CN107573231A - 一种3‑氯丙酸的生产方法 - Google Patents
一种3‑氯丙酸的生产方法 Download PDFInfo
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- CN107573231A CN107573231A CN201710892937.8A CN201710892937A CN107573231A CN 107573231 A CN107573231 A CN 107573231A CN 201710892937 A CN201710892937 A CN 201710892937A CN 107573231 A CN107573231 A CN 107573231A
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- QEYMMOKECZBKAC-UHFFFAOYSA-N 3-chloropropanoic acid Chemical compound OC(=O)CCCl QEYMMOKECZBKAC-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 58
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 33
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 31
- 238000010924 continuous production Methods 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 24
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 20
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 20
- 239000007789 gas Substances 0.000 claims description 19
- 229910000831 Steel Inorganic materials 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 17
- 239000010959 steel Substances 0.000 claims description 17
- 238000007599 discharging Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 4
- 238000003860 storage Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 3
- MTJGVAJYTOXFJH-UHFFFAOYSA-N 3-aminonaphthalene-1,5-disulfonic acid Chemical compound C1=CC=C(S(O)(=O)=O)C2=CC(N)=CC(S(O)(=O)=O)=C21 MTJGVAJYTOXFJH-UHFFFAOYSA-N 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- RIHODQKIOXUKLF-UHFFFAOYSA-N anisole;phenol Chemical compound OC1=CC=CC=C1.COC1=CC=CC=C1 RIHODQKIOXUKLF-UHFFFAOYSA-N 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 10
- 238000005265 energy consumption Methods 0.000 abstract description 2
- GAWAYYRQGQZKCR-UHFFFAOYSA-N 2-chloropropionic acid Chemical class CC(Cl)C(O)=O GAWAYYRQGQZKCR-UHFFFAOYSA-N 0.000 abstract 4
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229960003505 mequinol Drugs 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical class OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 description 1
- 238000010523 cascade reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 229960000380 propiolactone Drugs 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710892937.8A CN107573231B (zh) | 2017-09-27 | 2017-09-27 | 一种3-氯丙酸的生产方法 |
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| CN201710892937.8A CN107573231B (zh) | 2017-09-27 | 2017-09-27 | 一种3-氯丙酸的生产方法 |
Publications (2)
| Publication Number | Publication Date |
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| CN107573231A true CN107573231A (zh) | 2018-01-12 |
| CN107573231B CN107573231B (zh) | 2021-01-29 |
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| CN201710892937.8A Active CN107573231B (zh) | 2017-09-27 | 2017-09-27 | 一种3-氯丙酸的生产方法 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329202A (zh) * | 2018-03-16 | 2018-07-27 | 南昌大学 | 一种甘油酸制备3-碘丙酸的方法 |
| CN108329203A (zh) * | 2018-03-16 | 2018-07-27 | 南昌大学 | 一种甘油酸制备3-羟基丙酸的方法 |
| CN109534971A (zh) * | 2018-11-05 | 2019-03-29 | 宿迁市科莱博生物化学有限公司 | 5-氯茚酮生产装置及其生产方法 |
| CN109705026A (zh) * | 2019-02-25 | 2019-05-03 | 安徽国星生物化学有限公司 | 一种百草枯中间体连续化生产装置及生产方法 |
| CN113292413A (zh) * | 2021-06-08 | 2021-08-24 | 安徽星宇化工有限公司 | 一种3-氯丙酸的制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1138569A (zh) * | 1995-03-03 | 1996-12-25 | 埃勒夫阿托化学有限公司 | 3-氯代丙酸的制备方法 |
| CN1349969A (zh) * | 2000-10-20 | 2002-05-22 | 敖枝平 | 3－氯丙酰氯的制取方法 |
| CN1569799A (zh) * | 2004-04-23 | 2005-01-26 | 上海华谊丙烯酸有限公司 | 一种高纯3－氯丙酸的制备方法 |
| CN203235477U (zh) * | 2013-03-13 | 2013-10-16 | 南京师范大学 | 管式反应串联逆流反应装置 |
-
2017
- 2017-09-27 CN CN201710892937.8A patent/CN107573231B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1138569A (zh) * | 1995-03-03 | 1996-12-25 | 埃勒夫阿托化学有限公司 | 3-氯代丙酸的制备方法 |
| ATE181051T1 (de) * | 1995-03-03 | 1999-06-15 | Atochem Elf Sa | Verfahren zur herstellung von 3-chlorpropionsäure |
| CN1349969A (zh) * | 2000-10-20 | 2002-05-22 | 敖枝平 | 3－氯丙酰氯的制取方法 |
| CN1569799A (zh) * | 2004-04-23 | 2005-01-26 | 上海华谊丙烯酸有限公司 | 一种高纯3－氯丙酸的制备方法 |
| CN203235477U (zh) * | 2013-03-13 | 2013-10-16 | 南京师范大学 | 管式反应串联逆流反应装置 |
Non-Patent Citations (2)
| Title |
|---|
| 贡长生等，: "《绿色化学》", 30 June 2008, 华中科技大学出版社 * |
| 高金生，: "《功能材料及其应用手册》", 31 July 1991, 机械工业出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329202A (zh) * | 2018-03-16 | 2018-07-27 | 南昌大学 | 一种甘油酸制备3-碘丙酸的方法 |
| CN108329203A (zh) * | 2018-03-16 | 2018-07-27 | 南昌大学 | 一种甘油酸制备3-羟基丙酸的方法 |
| CN108329202B (zh) * | 2018-03-16 | 2021-07-20 | 南昌大学 | 一种甘油酸制备3-碘丙酸的方法 |
| CN109534971A (zh) * | 2018-11-05 | 2019-03-29 | 宿迁市科莱博生物化学有限公司 | 5-氯茚酮生产装置及其生产方法 |
| CN109534971B (zh) * | 2018-11-05 | 2021-12-28 | 宿迁市科莱博生物化学有限公司 | 5-氯茚酮生产装置及其生产方法 |
| CN109705026A (zh) * | 2019-02-25 | 2019-05-03 | 安徽国星生物化学有限公司 | 一种百草枯中间体连续化生产装置及生产方法 |
| CN113292413A (zh) * | 2021-06-08 | 2021-08-24 | 安徽星宇化工有限公司 | 一种3-氯丙酸的制备方法 |
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| Publication number | Publication date |
|---|---|
| CN107573231B (zh) | 2021-01-29 |
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Application publication date: 20180112 Assignee: Feile New Material Technology (Shandong) Co.,Ltd. Assignor: JINGCHU University OF TECHNOLOGY Contract record no.: X2023420000094 Denomination of invention: A production method of 3-chloropropionic acid Granted publication date: 20210129 License type: Common License Record date: 20230506 |
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Application publication date: 20180112 Assignee: Yunnan Goudeli Biotechnology Co.,Ltd. Assignor: JINGCHU University OF TECHNOLOGY Contract record no.: X2023420000118 Denomination of invention: A production method of 3-chloropropionic acid Granted publication date: 20210129 License type: Common License Record date: 20230519 Application publication date: 20180112 Assignee: Yunnan Benyi Biotechnology Co.,Ltd. Assignor: JINGCHU University OF TECHNOLOGY Contract record no.: X2023420000117 Denomination of invention: A production method of 3-chloropropionic acid Granted publication date: 20210129 License type: Common License Record date: 20230519 |
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Application publication date: 20180112 Assignee: Yunnan Benyi Lanche Environmental Protection Technology Co.,Ltd. Assignor: JINGCHU University OF TECHNOLOGY Contract record no.: X2023420000120 Denomination of invention: A production method of 3-chloropropionic acid Granted publication date: 20210129 License type: Common License Record date: 20230522 Application publication date: 20180112 Assignee: Yunnan Weiqiang An Biotechnology Co.,Ltd. Assignor: JINGCHU University OF TECHNOLOGY Contract record no.: X2023420000119 Denomination of invention: A production method of 3-chloropropionic acid Granted publication date: 20210129 License type: Common License Record date: 20230522 |
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Assignee: Feile New Material Technology (Shandong) Co.,Ltd. Assignor: JINGCHU University OF TECHNOLOGY Contract record no.: X2023420000094 Date of cancellation: 20230807 |
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Effective date of registration: 20240411 Address after: No. 317 Gongye 6th Road, Economic Development Zone, Yangxin County, Binzhou City, Shandong Province, 256600 Patentee after: Shandong Youying New Materials Co.,Ltd. Country or region after: China Address before: 448000 No.23 Xiangshan Avenue, Jingmen City, Hubei Province Patentee before: JINGCHU University OF TECHNOLOGY Country or region before: China |