CN107580593B - 制备不饱和羧酸盐的方法 - Google Patents

制备不饱和羧酸盐的方法 Download PDF

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Publication number
CN107580593B
CN107580593B CN201680027140.5A CN201680027140A CN107580593B CN 107580593 B CN107580593 B CN 107580593B CN 201680027140 A CN201680027140 A CN 201680027140A CN 107580593 B CN107580593 B CN 107580593B
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alkoxide
process according
liquid phase
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catalytic process
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Chinese (zh)
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CN107580593A (zh
Inventor
T·绍布
N·乌盖特苏比耶拉
R·帕切洛
D·M·弗莱斯
S·曼齐尼
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201680027140.5A 2015-05-13 2016-05-09 制备不饱和羧酸盐的方法 Active CN107580593B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15167626.9 2015-05-13
EP15167626 2015-05-13
PCT/EP2016/060328 WO2016180775A1 (en) 2015-05-13 2016-05-09 Process for preparing an unsaturated carboxylic acid salt

Publications (2)

Publication Number Publication Date
CN107580593A CN107580593A (zh) 2018-01-12
CN107580593B true CN107580593B (zh) 2021-03-02

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CN201680027140.5A Active CN107580593B (zh) 2015-05-13 2016-05-09 制备不饱和羧酸盐的方法

Country Status (6)

Country Link
US (1) US10138196B2 (OSRAM)
EP (1) EP3294701B1 (OSRAM)
JP (1) JP6808649B2 (OSRAM)
KR (1) KR20180008621A (OSRAM)
CN (1) CN107580593B (OSRAM)
WO (1) WO2016180775A1 (OSRAM)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9725393B2 (en) 2014-10-08 2017-08-08 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
CN113402375B (zh) 2015-12-15 2024-04-02 切弗朗菲利浦化学公司 由金属内酯和阴离子聚电解质形成α,β-不饱和羧酸和其盐
WO2017133995A1 (de) 2016-02-01 2017-08-10 Basf Se Verfahren zur herstellung von c4-c15-lactamen
US10544080B2 (en) 2017-06-14 2020-01-28 Chevron Phillips Chemical Company Lp Continuous process for the conversion of olefins and carbon dioxide to acrylates via solution phase reactor
US10550061B2 (en) 2017-06-14 2020-02-04 Chevron Phillips Chemical Company Lp Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
WO2019053541A1 (en) 2017-09-14 2019-03-21 Sabic Global Technologies B.V. ACRYLATES BY OLEFIN COUPLING / CARBON DIOXIDE
CN111587246B (zh) * 2017-12-25 2023-05-26 Ptt全球化学公共有限公司 一种用于得自二氧化碳和烯烃的不饱和羧酸盐及其衍生物的生产方法的催化剂组合物
CN111587236A (zh) * 2018-03-28 2020-08-25 积水化学工业株式会社 α,β-不饱和羧酸盐的制备方法
US11174213B2 (en) 2018-10-12 2021-11-16 Chevron Phillips Chemical Company, Lp Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates
WO2021185879A1 (en) 2020-03-20 2021-09-23 Basf Se CATALYTIC PROCESS FOR PREPARING AN α,β-ETHYLENICALLY UNSATURATED CARBOXYLIC ACID SALT
US12162829B2 (en) 2021-12-16 2024-12-10 Chevron Phillips Chemical Company Lp Gas phase process for acrylate production from ethylene and carbon dioxide

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104011004A (zh) * 2011-12-29 2014-08-27 巴斯夫欧洲公司 通过催化羧化烯烃制备α,β-烯属不饱和羧酸盐

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE968903C (de) 1952-05-13 1958-04-10 Huels Chemische Werke Ag Verfahren zur kontinuierlichen Herstellung von Alkalialkoholaten
US4792620A (en) * 1983-10-14 1988-12-20 Bp Chemicals Limited Carbonylation catalysts
JP4518671B2 (ja) * 1998-06-12 2010-08-04 ビーエーエスエフ ソシエタス・ヨーロピア アルカリ金属アルコキシドの製造方法
US8642803B2 (en) * 2010-03-03 2014-02-04 Basf Se Preparation of ethylenically unsaturated carboxylic salts by carboxylation of alkenes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104011004A (zh) * 2011-12-29 2014-08-27 巴斯夫欧洲公司 通过催化羧化烯烃制备α,β-烯属不饱和羧酸盐

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《Nickel-Catalyzed Direct Carboxylation of Olefins with CO2: One-Pot Synthesis of a,b-Unsaturated Carboxylic Acid Salts》;Núria Huguet等;《Chem. Eur. J.》;20141231;第20卷(第51期);第16858-16862页 *

Also Published As

Publication number Publication date
EP3294701A1 (en) 2018-03-21
US10138196B2 (en) 2018-11-27
JP2018515535A (ja) 2018-06-14
WO2016180775A1 (en) 2016-11-17
KR20180008621A (ko) 2018-01-24
EP3294701B1 (en) 2020-08-12
CN107580593A (zh) 2018-01-12
US20180134646A1 (en) 2018-05-17
JP6808649B2 (ja) 2021-01-06

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