CN107574036A - A kind of preparation method of antibacterial Tea stain detergent - Google Patents
A kind of preparation method of antibacterial Tea stain detergent Download PDFInfo
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Abstract
The invention discloses a kind of preparation method of antibacterial Tea stain detergent, belong to cleaning agent preparing technical field.The present invention extracts fruit of summer cypress decoction powder with the mode of ultrasonic wave cleaning treatment,Chitosan powder is prepared with shrimp shell,Chitosan powder compounds to obtain surface-active compound with alkylamide propyl dimethyl amine alkali solution of beet,Pulverize to obtain the antibacterial Tea stain detergent of low toxicity,Potato starch disperses that colloid can be formed in water in cleaning agent,Alkylamide propyl dimethyl amine glycine betaine is as a kind of surface reactive material,Micelle surface is attached to tear the oiliness film layer of tea stain,Contain abundant triterpenoid saponin and flavone compound in the fruit of summer cypress,When having stronger inhibitory action cleaning agent cleaning tea stain to Escherichia coli and staphylococcus aureus etc.,Entanglement effect is strong in micelle,After tea stain is cleaned, all kinds of antibacterial substance killings in the gel that bacterium can be formed by potato starch are exposed,So as to reach the purpose sterilized and have no toxic side effect material discharge.
Description
Technical field
The invention discloses a kind of preparation method of antibacterial Tea stain detergent, belong to cleaning agent preparing technical field.
Background technology
Tea stain nickname tea stain, tea hill, refer to the dirty thing of tea set inwall, because long-term receiving tea alluvial forms.Especially old tea
Kettle builds up a thick layer of tea stain, and tea hill is referred to as in tea culture.This teapot for carrying one layer of tea hill can often increase tea
The reserve value of kettle.
Some teapots with tea hill even can only put hot boiling water into, and hot water can dissolve the tea stain of inwall, change
Water is tea, and reputation claims also have three points of perfume (or spice) without tea.Mould growth is possible in moist environment without the tea set of cleaning tea stain for a long time.
There is rumour to claim tea stain to contain the various metals material such as cadmium, lead, iron, arsenic, mercury, can make one carcinogenic.But if tea stain contains this kind of heavy
Metal, is mostly derived from water used in infusing tea or tealeaves, cup are contaminated contain heavy metal in itself, rather than tea stain is in itself.
Cleaning agent, it is a kind of cleaning production for being used for washing clothing or implement or cleaning the things such as furniture of liquid condition
Product.It uses various new surfactant, and strong detergency, rinsing is easy, non-stimulated to skin.Most preferably wash kitchen tools, family
Tool, and fruit, melon and vegetable.
Cleaning agent mainly sees through the environmental protection such as agent and unique bright factor by surfactant, bactericide, polishing agent, import
The liquid ceramic tile cleaner that technology high-tech is formulated；When it is coated in cleaning of objects surface, is combined or melted with dirt, but
It needs flowing water to wash its residue.At present, the cleaning of daily tea set is still with drift ice, cleanser, liquid detergent, wiping sponge
Deng based on, these products otherwise have certain harm to human body and environment, otherwise be exactly using trouble, the toxicity when playing bactericidal action
It is stronger.Therefore, invent a kind of antibacterial Tea stain detergent has positive effect to cleaning agent preparing technical field.
The content of the invention
Present invention mainly solves technical problem, for Tea stain detergent rise bactericidal action when toxicity it is stronger the defects of,
Provide a kind of preparation method of antibacterial Tea stain detergent.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of preparation method of antibacterial Tea stain detergent, it is characterised in that specifically preparation process is：
（1）200~220g fruit of summer cypress is weighed, is placed in conical flask, 300~350mL deionized water dippings are added into conical flask,
Maceration extract is obtained, maceration extract is placed in ultrasonic cleaner, starts washer, cleaning, cleans repeatedly, obtain fruit of summer cypress medicine
Liquid, fruit of summer cypress decoction is filtered with non-woven fabrics, remove filter residue, obtain filtrate, filtrate is filtered, remove residue, received
Collection obtains extract solution, extract solution is transferred in evaporating dish, heat temperature raising, evaporation drying, obtains decoction powder；
（2）300~320g potatoes are weighed, ball milling in ball mill is placed in after chopping and obtains mashed potatoes, mashed potatoes is put into plastic tub
In, 1.0~1.2L water is added, stirring, mashed potatoes suspension is obtained, is filtered mashed potatoes suspension with gauze, filtrate is removed, obtains
Potato to the water containing part is starched, and potato is starched and stood, and layering, is removed upper liquid, mashed potatoes is obtained, by above-mentioned filtration step weight
It is multiple, mashed potatoes is placed in exposure on the plastic plate of dried and clean, obtains potato starch；
（3）Discarded shrimp shell is eluted with water, exposure is dried, and the shrimp shell of clean dried is obtained, by 100~120g clean drieds
Shrimp shell, which is placed in 200~230mL watery hydrochloric acid, soaks, and immersion takes out shrimp shell after terminating, and is in distillation water washing shrimp shell to cleaning solution
Neutrality, the shrimp shell of acidleach processing is obtained, the shrimp shell that acidleach is handled is placed in 120~150mL sodium hydroxide solutions, heating rises
Temperature, after boiling, filter off except filtrate obtains gel, gel is placed in baking oven, heat temperature raising, chitosan powder is obtained after drying
End；
（4）50~55g Chitosan powders are placed in beaker, acetum is added into beaker, obtain chitosan acid solution, by quality
The alkylamide propyl dimethyl amine alkali solution of beet that fraction is 20% mixes in equal volume with chitosan acid solution, is placed in high speed centrifugation
Centrifuged in machine, remove upper liquid, precipitated, precipitation is placed in baking oven, heat temperature raising, dried, obtain surface-active compounding
Thing；
（5）Count in parts by weight, by 20~30 parts of surface-active compounds, 50~60 parts of potato starches, 20~25 parts of decoction powder
End, 15~20 parts of Solid hydrogen peroxides, 100~120 parts of deionized water mixing, are placed in high speed dispersor high speed and disperse, mixed
Liquid is closed, is staticly settled, upper liquid is removed, lower sediment is placed in baking oven, heat temperature raising, dries, precipitation is placed in mortar
Grinding, it is antibacterial Tea stain detergent that sieving, which obtains powder,.
Step（1）Described dip time is 22~24h, and scavenging period is 15~20min, and wash number is 2~4 repeatedly
Secondary, temperature is 45~50 DEG C after heat temperature raising, and the evaporation drying time is 2~3h.
Step（2）Described Ball-milling Time is 30~40min, and mixing time is 20~25min, and time of repose is 3~5h,
The number that repeats the above steps is 2~3 times, and the exposure time is 3~5 days.
Step（3）Described exposure drying time is 2~3 days, and the mass fraction of watery hydrochloric acid is 5%, soak time is 2~
3h, the mass fraction of sodium hydroxide solution is 55%, and temperature is 100~110 DEG C after heat temperature raising, and digestion time is 4~5h, is dried
Temperature is 80~90 DEG C after case heat temperature raising, and drying time is 4~6h.
Step（4）The mass fraction of described acetum is 2%, adds acetum until pH is 5.2~5.6, at a high speed
Centrifuge speed is 4000~4200r/min, 15~20min of centrifugation time, and temperature is 100~120 DEG C after baking oven heat temperature raising,
Drying time is 2~3h.
Step（5）Described high speed dispersor rotating speed is 3000~3300r/min, and high speed jitter time is 13~15min,
It is 45~50min to staticly settle the time, and temperature is 35~40 DEG C after heat temperature raising, and drying time is 18~20h,
Milling time is 20~25min, and specification of sieving is 100 mesh.
The beneficial effects of the invention are as follows：
（1）The present invention extracts fruit of summer cypress decoction powder with the mode of ultrasonic wave cleaning treatment, and chitosan is prepared with shrimp shell
Powder, Chitosan powder compound to obtain surface-active compound with alkylamide propyl dimethyl amine alkali solution of beet, finally will
Fruit of summer cypress medicine company powder, surface-active compound, Solid hydrogen peroxide mixing are scattered, pulverize to obtain the antibacterial tea stain cleaning of low toxicity
Agent, potato starch disperses that colloid can be formed in water in cleaning agent, and alkylamide propyl dimethyl amine glycine betaine is as a kind of table
Face active material, be attached to micelle surface and tear the oiliness film layer of tea stain, cleaning agent neutral and alkali composition by acidity tea stain from
Solution, it is adsorbed in the gel of potato starch formation, reaches obvious cleaning action；
（2）Containing abundant triterpenoid saponin and flavone compound in the fruit of summer cypress in the present invention, to Escherichia coli and golden yellow Portugal
Grape coccus etc. has stronger inhibitory action, is the material of a kind of natural degradable, and toxicity is low, the Solid hydrogen peroxide oxidation disinfection time-division
Solution material is water and oxygen, and the material that has no toxic side effect residual, chitosan is a kind of natural animal-plant fiber, to aquatic pathogen
Antibacterial action is very strong and has very strong degradability, and when cleaning agent cleans tea stain, entanglement effect is strong in micelle, and tea stain is cleaned
All kinds of antibacterial substance killings in the gel that bacterium can be formed by potato starch are exposed afterwards, are sterilized and with nontoxic pair so as to reach
The purpose of working substance discharge.
Embodiment
200~220g fruit of summer cypress is weighed, is placed in conical flask, 300~350mL deionized water dippings are added into conical flask
22~24h, maceration extract is obtained, maceration extract is placed in ultrasonic cleaner, start washer, clean 15~20min, repeatedly
Cleaning 2~4 times, obtains fruit of summer cypress decoction, fruit of summer cypress decoction is filtered with non-woven fabrics, removes filter residue, obtains filtrate, to filter
Liquid is filtered, and removes residue, and collection obtains extract solution, extract solution is transferred in evaporating dish, is heated to 45~50 DEG C,
2~3h of evaporation drying, obtain decoction powder；300~320g potatoes are weighed, 30~40min of ball milling in ball mill is placed in after chopping
Mashed potatoes is obtained, mashed potatoes is put into plastic tub, adds 1.0~1.2L water, stirs 20~25min, obtains mashed potatoes suspension
Liquid, mashed potatoes suspension is filtered with gauze, removes filtrate, obtained the potato slurry of the water containing part, potato is starched and stands 3~5h,
Layering, upper liquid is removed, obtains mashed potatoes, above-mentioned filtration step is repeated 2~3 times, mashed potatoes is placed in the modeling of dried and clean
Exposure 3~5 days, obtain potato starch on flitch；Discarded shrimp shell is eluted with water, exposure is dried 2~3 days, is obtained clean dry
Dry shrimp shell, by the shrimp shell of 100~120g clean drieds be placed in 200~230mL mass fractions for immersion 2 in 5% watery hydrochloric acid~
3h, immersion take out shrimp shell after terminating, and with distillation water washing shrimp shell to cleaning solution in neutrality, the shrimp shell of acidleach processing are obtained, by acid
The shrimp shell of leaching processing is placed in 120~150mL mass fractions in 55% sodium hydroxide solution, to be heated to 100~110 DEG C, steams
After boiling 4~5h, filter off except filtrate obtains gel, gel is placed in baking oven, be heated to 80~90 DEG C, dry 4~6h
After obtain Chitosan powder；50~55g Chitosan powders are placed in beaker, it is molten that the acetic acid that mass fraction is 2% is added into beaker
Liquid, until pH is 5.2~5.6, chitosan acid solution is obtained, by the alkylamide propyl dimethyl amine beet that mass fraction is 20%
Aqueous slkali mixes in equal volume with chitosan acid solution, be placed in supercentrifuge with 4000~4200r/min rotating speed centrifugation 15~
20min, upper liquid is removed, is precipitated, precipitation is placed in baking oven, be heated to 100~120 DEG C, dried 2~3h, obtain
To surface-active compound；Count in parts by weight, by 20~30 parts of surface-active compounds, 50~60 parts of potato starches, 20~
25 parts of decoction powder, 15~20 parts of Solid hydrogen peroxides, 100~120 parts of deionized water mixing, are placed in high speed dispersor with 3000
~3300r/min rotating speed disperses at a high speed 13~15min, obtains mixed liquor, staticly settles 45~50min, removes upper liquid, will
Lower sediment is placed in baking oven, is heated to 35~40 DEG C, dries 18~20h, by precipitation be placed in grinding 20 in mortar~
25min, it is antibacterial Tea stain detergent to cross 100 mesh sieves and obtain powder.
Example 1
The 200g fruit of summer cypress is weighed, is placed in conical flask, 300mL deionized water dipping 22h are added into conical flask, are impregnated
Liquid, maceration extract is placed in ultrasonic cleaner, starts washer, clean 15min, cleaned 2 times repeatedly, obtain fruit of summer cypress medicine
Liquid, fruit of summer cypress decoction is filtered with non-woven fabrics, remove filter residue, obtain filtrate, filtrate is filtered, remove residue, received
Collection obtains extract solution, and extract solution is transferred in evaporating dish, 45 DEG C is heated to, evaporation drying 2h, obtains decoction powder；Claim
300g potatoes are taken, ball milling 30min in ball mill is placed in after chopping and obtains mashed potatoes, mashed potatoes is put into plastic tub, are added
1.0L water, 20min is stirred, mashed potatoes suspension is obtained, is filtered mashed potatoes suspension with gauze, removed filtrate, obtain the portion of containing
Divide the potato slurry of water, potato starched and stands 3h, layering, removal upper liquid, obtain mashed potatoes, above-mentioned filtration step is repeated 2 times,
Mashed potatoes is placed in exposure 3 days on the plastic plate of dried and clean, obtains potato starch；Discarded shrimp shell is eluted with water, exposure
Dry 2 days, obtain the shrimp shell of clean dried, the shrimp shell of 100g clean drieds is placed in 200mL mass fractions as in 5% watery hydrochloric acid
2h is soaked, immersion takes out shrimp shell after terminating, and is in neutrality with distillation water washing shrimp shell to cleaning solution, obtains the shrimp shell of acidleach processing,
The shrimp shell that acidleach is handled is placed in 120mL mass fractions in 55% sodium hydroxide solution, to be heated to 100 DEG C, boiling 4h
Afterwards, filter off except filtrate obtains gel, gel is placed in baking oven, be heated to 80 DEG C, chitosan powder is obtained after drying 4h
End；50g Chitosan powders are placed in beaker, the acetum that mass fraction is 2% is added into beaker, until pH is 5.2, is obtained
It is the bodies such as 20% alkylamide propyl dimethyl amine alkali solution of beet and chitosan acid solution by mass fraction to chitosan acid solution
Product mixing, is placed in supercentrifuge and centrifuges 15min with 4000r/min rotating speed, removes upper liquid, is precipitated, will precipitated
It is placed in baking oven, is heated to 100 DEG C, dries 2h, obtain surface-active compound；Count in parts by weight, by 20 parts of surfaces
Active compound, 50 parts of potato starches, 20 parts of decoction powder, 15 parts of Solid hydrogen peroxides, 100 parts of deionized water mixing, are placed in height
13min is disperseed at a high speed with 3000r/min rotating speed in fast dispersion machine, obtains mixed liquor, staticly settles 45min, removes upper liquid,
Lower sediment is placed in baking oven, is heated to 35 DEG C, 18h is dried, precipitation is placed in mortar and grinds 20min, crosses 100 mesh
It is antibacterial Tea stain detergent that sieve, which obtains powder,.
Example 2
The 210g fruit of summer cypress is weighed, is placed in conical flask, 325mL deionized water dipping 23h are added into conical flask, are impregnated
Liquid, maceration extract is placed in ultrasonic cleaner, starts washer, clean 17min, cleaned 3 times repeatedly, obtain fruit of summer cypress medicine
Liquid, fruit of summer cypress decoction is filtered with non-woven fabrics, remove filter residue, obtain filtrate, filtrate is filtered, remove residue, received
Collection obtains extract solution, and extract solution is transferred in evaporating dish, 47 DEG C is heated to, evaporation drying 2.5h, obtains decoction powder；
310g potatoes are weighed, ball milling 35min in ball mill is placed in after chopping and obtains mashed potatoes, mashed potatoes is put into plastic tub, are added
1.1L water, 22min is stirred, mashed potatoes suspension is obtained, is filtered mashed potatoes suspension with gauze, removed filtrate, obtain the portion of containing
Divide the potato slurry of water, potato starched and stands 4h, layering, removal upper liquid, obtain mashed potatoes, above-mentioned filtration step is repeated 2 times,
Mashed potatoes is placed in exposure 4 days on the plastic plate of dried and clean, obtains potato starch；Discarded shrimp shell is eluted with water, exposure
Dry 2 days, obtain the shrimp shell of clean dried, the shrimp shell of 110g clean drieds is placed in 210mL mass fractions as in 5% watery hydrochloric acid
2.5h is soaked, immersion takes out shrimp shell after terminating, and with distillation water washing shrimp shell to cleaning solution in neutrality, obtains the shrimp of acidleach processing
Shell, the shrimp shell that acidleach is handled is placed in 140mL mass fractions in 55% sodium hydroxide solution, to be heated to 105 DEG C, boiling
After 4.5h, filter off except filtrate obtains gel, gel is placed in baking oven, be heated to 85 DEG C, obtaining shell after dry 5h gathers
Icing Sugar end；52g Chitosan powders are placed in beaker, the acetum that mass fraction is 2% is added into beaker, until pH is
5.4, chitosan acid solution is obtained, by alkylamide propyl dimethyl amine alkali solution of beet and the chitosan acid that mass fraction is 20%
Liquid mixes in equal volume, is placed in supercentrifuge and centrifuges 17min with 4100r/min rotating speed, removes upper liquid, is precipitated,
Precipitation is placed in baking oven, is heated to 110 DEG C, 2.5h is dried, obtains surface-active compound；Count in parts by weight, will
25 parts of surface-active compounds, 55 parts of potato starches, 22 parts of decoction powder, 17 parts of Solid hydrogen peroxides, 110 parts of deionized waters are mixed
Close, be placed in high speed dispersor and 14min is disperseed at a high speed with 3100r/min rotating speed, obtain mixed liquor, staticly settle 47min, go
Except upper liquid, lower sediment is placed in baking oven, is heated to 37 DEG C, 19h is dried, precipitation is placed in mortar and ground
22min, it is antibacterial Tea stain detergent to cross 100 mesh sieves and obtain powder.
Example 3
The 220g fruit of summer cypress is weighed, is placed in conical flask, 350mL deionized water dipping 24h are added into conical flask, are impregnated
Liquid, maceration extract is placed in ultrasonic cleaner, starts washer, clean 20min, cleaned 4 times repeatedly, obtain fruit of summer cypress medicine
Liquid, fruit of summer cypress decoction is filtered with non-woven fabrics, remove filter residue, obtain filtrate, filtrate is filtered, remove residue, received
Collection obtains extract solution, and extract solution is transferred in evaporating dish, 50 DEG C is heated to, evaporation drying 3h, obtains decoction powder；Claim
320g potatoes are taken, ball milling 40min in ball mill is placed in after chopping and obtains mashed potatoes, mashed potatoes is put into plastic tub, are added
1.2L water, 25min is stirred, mashed potatoes suspension is obtained, is filtered mashed potatoes suspension with gauze, removed filtrate, obtain the portion of containing
Divide the potato slurry of water, potato starched and stands 5h, layering, removal upper liquid, obtain mashed potatoes, above-mentioned filtration step is repeated 3 times,
Mashed potatoes is placed in exposure 5 days on the plastic plate of dried and clean, obtains potato starch；Discarded shrimp shell is eluted with water, exposure
Dry 3 days, obtain the shrimp shell of clean dried, the shrimp shell of 120g clean drieds is placed in 230mL mass fractions as in 5% watery hydrochloric acid
3h is soaked, immersion takes out shrimp shell after terminating, and is in neutrality with distillation water washing shrimp shell to cleaning solution, obtains the shrimp shell of acidleach processing,
The shrimp shell that acidleach is handled is placed in 150mL mass fractions in 55% sodium hydroxide solution, to be heated to 110 DEG C, boiling 5h
Afterwards, filter off except filtrate obtains gel, gel is placed in baking oven, be heated to 90 DEG C, chitosan powder is obtained after drying 6h
End；55g Chitosan powders are placed in beaker, the acetum that mass fraction is 2% is added into beaker, until pH is 5.6, is obtained
It is the bodies such as 20% alkylamide propyl dimethyl amine alkali solution of beet and chitosan acid solution by mass fraction to chitosan acid solution
Product mixing, is placed in supercentrifuge and centrifuges 20min with 4200r/min rotating speed, removes upper liquid, is precipitated, will precipitated
It is placed in baking oven, is heated to 120 DEG C, dries 3h, obtain surface-active compound；Count in parts by weight, by 30 parts of surfaces
Active compound, 60 parts of potato starches, 25 parts of decoction powder, 20 parts of Solid hydrogen peroxides, 120 parts of deionized water mixing, are placed in height
15min is disperseed at a high speed with 3300r/min rotating speed in fast dispersion machine, obtains mixed liquor, staticly settles 50min, removes upper liquid,
Lower sediment is placed in baking oven, is heated to 40 DEG C, 20h is dried, precipitation is placed in mortar and grinds 25min, crosses 100 mesh
It is antibacterial Tea stain detergent that sieve, which obtains powder,.
Comparative example
With the antibacterial Tea stain detergent of Zhuhai company production as a comparison case to antibacterial Tea stain detergent produced by the present invention and
Antibacterial Tea stain detergent in comparative example carries out performance detection, and testing result is as shown in table 1：
1st, method of testing：
The test of Escherichia coli bacteriostasis rate carries out performance detection by the evaluation regulation of GB/T20944.2-2007 anti-microbial properties；
The test of staphylococcus aureus bacteriostasis rate carries out performance inspection by the evaluation regulation of GB/T20944.2-2007 anti-microbial properties
Survey；
The test of Candida albicans bacteriostasis rate carries out performance detection by the evaluation regulation of GB/T20944.2-2007 anti-microbial properties；
PH value test is detected using pH testers.
Table 1
It can be seen from above-mentioned middle data, antibacterial Tea stain detergent good antimicrobial effect produced by the present invention, toxicity is low, pH value journey weak base
State, and to be highly basic have corrosion function to respiratory tract, the skin of people to the pH value in comparative example, antibacterial tea stain produced by the present invention is clear
Clean dose will not produce injury to human body, have broad application prospects.
Claims (6)
1. a kind of preparation method of antibacterial Tea stain detergent, it is characterised in that specifically preparation process is：
（1）200~220g fruit of summer cypress is weighed, is placed in conical flask, 300~350mL deionized water dippings are added into conical flask,
Maceration extract is obtained, maceration extract is placed in ultrasonic cleaner, starts washer, cleaning, cleans repeatedly, obtain fruit of summer cypress medicine
Liquid, fruit of summer cypress decoction is filtered with non-woven fabrics, remove filter residue, obtain filtrate, filtrate is filtered, remove residue, received
Collection obtains extract solution, extract solution is transferred in evaporating dish, heat temperature raising, evaporation drying, obtains decoction powder；
（2）300~320g potatoes are weighed, ball milling in ball mill is placed in after chopping and obtains mashed potatoes, mashed potatoes is put into plastic tub
In, 1.0~1.2L water is added, stirring, mashed potatoes suspension is obtained, is filtered mashed potatoes suspension with gauze, filtrate is removed, obtains
Potato to the water containing part is starched, and potato is starched and stood, and layering, is removed upper liquid, mashed potatoes is obtained, by above-mentioned filtration step weight
It is multiple, mashed potatoes is placed in exposure on the plastic plate of dried and clean, obtains potato starch；
（3）Discarded shrimp shell is eluted with water, exposure is dried, and the shrimp shell of clean dried is obtained, by 100~120g clean drieds
Shrimp shell, which is placed in 200~230mL watery hydrochloric acid, soaks, and immersion takes out shrimp shell after terminating, and is in distillation water washing shrimp shell to cleaning solution
Neutrality, the shrimp shell of acidleach processing is obtained, the shrimp shell that acidleach is handled is placed in 120~150mL sodium hydroxide solutions, heating rises
Temperature, after boiling, filter off except filtrate obtains gel, gel is placed in baking oven, heat temperature raising, chitosan powder is obtained after drying
End；
（4）50~55g Chitosan powders are placed in beaker, acetum is added into beaker, obtain chitosan acid solution, by quality
The alkylamide propyl dimethyl amine alkali solution of beet that fraction is 20% mixes in equal volume with chitosan acid solution, is placed in high speed centrifugation
Centrifuged in machine, remove upper liquid, precipitated, precipitation is placed in baking oven, heat temperature raising, dried, obtain surface-active compounding
Thing；
（5）Count in parts by weight, by 20~30 parts of surface-active compounds, 50~60 parts of potato starches, 20~25 parts of decoction powder
End, 15~20 parts of Solid hydrogen peroxides, 100~120 parts of deionized water mixing, are placed in high speed dispersor high speed and disperse, mixed
Liquid is closed, is staticly settled, upper liquid is removed, lower sediment is placed in baking oven, heat temperature raising, dries, precipitation is placed in mortar
Grinding, it is antibacterial Tea stain detergent that sieving, which obtains powder,.
A kind of 2. preparation method of antibacterial Tea stain detergent according to claim 1, it is characterised in that：Step（1）It is described
Dip time be 22~24h, scavenging period is 15~20min, repeatedly wash number be 2~4 times, temperature is after heat temperature raising
45~50 DEG C, the evaporation drying time is 2~3h.
A kind of 3. preparation method of antibacterial Tea stain detergent according to claim 1, it is characterised in that：Step（2）It is described
Ball-milling Time be 30~40min, mixing time is 20~25min, and time of repose is 3~5h, and the number that repeats the above steps is 2
~3 times, the exposure time is 3~5 days.
A kind of 4. preparation method of antibacterial Tea stain detergent according to claim 1, it is characterised in that：Step（3）It is described
Exposure drying time be 2~3 days, the mass fraction of watery hydrochloric acid is 5%, and soak time is 2~3h, the matter of sodium hydroxide solution
It is 55% to measure fraction, and temperature is 100~110 DEG C after heat temperature raising, and digestion time be 4~5h, and temperature is 80 after baking oven heat temperature raising
~90 DEG C, drying time is 4~6h.
A kind of 5. preparation method of antibacterial Tea stain detergent according to claim 1, it is characterised in that：Step（4）It is described
Acetum mass fraction be 2%, add acetum until pH be 5.2~5.6, supercentrifuge rotating speed be 4000~
4200r/min, 15~20min of centrifugation time, temperature is 100~120 DEG C after baking oven heat temperature raising, and drying time is 2~3h.
A kind of 6. preparation method of antibacterial Tea stain detergent according to claim 1, it is characterised in that：Step（5）It is described
High speed dispersor rotating speed be 3000~3300r/min, high speed jitter time is 13~15min, staticly settle the time for 45~
50min, temperature is 35~40 DEG C after heat temperature raising, and drying time is 18~20h, and milling time is 20~25min, rule of sieving
Lattice are 100 mesh.
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| CN108383394A (en) * | 2018-02-10 | 2018-08-10 | 陈毅忠 | A kind of preparation method of thermal-insulation, self-cleaning glass-film |
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