CN106120314A - A kind of fabric antimildew and antibacterial agent - Google Patents
A kind of fabric antimildew and antibacterial agent Download PDFInfo
- Publication number
- CN106120314A CN106120314A CN201610542426.9A CN201610542426A CN106120314A CN 106120314 A CN106120314 A CN 106120314A CN 201610542426 A CN201610542426 A CN 201610542426A CN 106120314 A CN106120314 A CN 106120314A
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- Prior art keywords
- fabric
- nano
- antibacterial
- antimildew
- antibacterial agent
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention belongs to functional material preparation field, be specifically related to a kind of fabric antimildew and antibacterial agent.This antibacterial is based on weight/mass percentage composition, and nanometer silver composite particles 0.1~20%, soluble silane coupling agent 0.01~0.1%, surplus are water.Described nanometer silver composite particles is nano-silver loaded SiO2Granule.The technological merit of the present invention is: the fabric antimildew and antibacterial agent of the present invention is applicable to existing linen-cotton fabric so that linen-cotton fabric has preferable bacteriostasis property, protects skin, and the antibacterial preparation technology of the present invention is also simple simultaneously, and has good storage stability.
Description
Technical field
The invention belongs to functional material preparation field, be specifically related to a kind of fabric antimildew and antibacterial agent.
Background technology
Along with improving constantly of living standards of the people, the demand of anti-biotic material, antibacterial garment will be continuously increased, especially
It is as medical matters clothing, is effectively to protect medical personnel and the ideal of patient, and with the townwear city of antibacterial functions
Field is the most wide.Along with the increasingly extensive of anti-biotic material application and more effectively, persistently, antibacterial deodourizing hygienic finishing new
Continually developing of technology, antibacterial garment industry has become the developing emerging industry of world's materials industry, has progressively highlighted
Its huge internal potential and development prospect.
In antibacterial ion, owing to silver ion has has a broad antifungal spectrum, germicidal efficiency height, is not likely to produce drug-fast feature,
The principle of silver sterilization is exactly the physiology reproductive process blocking antibacterial.In the environment of warm moist, silver ion has the highest
Biological activity, easily combines with other material so that the protein coagulating inside and outside bacterial cell membrane, thus blocks bacterial cell
Breathing and breeding.Environment gets over warm moist, and ventilating air permeability is the poorest, and the activity of silver ion is the strongest, is general nano material
120 times of bactericidal potency, therefore silver ion is very suitable for being applied to antibiotic facing material field.In numerous metal ions, hydrargyrum, silver,
Cadmium, copper, zinc etc. are respectively provided with stronger antibacterial ability, but safety non-toxic, are only silver, zinc and copper without side effect such as skin irritations
Ion, and the antibacterial ability of silver ion is much stronger than zinc ion and copper ion.
Linen-cotton fabric has natural water absorption, has been widely used as the textile fabrics such as clothing, and common cotton flax fabric is raw
The daily textile such as clothing, the shoe pad etc. that produce can absorb human sweat by its water absorption character, but cannot solve in perspiration
Bacterial reproduction causes can problem frowzy.
Summary of the invention
It is an object of the invention to provide the technical problem for existing linen-cotton fabric antibacterial ability difference and provide a kind of new
Fabric antimildew and antibacterial agent so that linen-cotton fabric has the effect of long acting antibiotic.
The technical scheme realizing mesh of the present invention and use is: a kind of fabric antimildew and antibacterial agent, percent mass pressed by this antibacterial
Content meter, nanometer silver composite particles 0.1~20%, soluble silane coupling agent 0.01~0.1%, surplus are water.
Preferably, described nanometer silver composite particles is nano-silver loaded SiO2Granule.
It is further preferred that described nano-silver loaded SiO2Granule comprises the following steps: by Nano-meter SiO_22Powder disperses
In hydroxymethyl cellulose aqueous solution, form Nano-meter SiO_22Dispersion liquid;By Nano-meter SiO_2 under the conditions of lucifuge2Dispersant liquid drop adds to
AgNO3In solution, the pH value adjusting solution is 7~9, reacts 3~6 hours, centrifugation, is washed with deionized and is dried,
I.e. prepare nano-silver loaded SiO2Granule.
Wherein, described Nano-meter SiO_22Powder is 1g:5~10mL with the mass volume ratio of hydroxymethyl cellulose aqueous solution,
The mass fraction of described hydroxymethyl cellulose aqueous solution is 5~15%, described Nano-meter SiO_22Powder and AgNO3The matter of solution
Amount volume ratio is 1g:3~6mL, and the molar concentration of described silver nitrate solution is 0.1mol/L.
Preferably, described soluble silane coupling agent, its chemical structural formula is:
In formula, Me is-CH3, X is-OCH2CH3Or-OCH3, Y is-CH=CH2, Z is-OH, and molecular weight is 0.5~1.0 ten thousand.
It is furthermore preferred that specifically antibacterial treatment process is: 1) pending linen-cotton fabric is passed through padder at antibacterial
In carry out dipping process, use two leaching two roll process, pricking remaining rate is 75%~80%;2) hot-air seasoning fabric, then dries
Roasting makes antimicrobial particles be bonded on fabric, and stoving temperature is 160 DEG C, and the baking time is 2min.
The technological merit of the present invention is: the fabric antimildew and antibacterial agent of the present invention is applicable to existing linen-cotton fabric so that cotton
Flax fabric has preferable bacteriostasis property, protects skin, and the antibacterial preparation technology of the present invention is also simple simultaneously, and has good
Storage stability.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
1) preparation of nanometer silver composite particles
By 20 grams of Nano-meter SiO_22Powder is scattered in the hydroxymethyl cellulose aqueous solution that 100mL mass fraction is 15%, shape
Become Nano-meter SiO_22Dispersion liquid;By Nano-meter SiO_2 under the conditions of lucifuge2Dispersant liquid drop adds to the AgNO that 60mL molar concentration is 0.1mol/L3
In solution, the pH value adjusting solution is 9, reacts 3 hours, centrifugation, is washed with deionized and is dried, prepares nanometer silver multiple
Close granule.
2) preparation of antibacterial
Based on weight/mass percentage composition, by step 1) prepare nanometer silver composite particles 20%, soluble silane coupling agent
0.01%, surplus is water, mix homogeneously.
3) linen-cotton material treatment
Pending linen-cotton fabric is carried out dipping process by padder in antibacterial, uses two leaching two roll process,
Pricking remaining rate is 75%;2) hot-air seasoning fabric, then carries out baking and makes antimicrobial particles be bonded on fabric, and stoving temperature is
160 DEG C, the baking time is 2min.
Embodiment 2
1) preparation of nanometer silver composite particles
By 20 grams of Nano-meter SiO_22Powder is scattered in the hydroxymethyl cellulose aqueous solution that 200mL mass fraction is 5%, is formed
Nano-meter SiO_22Dispersion liquid;By Nano-meter SiO_2 under the conditions of lucifuge2Dispersant liquid drop adds to the AgNO that 120mL molar concentration is 0.1mol/L3
In solution, the pH value adjusting solution is 7, reacts 6 hours, centrifugation, is washed with deionized and is dried, prepares nanometer silver multiple
Close granule.
2) preparation of antibacterial
Based on weight/mass percentage composition, by step 1) prepare nanometer silver composite particles 0.1%, soluble silane coupling agent
0.1%, surplus is water, mix homogeneously.
3) linen-cotton material treatment
Pending linen-cotton fabric is carried out dipping process by padder in antibacterial, uses two leaching two roll process,
Pricking remaining rate is 80%;2) hot-air seasoning fabric, then carries out baking and makes antimicrobial particles be bonded on fabric, and stoving temperature is
160 DEG C, the baking time is 2min.
Embodiment 3
1) preparation of nanometer silver composite particles
By 20 grams of Nano-meter SiO_22Powder is scattered in the hydroxymethyl cellulose aqueous solution that 160mL mass fraction is 10%, shape
Become Nano-meter SiO_22Dispersion liquid;By Nano-meter SiO_2 under the conditions of lucifuge2It is 0.1mol/L's that dispersant liquid drop adds to 100mL molar concentration
AgNO3In solution, the pH value adjusting solution is 8, reacts 4 hours, centrifugation, is washed with deionized and is dried, prepares and receives
Rice silver composite particles.
2) preparation of antibacterial
Based on weight/mass percentage composition, by step 1) prepare nanometer silver composite particles 10%, soluble silane coupling agent
0.05%, surplus is water, mix homogeneously.
3) linen-cotton material treatment
Pending linen-cotton fabric is carried out dipping process by padder in antibacterial, uses two leaching two roll process,
Pricking remaining rate is 80%;2) hot-air seasoning fabric, then carries out baking and makes antimicrobial particles be bonded on fabric, and stoving temperature is
160 DEG C, the baking time is 2min.
Preferred soluble silane coupling agent in embodiment 1~3, its chemical structural formula is:
In formula, Me is-CH3, X is-OCH2CH3Or-OCH3, Y is-CH=CH2, Z is-OH, and molecular weight is 0.5~1.0 ten thousand.
The table 1 antibacterial obtained by embodiment 1~3 linen-cotton fabric is washed 50 times after bacteriostasis rate test table.Cotton
Flax fabric is local commercially available prod.
Table 1
Bacteriostasis rate (escherichia coli), % | Bacteriostasis rate (Candida albicans), % | |
Embodiment 1 | 96.6 | 95.8 |
Embodiment 2 | 85.6 | 86.5 |
Embodiment 3 | 94.6 | 92.8 |
Claims (6)
1. a fabric antimildew and antibacterial agent, it is characterised in that: this antibacterial based on weight/mass percentage composition, nanometer silver composite particles
0.1~20%, soluble silane coupling agent 0.01~0.1%, surplus be water.
A kind of fabric antimildew and antibacterial agent the most according to claim 1, it is characterised in that: described nanometer silver composite particles is
Nano-silver loaded SiO2Granule.
A kind of fabric antimildew and antibacterial agent the most according to claim 2, it is characterised in that: described nano-silver loaded SiO2?
Grain comprises the following steps: by Nano-meter SiO_22Powder is scattered in hydroxymethyl cellulose aqueous solution, forms Nano-meter SiO_22Dispersion liquid;
By Nano-meter SiO_2 under the conditions of lucifuge2Dispersant liquid drop adds to AgNO3In solution, the pH value adjusting solution is 7~9, reacts 3~6 hours,
Centrifugation, is washed with deionized and is dried, i.e. prepares nano-silver loaded SiO2Granule.
A kind of fabric antimildew and antibacterial agent the most according to claim 3, it is characterised in that: described Nano-meter SiO_22Powder and hydroxyl
The mass volume ratio of methylated cellulose aqueous solution is 1g:5~10mL, and the mass fraction of described hydroxymethyl cellulose aqueous solution is
5~15%, described Nano-meter SiO_22Powder and AgNO3The mass volume ratio of solution is 1g:3~6mL, described silver nitrate solution
Molar concentration be 0.1mol/L.
A kind of fabric antimildew and antibacterial agent the most according to claim 1, it is characterised in that: described soluble silane coupling
Agent, its chemical structural formula is:
In formula, Me is-CH3, X is-OCH2CH3Or-OCH3, Y is-CH=CH2, Z is-OH, and molecular weight is 0.5~1.0 ten thousand.
A kind of fabric antimildew and antibacterial agent the most according to claim 1, it is characterised in that: its antibacterial treatment process is: 1) will
Pending linen-cotton fabric carries out dipping process by padder in antibacterial, uses two leaching two roll process, pricks remaining rate and is
75%~80%;2) hot-air seasoning fabric, then carries out baking and makes antimicrobial particles be bonded on fabric, and stoving temperature is 160
DEG C, the baking time is 2min.
Priority Applications (1)
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CN201610542426.9A CN106120314A (en) | 2016-07-12 | 2016-07-12 | A kind of fabric antimildew and antibacterial agent |
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CN201610542426.9A CN106120314A (en) | 2016-07-12 | 2016-07-12 | A kind of fabric antimildew and antibacterial agent |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107164948A (en) * | 2017-06-25 | 2017-09-15 | 长沙善道新材料科技有限公司 | A kind of antibacterial and mouldproof nano fabrics and preparation method thereof |
CN107245884A (en) * | 2017-07-31 | 2017-10-13 | 苏州井村服饰有限公司 | A kind of garment material antibiosis and sterilization agent and preparation method thereof |
CN107523999A (en) * | 2017-07-28 | 2017-12-29 | 江苏新瑞贝科技股份有限公司 | A kind of preparation method of textile antibacterial agent |
CN107675482A (en) * | 2017-08-15 | 2018-02-09 | 江苏新瑞贝科技股份有限公司 | A kind of fabric multifunctional coating agent and preparation method thereof |
CN110331577A (en) * | 2019-05-16 | 2019-10-15 | 苏州佰旺纺织有限公司 | A kind of negative ion health fabric and its soaking agent and application |
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CN101713143A (en) * | 2008-10-06 | 2010-05-26 | 刘曦 | Antibacterial and antimildew function textile finishing agent prepared by adopting nano chambering process |
CN103266467A (en) * | 2013-06-13 | 2013-08-28 | 太仓协大申泰羊毛衫有限公司 | Preparation method of antibacterial wool fibers |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107164948A (en) * | 2017-06-25 | 2017-09-15 | 长沙善道新材料科技有限公司 | A kind of antibacterial and mouldproof nano fabrics and preparation method thereof |
CN107523999A (en) * | 2017-07-28 | 2017-12-29 | 江苏新瑞贝科技股份有限公司 | A kind of preparation method of textile antibacterial agent |
CN107245884A (en) * | 2017-07-31 | 2017-10-13 | 苏州井村服饰有限公司 | A kind of garment material antibiosis and sterilization agent and preparation method thereof |
CN107675482A (en) * | 2017-08-15 | 2018-02-09 | 江苏新瑞贝科技股份有限公司 | A kind of fabric multifunctional coating agent and preparation method thereof |
CN110331577A (en) * | 2019-05-16 | 2019-10-15 | 苏州佰旺纺织有限公司 | A kind of negative ion health fabric and its soaking agent and application |
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