CN107299437A - Anti-bacterial fibre yarn - Google Patents
Anti-bacterial fibre yarn Download PDFInfo
- Publication number
- CN107299437A CN107299437A CN201710699771.8A CN201710699771A CN107299437A CN 107299437 A CN107299437 A CN 107299437A CN 201710699771 A CN201710699771 A CN 201710699771A CN 107299437 A CN107299437 A CN 107299437A
- Authority
- CN
- China
- Prior art keywords
- fibre
- yarn
- cotton
- bacterial fibre
- bacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/449—Yarns or threads with antibacterial properties
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of antimicrobial yarn, belong to textile technology field.Quaternary ammonium type, quaternary phosphine salt types that the yarn is synthesized with patent CN101879466B, CN102720057B, CN103266473B, CN103835124B, carry in silver-colored cotton fiber type anti-bacterial fibre two kinds or two or more a variety of pass through the processes such as opening picking, conjunction hair, cotton carding, drafting, rove, spun yarn with one or several kinds of in cotton, viscose glue, tencel, terylene, polyamide fibre, Modal, soybean fiber blend fibre with bamboo-carbon fibre and be prepared from.The thread fabric of the antibacterial yarn is to Staphylococcus aureus, Escherichia coli and Pseudomonas aeruginosa is antibacterial, anti-microbial property good, and antibiotic property can keep and regenerate after 50 times are cleaned.Not only anti-microbial property is good for the antibiotic fabric, and good spinnability, quality are light, mechanical strength is excellent, can develop the series of products such as antimicrobial socks, antibacterial underwear, improves close Cutaneous, hygroscopicity, comfort level etc..
Description
Technical field
The invention belongs to textile technology field, more particularly to a kind of chemical graft anti-bacterial fibre yarn.
Background technology
In China, with the raising of people's living standard and health consciousness, the demand to antibiotic fabric increases increasingly, antibacterial
Fabric can block contact of the various harmful bacterias with human body and kill bacterium.Current anti-bacterial fibre mainly passes through co-blended spinning
It is prepared by method, compound blending method, finishing method, graft modification method.It is difficult that usual exclusive use anti-bacterial fibre prepares civilian, medical textile
It is Cutaneous etc. to have spinnability, hygroscopicity, gas permeability, antistatic behaviour, anti-pilling, parent concurrently simultaneously so that anti-bacterial fibre fabric
Bring benefit to the people, benefit the society by a definite limitation.There is following report on antimicrobial yarn, fiber at present：
1. Chinese patent CN1303281C reports a kind of antibacterial processing method of yarn, by finishing method, to yarn
To yarn waxing after progress antibacterial processing, antiseptic and wax fusion, then steam treatment makes antiseptic penetrate into yarn, resists
Microbial inoculum is chitosan, carboxymethylchitosan, the chloro- 2- hydroxy-diphenylethers of 2,4,4- tri- etc.；2. Chinese patent
CN100537867C reports the scribbled of a kind of dissolution type uvioresistant, antibacterial and wet-guide quick-drying, dissolution type anti-bacterial fibre
(Triclosan antiseptics or Nano Silver are added in spinning solution) 30%：Antiultraviolet fiber 30%：Wet fiber 40%；3. it is Chinese
Patent CN103806151B reports a kind of apocynum fibre blended antibacterial cool and comfortable yarn and preparation method thereof, aloe viscose glue
Fiber 35-50%：Apocynum fibre 15-30%：Milk fibre 35-45%；4. Chinese patent CN103911708B reports one
Antibacterial blended yarn manufacturing process is planted, blending ratio is black bamboo charcoal 40-50%：Modal 10-15%：Long-staple cotton 15-20%：Spread out
Flaxen fiber 20-25%；5. a kind of preparation methods of antibacterial antistatic color-woven fabric of Chinese patent CN103882601B report one
Plant dyeing melt spinning yarn fabric and antibiotic facing material method is prepared with quaternary ammonium salt Final finishing；6. Chinese patent CN102817238B is reported
A kind of antibacterial wool in road and preparation method thereof, to wool yarn, wool Acrylic Fiber, wool spun polyester thread quaternization makes it
With antibiotic property；7. a kind of antibacterial thermal insulating yarns of Chinese patent CN206244974U report a kind of composite spinning antimicrobial yarn,
Sandwich layer is that titanium dioxide catalyst fiber and bamboo charcoal blend fibre and thermal fiber are handed over and twisted with the fingers, top layer be antimicrobial coating, warming coating, every
Hot coating；8. a kind of numb cottons of Chinese patent CN106012551A add the preparation method of anti-bacterial fibre scribbled to report a kind of resist
Bacterium scribbled, wherein fiber crops：Cotton=2-6:1, anti-bacterial fibre is multiple by 10-30 parts of nano zine oxide polyurethane microcapsule, silver nitrate
Close 10-20 parts of particle, 10-20 parts of nano phase ag_2 o composite particles, 10-20 parts of gauze, 10-15 parts of sisal hemp yarn etc.；9. document
" synthesis of quaternary alkylphosphonium salt antibacterial finishing agent and application study (Donghua University's Master's thesis in 2013) ", it was recently reported that quaternary alkylphosphonium salt antiseptic
Synthesis and Final finishing pure-cotton antimicrobial fabric.
2. 8. from document above report as can be seen that antimicrobial yarn is mainly silver system yarn, such as patent；Co-blended spinning method,
2. 7. composite spinning method anti-bacterial fibre yarn, such as patent；3. 4. natural antibacterial fiber yarn, such as patent；Finishing method antibacterial is fine
Tie up yarn, such as patent 1. 5. 6. 8. with document 9..
The non-dissolution anti-bacterial fibre of chemical graft process has that anti-microbial property is strong, durable antibiotic compared with dissolution type anti-bacterial fibre
The features such as.But due to fiber in itself by various chemical methodes processing after, mechanical strength reduction, be woven into yarn difficulty
Larger, fiber hardens, close Cutaneous difference.Therefore, it is badly in need of exploitation chemical graft antimicrobial yarn, meets the market demand.
The content of the invention
Present invention aims at providing, a kind of anti-microbial property is good and chemical graft process anti-bacterial fibre yarn of good mechanical property.
Based on the market demand and the object of the invention, the applicant early stage patent CN101879466B, CN102720057B,
It is excellent for synthesized quaternary ammonium type, quaternary alkylphosphonium salts, the silver-colored cotton anti-bacterial fibre of load on the basis of CN103266473B, CN103835124B
Anti-microbial property develop and apply, overcome exclusive use anti-bacterial fibre processing antibiotic fabric, can textile, skin-friendly difference etc. no
Foot, is conducive to marketing application.
Technical solution of the present invention is as follows：With patent CN101879466B, CN102720057B, CN103266473B,
The quaternary ammonium type, quaternary alkylphosphonium salts of CN103835124B synthesis, carry two or more in silver-colored cotton anti-bacterial fibre and cotton, viscose glue, tencel,
One or more of a variety of blend fibres and bamboo-carbon fibre carry out blending, anti-bacterial fibre in terylene, polyamide fibre, Modal, soybean fiber
With blend fibre, bamboo-carbon fibre according to (30~70)：(5~50)：(5~70) blending ratio, by opening picking, closes hair, cotton carding, simultaneously
The processes such as bar, rove, spun yarn, prepare anti-bacterial fibre yarn.
It is preferred that：Anti-bacterial fibre and blend fibre and bamboo-carbon fibre blending rate：(50~60)：(20~30)：(20~30).
It is preferred that:The season of patent CN101879466B, CN102720057B, CN103266473B, CN103835124B synthesis
Two kinds and in cotton, viscose glue, tencel, terylene, polyamide fibre, Modal, soybean fiber one in the silver-colored cotton anti-bacterial fibre of ammonium type, quaternary alkylphosphonium salts, load
Plant and carry out blending with bamboo-carbon fibre,
Beneficial effect of the present invention is：1st, chemical graft quaternary ammonium group, quaternary alkylphosphonium salts, the silver-colored cotton anti-bacterial fibre blending of load are made anti-
Bacterium yarn, anti-bacterial fibre spinnability and skin-friendly are improved by blending so that the fabric that the yarn is made into is ensureing anti-microbial property
On the premise of, possess enough mechanical performances, yarn breakage intensity reaches 12~20cN/tex, and close Cutaneous, deodorization performance is excellent
It is good, the consumption demand of consumers in general can be met, the popularity rate of antibiotic fabric is improved.2nd, the antibiotic fabric being made is to golden yellow grape
Coccus, Escherichia coli and Pseudomonas aeruginosa bacteriostasis antibiosis are functional, and gold-coloured staphylococci, Escherichia coli, Candida albicans are pressed down
Bacterium rate >=99%, bacteriostasis rate reaches the AAA grades of requirements of FZ/T 73023-2006 antibiosis knitting product, antibacterial after 50 times are washed
Property persistently, excellent antibacterial performance.3rd, the fabric such as socks, shoe-pad, clothes of exploitation realizes antibiotic property, spinnability, skin-friendly, suction
Moist, deodorization unification, is conducive to the later stage to realize the industrialization of the antibiotic fabric, the marketization.
Embodiment
The present invention is further described with reference to embodiment.
Embodiment 1
The antimicrobial yarn blending ratio, anti-bacterial fibre：Cotton or polyamide fibre：Bamboo-carbon fibre=45：45：10, by opening picking, close
The processes such as hair, cotton carding, drafting, rove, spun yarn are made 40sYarn.
The anti-bacterial fibre selects the anti-bacterial fibre that CN102720057B and CN103266473B is synthesized.
The high material of paying close attention to for authorizing review for affixing one's name to cut-off announcement on December 17th, 2014 based on European chemical balance motion is waited
Inventory (according to No. 1907/2006 REACH regulation of European Union) is selected, concern material (SVHC) high to 161 kinds carries out screening test.Adopt
With ICP-OES, UV-VIS, GC-MS, HPLC-DAD/MS and colorimetrically analysing.As a result such as table 1：
Table 1
| Concentration % | |
| SVHC in the candidate list of all tests | ND |
161 kinds high attention rate material includes 4,4- MDAs, anthracene, cobaltous dichloride, arsenic trioxide, dichromic acid
Sodium, plumbous chromate, formamide, 1- N-Propyl Bromides, 4- aminobphenyls, dinoseb etc..
Raw material anti-bacterial fibre intensity is shown in Table 2：
Table 2
| Pull-off force cN | |
| Quaternary ammonium antibacterial fiber | 6.12 |
| Quaternary alkylphosphonium salt anti-bacterial fibre | 3.9‐4.4 |
Anti-bacterial blended yarn line strength of the present invention is shown in Table 3：
Table 3
Antibacterial blended yarn anti-microbial property test of the present invention, using FZ/T 73023-2006 antibiosis knitting product, shakes method,
It the results are shown in Table 4：
Table 4
Embodiment 2
The antimicrobial yarn blending ratio, anti-bacterial fibre：Viscose rayon：Bamboo-carbon fibre 60：20：20, by opening picking, close
The processes such as hair, cotton carding, drafting, rove, spun yarn are made 40sYarn.Anti-bacteria cloth is made into through antimicrobial yarn.
The anti-bacterial fibre selects the anti-bacterial fibre that CN103266473B and CN103835124B is synthesized.
Antibiosis knitting cloth anti-microbial property test, using FZ/T 73023-2006 antibiosis knitting product, shakes method, the results are shown in Table
5：
Table 5
The multiple integrality Skin Irritation Test of antibiosis knitting cloth,《Disinfection technology standard》Ministry of Public Health's (version in 2002)
2.3.3.3.3, the results are shown in Table 6：
Table 6
According to GB/T8629 washings 10,30,50 times, anti-bacteria cloth bacteriostasis property is shown in Table 7：
Table 7
Antibiosis knitting product FZ/T 73023-2006 standards are shown in Table 8：
Table 8
Embodiment 3
The antimicrobial yarn blending ratio, anti-bacterial fibre：Blend fibre (cotton, terylene, Modal):Bamboo-carbon fibre=50：
(10：10：10)：20, it is made 40 by processes such as opening picking, conjunction hair, cotton carding, drafting, rove, spun yarnssYarn, passes through antimicrobial yarn
It is processed into antimicrobial socks.
The anti-bacterial fibre selects the anti-bacterial fibre that CN101879466B and CN102720057B is synthesized.
Antimicrobial socks antibiotic property is tested, using the evaluation Part II of GB/T20944.2-2007 antibacterial textile performances：
Absorption process, the results are shown in Table 9：
Table 9
Embodiment 4
The antimicrobial yarn blending ratio, anti-bacterial fibre：(cotton, viscose glue, tencel, soybean fiber):(bamboo-carbon fibre)=55：
(5：5：5：5)：25, it is made 40 by processes such as opening picking, conjunction hair, cotton carding, drafting, rove, spun yarnssYarn, passes through antimicrobial yarn
It is processed into antibacterial towel.
The anti-bacterial fibre selects the anti-bacterial fibre that CN102720057B and CN103835124B is synthesized.
Antibacterial towel antibiotic property is tested, using the evaluation Part II of GB/T20944.2-2007 antibacterial textile performances：
Absorption process, the results are shown in Table 10：
Table 10
Claims (3)
1. anti-bacterial fibre yarn, it is characterised in that with patent CN101879466B, CN102720057B, CN103266473B,
The quaternary ammonium type, quaternary phosphine salt types of CN103835124B synthesis, carry two or more in silver-colored cotton fiber type anti-bacterial fibre and cotton, it is viscous
The one or more kinds of blend fibres of glue, tencel, terylene, polyamide fibre, Modal, soybean fiber and bamboo-carbon fibre carry out blending, pass through
Opening picking, conjunction hair, cotton carding, drafting, rove, spinning process prepare antimicrobial yarn；Anti-bacterial fibre is fine with bamboo charcoal with blend fibre
Tie up blending rate：（30~70）：（5~50）：（5~70）.
2. anti-bacterial fibre yarn according to claim 1, it is characterised in that anti-bacterial fibre and blend fibre and bamboo-carbon fibre
Blending rate is preferred（50~60）：（20~30）：（20~30）.
3. anti-bacterial fibre yarn according to claim 1 or 2, it is characterised in that patent CN101879466B,
Two in the silver-colored cotton anti-bacterial fibre of the quaternary ammonium type, quaternary alkylphosphonium salts of CN102720057B, CN103266473B, CN103835124B synthesis, load
Plant and carry out blending with bamboo-carbon fibre with a kind of in cotton, viscose glue, tencel, terylene, polyamide fibre, Modal, soybean fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710699771.8A CN107299437A (en) | 2017-08-16 | 2017-08-16 | Anti-bacterial fibre yarn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710699771.8A CN107299437A (en) | 2017-08-16 | 2017-08-16 | Anti-bacterial fibre yarn |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107299437A true CN107299437A (en) | 2017-10-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710699771.8A Pending CN107299437A (en) | 2017-08-16 | 2017-08-16 | Anti-bacterial fibre yarn |
Country Status (1)
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108950813A (en) * | 2018-09-07 | 2018-12-07 | 南通芳翠家纺设计有限公司 | A kind of textile fabric and processing method |
| CN112075893A (en) * | 2020-08-21 | 2020-12-15 | 深圳市优代尔互联网科技有限公司 | Multi-surface cleaning towel, manufacturing method thereof and towel assembly |
| CN112877825A (en) * | 2021-02-04 | 2021-06-01 | 潍坊迅纺新材料科技有限公司 | Air-jet vortex spinning multi-component antibacterial yarn and preparation method thereof |
| CN116121930A (en) * | 2023-02-27 | 2023-05-16 | 亿吉万(深圳)新材料科技有限公司 | Moisture-absorbing antibacterial textile |
| WO2024027051A1 (en) * | 2022-11-30 | 2024-02-08 | 安徽翰联色纺股份有限公司 | Antibacterial colored spun yarn and production method therefor |
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| US20040187471A1 (en) * | 2000-10-31 | 2004-09-30 | World Fibers, Inc. | Antimicrobial cut-resistant composite yarn and garments knitted or woven therefrom |
| CN102011227A (en) * | 2010-10-27 | 2011-04-13 | 江南大学 | Antibacterial blended yarn and spinning process thereof |
| CN102720057A (en) * | 2012-07-03 | 2012-10-10 | 河南省科学院化学研究所有限公司 | Fibre material containing quaternary ammonium groups and synthetic method thereof |
| CN103266473A (en) * | 2013-06-24 | 2013-08-28 | 河南省科学院化学研究所有限公司 | Phosphonium salt modified acrylic fibre antibacterial material and preparation method thereof |
| CN103835124A (en) * | 2014-02-28 | 2014-06-04 | 河南省科学院化学研究所有限公司 | Silver-carried cotton fabric antibacterial material and preparation method thereof |
| CN104480592A (en) * | 2014-11-26 | 2015-04-01 | 德州华源生态科技有限公司 | Blended yarn containing 11 different fibers and production method |
| CN106149160A (en) * | 2016-08-16 | 2016-11-23 | 长兴天川非织造布有限公司 | A kind of antibacterial textile material |
-
2017
- 2017-08-16 CN CN201710699771.8A patent/CN107299437A/en active Pending
Patent Citations (7)
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| US20040187471A1 (en) * | 2000-10-31 | 2004-09-30 | World Fibers, Inc. | Antimicrobial cut-resistant composite yarn and garments knitted or woven therefrom |
| CN102011227A (en) * | 2010-10-27 | 2011-04-13 | 江南大学 | Antibacterial blended yarn and spinning process thereof |
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| CN104480592A (en) * | 2014-11-26 | 2015-04-01 | 德州华源生态科技有限公司 | Blended yarn containing 11 different fibers and production method |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108950813A (en) * | 2018-09-07 | 2018-12-07 | 南通芳翠家纺设计有限公司 | A kind of textile fabric and processing method |
| CN112075893A (en) * | 2020-08-21 | 2020-12-15 | 深圳市优代尔互联网科技有限公司 | Multi-surface cleaning towel, manufacturing method thereof and towel assembly |
| CN112877825A (en) * | 2021-02-04 | 2021-06-01 | 潍坊迅纺新材料科技有限公司 | Air-jet vortex spinning multi-component antibacterial yarn and preparation method thereof |
| WO2024027051A1 (en) * | 2022-11-30 | 2024-02-08 | 安徽翰联色纺股份有限公司 | Antibacterial colored spun yarn and production method therefor |
| CN116121930A (en) * | 2023-02-27 | 2023-05-16 | 亿吉万(深圳)新材料科技有限公司 | Moisture-absorbing antibacterial textile |
| CN116121930B (en) * | 2023-02-27 | 2023-11-03 | 亿吉万(深圳)新材料科技有限公司 | Moisture-absorbing antibacterial textile |
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Application publication date: 20171027 |