulp, 180 kg of hardwood pulp and 4 kg of calcium silicate with the particle size of 2.0-4.0 microns, adding 160 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and calcium silicate added in the cigarette paper in an amount of 1.5% (No. P28). And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with 1% of sodium phosphate. The prepared cigarette paper and tobacco shreds are together trial-manufactured into a certain brand of cigarette (serial number C28), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test evaluation, and the result is shown in figure 1 and table 1.
Comparative example 9
Compared with the examples, the difference is mainly that the addition amount of the sodium phosphate is not controlled in a preferable range, and specifically:
taking 120 kg of softwood pulp, 180 kg of hardwood pulp and 4 kg of calcium silicate with the particle size of 2.0-4.0 microns, adding 160 kg of calcium carbonate for pulping and papermaking, preparing a mixed combustion improver solution of 4% of potassium citrate and 2% of sodium citrate in percentage by mass, uniformly adding the prepared combustion improver solution into cigarette paper through a metering rod type film transfer sizing applicator in a sizing process of cigarette paper production, producing the cigarette paper according to a conventional papermaking method, and controlling the parameters of the cigarette paper on equipment as follows: quantitative 29g m-2Air permeability of 60CORESTA, combustion improver content of 2.4%, and calcium silicate content of 3% (numbered P29) in the cigarette paper. And spraying a 5% sodium phosphate solution on the tobacco shreds, and drying to obtain the tobacco shreds with the sodium phosphate addition of 0.1%. Will be preparedThe cigarette paper and the tobacco shred are together trial-manufactured into a certain brand of cigarette (number C29), a high-resolution camera is adopted to photograph the burning appearance of the cigarette, and the obtained photograph is subjected to ash wrapping performance test and evaluation, and the result is shown in Table 1.
Comparative example 10
100 kg of softwood pulp, 200 kg of hardwood pulp and 15 kg of sodium silicate with the particle size of 2.0-4.0 microns are taken, 150 kg of calcium carbonate is added for pulping and papermaking, and in the papermaking process, the sodium silicate is dissolved to form a viscous water glass solvent, so that the papermaking failure is caused.
TABLE 1 Ash Performance index for the cigarette of the examples and comparative examples
Compared with the comparative example, the split rate of the cigarette in the example is obviously reduced, the ash column after combustion also shows inward shrinkage, the shrinkage rate is increased, and the large split and ash explosion phenomena of the ash column in the comparative example do not occur. The ash coating effect of the cigarettes in the examples is obviously better than that of the cigarettes in the comparative examples (the evaluation method of the ash coating of the cigarettes is detailed in CN107084985A and CN105783647A, generally, the higher the whiteness, the lower the splitting ratio, the higher the shrinkage and the higher the ash holding force, the better the ash coating effect is indicated).
When the A is added into tobacco shreds, the B is added into cigarette paper and the A and B additives are compounded, the cigarette has the best ash wrapping effect.
Table 2 shows the release of the optimized 7 components in the mainstream smoke of the cigarettes of example 19 and comparative example 1. As can be seen from Table 2, compared with comparative example 1, the release amount of NNK and benzopyrene in example 1 is reduced by about 10%, and the harmfulness index H value of the cigarette is also reduced by 0.22, which shows that the tobacco of the application not only has the effect of improving ash wrapping, but also has a certain harm reduction effect.
Table 2 release of 7 harmful constituents from comparative example 1 and example 1 mainstream smoke
In conclusion, by adopting the additives A and B of the invention and further matching with the special control of the addition mode, the synergy can be demonstrated, the ash coating effect can be effectively improved, and the compounded additives are further adopted, which is beneficial to further improving the ash coating effect. Moreover, the technical scheme of the application also helps to have a certain harm reducing effect on main harmful components such as HCN, NNK, benzopyrene, crotonaldehyde and the like.
Claims (25)
1. A cigarette rod for improving ash wrapping performance comprises a tobacco rod and cigarette paper wrapping the tobacco rod, and is characterized in that an additive A is added into the tobacco rod, and an additive B is added into the cigarette paper;
wherein the additive A is at least one of alkali metal phosphate, dibasic hydrogen phosphate and monobasic hydrogen phosphate;
the additive B is water-insoluble silicate particles.
2. The cigarette rod with improved ash wrapping performance of claim 1, wherein the additive a is at least one of sodium phosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate, potassium dihydrogen phosphate and dipotassium hydrogen phosphate.
3. The cigarette rod with improved ash wrapping performance of claim 2, wherein the additive A is a compounded additive A.
4. The cigarette rod with improved ash coating performance of claim 3, wherein the additive A is compounded and comprises at least sodium phosphate and optionally at least one of sodium dihydrogen phosphate, disodium hydrogen phosphate, potassium dihydrogen phosphate and dipotassium hydrogen phosphate.
5. The cigarette rod with improved ash wrapping performance of claim 4, wherein the content of sodium phosphate in the compounded additive A is not less than 10 wt%.
6. A cigarette rod with improved ash wrapping performance according to any one of claims 1 to 5, wherein the additive A is uniformly added into tobacco shreds of the tobacco shred rod.
7. The cigarette rod with improved ash wrapping performance according to any one of claims 1 to 6, wherein the mass percentage of the additive A in the tobacco rod is 0.2-2.0%.
8. The cigarette rod for improving ash wrapping performance of any one of claims 1 to 6, wherein the mass percentage of the additive A in the tobacco rod is 0.5 to 1.8%; more preferably 0.7 to 1.5%.
9. The cigarette rod with improved ash coating performance of claim 1, wherein the additive B is at least one of magnesium silicate, calcium silicate and iron silicate.
10. The cigarette rod with improved ash coating performance of claim 9, wherein the additive B is a binary mixture or a ternary mixture of two of magnesium silicate, calcium silicate and iron silicate.
11. The cigarette rod for improving ash wrapping performance of claim 10, wherein the additive B is a binary mixture, and the mass ratio of the components is 1-8: 8 to 1.
12. A cigarette rod with improved ash wrapping performance according to any one of claims 1 and 9 to 11, wherein the cigarette paper further comprises plant fibers, a filler and a combustion improver.
13. The cigarette rod with improved ash wrapping performance of claim 12, wherein the plant fiber is at least one of softwood fiber and hardwood fiber.
14. The cigarette rod with improved ash wrapping performance of claim 12, wherein the filler is calcium carbonate.
15. The cigarette rod with improved ash wrapping performance of claim 12, wherein the combustion improver is at least one of potassium citrate and sodium citrate.
16. The cigarette rod for improving ash wrapping performance of claim 15, wherein the combustion improver is a mixture of potassium citrate and sodium citrate in a mass ratio of 5:1 to 1: 5.
17. A cigarette rod having improved ash wrapping properties according to claim 12 wherein the additive B in the cigarette paper has a particle size of 0.2 to 5.0 microns.
18. A cigarette rod with improved ash wrapping performance according to any one of claims 12 to 17, wherein the additive B is present in the cigarette paper in an amount of 2 to 10% by weight; the weight content of the combustion improver is 1-4%; the weight content of the filler is 20-35%; the balance being plant fiber.
19. The cigarette rod for improving ash wrapping performance according to any one of claims 1 to 18, wherein in the cigarette, the mass ratio of the additive A to the additive B is 1: 1-1: 15; more preferably 1:2 to 1: 10.
20. A preparation method of the cigarette rod with the improved ash wrapping performance according to any one of claims 1 to 19, wherein a tobacco rod with an additive A and a cigarette paper with an additive B are obtained, and the tobacco rod is wrapped by the cigarette paper.
21. The method of making a cigarette rod with improved ash wrapping properties of claim 20 wherein the step of obtaining a tobacco rod with additive a is: spraying a solution in which the additive A is dissolved into the tobacco shred raw material, uniformly mixing, drying and rolling to obtain a tobacco shred rod;
or, the cigarette is made into a cigarette rod, and the solution containing the additive A is directly sprayed into the cigarette rod and then dried to obtain the cigarette.
22. The method of claim 21, wherein the solution in which the additive a is dissolved is an aqueous solution of the additive a, and wherein the solute concentration is 5-10% by mass.
23. A method of making a cigarette rod with improved ash wrapping properties according to claim 20, wherein said cigarette paper is made by:
pulping the plant fiber pulp, the filler, the combustion improver and the additive B, then papermaking and drying to obtain the cigarette paper.
24. A cigarette, which is characterized by comprising the cigarette rod with improved ash wrapping performance of claims 1-19 or the cigarette rod with improved ash wrapping performance prepared by the preparation method of any one of claims 20-23.
25. The cigarette of claim 24, further comprising a filter rod attached to the cigarette rod.
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Cited By (1)
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CN116446220A (en) * | 2023-04-06 | 2023-07-18 | 云南中烟工业有限责任公司 | Cigarette paper capable of improving ash condensation, preparation method and application thereof |
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