CN1429946A - Functional cigarette paper - Google Patents

Functional cigarette paper Download PDF

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Publication number
CN1429946A
CN1429946A CN 02128134 CN02128134A CN1429946A CN 1429946 A CN1429946 A CN 1429946A CN 02128134 CN02128134 CN 02128134 CN 02128134 A CN02128134 A CN 02128134A CN 1429946 A CN1429946 A CN 1429946A
Authority
CN
China
Prior art keywords
cigarette paper
potassium
oxide
alkali
functional cigarette
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 02128134
Other languages
Chinese (zh)
Other versions
CN1200167C (en
Inventor
杨伟祖
于鲁渝
倪军
陆懋昆
郑勇
杨绍文
尧珍玉
邱晔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Jinfeng Paper Ltd By Share Ltd
Yunnan Ruisheng Science & Technology Co Ltd
Original Assignee
Sichuan Jinfeng Paper Ltd By Share Ltd
Yunnan Ruisheng Science & Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Jinfeng Paper Ltd By Share Ltd, Yunnan Ruisheng Science & Technology Co Ltd filed Critical Sichuan Jinfeng Paper Ltd By Share Ltd
Priority to CN 02128134 priority Critical patent/CN1200167C/en
Publication of CN1429946A publication Critical patent/CN1429946A/en
Application granted granted Critical
Publication of CN1200167C publication Critical patent/CN1200167C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

A function cigarette paper for reducing tar and improving combustion quality features that it contains the assistant composed of inorganic filler, combustion promoter and flavouring. Said inorganic filler consists of calcium carbonate, alkalimetal algate, nano-class oxide, and silicon oxide or alkali-earth metal silicate or alkali-earth metal carbonate or their mixture. Said combustion promoter is composed of alkali metal (or alkali-earth metal) carboxylate and alkali metal carbonate. Said flavouring contains cylitol or sorbitol or glocose.

Description

A kind of functional cigarette paper
Technical field
The present invention relates to a kind of cigarette paper, especially relate to a kind of functional cigarette paper.
Background technology
Along with cigarette develops to " low tar, low harm, top grade " direction, when the consumer is concerned about the smoking security, pay attention to the presentation quality that cigarette props up gray columns during the vision class of cigarette and the suction more.Be that cigarette can provide good parcel outward appearance, the cigarette quality of high-quality, when suction cigarette prop up the gray columns good looking appearance, the ash that do not waft, do not fall ash.In view of the effective way the most that can play the parcel pipe tobacco at present and can address the above problem adopts high performance cigarette paper exactly, and the market demand is urgent, so development function type cigarette paper is imperative.
Up to now, commercially available cigarette paper also has the following disadvantages:
Though 1. have the good burnt performance of falling, cigarette suction the time waft ash, to fall grey phenomenon serious; 2. the production process complexity often needs equipment, technology are done bigger change, is difficult to drop into suitability for industrialized production; 3. select the material costliness for use, and cause unit cost higher, be not easy extensively to promote; 4. though wrap grey performance bigger improvement is arranged, product has a negative impact to the original suction of cigarette flavor or only the cigarette of certain several trade mark is not had a negative impact or is unsuitable for running up on the cigarette unit; 5. product function is single.
Summary of the invention
The objective of the invention is at above-mentioned the deficiencies in the prior art, provide a kind of and can reduce cigarette tar content, can improve cigarette again and prop up and burn and suck the posterior gray column of spinal cord presentation quality, have good bag ash performance, and the functional cigarette paper that the original suction flavor of cigarette is not had a negative impact.
Purpose of the present invention is achieved by following technical proposals.
Except as otherwise noted, the percentage that is adopted among the present invention is percetage by weight.
Functional cigarette paper provided by the invention is to add auxiliary agent in the cigarette paper production process, and described auxiliary agent is adjusted agent three parts by inorganic filler, combustion adjuvant and suction flavor and formed.Weight with finished paper is benchmark, the composition of described inorganic filler and content are: calcium carbonate 15%~50%, alkali metal alginate 0.1%-1.0%, nano-oxide 0.1%~1.5%, the mixture 8%-40% that Si oxide or alkaline-earth-metal silicate or alkaline earth metal carbonate or three form; The composition of described combustion adjuvant and content are: alkali metal carboxylate or alkaline earth metal carboxylation 0.1%~2%, alkali carbonate 0.1%~4%; Composition and content that described suction flavor is adjusted agent are: xylitol or sorbierite or glucose 0.2%~5%.
Described calcium carbonate is the precipitated calcium carbonate powder; Described alkali metal alginate is sodium alginate or potassium alginate; Described nano-oxide is nano-aluminium oxide or titanium dioxide or zinc oxide; Described alkali metal carboxylate is selected from a kind of in potassium, lithium, sodium malate, potassium, sodium lactate or potassium, na citrate, tartrate or fumarate or the double salt; Described alkaline earth metal carboxylation is selected from malate, the lactate of calcium, magnesium.
Described inorganic filler is equipped with slurry process at wood pulp to be added, and main purpose is to make inorganic filler and fiber that mixing and mixing time of abundance be arranged, and guarantees that filler evenly disperses in fibrous raw material and is adsorbed to fiber surface.Described combustion adjuvant and inhale flavor and adjust agent is with 1.0%~20% the combustion adjuvant aqueous solution; 0.5%~10% the odor absorber aqueous solution adds in the cigarette paper by sizing applicator, and addition manner is to choose coating and the mode of dip-coating is carried out the single or double applying glue according to product type.And addition manner does not need to do any change to existing cigarette paper production equipment, production technology, and examples of such additives can be produced unit, this functional cigarette paper of explained hereafter at difference.
Compared with prior art, the present invention has following outstanding beneficial effect:
Cigarette is when suction, and the gray columns good looking appearance does not have the ash that wafts, falls grey phenomenon, wraps grey effect and obviously improves.And successfully realized falling burnt function, 0.6~1 milligram/in reduction tar effectively improves the cigarette burning quality, and original suction flavor of multiple trade mark cigarette is not had a negative impact.Cigarette paper production does not need original technology, equipment are done any change, adopts conventional production process just can realize, and product can satisfy and runs up.The present invention has good social benefit and economic benefit, is rich in the prospect of marketing.
In line with the attitude that the consumer is responsible for, strict check has been carried out in the security of adding auxiliary agent, additive detects institute through China Preventive Medicial Science Institute's environmental sanitation and carries out the toxicity check.Assay such as table 1~table 4.
The result of the test of acute oral toxicity test sees Table 1.As can be seen from Table 1, the auxiliary agent of the present invention's interpolation is to female, the male per os LD of small white mouse 50All, belong to actual nontoxic level greater than the 10000mg/kg body weight.
Mouse marrow cell micro nuclear test the results are shown in Table 2.The data of table 2 show that the auxiliary agent 2500,5000 that the present invention adds and three dosage groups of 10000mg/kg body weight are to the undistorted effect of bone marrow cells in mice.
Tried thing to rabbit acute skin irritation/corrosion test the results are shown in Table 3, table 4.The data of table 3, table 4 show, the auxiliary agent that the present invention adds once contacts animal at working concentration and 2.5 times and 5 times of three dosage and does not cause that all skin irritatin reacts, its the highest total mark average is 0, and by skin irritatin strength grading standard, this is tried thing and belongs to nonirritant.
Description of drawings
Fig. 1 is practical application effect figure of the present invention.
The specific embodiment
By specific embodiment given below, can further be well understood to the present invention.But they are not limitation of the invention.
Embodiment 1
Get 600 kilograms of wood pulps, add and close 72 kilograms in silicon mixture, precipitated calcium carbonate 120 kg, 3 kilograms of nano-aluminium oxides, 4 kilograms of sodium alginates.Preparation 12% potassium malate lithium, 16% potassium malate sodium, 8% the potash and 4% the xylitol aqueous solution adopt coating method to carry out single face in combustion adjuvant interpolation place to add.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment: quantitatively: 34.0g/m2, air permeability: 60 Ke Ruisita.
Embodiment 2
Get 600 kilograms of wood pulps, add 130 kilograms of precipitated calcium carbonates, 6 kilograms of nano-aluminium oxides, the potassium malate lithium of preparation 12%, 20% potassium malate sodium, 10% wet chemical adopts coating method to carry out the single face interpolation in combustion adjuvant interpolation place.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment: quantitatively: 28.0g/m2; Air permeability: 60 Ke Ruisita.
Embodiment 3
Get 600 kilograms of wood pulps, add 92 kilograms in siliceous mixture, 100 kilograms of precipitated calcium carbonates, 2 kilograms of nano-aluminium oxides, the potassium malate lithium of preparation 16%, 10% potassium malate sodium, 10% wet chemical adopts coating method to carry out the single face interpolation in combustion adjuvant interpolation place.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment: quantitatively: 34.09/m2; Air permeability: 60 Ke Ruisita.
Embodiment 4
Get 600 kilograms of wood pulps, add 75 kilograms in siliceous mixture, the precipitated calcium carbonate 120 kg, 4 kilograms of sodium alginates, 3 kilograms of nano-aluminium oxides, the Potassium fumarate of preparation 15%, 12% malic acid lithium, 8% potassium acetate and 5% D/W adopt coating method to carry out the single face interpolation in combustion adjuvant interpolation place.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment, quantitatively: 28.0g/m 2, air permeability: 80 Ke Ruisita.
Embodiment 5
Get 600 kilograms of wood pulps, add 80 kilograms in siliceous mixture, 100 kilograms of precipitated calcium carbonates, 3 kilograms of sodium alginates, 2 kilograms of nano titanium oxides, the potassium malate lithium of preparation 15%, 10% calcium lactate, 8% magnesium malate and 5% sorbitol aqueous solution adopt coating method to carry out two-sided interpolation in combustion adjuvant interpolation place.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment, quantitatively: 30.0g/m 2Air permeability: 80 Ke Ruisita.
Embodiment 6
Get 600 kilograms of wood pulps, add 75 kilograms in siliceous mixture, the precipitated calcium carbonate 120 kg, 4 kilograms of sodium alginates, 2 kilograms of nano titanium oxides, the calcium malate of preparation 10%, 10% sodium potassium tartrate tetrahydrate and the aqueous potassium lactate solution of t0% adopt coating method to carry out two-sided interpolation in combustion adjuvant interpolation place.Skill is produced cigarette paper in the papermaking routinely, and control cigarette paper index is on equipment, quantitatively: 30.0g/m 2Air permeability: 60 Ke Ruisita.
Embodiment 7
Remove nanometer Al 2O 3Replace to outside the ZnO, all the other auxiliary agents add quantity, kind, mode and production method with embodiment 1.
Embodiment 8
The Potassium fumarate aqueous solution except that 15% replaces to 10% the potassium citrate aqueous solution, and all the other auxiliary agents add quantity, kind, mode and production method with embodiment 4.
Embodiment 9
Wet chemical except that 10% replaces to 8% the magnesium lactate aqueous solution, and all the other auxiliary agents add quantity, kind, mode and production method with embodiment 3.
Embodiment 10
Except that sodium alginate replaced to potassium alginate, all the other auxiliary agents added quantity, kind, mode and production method with embodiment 6.
Embodiment 11
Wet chemical except that 10% replaces to 14% the potassium citrate aqueous solution, and all the other auxiliary agents add quantity, kind, mode and production method with embodiment 2.Table 1.
Dosage grouping number of animals dead animal is counted death rate sex
(mg/kg) (only) (only) (%)
1000 5 0 0
2150 5 0 0♀
4640 5 0 0
10000 5 0 0
1000 5 0 0
2150 5 0 0♂
4640 5 0 0
10,000 500 tables 2.
The dosage number of animals is had a liking for the red micronucleus that contains of polychromatophilia and is had a liking for many micronuclear rateses
Tried thing
The P value
(mg/kg) (only) TCS incarnadines cell number (‰)
2500 5 5000 4 0.80 >0.05
Tried thing 5,000 5 5,000 5 1.00>0.05
10000 5 5000 7 1.40 >0.05
Sodium carboxymethylcellulose (1%) 5 5,000 4 0.80-
Endoxan (50mg/kg) 5 5,000 198 39.60<0.01 table 3.
Skin irritatin reaction scoring
Dosage animal gonosome 1h 24h 48h
Grouping is heavy
The contrast of sample control sample control sample
(%) numbering other (kg)
The total red water of the total red water of the total red water of the total red water of the total red water of red water is total
Spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to be divided
1 ♀ 2.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2 ♀ 2.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Use
3 ♂ 2.3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Concentration
4 ♂ 2.5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Total mark average 000000 tables 4.
Skin irritatin reaction scoring
Dosage animal gonosome 1h 24h 48h
Grouping is heavy
The contrast of sample control sample control sample
(%) numbering other (kg)
The total red water of the total red water of the total red water of the total red water of the total red water of red water is total
Spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to be divided
1 ♀ 2.3?0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2 ♀ 2.5?0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Use
Concentration
3 ♂ 2.4?0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2.5 doubly
4 ♂ 2.3?0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Total mark average 000000
1 ♀ 2.2?0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2 ♀ 2.5?0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Use
Concentration
3 ♂ 2.3?0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
5 times
4 ♂ 2.4?0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Total mark average 000000

Claims (6)

1. functional cigarette paper, it is characterized in that in the cigarette paper production process, adding auxiliary agent, described auxiliary agent is adjusted agent three parts by inorganic filler, combustion adjuvant and suction flavor and is formed, weight with finished paper is benchmark, the composition of described inorganic filler and percetage by weight are: calcium carbonate 15%~50%, alkali metal alginate 0.1%-1.0%, nano-oxide 0.1%~1.5%, the mixture 8%-40% that Si oxide or alkaline-earth-metal silicate or alkaline earth metal carbonate or three form; The composition of described combustion adjuvant and percetage by weight are: alkali metal carboxylate or alkaline earth metal carboxylation 0.1%~2%, alkali carbonate 0.1%~4%; Composition and percetage by weight that described suction flavor is adjusted agent are: xylitol or sorbierite or glucose 0.2%~5%.
2. functional cigarette paper according to claim 1, wherein said calcium carbonate are the precipitated calcium carbonate powder.
3. functional cigarette paper according to claim 1, wherein said alkali metal alginate are sodium alginate or potassium alginate.
4. functional cigarette paper according to claim 1, wherein said nano-oxide are nano-aluminium oxide or titanium dioxide or zinc oxide.
5. functional cigarette paper according to claim 1, wherein said alkali metal carboxylate are selected from potassium, lithium, sodium malate, a kind of in potassium, sodium lactate or potassium, na citrate, tartrate or fumarate or the double salt.
6. functional cigarette paper according to claim 1, wherein said alkaline earth metal carboxylation is selected from a kind of in the malate, lactate of calcium, magnesium.
CN 02128134 2002-12-27 2002-12-27 Functional cigarette paper Expired - Fee Related CN1200167C (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN1200167C CN1200167C (en) 2005-05-04

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1316122C (en) * 2004-10-22 2007-05-16 云南瑞升科技有限公司 Cigarette paper and preparation method
CN1327082C (en) * 2005-09-08 2007-07-18 郑州瑞普生物工程有限公司 Cigarette paper additive and its preparation method
CN100519931C (en) * 2007-02-15 2009-07-29 云南瑞升烟草技术(集团)有限公司 Cigarette paper employing natural baccy fiber
CN101864698A (en) * 2010-06-10 2010-10-20 红云红河烟草(集团)有限责任公司 Method for improving quality of cigarette paper
CN102199902A (en) * 2011-05-13 2011-09-28 民丰特种纸股份有限公司 Cigarette paper with low ignition tendency and preparation method
CN101781867B (en) * 2010-02-09 2012-01-04 广东中烟工业有限责任公司 Low ignition tendency cigarette paper and preparation method thereof
CN102733254A (en) * 2012-07-02 2012-10-17 川渝中烟工业有限责任公司 Cigarette paper additive with harm-reduction function, and application thereof
CN101983270B (en) * 2008-05-16 2012-11-21 日本烟草产业株式会社 Process for production of cigarett wrapping paper having low ignitability
CN103046431A (en) * 2012-12-16 2013-04-17 青岛盛瀚色谱技术有限公司 Cigarette paper
CN103321102A (en) * 2013-06-27 2013-09-25 苏州工业园区依利电子贸易有限公司 Cigarette wrapping paper
CN103556541A (en) * 2013-10-18 2014-02-05 湖南中烟工业有限责任公司 Cigarette paper with variable diffusion rate and pore structure and application thereof
CN103882778A (en) * 2014-04-02 2014-06-25 湖南中烟工业有限责任公司 Method for preparing pore-forming cigarette paper capable of reducing release of hazardous substances such as CO in main stream smoke of cigarettes
CN105040511A (en) * 2015-07-28 2015-11-11 湖北中烟工业有限责任公司 Method for preparing reconstructed tobacco-leaf cigarette paper by replacing part of wood pulp with bamboo pulp
CN105220561A (en) * 2015-07-27 2016-01-06 杭州华丰纸业有限公司 A kind of cigarette paper containing non-wood-fiber
CN107587382A (en) * 2017-09-07 2018-01-16 滁州市光威化工有限公司 A kind of cigarette paper with the inflammable function that eliminates smoke
CN114182572A (en) * 2020-09-14 2022-03-15 中国制浆造纸研究院有限公司 Cigarette paper capable of improving whiteness and ash wrapping performance of cigarette ash and preparation method thereof
CN114304726A (en) * 2020-09-30 2022-04-12 湖南中烟工业有限责任公司 Cigarette rod for improving ash wrapping performance, cigarette containing cigarette rod and preparation method of cigarette
CN116411485A (en) * 2023-04-06 2023-07-11 云南中烟工业有限责任公司 Cigarette paper, preparation method and application thereof

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CN101195977B (en) * 2007-12-21 2010-12-29 湖南中烟工业有限责任公司 Cigarette tissue with variable permeating degree and method for producing the same

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1316122C (en) * 2004-10-22 2007-05-16 云南瑞升科技有限公司 Cigarette paper and preparation method
CN1327082C (en) * 2005-09-08 2007-07-18 郑州瑞普生物工程有限公司 Cigarette paper additive and its preparation method
CN100519931C (en) * 2007-02-15 2009-07-29 云南瑞升烟草技术(集团)有限公司 Cigarette paper employing natural baccy fiber
CN101983270B (en) * 2008-05-16 2012-11-21 日本烟草产业株式会社 Process for production of cigarett wrapping paper having low ignitability
CN101781867B (en) * 2010-02-09 2012-01-04 广东中烟工业有限责任公司 Low ignition tendency cigarette paper and preparation method thereof
CN101864698A (en) * 2010-06-10 2010-10-20 红云红河烟草(集团)有限责任公司 Method for improving quality of cigarette paper
CN102199902A (en) * 2011-05-13 2011-09-28 民丰特种纸股份有限公司 Cigarette paper with low ignition tendency and preparation method
CN102199902B (en) * 2011-05-13 2014-02-12 民丰特种纸股份有限公司 Cigarette paper with low ignition tendency and preparation method
CN102733254B (en) * 2012-07-02 2014-10-01 川渝中烟工业有限责任公司 Cigarette paper additive with harm-reduction function, and application thereof
CN102733254A (en) * 2012-07-02 2012-10-17 川渝中烟工业有限责任公司 Cigarette paper additive with harm-reduction function, and application thereof
CN103046431A (en) * 2012-12-16 2013-04-17 青岛盛瀚色谱技术有限公司 Cigarette paper
CN103321102A (en) * 2013-06-27 2013-09-25 苏州工业园区依利电子贸易有限公司 Cigarette wrapping paper
CN103556541A (en) * 2013-10-18 2014-02-05 湖南中烟工业有限责任公司 Cigarette paper with variable diffusion rate and pore structure and application thereof
CN103556541B (en) * 2013-10-18 2016-03-16 湖南中烟工业有限责任公司 A kind of cigarette paper and application thereof with variable diffusivity and pore structure
CN103882778A (en) * 2014-04-02 2014-06-25 湖南中烟工业有限责任公司 Method for preparing pore-forming cigarette paper capable of reducing release of hazardous substances such as CO in main stream smoke of cigarettes
CN103882778B (en) * 2014-04-02 2016-08-17 湖南中烟工业有限责任公司 A kind of reduce the preparation method of the pore cigarette paper of the harmful substance burst size such as CO in cigarette mainstream flue gas
CN105220561A (en) * 2015-07-27 2016-01-06 杭州华丰纸业有限公司 A kind of cigarette paper containing non-wood-fiber
CN105040511A (en) * 2015-07-28 2015-11-11 湖北中烟工业有限责任公司 Method for preparing reconstructed tobacco-leaf cigarette paper by replacing part of wood pulp with bamboo pulp
CN107587382A (en) * 2017-09-07 2018-01-16 滁州市光威化工有限公司 A kind of cigarette paper with the inflammable function that eliminates smoke
CN114182572A (en) * 2020-09-14 2022-03-15 中国制浆造纸研究院有限公司 Cigarette paper capable of improving whiteness and ash wrapping performance of cigarette ash and preparation method thereof
CN114304726A (en) * 2020-09-30 2022-04-12 湖南中烟工业有限责任公司 Cigarette rod for improving ash wrapping performance, cigarette containing cigarette rod and preparation method of cigarette
CN116411485A (en) * 2023-04-06 2023-07-11 云南中烟工业有限责任公司 Cigarette paper, preparation method and application thereof

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