CN101822430A - Nano silver antibacterial deodorant socks - Google Patents

Nano silver antibacterial deodorant socks Download PDF

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Publication number
CN101822430A
CN101822430A CN200910037683A CN200910037683A CN101822430A CN 101822430 A CN101822430 A CN 101822430A CN 200910037683 A CN200910037683 A CN 200910037683A CN 200910037683 A CN200910037683 A CN 200910037683A CN 101822430 A CN101822430 A CN 101822430A
Authority
CN
China
Prior art keywords
nano silver
socks
nano
antibacterial deodorant
silver antibacterial
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN200910037683A
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Chinese (zh)
Inventor
尹荔松
胡社军
柳庆新
杨婧
何鑫
范海陆
赵燕
阳素玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Falcon Medical And Sanitary Materials Co ltd
Wuyi University
Original Assignee
Hunan Falcon Medical And Sanitary Materials Co ltd
Wuyi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Falcon Medical And Sanitary Materials Co ltd, Wuyi University filed Critical Hunan Falcon Medical And Sanitary Materials Co ltd
Priority to CN200910037683A priority Critical patent/CN101822430A/en
Publication of CN101822430A publication Critical patent/CN101822430A/en
Pending legal-status Critical Current

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  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention relates to nano-silver antibacterial deodorant socks and a process thereof. In the invention, a nano silver composite antibacterial material is added in socks for daily life for treatment, the preparation method thereof is as follows: utilizing a liquid-phase chemical reduction method to prepare nano silver to obtain spherical particles the particle size of which is 10-80nm, dispersing the particles to obtain nano silver solution with efficient antibiosis and deodorization activity, utilizing nano silver, 0.1-1% of adhesive PDA, 0.02-0.1% of softening agent amino-silicone and the like to form modified nano silver composite dispersion liquid, and utilizing the processes of impregnating, drying and finishing to adhere nana silver on the surface of socks, thus obtaining antibacterial deodorant socks meeting requirements.

Description

Nano silver antibacterial deodorant socks
One, technical field:
The present invention relates to daily textile clothing articles for use and nano anti-biotic material field, particularly a kind of socks with health cares such as antibacterial and deodourings.
Two, background technology:
There are various bacteriums and mould in the environment for human survival, socks adsorb sweat when wearing, metabolin such as sebum and dirt, become the good breeding place of bacterium, some work to metabolins such as human sweats and grow " the stink bacterium " of breeding, under hot and humid environment, when these microorganisms breed on socks in a large number, fiber is subjected to the effect of its acidity or alkaline metabolin easily and degrades, variable color, and generation volatility odorant such as acetic acid, ammonia etc., also cause some skin disease of human body easily, therefore, antibiotic and deodorization always is closely bound up.
The socks of Chu Shouing are antibiotic by chemical organic antibacterial agent realization mostly in the market, the people is known from experience produce certain toxic and side effect, and washability are relatively poor.Nano Silver has the antibacterial activity more excellent than common silver owing to have the special construction and the performance of nano material.Few Nano Silver can produce powerful bactericidal action, broad-spectrum sterilization and human body do not had any toxicity and IR, and safety has no drug resistance, thereby Nano Silver is the main flow of the nano inorganic antimicrobial agent of present latest generation.In order to satisfy people's hygiene and health and comfortable and easy to wear, the socks with antibacterial and deodouring function become one of needed product of people, so the antibacterial deodourizing of fibre, the smelly processing that disappears also just seem very necessary.Reach the antibacterial deodourizing purpose by following two kinds of methods: (1) is dissolved in antiseptic and is made anti-bacterial fibre in the spinning solution; (2) with antibacterial deodourizing agent or bacteriostatic agent post processing fabric.Fabric post-treatment has simple characteristics, therefore, is anti-bacteria health finishing method commonly used.The socks of handling by nano silver antibacterial deodorant not only have superpower sterilization, antibacterial effect, and dress is ventilative soft, and its antibacterial effect keeps lastingly, water-fast washing, and can effectively eliminate stink, be a kind of multiple functional, complete health-protection socks.
Three, summary of the invention:
Technical problem to be solved by this invention is: produce a kind of nanometer silver antimicrobial socks with fabulous antibacterial and deodouring.
For solving above technical problem, take following technical scheme: utilize the get everything ready spherical nano silver particles of 10~80nm particle size of liquid phase chemical reduction legal system, obtain having 200~1000ppm concentration nano silver dispersion efficient, quick-acting, broad spectrum antibiotic activity, utilize postfinishing process, Nano Silver is bonded in the socks top layer, is met the different antibacterial and deodouring socks that require.
Production stage of the present invention is as follows:
(1) utilizes liquid chemical method with low cost to prepare nano silver particles, prevent the nano-powder reunion, and nano silver particles is dispersed in the stable dispersion of formation in the aqueous solution with dispersants such as PVP;
(2) with the adhesive PDA of 200~100ppm concentration nano silver dispersion body and 0.1%-1%, the amino silicon of the softening agent of 0.02%-0.1% etc. is compounded to form the nano silver dispersion body of modification;
(3) above-mentioned finely dispersed Nano Silver composite dispersion liquid is cohered on the socks surface by impregnation process technology, 120 ℃ then~130 ℃ are cured 5~8min, and oven dry can obtain nano silver antibacterial deodorant socks.
Four, the specific embodiment;
Embodiment one:
With the particle size for preparing is that the nano silver particles of the 0.1g of 10nm evenly spreads in the 500g water and forms dispersion, successively add amino silicon 0.2g then, PDA 0.5g, after evenly disperseing, by infusion process nano silver particles in the above-mentioned Nano silver solution is bonded in the socks surface then, last 120 ℃ bake 8min, and oven dry can obtain the nano silver antibacterial deodorant socks product.
Embodiment two:
With the particle size for preparing is that the nano silver particles of the 0.2g of 10nm evenly spreads in the 500g water and forms dispersion, successively add amino silicon 0.2g then, PDA 1.0g, after evenly disperseing, by impregnation process nano silver particles in the above-mentioned Nano silver solution is bonded in the socks surface then, last 120 ℃ bake 8min, and oven dry can obtain the nano silver antibacterial deodorant socks product.
Embodiment three:
With the particle size for preparing is that the nano silver particles of the 0.3g of 30nm evenly spreads in the 500g water and forms dispersion, successively add amino silicon 0.4g then, PDA 1.5g, after evenly disperseing, by impregnation process nano silver particles in the above-mentioned Nano silver solution is bonded in the socks surface then, last 120 ℃ bake 8min, and oven dry can obtain the nano silver antibacterial deodorant socks product.
Embodiment four:
With the particle size for preparing is that the nano silver particles of the 0.4g of 50nm evenly spreads in the 500g water and forms dispersion, successively add basic silicon 0.5g then, PDA 2g, after evenly disperseing, by impregnation process nano silver particles in the above-mentioned Nano silver solution is bonded in the socks surface then, last 120 ℃ are cured 8min, and oven dry can obtain the nano silver antibacterial deodorant socks product.
Embodiment five:
With the particle size for preparing is that the nano silver particles of the 0.5g of 80nm evenly spreads in the 500g water and forms dispersion, successively add amino silicon 0.5g then, PDA 2.5g, after evenly disperseing, by impregnation process nano silver particles in the above-mentioned Nano silver solution is bonded in the socks surface then, last 120 ℃ are cured 8min, and oven dry can obtain the nano silver antibacterial deodorant socks product.

Claims (5)

1. nano silver antibacterial deodorant socks is characterized in that: socks through impregnation process technology, make after baking in special nano-silver antiseptic solution.
2. a kind of nano silver antibacterial deodorant socks according to claim 1, it is characterized in that: utilize the get everything ready spherical nano silver particles of different-grain diameter size of liquid phase chemical reduction legal system, the nano silver particles size obtains the nano-silver antiseptic solution of stable dispersion at 10~80nm.
3. a kind of nano silver antibacterial deodorant socks according to claim 1 is characterized in that: described socks are made into by cotton fibre.
4. a kind of nano silver antibacterial deodorant socks according to claim 1 is characterized in that: described socks comprise stocking blank, the stocking leg, socks body and toe cover.
5. a kind of nano silver antibacterial deodorant socks according to claim 1, it is characterized in that: Nano Silver utilizes the effect of adhesive PDA and the amino silicon of softening agent etc., dry behind the impregnation process socks, make nano silver particles be evenly distributed on the socks surface, reach high-efficiency antimicrobial and deodorant activities.
CN200910037683A 2009-03-06 2009-03-06 Nano silver antibacterial deodorant socks Pending CN101822430A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200910037683A CN101822430A (en) 2009-03-06 2009-03-06 Nano silver antibacterial deodorant socks

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200910037683A CN101822430A (en) 2009-03-06 2009-03-06 Nano silver antibacterial deodorant socks

Publications (1)

Publication Number Publication Date
CN101822430A true CN101822430A (en) 2010-09-08

Family

ID=42686770

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200910037683A Pending CN101822430A (en) 2009-03-06 2009-03-06 Nano silver antibacterial deodorant socks

Country Status (1)

Country Link
CN (1) CN101822430A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103535865A (en) * 2013-10-15 2014-01-29 常熟市凯博尔纺织品有限公司 Antibacterial and warmth keeping stocking
CN103919286A (en) * 2014-04-26 2014-07-16 于哲永 Multifunctional healthcare socks
CN104687260A (en) * 2013-12-09 2015-06-10 东丽纤维研究所(中国)有限公司 Underwear
CN104997170A (en) * 2014-04-26 2015-10-28 于哲永 Health care sock used at night
CN105146763A (en) * 2015-08-21 2015-12-16 沈汇明 Anti-bacterial pure cotton mid-calf length stock production technology
CN105795531A (en) * 2016-05-11 2016-07-27 宜兴市艺蝶针织有限公司 Production process of antibacterial healthcare socks
CN106473240A (en) * 2016-09-30 2017-03-08 天津宝兴威科技有限公司 A kind of preparation technology of nano-silver thread antibacterial deodourizing socks
CN110432559A (en) * 2018-05-03 2019-11-12 安徽世龙生物医药科技有限公司 A kind of antibacterial odour oliminating health care stocks

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103535865A (en) * 2013-10-15 2014-01-29 常熟市凯博尔纺织品有限公司 Antibacterial and warmth keeping stocking
CN104687260A (en) * 2013-12-09 2015-06-10 东丽纤维研究所(中国)有限公司 Underwear
CN103919286A (en) * 2014-04-26 2014-07-16 于哲永 Multifunctional healthcare socks
CN104997170A (en) * 2014-04-26 2015-10-28 于哲永 Health care sock used at night
CN105146763A (en) * 2015-08-21 2015-12-16 沈汇明 Anti-bacterial pure cotton mid-calf length stock production technology
CN105795531A (en) * 2016-05-11 2016-07-27 宜兴市艺蝶针织有限公司 Production process of antibacterial healthcare socks
CN106473240A (en) * 2016-09-30 2017-03-08 天津宝兴威科技有限公司 A kind of preparation technology of nano-silver thread antibacterial deodourizing socks
CN106473240B (en) * 2016-09-30 2018-07-24 天津宝兴威科技股份有限公司 A kind of preparation process of nano-silver thread antibacterial deodourizing socks
CN110432559A (en) * 2018-05-03 2019-11-12 安徽世龙生物医药科技有限公司 A kind of antibacterial odour oliminating health care stocks

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Open date: 20100908