CN103173162A - Acidic flame-retardant holder adhesive for cigarettes - Google Patents
Acidic flame-retardant holder adhesive for cigarettes Download PDFInfo
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- CN103173162A CN103173162A CN2013101157814A CN201310115781A CN103173162A CN 103173162 A CN103173162 A CN 103173162A CN 2013101157814 A CN2013101157814 A CN 2013101157814A CN 201310115781 A CN201310115781 A CN 201310115781A CN 103173162 A CN103173162 A CN 103173162A
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Abstract
The invention discloses an acidic flame-retardant holder adhesive for cigarettes. The acidic flame-retardant holder adhesive comprises the following components in percentage by mass: 5-15 percent of acidic flame-retardant additive and 85-95 percent of acidic adhesive. The holder adhesive is inexpensive and easily available raw materials, safe and nontoxic to use, stable in property and free of foreign smell; the acidic flame-retardant holder adhesive can be used for keeping the original smoking quality of cigarettes and ensuring that a cigarette end has a rapid self-extinguishing function; and a preparation method is simple and rapid and can be industrially applied.
Description
Technical field
The present invention relates to a kind of cigarette with acid fire-retardant mouth glue, the technical field of cigarettes of connecing.
Background technology
China is maximum in the world cigarette producing country, is also maximum in the world tobacco consumption state.Along with the development of tobacco science and technology, " smoking is with healthy ", " smoking and safety " become the main flow trend of tobacco industry development gradually.This mainly considers from two aspects: the one, and infringement and pollution that the flue gas that cigarette burning produces produces human body and surrounding environment, two refer to the fire that caused by smoking.
The lighted cigarette butt surface temperature is 200 ℃～300 ℃, and core temperature is 700 ℃～800 ℃, apparently higher than the burning-point of other combustible materials.Be 130 ℃ as paper, cotton-wadded quilt, numb suede are 150 degree, and pine is 250 ℃.It is 4～15 minutes that the Linear Leaf Speedwell cigarette prolongs the burning time, inhales surplus cigarette end and generally can continue firing 1～4 minute, and within this time, many inflammableness article all can be lighted.Sometimes cigarette end is thrown away in cotton-wadded quilt, wood shavings, wood chip or thick grass, and the dozens of minutes of glowing is not easy to be noted by the people that danger is larger.
According to statistics, what in Japanese family fire, smoking caused accounts for 26%, and what in the American family fire, smoking caused accounts for 29.1%.These countries are annual to be had many people to die from smoking due to carelessness or throws out without care in the fire that cigarette end causes.The fire that cigarette end causes in some cities of China accounts for 1/7th of fire sum, causes the news report of personnel and property damage to happen occasionally by house or the hill fire of throwing out the cigarette end initiation without care.
Summary of the invention
The present invention is directed to and inhale surplus stub and have very wildfire hidden danger, purpose is to provide that a kind of raw material is cheap and easy to get, safety non-toxic evil when using, proterties are stable, free from extraneous odour and keep the original suction quality of cigarette, stub is had fast from the acid fire-retardant mouth glue that connects that puts out function.
The invention provides a kind of cigarette with the acid fire-retardant mouth glue that connects, the fire-retardant mouth glue that connects of this acidity comprises following mass component: acid flame-retardant additive 5～15%; Aci-Jel stick 85～95%; Described acid flame-retardant additive is one or more in oxalic acid, oxysuccinic acid, coffic acid, Citric Acid, usp, Anhydrous Powder, citric acid, tartrate, xitix or Tai-Ace S 150; Described Aci-Jel stick is one or more in polyvinyl acetate, vinyl acetate copolymer or polyvinyl alcohol.
Preferred acid flame-retardant additive is tartrate and caffeinic composite, or oxalic acid, oxysuccinic acid and xitix is composite, or citric acid and caffeinic composite, or citric acid and Tai-Ace S 150 is composite.
Described tartrate and coffic acid are that 1:0.5～2 are composite in mass ratio; Described oxalic acid, oxysuccinic acid and xitix are that 1:0.5～2:0.5～2 are composite in mass ratio; Described citric acid and coffic acid are that 1:0.5～2 are composite in mass ratio; Described citric acid and Tai-Ace S 150 are that 1:0.5～2 are composite in mass ratio.
The pH of described Aci-Jel stick is 4～6.
In the present invention, the acid fire-retardant preparation method who connects mouth glue mixes with the Aci-Jel stick acid flame-retardant additive according to mass ratio, and get final product.
Described preparation method mixes acid flame-retardant additive and Aci-Jel stick and gets final product at normal temperatures according to mass ratio.
Remarkable advantage of the present invention:
Through repetition test, the acid flame-retardant additive that filters out is more cheap and easy to get with respect to other flame-retardant additive from numerous materials for a, the present invention, safer environmental protection, and totally nontoxic meets the foodstuff additive requirement;
B, connect with acidity of the present invention is fire-retardant the cigarette that mouth glue rolls, when being burned to the position of tipping paper, stub can all extinguish voluntarily in 1～2 minute, and the rate of certainly putting out be for can reach 100%, can effectively prevent and reduce because of the caused fire of extingushing cigarette tip not;
C, acidity of the present invention be fire-retardant to be connect mouth glue color, smell, acid-basicity, viscosity, stability, quality guaranteed period etc. and has kept the common characteristic that connects mouth glue;
D, can keep the original suction quality of cigarette and taste by the fire-retardant cigarette that connects mouth film system of the present invention, the smoke chemistry index is substantially unchanged;
E, the fire-retardant mouth glue preparation technology Simple fast that connects of the present invention need not be done any change to cigarette machine, can be applicable to all cigarette tipping papers.
Embodiment
Now further illustrate in conjunction with the embodiments, and can not form restriction to the present invention:
Embodiment 1
The acid fire-retardant preparation that connects mouth glue:
In connecing mouth glue, 450 gram regular-size cigarettes add while stirring 50 gram tartrate to get final product till dissolving fully, mixing.
Adopt respectively that above-mentioned acidity is fire-retardant connects mouth glue and regular-size cigarette connects mouth glue, identical pipe tobacco and other auxiliary material, the production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, pungency, pleasant impression etc.) are estimated; By standard method, two kinds of cigarette sample main flume conventional chemical indexs are carried out analyzing and testing simultaneously;
Cigarette sample quality evaluation result shows: can substantially keep the original suction quality of cigarette and taste by the fire-retardant cigarette that connects mouth film system of above-mentioned acidity, cigarette sample main flume conventional chemical index analysis detected result shows both basic indifferences.
The end extinguishing test:
F, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
G, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear vertical placement (combustion head-up), and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
The results are shown in following table 1:
Table 1 end extinguishing test-results
| ? | Light number | From putting out number | From putting out rate |
| The common cigarette that connects mouth film system | 40 | 4 | 10% |
| The acid fire-retardant cigarette that connects mouth film system | 40 | 40 | 100% |
Embodiment 2
The fire-retardant preparation that connects mouth glue:
In connecing mouth glue, 440 gram regular-size cigarettes add respectively while stirring 30 gram citric acids and 30 gram coffic acids to get final product till dissolving fully, mixing.
Adopt respectively that above-mentioned acidity is fire-retardant connects mouth glue and regular-size cigarette connects mouth glue, identical pipe tobacco and other auxiliary material, the production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, pungency, pleasant impression etc.) are estimated; By standard method, two kinds of cigarette sample main flume conventional chemical indexs are carried out analyzing and testing simultaneously;
Cigarette sample quality evaluation result shows: can substantially keep the original suction quality of cigarette and taste by the fire-retardant cigarette that connects mouth film system of acidity, cigarette sample main flume conventional chemical index analysis detected result shows both basic indifferences.
The end extinguishing test:
H, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
I, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear vertical placement (combustion head-up), and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
The results are shown in following table 2:
Table 2 end extinguishing test-results
| ? | Light number | From putting out number | From putting out rate |
| The common cigarette that connects mouth film system | 40 | 2 | 5% |
| The acid fire-retardant cigarette that connects mouth film system | 40 | 40 | 100% |
Embodiment 3
The fire-retardant preparation that connects mouth glue:
In connecing mouth glue, 440 gram regular-size cigarettes add respectively while stirring 30 gram citric acids and 30 gram Tai-Ace S 150 to get final product till dissolving fully, mixing.
Adopt respectively that above-mentioned acidity is fire-retardant connects mouth glue and regular-size cigarette connects mouth glue, identical pipe tobacco and other auxiliary material, the production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, pungency, pleasant impression etc.) are estimated; By standard method, two kinds of cigarette sample main flume conventional chemical indexs are carried out analyzing and testing simultaneously;
Cigarette sample quality evaluation result shows: can substantially keep the original suction quality of cigarette and taste by the fire-retardant cigarette that connects mouth film system of acidity, cigarette sample main flume conventional chemical index analysis detected result shows both basic indifferences.
The end extinguishing test:
J, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
K, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear vertical placement (combustion head-up), and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
The results are shown in following table 3:
Table 3 end extinguishing test-results
| ? | Light number | From putting out number | From putting out rate |
| The common cigarette that connects mouth film system | 40 | 2 | 5% |
| The acid fire-retardant cigarette that connects mouth film system | 40 | 40 | 100% |
Embodiment 4
The preparation of fire-retardant splicing mouth glue:
In connecing mouth glue, 450 gram regular-size cigarettes add respectively while stirring 10 gram oxalic acid (being oxalic acid), 20 gram oxysuccinic acid, 20 gram xitix (Vc) to get final product till dissolving fully, mixing.
Adopt respectively that above-mentioned acidity is fire-retardant connects mouth glue and regular-size cigarette connects mouth glue, identical pipe tobacco and other auxiliary material, the production method cigarette becomes two kinds of cigarette samples routinely; By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, pungency, pleasant impression etc.) are estimated; By standard method, two kinds of cigarette sample main flume conventional chemical indexs are carried out analyzing and testing simultaneously;
Cigarette sample quality evaluation result shows, can substantially keep the original suction quality of cigarette and taste by the fire-retardant cigarette that connects mouth film system of acidity, and cigarette sample main flume conventional chemical index analysis detected result shows both basic indifferences.
The end extinguishing test:
L, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
M, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear vertical placement (combustion head-up), and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
The results are shown in following table 4:
Table 4 end extinguishing test-results
| ? | Light number | From putting out number | From putting out rate |
| The common cigarette that connects mouth film system | 40 | 3 | 7.5% |
| The acid fire-retardant cigarette that connects mouth film system | 40 | 40 | 100% |
Embodiment 5
The fire-retardant preparation that connects mouth glue:
In connecing mouth glue, 450 gram regular-size cigarettes add while stirring 50 gram oxalic acid to get final product till dissolving fully, mixing.
Adopt respectively fire-retardant mouth glue and common the High-speed Cigarette Adhesives for Filter Tipping, identical pipe tobacco and other auxiliary material of connecing of above-mentioned acidity, the production method cigarette becomes two kinds of cigarette samples routinely.By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, pungency, pleasant impression etc.) are estimated; By standard method, two kinds of cigarette sample main flume conventional chemical indexs are carried out analyzing and testing simultaneously;
Cigarette sample quality evaluation result shows: when being aspirated by the prepared acid fire-retardant cigarette that connects mouth film system of oxalic acid, the pungent taste mouthfeel strengthens, but both basic indifferences of cigarette sample main flume conventional chemical index analysis detected result.
The end extinguishing test:
N, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
O, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear vertical placement (combustion head-up), and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
The results are shown in following table 5:
Table 5 end extinguishing test-results
| ? | Light number | From putting out number | From putting out rate |
| The common cigarette that connects mouth film system | 40 | 2 | 5% |
| The acid fire-retardant cigarette that connects mouth film system | 40 | 24 | 60% |
The comparative example 1
The fire-retardant preparation that connects mouth glue:
In connecing mouth glue, 450 gram regular-size cigarettes add respectively while stirring 25 gram Whitfield's ointments and 25 gram phenylformic acid to get final product till dissolving fully, mixing.
Adopt respectively fire-retardant mouth glue and common the High-speed Cigarette Adhesives for Filter Tipping, identical pipe tobacco and other auxiliary material of connecing of above-mentioned acidity, the production method cigarette becomes two kinds of cigarette samples routinely.By specialty teacher of the smokeing panel test, two kinds of cigarette sample qualities (fragrance, harmony, assorted gas, pungency, pleasant impression etc.) are estimated; By standard method, two kinds of cigarette sample main flume conventional chemical indexs are carried out analyzing and testing simultaneously;
Cigarette sample quality evaluation result shows: when being aspirated by the prepared acid fire-retardant cigarette that connects mouth film system of Whitfield's ointment, the pungent taste mouthfeel strengthens, it is unclean that pleasant impression shows slightly, but both basic indifferences of cigarette sample main flume conventional chemical index analysis detected result.
The end extinguishing test:
P, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear horizontal positioned, and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
Q, two kinds of cigarette samples are divided into two groups, respectively get 20 and light rear vertical placement (combustion head-up), and self-burning when the position of firing to tipping paper, is observed it from putting out rate;
The results are shown in following table 6:
Table 6 end extinguishing test-results
| ? | Light number | From putting out number | From putting out rate |
| The common cigarette that connects mouth film system | 40 | 4 | 10% |
| The acid fire-retardant cigarette that connects mouth film system | 40 | 16 | 40% |
Claims (4)
1. a cigarette with the acid fire-retardant mouth glue that connects, is characterized in that, comprises following mass component: acid flame-retardant additive 5～15%; Aci-Jel stick 85～95%; Described acid flame-retardant additive is one or more in oxalic acid, oxysuccinic acid, coffic acid, Citric Acid, usp, Anhydrous Powder, citric acid, tartrate, xitix or Tai-Ace S 150; Described Aci-Jel stick is one or more in polyvinyl acetate, vinyl acetate copolymer or polyvinyl alcohol.
2. the fire-retardant mouth glue that connects of acidity as claimed in claim 1, it is characterized in that, described acid flame-retardant additive is tartrate and caffeinic composite, or oxalic acid, oxysuccinic acid and xitix is composite, or citric acid and caffeinic composite, or citric acid and Tai-Ace S 150 is composite.
3. the fire-retardant mouth glue that connects of acidity as claimed in claim 2, is characterized in that, described tartrate and coffic acid are that 1:0.5～2 are composite in mass ratio; Described oxalic acid, oxysuccinic acid and xitix are that 1:0.5～2:0.5～2 are composite in mass ratio; Described citric acid and coffic acid are that 1:0.5～2 are composite in mass ratio; Described citric acid and Tai-Ace S 150 are that 1:0.5～2 are composite in mass ratio.
4. the fire-retardant mouth glue that connects of acidity as described in claim 1～3 any one, is characterized in that, the pH of described Aci-Jel stick is 4～6.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310115781.4A CN103173162B (en) | 2013-04-03 | 2013-04-03 | Acidic flame-retardant holder adhesive for cigarettes |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310115781.4A CN103173162B (en) | 2013-04-03 | 2013-04-03 | Acidic flame-retardant holder adhesive for cigarettes |
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| CN103173162A true CN103173162A (en) | 2013-06-26 |
| CN103173162B CN103173162B (en) | 2015-07-15 |
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| CN201310115781.4A Active CN103173162B (en) | 2013-04-03 | 2013-04-03 | Acidic flame-retardant holder adhesive for cigarettes |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694930A (en) * | 2013-12-20 | 2014-04-02 | 陕西科技大学 | Method for preparing waterproof polyvinyl alcohol trademark adhesive |
| CN108531110A (en) * | 2018-04-19 | 2018-09-14 | 滁州君越高分子新材料有限公司 | A kind of retardant adhesive additive, fire retardant glue and its application process |
| CN108822762A (en) * | 2018-06-20 | 2018-11-16 | 滁州市光威化工有限公司 | A kind of flame-proof starch connects mouth glue and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110207867A1 (en) * | 2010-02-24 | 2011-08-25 | Fuji Xerox Co., Ltd. | Polylactic acid resin composition, method for producing polylactic acid resin composition, and polylactic acid resin molded article |
| CN102321438A (en) * | 2011-08-04 | 2012-01-18 | 湖南中烟工业有限责任公司 | Flame-retardant adhesive additive, and flame-retardant adhesive and application method thereof |
| CN102391795A (en) * | 2011-09-26 | 2012-03-28 | 湖南中烟工业有限责任公司 | Acidic flame-retardant adhesive for automatically extinguishing cigarettes and application method |
-
2013
- 2013-04-03 CN CN201310115781.4A patent/CN103173162B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110207867A1 (en) * | 2010-02-24 | 2011-08-25 | Fuji Xerox Co., Ltd. | Polylactic acid resin composition, method for producing polylactic acid resin composition, and polylactic acid resin molded article |
| CN102321438A (en) * | 2011-08-04 | 2012-01-18 | 湖南中烟工业有限责任公司 | Flame-retardant adhesive additive, and flame-retardant adhesive and application method thereof |
| CN102391795A (en) * | 2011-09-26 | 2012-03-28 | 湖南中烟工业有限责任公司 | Acidic flame-retardant adhesive for automatically extinguishing cigarettes and application method |
Non-Patent Citations (1)
| Title |
|---|
| 李广宇等: ""阻燃胶粘剂及其应用"", 《当代化工》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694930A (en) * | 2013-12-20 | 2014-04-02 | 陕西科技大学 | Method for preparing waterproof polyvinyl alcohol trademark adhesive |
| CN103694930B (en) * | 2013-12-20 | 2015-09-30 | 陕西科技大学 | A kind of preparation method of water-resistant polyvinyl alcohol trade mark adhesive |
| CN108531110A (en) * | 2018-04-19 | 2018-09-14 | 滁州君越高分子新材料有限公司 | A kind of retardant adhesive additive, fire retardant glue and its application process |
| CN108822762A (en) * | 2018-06-20 | 2018-11-16 | 滁州市光威化工有限公司 | A kind of flame-proof starch connects mouth glue and preparation method thereof |
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| Publication number | Publication date |
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| CN103173162B (en) | 2015-07-15 |
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