CN1200167C - Functional cigarette paper - Google Patents
Functional cigarette paper Download PDFInfo
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- CN1200167C CN1200167C CN 02128134 CN02128134A CN1200167C CN 1200167 C CN1200167 C CN 1200167C CN 02128134 CN02128134 CN 02128134 CN 02128134 A CN02128134 A CN 02128134A CN 1200167 C CN1200167 C CN 1200167C
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Abstract
The present invention relates to a functional cigarette paper. A suitable addition agent is added in the process of a cigarette paper producing technology. The addition agent is composed of inorganic filling materials, combustion-supporting agents and taste smoking and regulating agents. The weigh of finished product paper is used as a reference, the inorganic filling materials comprise components: 15 to 50 wt%, of calcium carbonate, 0.1 to 1.0 wt% of alkali metal alginate, 0.1 to 1.5 wt% of nanometer oxide, and 8 to 40 wt% of silicon oxide, or alkaline earth metal silicate, or alkaline earth metal carbonate, or mixture of the silicon oxide, the alkaline earth metal silicates and the alkaline earth metal carbonate. The combustion-supporting agents comprise components: 0.1 to 2 wt% of alkali metal carboxylate or alkaline earth metal carboxylate, and 0.1 to 4 wt% alkali metal carbonate. The taste smoking and regulating agents comprise components: 0.2 to 5 wt% of xylitol, or sorbitol, or dextrose. The ash packing effect of the present invention is obviously improved, and the present invention has the function of reducing tar. The tar is reduced to 0.6 to 1 mg per cigarette, and the combustion quality of the cigarette is effectively improved. Negative effect does not generated for previous smoking taste, and the present invention can be realized by adopting a conventional production technology.
Description
Technical field
The present invention relates to a kind of cigarette paper, especially relate to a kind of functional cigarette paper.
Background technology
Along with cigarette develops to " low tar, low harm, top grade " direction, when the consumer is concerned about the smoking security, pay attention to the presentation quality that cigarette props up gray columns during the vision class of cigarette and the suction more.Be that cigarette can provide good parcel outward appearance, the cigarette quality of high-quality, when suction cigarette prop up the gray columns good looking appearance, the ash that do not waft, do not fall ash.In view of the effective way the most that can play the parcel pipe tobacco at present and can address the above problem adopts high performance cigarette paper exactly, and the market demand is urgent, so development function type cigarette paper is imperative.
Up to now, commercially available cigarette paper also has the following disadvantages:
Though 1. have the good burnt performance of falling, cigarette suction the time waft ash, to fall grey phenomenon serious; 2. the production process complexity often needs equipment, technology are done bigger change, is difficult to drop into suitability for industrialized production; 3. select the material costliness for use, and cause unit cost higher, be not easy extensively to promote; 4. though wrap grey performance bigger improvement is arranged, product has a negative impact to the original suction of cigarette flavor or only the cigarette of certain several trade mark is not had a negative impact or is unsuitable for running up on the cigarette unit; 5. product function is single.
Summary of the invention
The objective of the invention is at above-mentioned the deficiencies in the prior art, provide a kind of and can reduce cigarette tar content, can improve cigarette again and prop up and burn and suck the posterior gray column of spinal cord presentation quality, have good bag ash performance, and the functional cigarette paper that the original suction flavor of cigarette is not had a negative impact.
Purpose of the present invention is achieved by following technical proposals.
Except as otherwise noted, the percentage that is adopted among the present invention is percetage by weight.
Cigarette paper provided by the invention is to add auxiliary agent in the cigarette paper production process, and described auxiliary agent is adjusted agent three parts by inorganic filler, combustion adjuvant and suction flavor and formed.Weight with finished paper is benchmark, the composition of described inorganic filler and content are: calcium carbonate 15%～50%, alkali metal alginate 0.1%-1.0%, nano-oxide 0.1%～1.5%, the mixture 8%-40% that Si oxide, alkaline-earth-metal silicate and alkaline earth metal carbonate three form; The composition of described combustion adjuvant and content are: alkali metal carboxylate or alkaline earth metal carboxylation 0.1%～2%, potash 0.1%～4%; Composition and content that described suction flavor is adjusted agent are: xylitol or sorbierite or glucose 0.2%～5%.
Described calcium carbonate is the precipitated calcium carbonate powder; Described alkali metal alginate is sodium alginate or potassium alginate; Described nano-oxide is nano-aluminium oxide or titanium dioxide or zinc oxide; Described alkali metal carboxylate is selected from potassium malate, malic acid lithium, natrium malicum, potassium lactate, sodium lactate; Described alkaline earth metal carboxylation is selected from calcium malate, magnesium malate, calcium lactate or magnesium lactate.
Described inorganic filler is equipped with slurry process at wood pulp to be added, and main purpose is to make inorganic filler and fiber that mixing and mixing time of abundance be arranged, and guarantees that filler evenly disperses in fibrous raw material and is adsorbed to fiber surface.Described combustion adjuvant and inhale flavor and adjust agent is with 1.0%～20% the combustion adjuvant aqueous solution; 0.5%～10% the odor absorber aqueous solution adds in the cigarette paper by sizing applicator, and addition manner is to choose coating and the mode of dip-coating is carried out the single or double applying glue according to product type.And addition manner does not need to do any change to existing cigarette paper production equipment, production technology, and examples of such additives can be produced unit, this functional cigarette paper of explained hereafter at difference.
Compared with prior art, the present invention has following outstanding beneficial effect:
Cigarette is when suction, and the gray columns good looking appearance does not have the ash that wafts, falls grey phenomenon, wraps grey effect and obviously improves.And successfully realize falling burnt function, 0.6～1 milligram/in reduction tar effectively improves the cigarette burning quality, and original suction flavor of multiple trade mark cigarette is not had a negative impact.Cigarette paper production does not need original technology, equipment are done any change, adopts conventional production process just can realize, and product can satisfy and runs up.The present invention has good social benefit and economic benefit, is rich in the prospect of marketing.
In line with the attitude that the consumer is responsible for, strict check has been carried out in the security of adding auxiliary agent, additive detects institute through China Preventive Medicial Science Institute's environmental sanitation and carries out the toxicity check.Assay such as table 1～table 4.
The result of the test of acute oral toxicity test sees Table 1.As can be seen from Table 1, the auxiliary agent of the present invention's interpolation is to female, the male per os LD of small white mouse
50All, belong to actual nontoxic level greater than the 10000mg/kg body weight.
Mouse marrow cell micro nuclear test the results are shown in Table 2.The data of table 2 show that the auxiliary agent 2500,5000 that the present invention adds and three dosage groups of 10000mg/kg body weight are to the undistorted effect of bone marrow cells in mice.
Tried thing to rabbit acute skin irritation/corrosion test the results are shown in Table 3, table 4.The data of table 3, table 4 show, the auxiliary agent that the present invention adds once contacts animal at working concentration and 2.5 times and 5 times of three dosage and does not cause that all skin irritatin reacts, its the highest total mark average is 0, and by skin irritatin strength grading standard, this is tried thing and belongs to nonirritant.
Description of drawings
Fig. 1 is practical application effect figure of the present invention.
The specific embodiment
By specific embodiment given below, can further be well understood to the present invention.But they are not limitation of the invention.
Embodiment 1
Get 600 kilograms of wood pulps, add 72 kilograms in siliceous mixture, precipitated calcium carbonate 120 kg, 3 kilograms of nano-aluminium oxides, 4 kilograms of sodium alginates.Preparation 12% potassium malate lithium, 16% potassium malate sodium, 8% the potash and 4% the xylitol aqueous solution adopt coating method to carry out single face in combustion adjuvant interpolation place to add.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment: quantitatively: 34.0g/m2, air permeability: 60 Ke Ruisita.
Embodiment 2
Get 600 kilograms of wood pulps, add 130 kilograms of precipitated calcium carbonates, 6 kilograms of nano-aluminium oxides, the potassium malate lithium of preparation 12%, 20% potassium malate sodium, 10% wet chemical adopts coating method to carry out the single face interpolation in combustion adjuvant interpolation place.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment: quantitatively: 28.0g/m2; Air permeability: 60 Ke Ruisita.
Embodiment 3
Get 600 kilograms of wood pulps, add 92 kilograms in siliceous mixture, 100 kilograms of precipitated calcium carbonates, 2 kilograms of nano-aluminium oxides, the potassium malate lithium of preparation 16%, 10% potassium malate sodium, 10% wet chemical adopts coating method to carry out the single face interpolation in combustion adjuvant interpolation place.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment: quantitatively: 34.09/m2; Air permeability: 60 Ke Ruisita.
Embodiment 4
Get 600 kilograms of wood pulps, add 75 kilograms in siliceous mixture, the precipitated calcium carbonate 120 kg, 4 kilograms of sodium alginates, 3 kilograms of nano-aluminium oxides, the Potassium fumarate of preparation 15%, 12% malic acid lithium, 8% potassium acetate and 5% D/W adopt coating method to carry out the single face interpolation in combustion adjuvant interpolation place.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment, quantitatively: 28.0g/m2, air permeability: 80 Ke Ruisita.
Embodiment 5
Get 600 kilograms of wood pulps, add 80 kilograms in siliceous mixture, 100 kilograms of precipitated calcium carbonates, 3 kilograms of sodium alginates, 2 kilograms of nano titanium oxides, the potassium malate lithium of preparation 15%, 10% calcium lactate, 8% magnesium malate and 5% sorbitol aqueous solution adopt coating method to carry out two-sided interpolation in combustion adjuvant interpolation place.Paper technology is produced cigarette paper routinely, and control cigarette paper index is on equipment, quantitatively: 30.0g/m
2Air permeability: 80 Ke Ruisita.
Embodiment 6
Get 600 kilograms of wood pulps, add 75 kilograms in siliceous mixture, the precipitated calcium carbonate 120 kg, 4 kilograms of sodium alginates, 2 kilograms of nano titanium oxides, the calcium malate of preparation 10%, 10% sodium potassium tartrate tetrahydrate and the aqueous potassium lactate solution of t0% adopt coating method to carry out two-sided interpolation in combustion adjuvant interpolation place.Skill is produced cigarette paper in the papermaking routinely, and control cigarette paper index is on equipment, quantitatively: 30.0g/m
2Air permeability: 60 Ke Ruisita.
Embodiment 7
Remove nanometer Al
2O
3Replace to outside the ZnO, all the other auxiliary agents add quantity, kind, mode and production method with embodiment 1.
Embodiment 8
The Potassium fumarate aqueous solution except that 15% replaces to 10% the potassium citrate aqueous solution, and all the other auxiliary agents add quantity, kind, mode and production method with embodiment 4.
Embodiment 9
Wet chemical except that 10% replaces to 8% the magnesium lactate aqueous solution, and all the other auxiliary agents add quantity, kind, mode and production method with embodiment 3.
Embodiment 10
Except that sodium alginate replaced to potassium alginate, all the other auxiliary agents added quantity, kind, mode and production method with embodiment 6.
Embodiment 11
Wet chemical except that 10% replaces to 14% the potassium citrate aqueous solution, and all the other auxiliary agents add quantity, kind, mode and production method with embodiment 2.
Table 1.
Dosage grouping number of animals dead animal is counted the death rate
Sex
(mg/kg) (only) (only) (%)
1000 5 0 0
2150 5 0 0
♀
4640 5 0 0
10000 5 0 0
1000 5 0 0
2150 5 0 0
♂
4640 5 0 0
10000 5 0 0
Table 2.
The dosage number of animals is had a liking for the red micronucleus that contains of polychromatophilia and is had a liking for many micronuclear rateses
Tried thing P value
(mg/kg) (only) TCS incarnadines cell number (‰)
2500 5 5000 4 0.80 ＞0.05
Tried thing 5,000 5 5,000 5 1.00＞0.05
10000 5 5000 7 1.40 ＞0.05
Sodium carboxymethylcellulose (1%) 5 5,000 4 0.80-
Endoxan (50mg/kg) 5 5,000 198 39.60＜0.01
Table 3.
Skin irritatin reaction scoring
Dosage animal gonosome 1h 24h 48h
Grouping is heavy
The contrast of sample control sample control sample
(%) numbering other (kg)
The total red water of the total red water of the total red water of the total red water of the total red water of red water is total
Spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to be divided
1 ♀ 2.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2 ♀ 2.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Use 3 ♂ 2.3 000000000000000000
Concentration 4 ♂ 2.5 000000000000000000
Total mark average 000000
Table 4.
Skin irritatin reaction scoring
Dosage animal gonosome
1h 24h 48h
Grouping is heavy
The contrast of sample control sample control sample
(%) numbering other (kg)
The total red water of the total red water of the total red water of the total red water of the total red water of red water is total
Spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to divide that spot is swollen to be divided
1 ♀ 2.3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Use 2 ♀ 2.5 000000000000000000
Concentration 3 ♂ 2.4 000000000000000000
2.5 4 ♂ 2.3 000000000000000000 doubly
Total mark average 000000
1 ♀ 2.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Use 2 ♀ 2.5 000000000000000000
Concentration 3 ♂ 2.3 000000000000000000
5 times of 4 ♂ 2.4 000000000000000000
Total mark average 000000
Claims (1)
1. cigarette paper, employing is added auxiliary agent in the cigarette paper production process, described auxiliary agent is adjusted agent three parts by inorganic filler, combustion adjuvant and suction flavor and is formed, weight with finished paper is benchmark, and the composition of described inorganic filler and percetage by weight are: the mixture that 15%～50% calcium carbonate, 8%～40% Si oxide, alkaline-earth-metal silicate and alkaline earth metal carbonate three form, the sodium alginate of 0.1%-1.0% or potassium alginate, 0.1%～1.5% nano-aluminium oxide or sodium rice titanium dioxide or sodium rice zinc oxide; The composition of described combustion adjuvant and percetage by weight are: 0.1%～2% potassium malate, malic acid lithium, natrium malicum, potassium lactate, sodium lactate, calcium malate, magnesium malate, calcium lactate or magnesium lactate, 0.1%～4% potash; Composition and percetage by weight that described suction flavor is adjusted agent are: 0.2%～5% xylitol, sorbierite or glucose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02128134 CN1200167C (en) | 2002-12-27 | 2002-12-27 | Functional cigarette paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02128134 CN1200167C (en) | 2002-12-27 | 2002-12-27 | Functional cigarette paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1429946A CN1429946A (en) | 2003-07-16 |
| CN1200167C true CN1200167C (en) | 2005-05-04 |
Family
ID=4745939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02128134 Expired - Fee Related CN1200167C (en) | 2002-12-27 | 2002-12-27 | Functional cigarette paper |
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| Country | Link |
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| CN (1) | CN1200167C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101195977B (en) * | 2007-12-21 | 2010-12-29 | 湖南中烟工业有限责任公司 | Cigarette tissue with variable permeating degree and method for producing the same |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1316122C (en) * | 2004-10-22 | 2007-05-16 | 云南瑞升科技有限公司 | Cigarette paper and preparation method |
| CN1327082C (en) * | 2005-09-08 | 2007-07-18 | 郑州瑞普生物工程有限公司 | Cigarette paper additive and its preparation method |
| CN100519931C (en) * | 2007-02-15 | 2009-07-29 | 云南瑞升烟草技术（集团）有限公司 | Cigarette paper employing natural baccy fiber |
| EP2278069B8 (en) * | 2008-05-16 | 2016-07-13 | Japan Tobacco, Inc. | Process for producing cigarette paper having low ignition propensity |
| CN101781867B (en) * | 2010-02-09 | 2012-01-04 | 广东中烟工业有限责任公司 | Low ignition tendency cigarette paper and preparation method thereof |
| CN101864698A (en) * | 2010-06-10 | 2010-10-20 | 红云红河烟草(集团)有限责任公司 | Method for improving quality of cigarette paper |
| CN102199902B (en) * | 2011-05-13 | 2014-02-12 | 民丰特种纸股份有限公司 | Cigarette paper with low ignition tendency and preparation method |
| CN102733254B (en) * | 2012-07-02 | 2014-10-01 | 川渝中烟工业有限责任公司 | Cigarette paper additive with harm-reduction function, and application thereof |
| CN103046431A (en) * | 2012-12-16 | 2013-04-17 | 青岛盛瀚色谱技术有限公司 | Cigarette paper |
| CN103321102A (en) * | 2013-06-27 | 2013-09-25 | 苏州工业园区依利电子贸易有限公司 | Cigarette wrapping paper |
| CN103556541B (en) * | 2013-10-18 | 2016-03-16 | 湖南中烟工业有限责任公司 | A kind of cigarette paper and application thereof with variable diffusivity and pore structure |
| CN103882778B (en) * | 2014-04-02 | 2016-08-17 | 湖南中烟工业有限责任公司 | A kind of reduce the preparation method of the pore cigarette paper of the harmful substance burst size such as CO in cigarette mainstream flue gas |
| CN105220561A (en) * | 2015-07-27 | 2016-01-06 | 杭州华丰纸业有限公司 | A kind of cigarette paper containing non-wood-fiber |
| CN105040511A (en) * | 2015-07-28 | 2015-11-11 | 湖北中烟工业有限责任公司 | Method for preparing reconstructed tobacco-leaf cigarette paper by replacing part of wood pulp with bamboo pulp |
| CN107587382A (en) * | 2017-09-07 | 2018-01-16 | 滁州市光威化工有限公司 | A kind of cigarette paper with the inflammable function that eliminates smoke |
| CN114182572A (en) * | 2020-09-14 | 2022-03-15 | 中国制浆造纸研究院有限公司 | Cigarette paper capable of improving whiteness and ash wrapping performance of cigarette ash and preparation method thereof |
| CN116411485A (en) * | 2023-04-06 | 2023-07-11 | 云南中烟工业有限责任公司 | Cigarette paper, preparation method and application thereof |
-
2002
- 2002-12-27 CN CN 02128134 patent/CN1200167C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101195977B (en) * | 2007-12-21 | 2010-12-29 | 湖南中烟工业有限责任公司 | Cigarette tissue with variable permeating degree and method for producing the same |
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| Publication number | Publication date |
|---|---|
| CN1429946A (en) | 2003-07-16 |
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