CN107587252A - A kind of antibacterial socks not easy to fade and preparation method thereof - Google Patents
A kind of antibacterial socks not easy to fade and preparation method thereof Download PDFInfo
- Publication number
- CN107587252A CN107587252A CN201710827073.1A CN201710827073A CN107587252A CN 107587252 A CN107587252 A CN 107587252A CN 201710827073 A CN201710827073 A CN 201710827073A CN 107587252 A CN107587252 A CN 107587252A
- Authority
- CN
- China
- Prior art keywords
- weight
- yarn
- parts
- socks
- antibacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Socks And Pantyhose (AREA)
- Knitting Of Fabric (AREA)
- Undergarments, Swaddling Clothes, Handkerchiefs Or Underwear Materials (AREA)
Abstract
The invention discloses a kind of antibacterial socks not easy to fade and preparation method thereof.The present invention prepares antimicrobial yarn by adding the raw materials such as plating nano silver fibre, zinc oxide/gelatin/polyvinyl alcohol composite antibacterial fibre, antiseptic in the feed, collard extract dyes as natural dyeing agent to yarn, finally gives a kind of antibacterial socks not easy to fade.The invention also discloses the preparation method of antibacterial socks not easy to fade.Compared with prior art, the antibacterial socks not easy to fade that the present invention is prepared not only possess excellent anti-microbial property while are also equipped with good color firmness.
Description
Technical field
The present invention relates to a kind of antimicrobial socks, more particularly to a kind of antibacterial socks not easy to fade and preparation method thereof.
Background technology
Microorganism is closely bound up with daily life.On the one hand, human use's biotechnology transports certain micro-organisms
Use in fermentation industry, biological pesticide and bacterial manure work；Probiotics in human body provides life by metabolism to human body must
Need material or help absorption of human body nutriment.On the other hand, part microorganism is pathogenic bacteria.The mankind that are broadcast to of pathogenic bacteria are good for
Health and the very big threat of personal safety.
According to records, silver is the 3rd metalloid that ancients use after gold, copper.The mankind are before more than 7000 years, just by gold
Category silver casts silverware and is used for daily life.In past thousands of years, silver has been used for many medical treatment aspects, is mainly used for
Tackle microorganism infection.But there is not the purposes that history secretary's system recorded silver always.Until modern age, Alexander is total first
The application of silver is medically tied.Silver nano-grain has been acknowledged as new and effective antiseptic.Antibacterial is silver nanostructured overall
Anti-microbial property significantly improves the anti-microbial property of Conventional nano structure antibacterials, and in the life for suppressing microorganism such as bacterium and fungi
Long, proliferation shows more preferable effect.
Silver has good broad-spectrum bactericidal action, and it is commonly used to the nano-particle in clinical and daily living article.With
For silver is compared existing for ionic species, Nano Silver size is small, specific surface area is big, with microorganism contact with each other effect probability just
It can increase, antibacterial effect will be stronger.
Also some researchs think that in nanometer silver surface silver ion can be discharged so that the hereditary material DNA of bacterium is reunited,
Hinder the proper splitting of bacterium.In addition, there are some researches show Nano Silver oxidable molecular oxygen under illumination condition, produce light
Catalytically bactericidal process acts on.Also research confirms, the anti-microbial property of Nano Silver is better than silver ion.Single compared to Antibacterial Mechanism is each
Class anti-biotic material, nano silver particles Antibacterial Mechanism complexity is various, therefore it has low drug resistance.
Socks are one of weft-knitted fabric major classes, there is stockings, knee length stocking, half hose and panty hose etc..Socks and clothes,
It is the part of world's dress ornament civilization.So socks are also " sufficient clothing ", " sufficient bag ".With the increasingly raising of living standard,
Modern increasingly focuses on health, is selecting personal clothing, for example socks, in addition to warming foot protection effect, Geng Duokao
What is considered is the security of socks, the feature of environmental protection and feature, does not require nothing more than dress conveniently, elegant in appearance, also requires that socks have and kills
Bacterium deodorization, the release function such as anion and infrared emitting.
Existing domestic socks function is relatively simple, species is few, and what is considered mostly is the outward appearance and comfort level of socks, main
To fall behind relevant with the bill of materials one of socks, processing technology.There is the raw material of special efficacy for some, added using irrational
Work technique, obtained new material can be made to reduce or lose some effects, do not reach the demand of people.Particularly in summer, heat
It is hard to bear, it is desirable to there is a socks to have excellent comfortableness, endurable conformality, and can smelly eliminating sterilization.
At present, as the improvement of people's living standards, the quality of textile can have been to be concerned by more and more people, city at present
Occur the fabric of many blending on field, but these fabrics are during dyeing, using substantial amounts of chemical dye, and finished product
Dyestuff it is easy to fall off during use, health is impacted.
Therefore, develop it is a kind of possess antibacterial socks that are safe, not easy to fade, possessing excellent anti-bacterium capability have it is important
Meaning.
The content of the invention
To achieve the above object, the invention provides a kind of antibacterial socks not easy to fade, it is characterised in that by 40~
60wt% outer shell fabrics and 40~60wt% nexines fabric composition.
Preferably, described outer shell fabric is made into by outer shell fabric with yarn.
Preferably, described outer shell fabric is made up with yarn of the raw material of following parts by weight：
Preferably, described nexine fabric plates Nano Silver fibre by 70~80wt% nexine fabric yarns and 20~30wt%
Dimension or filamentary silver are made into；
Preferably, described nexine fabric is made up with yarn of the raw material of following parts by weight：
It is further preferred that 15~20wt% of silver content in described plating nano silver fibre, fibre number is 40~140D；
Described filamentary silver is 40~140D filamentary silvers.
Preferably, described zinc oxide/gelatin/polyvinyl alcohol composite antibacterial fibre by 0.5~2.0wt%ZnO, 2.0~
3.0wt% gelatin, 10~20wt% polyvinyl alcohol, surplus are prepared for the raw material of water.
Zinc oxide nanoparticle in zinc oxide/gelatin/polyvinyl alcohol composite antibacterial fibre that the present invention adds by with
Bacterium contact failure cell membrane is so as to destroying the integrality of cell.Meanwhile Zinc oxide nanoparticle can produce O under visible light2-、
H2O2Etc. a series of reactive oxygen specieses；These materials all can be penetrated into bacterial cell, by destroying enzyme in bacterial cell, lipid and DNA
The metabolism of cell is limited, ultimately results in bacterial death.
Preferably, the softening agent in described outer shell fabric yarn and the softening agent in nexine fabric yarn are each only
It is on the spot polyethers amino modified polysiloxane, one in dioctadecyl dimethyl ammonium chloride, triethanolamine stearate glycine betaine
Kind is a variety of.
Preferably, the dispersant in described outer shell fabric yarn and the dispersant in nexine fabric yarn are each only
It is on the spot vinyl bis-stearamides or sodium lignin sulfonate.
Preferably, described antiseptic is the one or more in lady's thumb extract, dehydrogenation quassia alkali, vanillic aldehyde.
It is further preferred that described antiseptic is by lady's thumb extract, dehydrogenation quassia alkali, vanillic aldehyde in mass ratio 1：(2~
4)：(2~4) are obtained by mixing.
Lady's thumb：Polygonumpersicaria L., the compositions such as flavones, anthraquinones may be contained in lady's thumb herb,
So that lady's thumb extract has antimicrobial property.
Dehydrogenation quassia alkali：1-ethenyl-4,8-dimethoxy-9H-pyrido (3,4- β) indole, No. CAS：
65236-62-2, it is one of active ingredient of quassia antibacterial from quassia.
A kind of preparation method of antibacterial socks, it is characterised in that comprise the steps of：
1) preparation of outer shell fabric yarn：
By 40~50 parts by weight bombax cottons, 40~50 parts by weight cotton fibers or tencel or Modal fibre or flax fiber
Or bamboo fibre is placed in mixer；Add 1~3 parts by weight softening agent, 2~6 parts per weight dispersing agents, 80~100 parts by weight water
It is stirred, obtains mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
40~140D scribbleds；
Above-mentioned scribbled is immersed in dye liquor, is warming up to 70~90 DEG C, dyes 60~90min；Take out scribbled,
Washing, dehydration, drying, produce outer shell fabric yarn；
2) preparation of nexine fabric yarn：
By 10~20 parts by weight spandexs, 20~30 parts by weight bombax cottons, 20~30 parts by weight cotton fibers or tencel or not
Dai Er fibers or flax fiber or bamboo fibre, 10~20 part by weight of zinc oxide/gelatin/polyvinyl alcohol composite antibacterial fibre are placed in and stirred
Mix in machine；Add 1~3 parts by weight softening agent, 2~6 parts per weight dispersing agents, 0.15~0.90 parts by weight antiseptic, 80~100
Parts by weight water is stirred, and obtains mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
40~140D scribbleds；
Above-mentioned scribbled is immersed in dye liquor, is warming up to 70~90 DEG C, dyes 60~90min；Dye finishes, and takes out blending
Yarn, clear water is cleaned, dehydration, drying, produces nexine fabric yarn；
3) socks are knitted.
It is further preferred that a kind of preparation method of antibacterial socks, it is characterised in that comprise the steps of：
1) preparation of outer shell fabric yarn：
By 40~50 parts by weight bombax cottons, 40~50 parts by weight cotton fibers or tencel or Modal fibre or flax fiber
Or bamboo fibre is placed in mixer, 20~30min is stirred under 400~600 revs/min of rotating speed；Add 1~3 parts by weight
Softening agent, 2~6 parts per weight dispersing agents, 80~100 parts by weight water carry out secondary agitation, under 400~600 revs/min of rotating speed
5~10min is stirred, obtains mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
40~140D scribbleds；
Above-mentioned scribbled is immersed in 25~30 DEG C of dye liquor, 70~90 are warming up to 1.5~2.5 DEG C/min speed
DEG C, and 60~90min is dyed at 70~90 DEG C；Dye finishes, and takes out scribbled, and clear water is cleaned, is dehydrated after at 40~60 DEG C
24~36h is dried, produces outer shell fabric yarn；
2) preparation of nexine fabric yarn：
By 10~20 parts by weight spandexs, 20~30 parts by weight bombax cottons, 20~30 parts by weight cotton fibers or tencel or not
Dai Er fibers or flax fiber or bamboo fibre, 10~20 part by weight of zinc oxide/gelatin/polyvinyl alcohol composite antibacterial fibre are placed in and stirred
Mix in machine, 20~30min is stirred under 400~600 revs/min of rotating speed；Add 1~3 parts by weight softening agent, 2~6 weight
Part dispersant, 0.15~0.90 parts by weight antiseptic, 80~100 parts by weight water carry out secondary agitation, at 400~600 revs/min
Rotating speed under stir 5~10min, obtain mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
40~140D scribbleds；
Above-mentioned scribbled is immersed in 25~30 DEG C of dye liquor, 70~90 are warming up to 1.5~2.5 DEG C/min speed
DEG C, and 60~90min is dyed at 70~90 DEG C；Dye finishes, and takes out scribbled, and clear water is cleaned, is dehydrated after at 40~60 DEG C
24~36h is dried, produces nexine fabric yarn；
3) socks are knitted：
By hosiery machine weave base socks, control braiding during outer shell fabric with yarn all the time in the outer layer of socks, nexine face
Material yarn all the time under socks nexine, socks after machine, to undertoe suture without vestige, obtained with plating nano silver fibre or filamentary silver
To base socks；Base socks pass through conventional sizing, quality inspection, are packaged to be a kind of antibacterial socks not easy to fade.
Preferably, described step 1) and the mass volume ratio example of scribbled and dye liquor in step 2) are 1Kg：(30~
50)L；
The dye liquor includes the water of 2.5~5.0wt% collards extract, 2~10wt% metal salt mordants and surplus；
The dye liquor pH value is adjusted to 4~6 by acetic acid or sodium hydroxide；
Described metal salt mordant is one kind in copper sulphate, ferrous sulfate, potassium bichromate, alum.
Collard：Brassica oleracea L.var.acephala form.tricolor Hort., one kind is not
Tie the wild cabbage of leaf-head.
Beneficial effects of the present invention：
1st, a kind of antibacterial socks not easy to fade of the present invention, in the feed addition possess zinc oxide/gelatin of antibacterial characteristics/poly-
Prepared by the antibacterial material such as vinyl alcohol composite antibacterial fibre and lady's thumb extract, dehydrogenation quassia alkali, vanillic aldehyde possesses antibacterial characteristics
Antimicrobial yarn, finally weave the antibacterial socks for possessing notable antibacterial characteristics.
2nd, a kind of antibacterial socks not easy to fade of the present invention not only possess excellent antibacterial characteristics, while are also equipped with good resistance to
WASHING COLOR FASTNESS.Yarn is dyed as a kind of natural dye present invention employs collard extract so that final
The soaping fastness of obtained antibacterial socks is more than 3 grades.
Embodiment
Each raw material sources in embodiment：
Spandex：Polyurethane fibre, fibre length 50mm, fiber number 2.4dtex, the great ship chemical fiber wire operation of Zhuji City
Portion；
Bombax cotton：Fibre length about 20mm, it is purchased from Sheng Hu trade Co., Ltds of Nanning City；
Bamboo fibre：Fibre length about 38mm, fibre number 1.5D, are purchased from Hangzhou Jie Kang bamboo fiber products Co., Ltd；
Plate nano silver fibre：It is matrix with nylon 6, silver content 18%, fibre number 140D, is purchased from Dongguan City life Mao Te
Kind weaving Science and Technology Ltd.；
Dioctadecyl dimethyl ammonium chloride：No. CAS：107-64-2, content >=75%, the limited public affairs of the chemical industry of Jining 101
Department；
Vinyl bis-stearamides：No. CAS：110-30-5, content >=99%, Shandong Hao Yao new materials Co., Ltd；
Dehydrogenation quassia alkali：CAS 65236-62-6, content >=98%, upper Haifeng county longevity bio tech ltd；
Vanillic aldehyde：Vanillin, No. CAS：The limited public affairs of clever chemical science and technology are praised in 121-33-5, content >=99%, Shandong；
The preparation method of zinc oxide/gelatin/polyvinyl alcohol composite antibacterial fibre：
It is that 20nm zinc oxide, 2Kg gelatin, 20Kg polyvinyl alcohol, 77Kg water mix by 1Kg average grain diameters, is heated to 95
DEG C, persistently to stir 30min under 200 revs/min of rotating speed, with 0.1mol/L salt acid for adjusting pH to 8.0, standing and defoaming 8h, obtain
Spinning solution；
Above-mentioned spinning solution is subjected to conventional wet lay spinning, coagulation bath temperature is 45 DEG C, pH 8.0, by drawing-off, is done
Dry, thermal finalization, obtains Semifinished fibre；By Semifinished fibre by washing, dry, cut-out step, be made zinc oxide/gelatin/
Polyvinyl alcohol composite antibacterial fibre.
Zinc oxide：20 ± 5nm of average grain diameter, Shanghai Aladdin biochemical technology limited company；
Gelatin：No. CAS：9000-70-8, Jining Tylenol Chemical Co., Ltd.；
Polyvinyl alcohol：Model PVA-117, molecular weight are about 145000, Shanghai Aladdin biochemical technology limited company；
Lady's thumb extract：
Lady's thumb herb is cleaned, dried, is crushed with ST-510Y Saites medicinal herb grinder, crosses 40 mesh sieves；After taking 500g to crush
Medicinal material be placed in 2L round-bottomed flasks, add 1.5L distilled water；
Round-bottomed flask is heated, is extracted with volatile oil extractor, the timing since backflow, extracts 24h；
Obtained distillate is extracted with petroleum ether, extract anhydrous sodium sulfate drying.Sulfuric acid is removed by filtration
Sodium, rotation, which is evaporated under reduced pressure to remove when petroleum ether to volume is no longer reduced, under 50 DEG C of water-baths stops evaporation, obtains lady's thumb extract, will
Its sealing is kept in dark place stand-by.
Fresh lady's thumb herb：Changchun Tai Ren bio tech ltd, the place of production：Changbai Mountain.
The preparation method of collard extract：
Fresh collard is cleaned, dries, shredded, and the above-mentioned collards of 1Kg and 2L water are added to 5L round bottom
2h is heated to reflux under 100 DEG C of oil baths in flask, is filtered after being cooled to room temperature, obtained filtrate rotating pressure-decreasing under 50 DEG C of water-baths
It is concentrated by evaporation 1h；Obtain collard extract.
Collard：Shouguang De Sheng agricultural developments Co., Ltd, the introduces a collection place of production：Holland.
Embodiment 1
A kind of preparation method of antibacterial socks, it is characterised in that comprise the steps of：
1st, the preparation of outer shell fabric yarn：
50 parts by weight bombax cottons, 50 parts by weight bamboo fibres are placed in mixer, stirred under 500 revs/min of rotating speed
Mix 20min；Add 2 parts by weight softening agents, 4 parts per weight dispersing agents, 100 parts by weight water and carry out secondary agitation, at 500 revs/min
10min is stirred under the rotating speed of clock, obtains mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
140D scribbleds；
Above-mentioned scribbled is immersed in 25 DEG C of dye liquor, 90 DEG C are warming up to 1.5 DEG C/min speed, and at 90 DEG C
Dye 60min；Dye finishes, and takes out scribbled, is placed in cleaning cylinder and cleans 6 times, cleaner bath ratio is 1Kg：50L；Wash it is complete, in rotating speed
To be dehydrated 3min under 800 revs/min of SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three), then in 60
24h is dried under DEG C FLD-2000 large scale industries heated-air circulation roaster (Shanghai Shi Bei instrument and equipments factory), produces outer shell fabric yarn；
2nd, the preparation of nexine fabric yarn：
20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight bamboo fibres are placed in mixer, at 500 revs/min
20min is stirred under the rotating speed of clock；Add 2 parts by weight softening agents, 4 parts per weight dispersing agents, 100 parts by weight water and carry out secondary stir
Mix, stir 10min under 500 revs/min of rotating speed, obtain mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
140D scribbleds；
Above-mentioned scribbled is immersed in 25 DEG C of dye liquor, 90 DEG C are warming up to 1.5 DEG C/min speed, and at 90 DEG C
Dye 60min；Dye finishes, and takes out scribbled, is placed in cleaning cylinder and cleans 6 times, cleaner bath ratio is 1Kg：50L；Wash it is complete, in rotating speed
To be dehydrated 3min under 800 revs/min of SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three), then in 60
24h is dried under DEG C FLD-2000 large scale industries heated-air circulation roaster (Shanghai Shi Bei instrument and equipments factory), produces nexine fabric yarn；
3rd, socks are knitted：
Base socks are woven by EW-016-DIALRIB single-needles footwear machine (big latitude textile machine (Guangdong) Co., Ltd in Europe),
Outer shell fabric is with yarn all the time in the outer layer of socks during control braiding, and nexine fabric yarn is with plating nano silver fibre or silver
Silk all the time under socks nexine, socks after machine, to undertoe suture without vestige, obtains base socks；Base socks are by conventional sizing, matter
Examine, be packaged to be a kind of antibacterial socks not easy to fade.Outer shell fabric accounts for 40wt% with yarn in control antibacterial socks, and nexine fabric is used
Yarn accounts for 48wt%, and plating nano silver fibre accounts for 12wt%.
Described step 1 is 1Kg with the mass volume ratio example of scribbled and dye liquor in step 2：40L；The dye liquor bag
Include the water of 5.0wt% collards extract, 6wt% metal salt mordants and surplus；The pH of the dye liquor is 4, and pH value passes through
0.1mol/L acetic acid regulation；Described metal salt mordant is copper sulphate.
Silver content is 18wt%, fibre number 140D in described plating nano silver fibre.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Embodiment 2
A kind of preparation method of antibacterial socks, it is characterised in that comprise the steps of：
1st, the preparation of outer shell fabric yarn：
50 parts by weight bombax cottons, 50 parts by weight bamboo fibres are placed in mixer, stirred under 500 revs/min of rotating speed
Mix 20min；Add 2 parts by weight softening agents, 4 parts per weight dispersing agents, 100 parts by weight water and carry out secondary agitation, at 500 revs/min
10min is stirred under the rotating speed of clock, obtains mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
140D scribbleds；
Above-mentioned scribbled is immersed in 25 DEG C of dye liquor, 90 DEG C are warming up to 1.5 DEG C/min speed, and at 90 DEG C
Dye 60min；Dye finishes, and takes out scribbled, is placed in cleaning cylinder and cleans 6 times, cleaner bath ratio is 1Kg：50L；Wash it is complete, in rotating speed
To be dehydrated 3min under 800 revs/min of SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three), then in 60
24h is dried under DEG C FLD-2000 large scale industries heated-air circulation roaster (Shanghai Shi Bei instrument and equipments factory), produces outer shell fabric yarn；
2nd, the preparation of nexine fabric yarn：
By 20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight bamboo fibres, 20 part by weight of zinc oxide/gelatin/poly-
Vinyl alcohol composite antibacterial fibre is placed in mixer, and 20min is stirred under 500 revs/min of rotating speed；It is soft to add 2 parts by weight
Soft dose, 4 parts per weight dispersing agents, 100 parts by weight water carry out secondary agitation, stir 10min under 500 revs/min of rotating speed, obtain
Mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
140D scribbleds；
Above-mentioned scribbled is immersed in 25 DEG C of dye liquor, 90 DEG C are warming up to 1.5 DEG C/min speed, and at 90 DEG C
Dye 60min；Dye finishes, and takes out scribbled, is placed in cleaning cylinder and cleans 6 times, cleaner bath ratio is 1Kg：50L；Wash it is complete, in rotating speed
To be dehydrated 3min under 800 revs/min of SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three), then in 60
24h is dried under DEG C FLD-2000 large scale industries heated-air circulation roaster (Shanghai Shi Bei instrument and equipments factory), produces nexine fabric yarn；
3rd, socks are knitted：
Base socks are woven by EW-016-DIALRIB single-needles footwear machine (big latitude textile machine (Guangdong) Co., Ltd in Europe),
Outer shell fabric is with yarn all the time in the outer layer of socks during control braiding, and nexine fabric yarn is with plating nano silver fibre or silver
Silk all the time under socks nexine, socks after machine, to undertoe suture without vestige, obtains base socks；Base socks are by conventional sizing, matter
Examine, be packaged to be a kind of antibacterial socks not easy to fade.Outer shell fabric accounts for 40wt% with yarn in control antibacterial socks, and nexine fabric is used
Yarn accounts for 48wt%, and plating nano silver fibre accounts for 12wt%.
Described step 1 is 1Kg with the mass volume ratio example of scribbled and dye liquor in step 2：40L；The dye liquor bag
Include the water of 5.0wt% collards extract, 6wt% metal salt mordants and surplus；The pH of the dye liquor is 4, and pH value passes through
0.1mol/L acetic acid regulation；Described metal salt mordant is copper sulphate.
Silver content is 18wt%, fibre number 140D in described plating nano silver fibre.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Embodiment 3
A kind of preparation method of antibacterial socks, it is characterised in that comprise the steps of：
1st, the preparation of outer shell fabric yarn：
50 parts by weight bombax cottons, 50 parts by weight bamboo fibres are placed in mixer, stirred under 500 revs/min of rotating speed
Mix 20min；Add 2 parts by weight softening agents, 4 parts per weight dispersing agents, 100 parts by weight water and carry out secondary agitation, at 500 revs/min
10min is stirred under the rotating speed of clock, obtains mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
140D scribbleds；
Above-mentioned scribbled is immersed in 25 DEG C of dye liquor, 90 DEG C are warming up to 1.5 DEG C/min speed, and at 90 DEG C
Dye 60min；Dye finishes, and takes out scribbled, is placed in cleaning cylinder and cleans 6 times, cleaner bath ratio is 1Kg：50L；Wash it is complete, in rotating speed
To be dehydrated 3min under 800 revs/min of SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three), then in 60
24h is dried under DEG C FLD-2000 large scale industries heated-air circulation roaster (Shanghai Shi Bei instrument and equipments factory), produces outer shell fabric yarn；
2nd, the preparation of nexine fabric yarn：
By 20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight bamboo fibres, 20 part by weight of zinc oxide/gelatin/poly-
Vinyl alcohol composite antibacterial fibre is placed in mixer, and 20min is stirred under 500 revs/min of rotating speed；It is soft to add 2 parts by weight
Soft dose, 4 parts per weight dispersing agents, 0.60 parts by weight antiseptic, 100 parts by weight water carry out secondary agitation, 500 revs/min turn
The lower stirring 10min of speed, obtains mixture；
After said mixture is dried into processing, then it is made after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
140D scribbleds；
Above-mentioned scribbled is immersed in 25 DEG C of dye liquor, 90 DEG C are warming up to 1.5 DEG C/min speed, and at 90 DEG C
Dye 60min；Dye finishes, and takes out scribbled, is placed in cleaning cylinder and cleans 6 times, cleaner bath ratio is 1Kg：50L；Wash it is complete, in rotating speed
To be dehydrated 3min under 800 revs/min of SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three), then in 60
24h is dried under DEG C FLD-2000 large scale industries heated-air circulation roaster (Shanghai Shi Bei instrument and equipments factory), produces nexine fabric yarn；
3rd, socks are knitted：
Base socks are woven by EW-016-DIALRIB single-needles footwear machine (big latitude textile machine (Guangdong) Co., Ltd in Europe),
Outer shell fabric is with yarn all the time in the outer layer of socks during control braiding, and nexine fabric yarn is with plating nano silver fibre or silver
Silk all the time under socks nexine, socks after machine, to undertoe suture without vestige, obtains base socks；Base socks are by conventional sizing, matter
Examine, be packaged to be a kind of antibacterial socks not easy to fade.Outer shell fabric accounts for 40wt% with yarn in control antibacterial socks, and nexine fabric is used
Yarn accounts for 48wt%, and plating nano silver fibre accounts for 12wt%.
Described step 1 is 1Kg with the mass volume ratio example of scribbled and dye liquor in step 2：40L；The dye liquor bag
Include the water of 5.0wt% collards extract, 6wt% metal salt mordants and surplus；The pH of the dye liquor is 4, and pH value passes through
0.1mol/L acetic acid regulation；Described metal salt mordant is copper sulphate.
Silver content is 18wt%, fibre number 140D in described plating nano silver fibre.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Described antiseptic is by lady's thumb extract, dehydrogenation quassia alkali, vanillic aldehyde in mass ratio 1:3:3 are obtained by mixing.
Embodiment 4
It is substantially the same manner as Example 3, differ only in：Described antiseptic is pressed by lady's thumb extract, dehydrogenation quassia alkali
Mass ratio 1:6 are obtained by mixing.
Embodiment 5
It is substantially the same manner as Example 3, differ only in：Described antiseptic presses quality by lady's thumb extract, vanillic aldehyde
Than 1:6 are obtained by mixing.
Embodiment 6
It is substantially the same manner as Example 3, differ only in：Described antiseptic presses quality by dehydrogenation quassia alkali, vanillic aldehyde
Than 1:1 is obtained by mixing.
Test case 1
Using standard GB/T/T20994.3-2008《The evaluation third portion of antibacterial textile performance：Succusion》To reality
The antibacterial socks not easy to fade for applying the preparation of example 1~3 carry out antibiotic property quantitative test, using color fastness to washing testing machine washing side
Method, the bacteriostasis rate of fabric, test result are shown in Table 1 after test is washed 30 times.
Bacteriostasis rate test table (%) after table 1 is washed 30 times
As shown in table 1, the antibacterial socks not easy to fade that embodiment 3 is prepared possess significant fungistatic effect, to large intestine
Bacillus, staphylococcus aureus, the bacteriostasis rate of hay bacillus are respectively 99.9%, 97.6%, 99.3%.Pass through embodiment 1~3
Contrast it can be found that in the raw material of antibacterial socks not easy to fade add zinc oxide/gelatin/polyvinyl alcohol composite antibacterial fibre
The antibacterial ability of antibacterial socks not easy to fade can be obviously improved with antiseptic.Its reason may is that：Zinc oxide/gelatin/poly- second
Zinc oxide nanoparticle in enol composite antibacterial fibre with bacterium contact failure cell membrane by destroying the complete of cell
Property.Meanwhile Zinc oxide nanoparticle can produce O under visible light2-、H2O2Etc. a series of reactive oxygen specieses；These materials can all ooze
Enter in bacterial cell, the metabolism of cell is limited by destroying enzyme in bacterial cell, lipid and DNA, it is dead to ultimately result in bacterium
Die.Moreover, the antiseptic (lady's thumb extract, dehydrogenation quassia alkali, vanillic aldehyde) that the present invention adds is provided with good antibacterial
Effect.
Test case 2
The color fastness experiment for the antibacterial socks that embodiment is prepared refers to National Standard of the People's Republic of China GB/T3921-
2008《Textile color stability tests fastness to soaping》Tested.
The soaping fastness for the antibacterial socks not easy to fade that the embodiment of table 2 is prepared
| Embodiment | Soaping fastness |
| Embodiment 3 | 5 grades |
| Embodiment 4 | 3 grades |
| Embodiment 5 | 3~4 grades |
| Embodiment 6 | 3 grades |
Preferred embodiment of the invention described in detail above.It should be appreciated that one of ordinary skill in the art without
Creative work can is needed to make many modifications and variations according to the design of the present invention.Therefore, all technologies in the art
Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea
Technical scheme, all should be in the protection domain being defined in the patent claims.
Claims (10)
1. a kind of antibacterial socks not easy to fade, it is characterised in that by 40~60wt% outer shell fabrics and 40~60wt% nexines face
Material composition.
2. antibacterial socks as claimed in claim 1, it is characterised in that described outer shell fabric is made into by outer shell fabric with yarn；
Described outer shell fabric is made up with yarn of the raw material of following parts by weight：
3. antibacterial socks as claimed in claim 1 or 2, it is characterised in that described nexine fabric is by 70~80wt% nexines face
Material plates nano silver fibre with 20~30wt% with yarn or filamentary silver is made into；
Described nexine fabric is made up with yarn of the raw material of following parts by weight：
4. antibacterial socks as claimed in claim 3, it is characterised in that：Silver content 15 in described plating nano silver fibre~
20wt%, fibre number are 40~140D；Described filamentary silver is 40~140D filamentary silvers.
5. antibacterial socks as claimed in claim 3, it is characterised in that：Described zinc oxide/gelatin/polyvinyl alcohol composite antibacterial is fine
Dimension is prepared into by 0.5~2.0wt%ZnO, 2.0~3.0wt% gelatin, 10~20wt% polyvinyl alcohol, surplus for the raw material of water
Arrive.
6. antibacterial socks as claimed in claim 3, it is characterised in that：Softening agent and nexine in described outer shell fabric yarn
Fabric with the softening agent in yarn be each independently polyethers amino modified polysiloxane, dioctadecyl dimethyl ammonium chloride,
It is one or more kinds of in triethanolamine stearate glycine betaine；Dispersant and nexine fabric in described outer shell fabric yarn
Vinyl bis-stearamides or sodium lignin sulfonate are each independently with the dispersant in yarn.
7. antibacterial socks as claimed in claim 3, it is characterised in that：Described antiseptic be lady's thumb extract, dehydrogenation quassia alkali,
One or more in vanillic aldehyde.
8. the preparation method of the antibacterial socks as any one of claim 3-7, it is characterised in that comprise the steps of：
1) preparation of outer shell fabric yarn：
By 40~50 parts by weight bombax cottons, 40~50 parts by weight cotton fibers or tencel or Modal fibre or flax fiber or bamboo
Fiber is placed in mixer, adds 1~3 parts by weight softening agent, 2~6 parts per weight dispersing agents, the stirring of 80~100 parts by weight water,
Obtain mixture；
After said mixture is dried into processing, then obtained 40 after the rove by routine, spun yarn, winder, yarn steaming, doubling processing~
140D scribbleds；
Above-mentioned scribbled is immersed in dye liquor, is warming up to 70~90 DEG C, dyes 60~90min；Take out scribbled, water
Wash, be dehydrated, dry, produce outer shell fabric yarn；
2) preparation of nexine fabric yarn：
By 10~20 parts by weight spandexs, 20~30 parts by weight bombax cottons, 20~30 parts by weight cotton fibers or tencel or Modal
Fiber or flax fiber or bamboo fibre, 10~20 part by weight of zinc oxide/gelatin/polyvinyl alcohol composite antibacterial fibre are placed in mixer
In, add 1~3 parts by weight softening agent, 2~6 parts per weight dispersing agents, 0.15~0.90 parts by weight antiseptic, 80~100 weight
Part water stirring, obtains mixture；
After said mixture is dried into processing, then obtained 40 after the rove by routine, spun yarn, winder, yarn steaming, doubling processing~
140D scribbleds；
Above-mentioned scribbled is immersed in dye liquor, is warming up to 70~90 DEG C, dyes 60~90min；Dye finishes, and takes out mixed yarn
Line, clear water is cleaned, dehydration, drying, produces nexine fabric yarn；
3) socks are knitted.
9. the preparation method of antibacterial socks as claimed in claim 8, it is characterised in that comprise the steps of：
1) preparation of outer shell fabric yarn：
By 40~50 parts by weight bombax cottons, 40~50 parts by weight cotton fibers or tencel or Modal fibre or flax fiber or bamboo
Fiber is placed in mixer, and 20~30min is stirred under 400~600 revs/min of rotating speed；Add 1~3 parts by weight softness
Agent, 2~6 parts per weight dispersing agents, 80~100 parts by weight water carry out secondary agitation, are stirred under 400~600 revs/min of rotating speed
5~10min, obtain mixture；
After said mixture is dried into processing, then obtained 40 after the rove by routine, spun yarn, winder, yarn steaming, doubling processing~
140D scribbleds；
Above-mentioned scribbled is immersed in 25~30 DEG C of dye liquor, 70~90 DEG C is warming up to 1.5~2.5 DEG C/min speed,
And 60~90min is dyed at 70~90 DEG C；Dye finish, take out scribbled, washing, be dehydrated after at 40~60 DEG C dry 24~
36h, produce outer shell fabric yarn；
2) preparation of nexine fabric yarn：
By 10~20 parts by weight spandexs, 20~30 parts by weight bombax cottons, 20~30 parts by weight cotton fibers or tencel or Modal
Fiber or flax fiber or bamboo fibre, 10~20 part by weight of zinc oxide/gelatin/polyvinyl alcohol composite antibacterial fibre are placed in mixer
In, 20~30min is stirred under 400~600 revs/min of rotating speed；Add 1~3 parts by weight softening agent, 2~6 parts by weight point
Powder, 0.15~0.90 parts by weight antiseptic, 80~100 parts by weight water carry out secondary agitation, in 400~600 revs/min turn
Speed 5~10min of lower stirring, obtains mixture；
After said mixture is dried into processing, then obtained 40 after the rove by routine, spun yarn, winder, yarn steaming, doubling processing~
140D scribbleds；
Above-mentioned scribbled is immersed in 25~30 DEG C of dye liquor, 70~90 DEG C is warming up to 1.5~2.5 DEG C/min speed,
And 60~90min is dyed at 70~90 DEG C；Dye finishes, and takes out scribbled, and clear water is cleaned, is dehydrated after drying 24 at 40~60 DEG C
~36h, produce nexine fabric yarn；
3) socks are knitted；
Base socks are woven by hosiery machine, outer shell fabric is used in the outer layer of socks, nexine fabric all the time with yarn during control braiding
Yarn all the time under socks nexine, socks after machine, to undertoe suture without vestige, obtains base with plating nano silver fibre or filamentary silver
Socks；Base socks pass through conventional sizing, quality inspection, are packaged to be a kind of antibacterial socks not easy to fade.
10. the preparation method of antibacterial socks as claimed in claim 9, it is characterised in that described step 1) in step 2) with mixing
The mass volume ratio example of yarn and dye liquor is 1Kg：(30~50) L；
The dye liquor includes the water of 2.5~5.0wt% collards extract, 2~10wt% metal salt mordants and surplus；
The dye liquor pH value is adjusted to 4~6 by acetic acid or sodium hydroxide；
Described metal salt mordant is one kind in copper sulphate, ferrous sulfate, potassium bichromate, alum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710827073.1A CN107587252B (en) | 2017-09-14 | 2017-09-14 | Anti-fading antibacterial socks and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710827073.1A CN107587252B (en) | 2017-09-14 | 2017-09-14 | Anti-fading antibacterial socks and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107587252A true CN107587252A (en) | 2018-01-16 |
| CN107587252B CN107587252B (en) | 2020-07-28 |
Family
ID=61051528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710827073.1A Active CN107587252B (en) | 2017-09-14 | 2017-09-14 | Anti-fading antibacterial socks and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107587252B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108716115A (en) * | 2018-05-28 | 2018-10-30 | 陆爱明 | Anti-bacterial fibre, preparation method and applications |
| CN109338580A (en) * | 2018-10-24 | 2019-02-15 | 佛山源诚顺生态纺织科技有限公司 | A kind of antibiotic conductive silver fiber bamboo fiber blended knitted fabric |
| CN110318131A (en) * | 2019-04-15 | 2019-10-11 | 南通通州江华纺织有限公司 | A kind of processing method and resulting product of high resiliency tear-proof CVC mixed yarn |
| CN110820126A (en) * | 2019-11-26 | 2020-02-21 | 湖南尚珂伊针纺有限公司 | Comfortable and easy-to-dye sock-weaving fabric |
| CN111719196A (en) * | 2020-07-31 | 2020-09-29 | 储旭 | Composite antibacterial fiber and preparation method thereof |
| CN111876879A (en) * | 2020-07-31 | 2020-11-03 | 储旭 | Antibacterial fabric and preparation method thereof |
| CN112472420A (en) * | 2020-11-04 | 2021-03-12 | 胡数丽 | Ultrahigh molecular polyethylene fiber varicose vein socks and production equipment thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101112255A (en) * | 2006-07-27 | 2008-01-30 | 晏国新 | Underclothes, underdrawers, bra and swimsuit made by ceiba fiber |
| CN201640476U (en) * | 2010-02-10 | 2010-11-24 | 刘荣飞 | Moisture-absorbing and perspiring antibacterial socks |
| CN103835054A (en) * | 2014-03-12 | 2014-06-04 | 东华大学 | Ceiba textile with natural anti-mite function and processing technique thereof |
| CN204540849U (en) * | 2015-03-13 | 2015-08-12 | 浙江适康能新材料科技有限公司 | The anti-tinea socks of a kind of deodorizing |
| CN106551432A (en) * | 2015-09-28 | 2017-04-05 | 宜兴市艺蝶针织有限公司 | A kind of production technology of antibacterial health socks |
-
2017
- 2017-09-14 CN CN201710827073.1A patent/CN107587252B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101112255A (en) * | 2006-07-27 | 2008-01-30 | 晏国新 | Underclothes, underdrawers, bra and swimsuit made by ceiba fiber |
| CN201640476U (en) * | 2010-02-10 | 2010-11-24 | 刘荣飞 | Moisture-absorbing and perspiring antibacterial socks |
| CN103835054A (en) * | 2014-03-12 | 2014-06-04 | 东华大学 | Ceiba textile with natural anti-mite function and processing technique thereof |
| CN204540849U (en) * | 2015-03-13 | 2015-08-12 | 浙江适康能新材料科技有限公司 | The anti-tinea socks of a kind of deodorizing |
| CN106551432A (en) * | 2015-09-28 | 2017-04-05 | 宜兴市艺蝶针织有限公司 | A kind of production technology of antibacterial health socks |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108716115A (en) * | 2018-05-28 | 2018-10-30 | 陆爱明 | Anti-bacterial fibre, preparation method and applications |
| CN108716115B (en) * | 2018-05-28 | 2021-07-09 | 扬州天富龙科技纤维有限公司 | Antibacterial fiber, preparation method and application thereof |
| CN109338580A (en) * | 2018-10-24 | 2019-02-15 | 佛山源诚顺生态纺织科技有限公司 | A kind of antibiotic conductive silver fiber bamboo fiber blended knitted fabric |
| CN110318131A (en) * | 2019-04-15 | 2019-10-11 | 南通通州江华纺织有限公司 | A kind of processing method and resulting product of high resiliency tear-proof CVC mixed yarn |
| CN110820126A (en) * | 2019-11-26 | 2020-02-21 | 湖南尚珂伊针纺有限公司 | Comfortable and easy-to-dye sock-weaving fabric |
| CN111719196A (en) * | 2020-07-31 | 2020-09-29 | 储旭 | Composite antibacterial fiber and preparation method thereof |
| CN111876879A (en) * | 2020-07-31 | 2020-11-03 | 储旭 | Antibacterial fabric and preparation method thereof |
| CN112472420A (en) * | 2020-11-04 | 2021-03-12 | 胡数丽 | Ultrahigh molecular polyethylene fiber varicose vein socks and production equipment thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107587252B (en) | 2020-07-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107587252A (en) | A kind of antibacterial socks not easy to fade and preparation method thereof | |
| CN100460590C (en) | Antimicrobial yarn having nanosilver particles and methods for manufacturing the same | |
| CN104195735A (en) | Production technology for antibiosis moisture exhausting sock | |
| CN105648646B (en) | Anti-mite antibacterial healthy knitted fabric of one kind and preparation method thereof | |
| JP3179522B2 (en) | Dyed textile products and their production | |
| US20100003296A1 (en) | Manufacturing methods and applications of antimicrobial plant fibers having silver particles | |
| CN107475857A (en) | A kind of antibiotic facing material and preparation method thereof | |
| CN109385729A (en) | A kind of antimicrobial form blended fabric and its preparation process | |
| CN100535208C (en) | Nano silver-bamboo-charcoal dispersing liquid and method for preparing nano silver-bamboo-charcoal fiber | |
| CN105908280A (en) | Antibacterial viscose and preparation method thereof | |
| CN110273218A (en) | A kind of Wormwood fiber bedding and preparation method thereof | |
| CN106063659A (en) | A kind of production technology of copper ion antibacterial and deodouring fiber raschel blanket | |
| CN107299437A (en) | Anti-bacterial fibre yarn | |
| CN101564203A (en) | Method for manufacturing pineapple leaf fiber antibiosis health-protection socks | |
| CN106012092A (en) | Multifunctional protein fiber and preparation method thereof | |
| CN105908307A (en) | Textile material and preparation method thereof | |
| Samanta et al. | Potential of ligno-cellulosic and protein fibres in sustainable fashion | |
| KR20230022905A (en) | Mixed spun yarn comprising antibacterial extract and manufacturing method thereof | |
| JP3660891B2 (en) | Manufacturing method of antibacterial tea-dyed fiber products | |
| CN106388015A (en) | Special fabric for underpants and preparation method for special fabric | |
| Adnan et al. | Performance and Characterization of Aloe Vera Microcapsules on Silk/Lyocell Blended Fabric | |
| CN101187077A (en) | Nano photo-catalytic antibacterial moisture-absorbing dispersion and method for preparing fiber | |
| JP2003310721A (en) | Antibacterial cloth made of bamboo fibers | |
| JPH06192978A (en) | Production of textile product dyed with ganoderma lucidum karst. | |
| CN107503011A (en) | Preparation technology with the sun-proof Tourmaline fiber of health care, the fiber knitted underwear of banana stem |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200706 Address after: 322100 Jiangbei Street Light Industrial Park (Chemical Fiber Industrial Park), Dongyang City, Jinhua City, Zhejiang Province Applicant after: ZHEJIANG CHENYU CHEMICAL FIBER Co.,Ltd. Address before: No.21, chujiazhai, team 9, Xinbang village, Chuansha Liutuan, Pudong New Area, Shanghai Applicant before: Chu Xu |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |