CN107523044A - 一种无臭渔网的制备方法 - Google Patents

一种无臭渔网的制备方法 Download PDF

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CN107523044A
CN107523044A CN201710709931.2A CN201710709931A CN107523044A CN 107523044 A CN107523044 A CN 107523044A CN 201710709931 A CN201710709931 A CN 201710709931A CN 107523044 A CN107523044 A CN 107523044A
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odorless
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胡海燕
张俊
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Chaohu Junye Fishing Tackle Co Ltd
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Abstract

本发明公开一种无臭渔网的制备方法，包括以下操作步骤：（1）将艾叶、藿香、三桠苦、吴茱萸晒干后，加入至乙醇溶液中，加热回流提取2小时，将提取液过滤，滤过液回收乙醇后，制得中药提取液；（2）将树脂母粒、十二胺、四水偏硼酸钠、三氯乙基硅烷、3‑氨基邻苯二甲酰亚胺、偶联剂、增塑剂混合后，向其中加入中药提取液，混合搅拌均匀后，加入至塑料挤出机中，进行基础，牵伸，定型，纺织制得成品。本发明提供的无臭渔网的制备方法，操作简单，制得的无臭渔网，各项力学性能优异，耐腐蚀性能好，尤其是制得的渔网，无有机塑料的气味，使用后，鱼腥味也不易在渔网上残留，极大地延长了渔网的使用寿命。

Description

一种无臭渔网的制备方法
技术领域
本发明属于渔网制备技术领域，具体涉及一种无臭渔网的制备方法。
背景技术
我国渔网材料自六十年代初期逐步试用合成纤维材料以来，经过几十年的推广应用，基本上代替了原来棉麻材料，从目前国内外使用的渔网材料来看，品种分有聚酰胺（PA）、聚酯（PES）、聚乙烯（PE）、聚丙烯（PP），聚氯乙烯（PVC）、聚乙烯醇（PVA）、聚偏二氯乙烯（PVD）七类，从纤维形式来分：有单丝、复丝、裂膜纤维等，其品种和规格都比较齐全，纤维的强度指标与国外同类产品相比，除涤纶纤维差距较大以外，其他都比较接近。目前市售的普通渔网，在使用过程中，均存在着塑料气味较重和鱼腥味较重的现象，导致渔网在储存的过程中，易被微生物附着，进而加速了渔网的老化进程。
发明内容
为了解决上述问题，本发明提供一种无臭渔网的制备方法。
本发明是通过以下技术方案实现的。
一种无臭渔网的制备方法，包括以下操作步骤：
（1）将等重的艾叶、藿香、三桠苦、吴茱萸晒干后，加入至乙醇溶液中，加热回流提取2小时，将提取液过滤，滤过液回收乙醇后，制得中药提取液；
（2）按重量份计，将48-52份树脂母粒、11-15份十二胺、四水偏硼酸钠3-6份、三氯乙基硅烷2-5份、3-氨基邻苯二甲酰亚胺4-8份、偶联剂1-3份、增塑剂2-5份混合后，向其中加入步骤（1）所得的中药提取液，混合搅拌均匀后，加入至塑料挤出机中，进行基础，牵伸，定型，纺织制得成品。
具体地，上述步骤（2）中的树脂母粒为聚酰胺树脂母粒、聚乙烯树脂母粒、聚氯乙烯树脂母粒、聚氯乙烯树脂母粒中的任意一种。
具体地，上述偶联剂为钛酸酯偶联剂TMC-201、钛酸酯偶联剂TMC-102、钛酸酯偶联剂TMC-101中的任意一种。
具体地，上述增塑剂为邻苯二甲酸二辛酯、邻苯二甲酸二正辛酯、邻苯二甲酸二仲辛酯中的任意一种。
具体地，上述步骤（2）中中药提取液的添加量为树脂母粒质量的1-3%。
由以上的技术方案可知，本发明的有益效果是：
本发明提供的无臭渔网的制备方法，操作简单，制得的无臭渔网，各项力学性能优异，耐腐蚀性能好，尤其是制得的渔网，无有机塑料的气味，使用后，鱼腥味也不易在渔网上残留，极大地延长了渔网的使用寿命。其中，本发明提供的中药提取液，可有效的提升渔网的抗菌性能，并且其中的有效成分协同作用后，具有加速渔网上残留的鱼尸体分解速度的效果，可有效的避免鱼腥味物质在渔网表面残留；三氯乙基硅烷、3-氨基邻苯二甲酰亚胺协同作用后，可有效的避免渔网在使用过程中，渔网中有机塑料气味的散发，对其气味有特异性的吸附效果，进而有效的提升了渔网的品质。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下实施例对本发明进行进一步详细说明。应当理解，此处所描述的具体实施方例仅仅用以解释本发明，并不用于限定本发明。
实施例1
一种无臭渔网的制备方法，包括以下操作步骤：
（1）将等重的艾叶、藿香、三桠苦、吴茱萸晒干后，加入至乙醇溶液中，加热回流提取2小时，将提取液过滤，滤过液回收乙醇后，制得中药提取液；
（2）按重量份计，将48份树脂母粒、11份十二胺、四水偏硼酸钠3份、三氯乙基硅烷2份、3-氨基邻苯二甲酰亚胺4份、偶联剂1份、增塑剂2份混合后，向其中加入步骤（1）所得的中药提取液，混合搅拌均匀后，加入至塑料挤出机中，进行基础，牵伸，定型，纺织制得成品。
具体地，上述步骤（2）中的树脂母粒为聚酰胺树脂母粒。
具体地，上述偶联剂为钛酸酯偶联剂TMC-201。
具体地，上述增塑剂为邻苯二甲酸二辛酯。
具体地，上述步骤（2）中中药提取液的添加量为树脂母粒质量的1%。
实施例2
一种无臭渔网的制备方法，包括以下操作步骤：
（1）将等重的艾叶、藿香、三桠苦、吴茱萸晒干后，加入至乙醇溶液中，加热回流提取2小时，将提取液过滤，滤过液回收乙醇后，制得中药提取液；
（2）按重量份计，将50份树脂母粒、13份十二胺、四水偏硼酸钠5份、三氯乙基硅烷3份、3-氨基邻苯二甲酰亚胺6份、偶联剂2份、增塑剂3份混合后，向其中加入步骤（1）所得的中药提取液，混合搅拌均匀后，加入至塑料挤出机中，进行基础，牵伸，定型，纺织制得成品。
具体地，上述步骤（2）中的树脂母粒为聚乙烯树脂母粒。
具体地，上述偶联剂为钛酸酯偶联剂TMC-102。
具体地，上述增塑剂为邻苯二甲酸二正辛酯。
具体地，上述步骤（2）中中药提取液的添加量为树脂母粒质量的2%。
实施例3
一种无臭渔网的制备方法，包括以下操作步骤：
（1）将等重的艾叶、藿香、三桠苦、吴茱萸晒干后，加入至乙醇溶液中，加热回流提取2小时，将提取液过滤，滤过液回收乙醇后，制得中药提取液；
（2）按重量份计，将52份树脂母粒、15份十二胺、四水偏硼酸钠6份、三氯乙基硅烷5份、3-氨基邻苯二甲酰亚胺8份、偶联剂3份、增塑剂5份混合后，向其中加入步骤（1）所得的中药提取液，混合搅拌均匀后，加入至塑料挤出机中，进行基础，牵伸，定型，纺织制得成品。
具体地，上述步骤（2）中的树脂母粒为聚氯乙烯树脂母粒中。
具体地，上述偶联剂为钛酸酯偶联剂TMC-101。
具体地，上述增塑剂为邻苯二甲酸二仲辛酯。
具体地，上述步骤（2）中中药提取液的添加量为树脂母粒质量的3%。
分别用各实施例提供的方法制得渔网，并将制得的渔网和市售普通的渔网进行5次捕鱼操作后，清洗干净并晒干后进行储存，在储存的过程中查看渔网是否散发出刺激性气味，试验结果如表1所示：
表1 无臭渔网的制备方法效果验证
项目 有无腥臭味 有无刺激性塑料味
实施例1 无 无
实施例2 无 无
实施例3 无 无
对照组 味道较重 味道较轻
由表1可知，本发明提供的无臭渔网的制备方法，制得的渔网，在储存的过程中不易散发出鱼的腥臭味和刺激性的塑料味。
当然，上述说明并非是对本发明的限制，本发明也并不限于上述举例，本技术领域的普通技术人员，在本发明的实质范围内，作出的变化、改变、添加或替换，都应属于本发明的保护范围。

Claims (5)

1.一种无臭渔网的制备方法，其特征在于，包括以下操作步骤：
（1）将等重的艾叶、藿香、三桠苦、吴茱萸晒干后，加入至乙醇溶液中，加热回流提取2小时，将提取液过滤，滤过液回收乙醇后，制得中药提取液；
（2）按重量份计，将48-52份树脂母粒、11-15份十二胺、四水偏硼酸钠3-6份、三氯乙基硅烷2-5份、3-氨基邻苯二甲酰亚胺4-8份、偶联剂1-3份、增塑剂2-5份混合后，向其中加入步骤（1）所得的中药提取液，混合搅拌均匀后，加入至塑料挤出机中，进行基础，牵伸，定型，纺织制得成品。
2.根据权利要求1中所述的一种无臭渔网的制备方法，其特征在于，步骤（2）中的树脂母粒为聚酰胺树脂母粒、聚乙烯树脂母粒、聚氯乙烯树脂母粒、聚氯乙烯树脂母粒中的任意一种。
3.根据权利要求1中所述的一种无臭渔网的制备方法，其特征在于，上述偶联剂为钛酸酯偶联剂TMC-201、钛酸酯偶联剂TMC-102、钛酸酯偶联剂TMC-101中的任意一种。
4.根据权利要求1中所述的一种无臭渔网的制备方法，其特征在于，上述增塑剂为邻苯二甲酸二辛酯、邻苯二甲酸二正辛酯、邻苯二甲酸二仲辛酯中的任意一种。
5.根据权利要求1中所述的一种无臭渔网的制备方法，其特征在于，上述步骤（2）中中药提取液的添加量为树脂母粒质量的1-3%。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108691025A (zh) * 2018-04-11 2018-10-23 巢湖市瀚海渔具有限公司 一种磺酸酯改性远红外陶瓷粉末填充尼龙的渔网

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103757734A (zh) * 2013-12-11 2014-04-30 巢湖亚塑网具制造有限公司 一种增香诱鱼型渔网
CN105860236A (zh) * 2016-04-14 2016-08-17 巢湖市荷花渔网有限公司 一种高产捕鱼的渔网

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103757734A (zh) * 2013-12-11 2014-04-30 巢湖亚塑网具制造有限公司 一种增香诱鱼型渔网
CN105860236A (zh) * 2016-04-14 2016-08-17 巢湖市荷花渔网有限公司 一种高产捕鱼的渔网

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108691025A (zh) * 2018-04-11 2018-10-23 巢湖市瀚海渔具有限公司 一种磺酸酯改性远红外陶瓷粉末填充尼龙的渔网

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Application publication date: 20171229