CN107475857A - A kind of antibiotic facing material and preparation method thereof - Google Patents
A kind of antibiotic facing material and preparation method thereof Download PDFInfo
- Publication number
- CN107475857A CN107475857A CN201710827487.4A CN201710827487A CN107475857A CN 107475857 A CN107475857 A CN 107475857A CN 201710827487 A CN201710827487 A CN 201710827487A CN 107475857 A CN107475857 A CN 107475857A
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- facing material
- antibiotic facing
- fibre
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 47
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- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims 1
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- 150000004056 anthraquinones Chemical class 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
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- 239000003963 antioxidant agent Substances 0.000 description 2
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- 229910001431 copper ion Inorganic materials 0.000 description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
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- 239000007789 gas Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
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- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- UXAMZEYKWGPDBI-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC)Br(C)(C)C Chemical class C(CCCCCCCCCCCCCCC)Br(C)(C)C UXAMZEYKWGPDBI-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
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- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
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- OOSUHIIJYDMCCW-UHFFFAOYSA-N cyanamide;formaldehyde Chemical compound O=C.NC#N OOSUHIIJYDMCCW-UHFFFAOYSA-N 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
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- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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Abstract
The invention discloses a kind of antibiotic facing material and preparation method thereof.The raw material of the antibiotic facing material includes：Spandex, bombax cotton, cotton fiber or tencel or Modal fibre or flax fiber or bamboo fibre, melamine resin composite antibacterial fibre, plating nano silver fibre or filamentary silver, softening agent, dispersant and antiseptic.The invention also discloses the preparation method of the antibiotic facing material.Compared with prior art, the antibiotic facing material that present invention addition is prepared not only possesses excellent anti-microbial property while is also equipped with good fire resistance.
Description
Technical field
The present invention relates to a kind of fabric, more particularly to a kind of antibiotic facing material and preparation method thereof.
Background technology
Microorganism is closely bound up with daily life.On the one hand, human use's biotechnology transports certain micro-organisms
Use in fermentation industry, biological pesticide and bacterial manure work；Probiotics in human body provides life by metabolism to human body must
Need material or help absorption of human body nutriment.On the other hand, part microorganism is pathogenic bacteria.The mankind that are broadcast to of pathogenic bacteria are good for
Health and the very big threat of personal safety.
According to records, silver is the 3rd metalloid that ancients use after gold, copper.The mankind are before more than 7000 years, just by gold
Category silver casts silverware and is used for daily life.In past thousands of years, silver has been used for many medical treatment aspects, is mainly used for
Tackle microorganism infection.But there is not the purposes that history secretary's system recorded silver always.Until modern age, Alexander is total first
The application of silver is medically tied.Silver nano-grain has been acknowledged as new and effective antiseptic.Antibacterial is silver nanostructured overall
Anti-microbial property significantly improves the anti-microbial property of Conventional nano structure antibacterials, and in the life for suppressing microorganism such as bacterium and fungi
Long, proliferation shows more preferable effect.
Silver has good broad-spectrum bactericidal action, and it is commonly used to the nano-particle in clinical and daily living article.With
For silver is compared existing for ionic species, Nano Silver size is small, specific surface area is big, with microorganism contact with each other effect probability just
It can increase, antibacterial effect will be stronger.
Also some researchs think that in nanometer silver surface silver ion can be discharged so that the hereditary material DNA of bacterium is reunited,
Hinder the proper splitting of bacterium.In addition, there are some researches show Nano Silver oxidable molecular oxygen under illumination condition, produce light
Catalytically bactericidal process acts on.Also research confirms, the anti-microbial property of Nano Silver is better than silver ion.Single compared to Antibacterial Mechanism is each
Class anti-biotic material, nano silver particles Antibacterial Mechanism complexity is various, therefore it has low drug resistance.
In recent years, people require more and more higher to the comfortableness of garment material, health, security and feature of environmental protection etc., right
The functional requirement of safe and efficient antibacterial dress ornament is more and more；In life, people inevitably touch various thin
The microorganisms such as bacterium, fungi, these microorganisms can breed rapidly under suitable external condition, and be propagated by modes such as contacts
Disease, influence the health and normal work, studying and living of people.Fiber belongs to porous material, after superposition braiding
The polylayer forest in countless spaces can be formed again, therefore fabric is easier to adsorb mushroom.Antibiotic finish is exactly to have fabric to suppress bacterium
The function of class growth, the clothing living environment of health is maintained, ensures health.The application of antiseptic originates from second of the world
During Great War, German army greatly reduced the bacterium infection of the wounded due to wearing antibacterial military uniform at that time.In the sixties in last century, people
Mostly using organic antibacterial agent production antibacterial fabric；Into 21 century, with the arrival of aging society, bed old man and it is in
The person of recuperating gradually increases, and the demand for preventing old man's nursing materials of bedsore is also in increased trend.Due to the society based on the production
Can be to the Concept Change based on life, developmental research is advantageous to health, is advantageous to the product of earth environment, therefore antibacterial face
Material/fabric is increasingly subject to the attention of people.Therefore, a kind of possess environmental protection, face safe, that possess excellent anti-bacterium capability is developed
Material fabric has great importance.
The content of the invention
To achieve the above object, the invention provides a kind of antibiotic facing material, it is characterised in that by the raw material of following parts by weight
It is made：
It is further preferred that a kind of antibiotic facing material, it is characterised in that be made up of the raw material of following parts by weight：
Preferably, silver content 15~20% in described silver plated fiber, fibre number are 40~140D.
Preferably, described filamentary silver is 40~140D filamentary silvers.
The silver-plated nano fiber or filamentary silver that the present invention adds possess excellent antibacterial characteristics.
Preferably, described melamine resin composite antibacterial fibre is by 0.5~2.0wt%Cu (NO3)2, 0.1~
1.5wt%AgNO3, 0.2~2.0wt% PDDAs, 0.2~0.8wt% cetyl trimethyl bromines
Change ammonium, 12.5~25.0wt% melamine resins, surplus to be prepared for the raw material of water.
Cetyl trimethylammonium bromide in the melamine resin composite antibacterial fibre that the present invention adds may
The activity and bacterium for disturbing respiratory enzyme produce the energy, so as to delay the growth of bacterium.Moreover, silver ion is same with copper ion
There is stronger inhibitory action to bacterium.
Preferably, described softening agent is polyethers amino modified polysiloxane, dioctadecyl dimethyl ammonium chloride, three second
It is one or more kinds of in hydramine stearate glycine betaine.
Preferably, described dispersant is vinyl bis-stearamides or polyvinyl alcohol.
Preferably, described antiseptic is the one or more in Herba polygoni hydropiperis extract, triclosan, zinc niobate.
Preferably, described antiseptic is by Herba polygoni hydropiperis extract, triclosan, zinc niobate (1~3) in mass ratio:(1~3):(1
~3) mix.
The polygonum flaccidum herb that the present invention adds may contain the compositions such as flavones, anthraquinones so that polygonum flaccidum, which has, resists micro- life
Thing, desinsection is anti-oxidant, the multiple biological activities such as antitumor.Moreover, Herba polygoni hydropiperis extract and inorganic antiseptic are to microorganism
The difference of sterilizing mechanismses cause it is compound after antibacterial antiplaque agent effect it is more notable.
A kind of preparation method of antibiotic facing material, it is characterised in that comprise the steps of：
A) is by 10~20 parts by weight bombax cottons, 20~30 parts by weight cotton fibers or tencel or Modal fibre or flax
Fiber or bamboo fibre, 10~20 parts by weight melamine resin composite antibacterial fibres are placed in mixer, 400~600
Rev/min rotating speed under stir 20~30min；Add 1~3 parts by weight softening agent, 2~6 parts per weight dispersing agents, 0.15~
0.90 parts by weight antiseptic, 80~100 parts by weight water carry out secondary agitation, under 400~600 revs/min of rotating speed stir 5~
10min, obtain mixture；
B) after said mixture is dried processing by, then after the rove by routine, spun yarn, winder, yarn steaming, doubling processing,
40~140D mixed yarns are made；
C) is carried out above-mentioned mixed yarn and 4~8 parts by weight silver-plated nano fibers or filamentary silver woven into cloth；Described cloth
Warp density be 90~110/cm, weft density be 50~70/cm；
D) made cloth is put in 60~80min of immersion in the aqueous solution of the chitosan quaternary ammonium salt containing 1~2wt% by, 600
3~5min is dehydrated under rotating speed under~1000 revs/min, is then 20~25 ms/min in 100~120 DEG C, line speed
Shape and toast under dryer, obtain the antibiotic facing material；The aqueous solution of described cloth and the chitosan quaternary ammonium salt Han 1~2wt%
Mass volume ratio be 1Kg：(40~60L).
Beneficial effects of the present invention：
1st, a kind of antibiotic facing material of the present invention, in the feed addition possess antibacterial characteristics melamine resin it is compound anti-
The antibacterial material such as bacterium fiber and Herba polygoni hydropiperis extract, triclosan, zinc niobate, at the same by obtained mixed yarn with plating nano silver fibre or
Filamentary silver progress is woven, and sizing, which is toasted, after finally being soaked in the aqueous solution of chitosan quaternary ammonium salt obtains possessing notable antibacterial characteristics
Antibiotic facing material.
2nd, a kind of antibiotic facing material of the present invention not only possesses excellent antibacterial characteristics, while is also equipped with good fire resistance.
Embodiment
Each raw material sources in embodiment：
Melamine resin：Water white transparency thick liquid, solid content (120 DEG C of .2H)：69.0%~71.0%,
PH7.5~8.5, free formaldehyde≤1%, Jining Hua Kai resin Co., Ltd；
Cetyl trimethylammonium bromide：No. CAS：57-09-0, content >=99.0%, the Hongxin limited material of Shandong one hundred are public
Department；
Cu(NO3)2：Chemical Industry Science Co., Ltd is sprouted by content >=99.0%, upper Haixing County；
AgNO3：Content >=99.8%, Shanghai Aladdin biochemical technology limited company；
PDDA：No. CAS：26062-79-3, molecular weight 100000~200000,20wt% water
Solution, viscosity：400~1000cP (25 DEG C), Shanghai Aladdin biochemical technology limited company；
Sodium sulphate：Content >=99.9%, Guangzhou Sui Xin Chemical Co., Ltd.s；
Fresh polygonum flaccidum herb：Original producton location：Guangxi Yulin, it is purchased from nine day commerce and trade Co., Ltd of Yulin City；
Spandex：Polyurethane fibre, fibre length about 50mm, fiber number 2.4dtex, the great ship chemical fiber wire warp of Zhuji City
Battalion headquarter；
Bombax cotton：Fibre length about 20mm, it is purchased from Sheng Hu trade Co., Ltds of Nanning City；
Cotton fiber：Fibre length >=28mm, it is purchased from Xinjiang Kang pleasant virtue commerce and trade Co., Ltd；
Chitosan quaternary ammonium salt：HACC, substitution value >=90%, Beijing Hua Maike biotechnologys
Co., Ltd；
40D filamentary silvers：It is purchased from the extraordinary weaving Science and Technology Ltd. of Dongguan City life cyclopentadienyl；
Dioctadecyl dimethyl ammonium chloride：No. CAS：107-64-2, content >=75%, the limited public affairs of the chemical industry of Jining 101
Department；
Vinyl bis-stearamides：No. CAS：110-30-5, content >=99%, Shandong Hao Yao new materials Co., Ltd；
Tencel：Average fiber length 51mm, fiber number 3.3dtex, deer textile trade Co., Ltd of Jiangyin City hundred；
Modal fibre：Average fiber length 51mm, fiber number 1.7dtex, deer textile trade Co., Ltd of Jiangyin City hundred；
Plate nano silver fibre：It is matrix with nylon 6, silver content 18%, fibre number 40D, is purchased from Dongguan City life Mao Te
Kind weaving Science and Technology Ltd.；
Flax fiber：Fibre length >=26mm, the Shang Meixiang Textile Co., Ltd. of Tongxiang City three；
Bamboo fibre：Fibre length about 38mm, fibre number 1.5D, are purchased from Hangzhou Jie Kang bamboo fiber products Co., Ltd；
Triclosan：No. CAS：3380-34-5, content >=99%, Guangzhou Nan Jia Chemical Industry Science Co., Ltd；
Zinc niobate：No. CAS：12201-66-0, content >=99.99%, Beijing Hao Ke Science and Technology Ltd.s.
The preparation method of melamine resin composite antibacterial fibre：
23.0g melamine resins, 0.4g cetyl trimethylammonium bromides are added in 73g water in 200r/
30min is stirred under min rotating speeds, lucifuge stands 12h；Add 1.0g Cu (NO3)2、1.0gAgNO3, the allyl of 1.6g poly dimethyls two
Ammonium chloride, 8h is stirred at 50 DEG C, obtain melamine resin spinning solution.
By above-mentioned melamine resin spinning solution pressure filtration at 60 DEG C, deaeration, it is delivered to through measuring pump
Aperture 0.08mm spinneret orifice, stoste is through spinneret orifice with 500 DEG C of temperature of thread shape penetrating, pH=3 saturated aqueous sodium sulfate
Middle coagulation forming, is sent into the steam drying box humid heat treatment of 100 DEG C of temperature 15 minutes after 3 times of as-spun fibre stretching, fiber is through temperature
60 DEG C of warm water washing removes remaining salinity, and then to being sent into coiled up device after fiber drying, fiber is entered at 100 DEG C of temperature
Row curling, it is sent into 220 DEG C of xeothermic shaping equipment and is heat-treated 6 minutes, then the chopped fiber by fibre cutting to 5cm, obtain trimerization
Cyanamide formaldehyde resin composite antibacterial fibre.
Herba polygoni hydropiperis extract：
Fresh polygonum flaccidum herb 1000g is taken, cleans, chopping, is fitted into 3L three neck round bottom flask, adds 1L distilled water by polygonum flaccidum
Immersion, and from oil water separator upper end addition distilled water untill distilled water flows into flask.Experimental rig is connected, and checks gas
Close property.After soaking 5h, flask is heated to seething with excitement with electric jacket, and keep micro-boiling to distill 3h at ambient pressure into extractor, oil mass is not
It is further added by, stops heating.After system is cooled to room temperature, oil water separator lower end piston is opened, water is slowly discarded to oil reservoir
A moment is stood after dropping to 0 scale, it is that polygonum flaccidum carries to collect upper strata to have the yellow transparent oily liquids of strong fragrant breath
Take thing.
Embodiment 1
A kind of preparation method of antibiotic facing material, it is characterised in that comprise the steps of：
A) 20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight cotton fibers are placed in mixer by, 500
Rev/min rotating speed under stir 30min；Add 2 parts by weight softening agents, 4 parts per weight dispersing agents, 100 parts by weight water and carry out two
Secondary stirring, 10min is stirred under 500 revs/min of rotating speed, obtains mixture；
B) after said mixture is dried processing by, then after the rove by routine, spun yarn, winder, yarn steaming, doubling processing,
Obtain 40D mixed yarns；
C) by above-mentioned mixed yarn and 8 parts by weight filamentary silvers in HT11 small size automatics loom (Changyi City sky day textile machine
Co., Ltd) on it is woven into cloth；The warp density of described cloth is 100/cm, weft density is 60/cm；
D) made cloth is put in the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% by soaks 80min, is 800 in rotating speed
Rev/min SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three) under be dehydrated 3min, then 100 DEG C, pass
It is fixed under the XY-HD-005 hose shaping drying tunnels dryer (Shanghai Xiong Yi electric heating appliances Co., Ltd) that tape speed is 20 ms/min to send
Type toasts, and obtains antibiotic facing material.
The mass volume ratio of described cloth and the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% is 1Kg：50L.
Described filamentary silver is 40D filamentary silvers.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Embodiment 2
A kind of preparation method of antibiotic facing material, it is characterised in that comprise the steps of：
A) 20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight tencels are placed in mixer by, 500 turns/
30min is stirred under the rotating speed of minute；Add 2 parts by weight softening agents, 4 parts per weight dispersing agents, 100 parts by weight water and carry out secondary stir
Mix, stir 10min under 500 revs/min of rotating speed, obtain mixture；
B) after said mixture is dried processing by, then after the rove by routine, spun yarn, winder, yarn steaming, doubling processing,
Obtain 40D mixed yarns；
C) by above-mentioned mixed yarn and 8 parts by weight filamentary silvers in HT11 small size automatics loom (Changyi City sky day textile machine
Co., Ltd) on it is woven into cloth；The warp density of described cloth is 100/cm, weft density is 60/cm；
D) made cloth is put in the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% by soaks 80min, is 800 in rotating speed
Rev/min SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three) under be dehydrated 3min, then 100 DEG C, pass
It is fixed under the XY-HD-005 hose shaping drying tunnels dryer (Shanghai Xiong Yi electric heating appliances Co., Ltd) that tape speed is 20 ms/min to send
Type toasts, and obtains antibiotic facing material.
The mass volume ratio of described cloth and the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% is 1Kg：50L.
Described filamentary silver is 40D filamentary silvers.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Embodiment 3
A kind of preparation method of antibiotic facing material, it is characterised in that comprise the steps of：
A) 20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight Modal fibres are placed in mixer by,
30min is stirred under 500 revs/min of rotating speed；2 parts by weight softening agents, 4 parts per weight dispersing agents, 100 parts by weight water are added to carry out
Secondary agitation, 10min is stirred under 500 revs/min of rotating speed, obtains mixture；
B) after said mixture is dried processing by, then after the rove by routine, spun yarn, winder, yarn steaming, doubling processing,
Obtain 40D mixed yarns；
C) above-mentioned mixed yarn and 8 parts by weight are plated nano silver fibre in HT11 small size automatics loom (Changyi City sky day by
Textile Machinery Co., Ltd) on it is woven into cloth；The warp density of described cloth is 100/cm, weft density be 60/
cm；
D) made cloth is put in the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% by soaks 80min, is 800 in rotating speed
Rev/min SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three) under be dehydrated 3min, then 100 DEG C, pass
It is fixed under the XY-HD-005 hose shaping drying tunnels dryer (Shanghai Xiong Yi electric heating appliances Co., Ltd) that tape speed is 20 ms/min to send
Type toasts, and obtains antibiotic facing material.
The mass volume ratio of described cloth and the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% is 1Kg：50L.
Silver content is 18% in described plating nano silver fibre, fibre number 40D.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Embodiment 4
A kind of preparation method of antibiotic facing material, it is characterised in that comprise the steps of：
A) 20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight flax fibers are placed in mixer by, 500
Rev/min rotating speed under stir 30min；Add 2 parts by weight softening agents, 4 parts per weight dispersing agents, 100 parts by weight water and carry out two
Secondary stirring, 10min is stirred under 500 revs/min of rotating speed, obtains mixture；
B) after said mixture is dried processing by, then after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
Obtain 40D mixed yarns；
C) above-mentioned mixed yarn and 8 parts by weight are plated nano silver fibre in HT11 small size automatics loom (Changyi City sky day by
Textile Machinery Co., Ltd) on it is woven into cloth；The warp density of described cloth is 100/cm, weft density be 60/
cm；
D) made cloth is placed in the aqueous solution for be put in the chitosan quaternary ammonium salt containing 2wt% by soaks 80min, is in rotating speed
3min is dehydrated under 800 revs/min of SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three), then 100
DEG C, line speed be 20 ms/min of XY-HD-005 hose shaping drying tunnels dryer (Shanghai Xiong Yi electric heating appliances Co., Ltd)
Lower sizing baking, obtains antibiotic facing material.
The mass volume ratio of described cloth and the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% is 1Kg：50L.
Silver content is 18% in described plating nano silver fibre, fibre number 40D.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Embodiment 5
A kind of preparation method of antibiotic facing material, it is characterised in that comprise the steps of：
A) 20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight bamboo fibres are placed in mixer by, 500
Rev/min rotating speed under stir 30min；Add 2 parts by weight softening agents, 4 parts per weight dispersing agents, 100 parts by weight water and carry out two
Secondary stirring, 10min is stirred under 500 revs/min of rotating speed, obtains mixture；
B) after said mixture is dried processing by, then after the rove by routine, spun yarn, winder, yarn steaming, doubling processing,
Obtain 40D mixed yarns；
C) above-mentioned mixed yarn and 8 parts by weight are plated nano silver fibre in HT11 small size automatics loom (Changyi City sky day by
Textile Machinery Co., Ltd) on it is woven into cloth；The warp density of described cloth is 100/cm, weft density be 60/
cm；
D) made cloth is put in the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% by soaks 80min, is 800 in rotating speed
Rev/min SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three) under be dehydrated 3min, then 100 DEG C, pass
It is fixed under the XY-HD-005 hose shaping drying tunnels dryer (Shanghai Xiong Yi electric heating appliances Co., Ltd) that tape speed is 20 ms/min to send
Type toasts, and obtains antibiotic facing material.
The mass volume ratio of described cloth and the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% is 1Kg：50L.
Silver content is 18% in described plating nano silver fibre, fibre number 40D.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Embodiment 6
A kind of preparation method of antibiotic facing material, it is characterised in that comprise the steps of：
A) is by 20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight bamboo fibres, 10 parts by weight melamine first
Urea formaldehyde composite antibacterial fibre is placed in mixer, and 30min is stirred under 500 revs/min of rotating speed；It is soft to add 2 parts by weight
Soft dose, 4 parts per weight dispersing agents, 100 parts by weight water carry out secondary agitation, stir 10min under 500 revs/min of rotating speed, obtain
Mixture；
B) after said mixture is dried processing by, then after the rove by routine, spun yarn, winder, yarn steaming, doubling processing
Obtain 40D mixed yarns；
C) above-mentioned mixed yarn and 8 parts by weight are plated nano silver fibre in HT11 small size automatics loom (Changyi City sky day by
Textile Machinery Co., Ltd) on it is woven into cloth；The warp density of described cloth is 100/cm, weft density be 60/
cm；
D) made cloth is put in the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% by soaks 80min, is 800 in rotating speed
Rev/min SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three) under be dehydrated 3min, then 100 DEG C, pass
It is fixed under the XY-HD-005 hose shaping drying tunnels dryer (Shanghai Xiong Yi electric heating appliances Co., Ltd) that tape speed is 20 ms/min to send
Type toasts, and obtains antibiotic facing material.
The mass volume ratio of described cloth and the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% is 1Kg：50L.
Silver content is 18% in described plating nano silver fibre, fibre number 40D.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Embodiment 7
A kind of preparation method of antibiotic facing material, it is characterised in that comprise the steps of：
A) is by 20 parts by weight spandexs, 30 parts by weight bombax cottons, 30 parts by weight bamboo fibres, 10 parts by weight melamine first
Urea formaldehyde composite antibacterial fibre is placed in mixer, and 30min is stirred under 500 revs/min of rotating speed；It is soft to add 2 parts by weight
Soft dose, 4 parts per weight dispersing agents, 0.90 parts by weight antiseptic, 100 parts by weight water carry out secondary agitation, 500 revs/min turn
The lower stirring 10min of speed, obtains mixture；
B) after said mixture is dried processing by, then after the rove by routine, spun yarn, winder, yarn steaming, doubling processing,
Obtain 40D mixed yarns；
C) above-mentioned mixed yarn and 8 parts by weight are plated nano silver fibre in HT11 small size automatics loom (Changyi City sky day by
Textile Machinery Co., Ltd) on it is woven into cloth；
D) made cloth is put in the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% by soaks 80min, is 800 in rotating speed
Rev/min SS752-500 INDUSTRY SPINDRYERs (the Jiang Beng industry Co., Ltd of Taizhou City three) under be dehydrated 3min, then 100 DEG C, pass
It is fixed under the XY-HD-005 hose shaping drying tunnels dryer (Shanghai Xiong Yi electric heating appliances Co., Ltd) that tape speed is 20 ms/min to send
Type toasts, and obtains antibiotic facing material.
The mass volume ratio of described cloth and the aqueous solution of the chitosan quaternary ammonium salt containing 2wt% is 1Kg：50L.Described plating
Silver content is 18% in nano silver fibre, fibre number 40D.
Described softening agent is dioctadecyl dimethyl ammonium chloride.
Described dispersant is vinyl bis-stearamides.
Described antiseptic is Herba polygoni hydropiperis extract, triclosan, zinc niobate in mass ratio 1:1:1 mixes.
Embodiment 8
It is substantially the same manner as Example 7, differ only in：Described antiseptic is that Herba polygoni hydropiperis extract presses quality with triclosan
Than 1:1 mixes.
Embodiment 9
It is substantially the same manner as Example 7, differ only in：Described antiseptic is triclosan and zinc niobate mass ratio 1:1
Mix.
Embodiment 10
It is substantially the same manner as Example 7, differ only in：Described antiseptic is Herba polygoni hydropiperis extract and zinc niobate mass ratio
1:1 mixes.
Test case 1
Using standard GB/T/T20994.3-2008《The evaluation third portion of antibacterial textile performance：Succusion》To reality
The antibiotic facing material for applying the preparation of example 5~10 carries out antibiotic property quantitative test, using color fastness to washing testing machine washing methods, tests water
The bacteriostasis rate of fabric after 30 times is washed, test result is shown in Table 1.
Bacteriostasis rate test table (%) after table 1 is washed 30 times
| Embodiment | Escherichia coli | Staphylococcus aureus | Hay bacillus |
| Embodiment 5 | 86.2 | 85.3 | 84.8 |
| Embodiment 6 | 91.3 | 91.0 | 90.8 |
| Embodiment 7 | 99.9 | 99.5 | 99.4 |
| Embodiment 8 | 96.5 | 95.4 | 95.1 |
| Embodiment 9 | 95.7 | 95.3 | 95.2 |
| Embodiment 10 | 95.9 | 95.7 | 95.3 |
As shown in table 1, the antibiotic facing material that embodiment 5 is prepared possesses good fungistatic effect, to Escherichia coli, golden yellow
Color staphylococcus, the bacteriostasis rate of hay bacillus are respectively 86.2%, 85.3%, 84.8%.Can by the contrast of embodiment 5~7
To find, addition melamine resin composite antibacterial fibre can be obviously improved anti-with antiseptic in the raw material of antibiotic facing material
The antibacterial ability of bacterium fabric.Its reason may is that：Cetyl front three in melamine resin composite antibacterial fibre
Base ammonium bromide may interfere with the activity of respiratory enzyme and bacterium produces the energy, so as to delay the growth of bacterium.Moreover, silver ion
It is same with copper ion that there is stronger inhibitory action to bacterium.
By the contrast to embodiment 7~10 it can be found that in antibiotic facing material antiseptic by Herba polygoni hydropiperis extract, triclosan,
Compounding of the positive effect of zinc niobate compounding better than any two kinds in Herba polygoni hydropiperis extract, triclosan, zinc niobate.Its reason may be
In：Herba polygoni hydropiperis extract is as a kind of antimicrobial material for possessing complex component and inorganic substances zinc niobate, organic substance trichlorine
The raw suppression principle to bacterium is different, so that antibacterial effect is obviously improved.Polygonum flaccidum herb may contain flavones, Anthraquinones thing
The compositions such as matter so that polygonum flaccidum has antimicrobial, desinsection, anti-oxidant, the multiple biological activities such as antitumor.
Test case 2
Limited oxygen index method：Sample is placed under vertical experimental condition, and in oxygen, nitrogen mixed gas stream, measure sample is just
Maintain the test method of minimum oxygen concentration (also known as limited oxygen index) needed for burning.
The present invention refers to standard GB/T/T 5454-1997《Textile combustion performance test oxygen index method》To embodiment 5
~7 antibiotic facing materials being prepared carry out the test of fire resistance.After oxygen index (OI) (LOI) refers to that material is lighted, in oxygen-nitrogen air
In maintain burning required for minimum oxygen content percentage by volume.In general, there is the fabric of fire resistance, its LOI value
28% should be equal to or more than.
Provided according to standard, prepare sample (each 15 pieces of warp-wise, broadwise, being 150mm × 38mm per block size), by GB/T
6529-2008《Textile damping and experiment normal atmosphere》Damping requirement, according to the thickness degree of sample, damping 8h~
24h, the sample after damping are put into be measured in sealing container.During experiment, sample is sandwiched on specimen holder and is vertically put into combustion barrel,
In the nitrogen oxygen stream flowed up, sample upper end is lighted, observes its combustion characteristics, and compare its burning in defined limiting value
Time or char length.
The limited oxygen index for the antibiotic facing material that the embodiment 5~7 of table 2 is prepared
| Embodiment | Limited oxygen index |
| Embodiment 5 | 14 |
| Embodiment 6 | 34 |
| Embodiment 7 | 36 |
By embodiment 5 with the contrast of embodiment 6~7 it can be found that embodiment 5 is in antibiotic facing material compared with embodiment 6~7
Preparation process in the addition of melamine resin composite antibacterial fibre so that the anti-flammability for the antibiotic facing material being prepared
It can be obviously improved.Its reason may is that the melamino-formaldehyde tree in melamine resin composite antibacterial fibre
Fat, Cu (NO)3、AgNO3Etc. being provided with good fire resistance so that the antibiotic facing material being prepared possesses good anti-flammability
Energy.
Preferred embodiment of the invention described in detail above.It should be appreciated that one of ordinary skill in the art without
Creative work can is needed to make many modifications and variations according to the design of the present invention.Therefore, all technologies in the art
Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea
Technical scheme, all should be in the protection domain being defined in the patent claims.
Claims (10)
1. a kind of antibiotic facing material, it is characterised in that be made up of the raw material of following parts by weight：
2. a kind of antibiotic facing material, it is characterised in that be made up of the raw material of following parts by weight：
3. antibiotic facing material as claimed in claim 1 or 2, it is characterised in that：Silver content 15 in described plating nano silver fibre~
20wt%, fibre number are 40~140D.
4. antibiotic facing material as claimed in claim 1 or 2, it is characterised in that：Described filamentary silver is 40~140D filamentary silvers.
5. antibiotic facing material as claimed in claim 1 or 2, it is characterised in that：Described melamine resin composite antibacterial
Fiber is by 0.5~2.0wt%Cu (NO3)2, 0.1~1.5wt%AgNO3, 0.2~2.0wt% poly dimethyl allyl chlorinations
Ammonium, 0.2~0.8wt% cetyl trimethylammonium bromides, 12.5~25.0wt% melamine resins, surplus are water
Raw material is prepared.
6. antibiotic facing material as claimed in claim 1 or 2, it is characterised in that：Described softening agent is the amino modified poly- silicon of polyethers
It is one or more kinds of in oxygen alkane, dioctadecyl dimethyl ammonium chloride, triethanolamine stearate glycine betaine.
7. antibiotic facing material as claimed in claim 1 or 2, it is characterised in that：Described dispersant is vinyl bis-stearamides
Or polyvinyl alcohol.
8. preparation method as claimed in claim 1 or 2, it is characterised in that：Described antiseptic is Herba polygoni hydropiperis extract, trichlorine
One or more in raw, zinc niobate.
9. preparation method as claimed in claim 1 or 2, it is characterised in that：Described antiseptic is by Herba polygoni hydropiperis extract, trichlorine
Raw, zinc niobate (1~3) in mass ratio:(1~3):(1~3) mixes.
10. the preparation method of the antibiotic facing material as any one of claim 2~9, it is characterised in that include following step
Suddenly：
A) is by 10~20 parts by weight spandexs, 20~30 parts by weight bombax cottons, 20~30 parts by weight cotton fibers or tencel or not generation
That fiber or flax fiber or bamboo fibre, 10~20 parts by weight melamine resin composite antibacterial fibres are placed in mixer
In；Add 1~3 parts by weight softening agent, 2~6 parts per weight dispersing agents, 0.15~0.90 parts by weight antiseptic, 80~100 weight
Part water is stirred, and obtains mixture；
Preferably, by 10~20 parts by weight spandexs, 20~30 parts by weight bombax cottons, 20~30 parts by weight cotton fibers or tencel or
Modal fibre or flax fiber or bamboo fibre, 10~20 parts by weight melamine resin composite antibacterial fibres are placed in stirring
In machine, 20~30min is stirred under 400~600 revs/min of rotating speed；Add 1~3 parts by weight softening agent, 2~6 parts by weight
Dispersant, 0.15~0.90 parts by weight antiseptic, 80~100 parts by weight water carry out secondary agitation, at 400~600 revs/min
5~10min is stirred under rotating speed, obtains mixture；
B) after said mixture is dried processing by, then after the rove by routine, spun yarn, winder, yarn steaming, doubling processing, it is made
40~140D mixed yarns；
C) above-mentioned mixed yarn and 4~8 parts by weight are plated nano silver fibre by or filamentary silver progress is woven into cloth；Preferably, it is described
The warp density of cloth is 90~110/cm, weft density is 50~70/cm；
D) made cloth is put in the aqueous solution of chitosan quaternary ammonium salt and soaked by, is dehydrated, and baking, obtains the antibiotic facing material；
Preferably, made cloth is put in 60~80min of immersion in the aqueous solution of the chitosan quaternary ammonium salt containing 1~2wt%, 600
3~5min is dehydrated under~1000 revs/min of rotating speed, then in 100~120 DEG C, the baking that line speed is 20~25 ms/min
Shaped under dry machine baking, the antibiotic facing material is obtained, wherein described cloth and the chitosan quaternary ammonium salt Han 1~2wt% is water-soluble
The mass volume ratio of liquid is 1Kg：(40~60L).
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