CN107502981A - 一种羽绒服用抗菌防潮羽绒的加工工艺 - Google Patents

一种羽绒服用抗菌防潮羽绒的加工工艺 Download PDF

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CN107502981A
CN107502981A CN201710732789.3A CN201710732789A CN107502981A CN 107502981 A CN107502981 A CN 107502981A CN 201710732789 A CN201710732789 A CN 201710732789A CN 107502981 A CN107502981 A CN 107502981A
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王妍
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Haiyan Paitepu Technology Co Ltd
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Abstract

本发明公开了一种羽绒服用抗菌防潮羽绒的加工工艺,包括家禽羽毛80‑110份、鹅绒12‑17份、苎麻纤维35‑55份、整理液8‑10份、蛋白降解液4‑7份、三甲铵乙内酯0.5‑3.5份、纳米三氧化二铁0.2‑2.3份、海藻纤维纺丝液2.2‑3.8份、山梨醇0.1‑0.8份、水2‑4份,抗菌剂1‑4份,有益效果为:上述成分原料加工后能够使羽绒服抗菌效果好、透气性强、防潮;弹性好,手感柔,对皮肤无刺激性,亲和性好,且羽绒更加柔软、轻薄;成份配比合理,降低了生产成本,具有巨大的经济效益和社会效益。

Description

一种羽绒服用抗菌防潮羽绒的加工工艺
技术领域
本发明涉及纺织技术领域,具体是一种羽绒服用抗菌防潮羽绒的加工工艺。
背景技术
在现实生活中, 人们不可避免地要接触到各种各样的细菌、真菌等微生物。其中一些有害微生物在合适环境条件下会迅速生长繁殖, 并通过接触传播疾病, 影响人们的身体健康,日常生活中,人们使用的纺织品上一般都存在着微生物,它们在适宜的条件下迅速繁殖, 使纺织纤维表面附着杂色、变色、脆化、霉变、虫蛀等, 当织物与人体接触时, 还能引起人体皮肤感染。这些微生物分泌的酶还能分解汗水中的糖分、脂肪酸、皮脂和皮屑以及其它人体分泌物, 使织物产生臭味。
现有技术如授权公告号为CN 104070711 B的中国发明专利,公开了抗菌抗静电环保高弹面料的生产工艺,面料是由超细旦丙纶纤维和莫代尔纤维混纺成的粗细度为32-50S的混纺纱线添加粗细度为 20-30D 氨纶织造而成,面料中各成分重量比例为超细旦丙纶纤维占55-76%、莫代尔纤维占21-38%、氨纶占3-7%,其生产工艺如下:织造针织单面布→前处理→染色→脱水→剖幅→烘干→定型→成品;在染色过程中,采用两次染色,第一次主要对超细旦丙纶纤维进行染色,第二次主要对莫代尔纤维进行染色;在烘干中,烘干温度为90-100℃,速度为 10-15m/min;在定型中,定型温度为120-130℃,速度为 14-18m/min,其优点是:使面料具有抗菌、抗静电、环保、高弹等优良性能,但技术含量高,难度大,抗菌纤维的生产较为不易,对抗菌剂要求高。
发明内容
本发明的目的在于提供一种抗菌效果好、透气性好、防潮的一种羽绒服用抗菌防潮羽绒的加工工艺。
本发明针对上述技术中提到的问题,采取的技术方案为:一种羽绒服用抗菌防潮羽绒的加工工艺,抗菌防潮羽绒成分包括家禽羽毛80-110份、鹅绒12-17份、苎麻纤维35-55份、整理液8-10份、蛋白降解液4-7份、三甲铵乙内酯0.5-3.5份、纳米三氧化二铁0.2-2.3份、海藻纤维纺丝液2.2-3.8份、山梨醇0.1-0.8份、水2-4份,抗菌剂1-4份,上述成分原料加工后能够使羽绒服抗菌效果好、透气性强、防潮;弹性好,手感柔,对皮肤无刺激性,亲和性好,且羽绒更加柔软、轻薄;成份配比合理,降低了生产成本,具有巨大的经济效益和社会效益。
一种羽绒服用抗菌防潮羽绒的加工工艺,包括以下步骤:
按配方量称取家禽羽毛、鹅绒混合后,对其在150-200℃的环境下进行高压灭菌,冷却后在酒精中浸泡4-8小时,再用清水漂洗,然后在80-100℃的环境下对其进行烘干,最后研磨成粉末状备用;
在整理液中加入研磨好的羽毛粉搅拌均匀,在90-95℃环境下预烘1-1.5h,然后再在120-150℃的温度下进行烘干去溶剂,获得改性羽毛粉;
将改性羽毛粉加到蛋白降解液中,密封置于90-100℃下30-45min,然后用纱布去除残渣,得到羽毛角蛋白溶液备用;
按配方量加入三甲铵乙内酯、纳米三氧化二铁、海藻纤维纺丝液、山梨醇、水混合搅拌均匀,再将苎麻纤维经碱液浸泡后再经黄化处理成纤维素磺酸酯溶液,后加入三甲铵乙内酯混合溶液搅拌均匀,然后和备用羽毛蛋白溶液混合进行湿法纺丝得到羽毛蛋白粘胶丝;通过角蛋白溶液和经改性的苎麻纤维溶解液混合均匀进行纺丝,极大的增强了羽毛纤维的韧性、抗拉强度、脆性、耐磨性、可纺性等特性,添加的纳米三氧化二铁、海藻纤维、山梨醇互相作用能够增强羽绒纤维的透气、抗电磁波辐射、杀菌、防霉等方面的性能,对皮肤无刺激,制备方法简单,值得推广;
将得到的羽毛蛋白粘胶丝先后进行凝固浴处理、酸洗、水洗烘干得到蛋白羽毛纤维备用;
将得到的蛋白羽毛纤维浸渍到抗菌剂中,烘干处理后得到抗菌透气蛋白羽毛纤维,再将羽毛纤维做出人工羽绒。通过添加抗菌剂使羽绒具备抗菌、防潮、透气的特性。
蛋白降解液含有尿素4-8份、偏重亚硫酸钾0.1-0.5份、十二烷基硫酸钠0.02-0.4份、水2-4份,通过利用适宜配比制得的蛋白降解液使羽毛粉末溶解得到粘度、流变性较好的角蛋白溶液。
整理液包括硅烷偶联剂kh5906-9份、丙酮溶液55-60份,通过硅烷偶联剂改性得到整理液,使混合羽毛粉末具有优良的疏水的性能。
抗菌剂为一种抗菌纤维浸渍组合物,其主要组分按重量份计为:液体橡胶15-55份、异氰酸酯20-30份、单硬脂酸甘油酯9-21份、尼泊金乙酯1-2.5份、增塑剂12-19份、二氧化钛1-7份、超细二氧化硅2-9份、催化剂1-6份、三聚磷酸钠0.2-0.9份,抗菌增效剂1-6份。上述抗菌剂使用方法简单,通过浸渍液处理的织物,具有与橡胶一般良好的粘结性能和表面光滑,热处理温度低,因此能耗低,化学性能稳定,可降低生产的成本,提高成品率,处理后的织物涂层均匀,表面光滑,易编织和缠绕且抗菌效果稳定。
抗菌增效剂,包括磺胺氯达嗪钠58-60份、吲哚美辛钾1-6份、助悬剂12-20份、矫味剂1-6份,活性多肽1-2份,上述抗菌增效剂具有良好的流动性、混悬水溶性,溶解后容易倾倒、沉降缓慢、沉降后轻轻振摇能再分散,并且溶解后的混悬微粒的大小在水中长期贮存中保持不变,有效提升了抗菌剂抗菌活性使抗菌剂抗菌效力大幅提高。
活性多肽的氨基酸序列为SCASRRCSFRCRAGRCKGYACRSFGRRSRICKCFRC。在抗菌剂的成分中添加含有活性多肽的抗菌增效剂,可以通过抗菌肽分子中的疏水端插入质膜中,而刚性分子则不能完成这一步,然后两亲性的α螺旋也插入质膜中,从而破坏了脂质双层原有的有序结构,由于两亲性的存在,抗菌肽分子在质膜上形成通道,细菌因而便失去膜势,不能保持正常渗透压而死亡,从而达到抑菌、杀菌的效果。
与现有技术相比,本发明的优点在于:
1.本发明服装面料破坏细菌质膜,使细菌失去膜势,不能保持正常渗透压而死亡,从而达到抑菌的效果,且电导率高,利用织物中含有特种复合纱的导电特性来传导静电,防止了由于衣服产生静电而吸附灰尘黏附身体,给人以瘙痒等不适感;
2.添加的纳米三氧化二铁、海藻纤维、山梨醇互相作用能够增强羽绒纤维的透气、防潮、抗电磁波辐射、杀菌、防霉等方面的性能,对皮肤无刺激,制备方法简单,值得推广;
3.氨基酸序列为SCASRRCSFRCRAGRCKGYACRSFGRRSRICKCFRC的活性多肽。通过在抗菌剂的成分中添加含有活性多肽的抗菌增效剂,使抗菌肽分子中的疏水端插入质膜中,而刚性分子则不能完成这一步,然后两亲性的α螺旋也插入质膜中,从而破坏了脂质双层原有的有序结构,由于两亲性的存在,抗菌肽分子在质膜上形成通道,细菌因而便失去膜势,不能保持正常渗透压而死亡,从而达到抑菌、杀菌的效果;
4.该织物更有弹性,手感更好、穿着舒服,适合不同年龄段人群的服装面料。
具体实施方式
下面通过实施例对本发明作进一步说明:
实施例1:
一种羽绒服用抗菌防潮羽绒的加工工艺,抗菌防潮羽绒的成分包括家禽羽毛80-110份、鹅绒12-17份、苎麻纤维35-55份、整理液8-10份、蛋白降解液4-7份、三甲铵乙内酯0.5-3.5份、纳米三氧化二铁0.2-2.3份、海藻纤维纺丝液2.2-3.8份、山梨醇0.1-0.8份、水2-4份,抗菌剂1-4份。
一种羽绒服用抗菌防潮羽绒的加工工艺,包括以下步骤:
1)按配方量称取家禽羽毛、鹅绒混合后,对其在150-200℃的环境下进行高压灭菌,冷却后在酒精中浸泡4-8小时,再用清水漂洗,然后在80-100℃的环境下对其进行烘干,最后研磨成粉末状备用;
2)在整理液中加入研磨好的羽毛粉搅拌均匀,在90-95℃环境下预烘1-1.5h,然后再在120-150℃的温度下进行烘干去溶剂,获得改性羽毛粉;
3)将改性羽毛粉加到蛋白降解液中,密封置于90-100℃下30-45min,然后用纱布去除残渣,得到羽毛角蛋白溶液备用;
4)按配方量加入三甲铵乙内酯、纳米三氧化二铁、海藻纤维纺丝液、山梨醇、水混合搅拌均匀,再将苎麻纤维经碱液浸泡后再经黄化处理成纤维素磺酸酯溶液,后加入三甲铵乙内酯混合溶液搅拌均匀,然后和备用羽毛蛋白溶液混合进行湿法纺丝得到羽毛蛋白粘胶丝;
5)将得到的羽毛蛋白粘胶丝先后进行凝固浴处理、酸洗、水洗烘干得到蛋白羽毛纤维备用;
6)将得到的蛋白羽毛纤维浸渍到抗菌剂中,烘干处理后得到抗菌透气蛋白羽毛纤维,再将羽毛纤维做出人工羽绒。
蛋白降解液含有尿素4-8份、偏重亚硫酸钾0.1-0.5份、十二烷基硫酸钠0.02-0.4份、水2-4份。
整理液包括硅烷偶联剂kh5906-9份、丙酮溶液55-60份。
抗菌剂为一种抗菌纤维浸渍组合物,其主要组分按重量份计为:液体橡胶15-55份、异氰酸酯20-30份、单硬脂酸甘油酯9-21份、尼泊金乙酯1-2.5份、增塑剂12-19份、二氧化钛1-7份、超细二氧化硅2-9份、催化剂1-6份、三聚磷酸钠0.2-0.9份,抗菌增效剂1-6份。
抗菌增效剂,包括磺胺氯达嗪钠58-60份、吲哚美辛钾1-6份、助悬剂12-20份、矫味剂1-6份,活性多肽1-2份。
活性多肽的氨基酸序列为SCASRRCSFRCRAGRCKGYACRSFGRRSRICKCFRC。
实施例2:
一种羽绒服用抗菌防潮羽绒的最优加工工艺,抗菌防潮羽绒的成分包括家禽羽毛98份、鹅绒14份、苎麻纤维37份、整理液9份、蛋白降解液6份、三甲铵乙内酯2份、纳米三氧化二铁1.5份、海藻纤维纺丝液2.6份、山梨醇0.5份、水3份,抗菌剂3份。
一种羽绒服用抗菌防潮羽绒的加工工艺,包括以下步骤:
1)按配方量称取家禽羽毛、鹅绒混合后,对其在170℃的环境下进行高压灭菌,冷却后在酒精中浸泡6小时,再用清水漂洗,然后在90℃的环境下对其进行烘干,最后研磨成粉末状备用;
2)在整理液中加入研磨好的羽毛粉搅拌均匀,在95℃环境下预烘1.5h,然后再在120℃的温度下进行烘干去溶剂,获得改性羽毛粉;
3)将改性羽毛粉加到蛋白降解液中,密封置于100℃下30min,然后用纱布去除残渣,得到羽毛角蛋白溶液备用;
4)按配方量加入三甲铵乙内酯、纳米三氧化二铁、海藻纤维纺丝液、山梨醇、水混合搅拌均匀,再将苎麻纤维经碱液浸泡后再经黄化处理成纤维素磺酸酯溶液,后加入三甲铵乙内酯混合溶液搅拌均匀,然后和备用羽毛蛋白溶液混合进行湿法纺丝得到羽毛蛋白粘胶丝;
5)将得到的羽毛蛋白粘胶丝先后进行凝固浴处理、酸洗、水洗烘干得到蛋白羽毛纤维备用;
6)将得到的蛋白羽毛纤维浸渍到抗菌剂中,烘干处理后得到抗菌透气蛋白羽毛纤维,再将羽毛纤维做出人工羽绒。
蛋白降解液含有尿素5份、偏重亚硫酸钾0.3份、十二烷基硫酸钠0.2份、水3份。
整理液包括硅烷偶联剂kh5909份、丙酮溶液60份。
抗菌剂为一种抗菌纤维浸渍组合物,其主要组分按重量份计为:液体橡胶30份、异氰酸酯25份、单硬脂酸甘油酯16份、尼泊金乙酯2份、增塑剂16份、二氧化钛6份、超细二氧化硅5份、催化剂4份、三聚磷酸钠0.7份,抗菌增效剂4份。
抗菌增效剂,包括磺胺氯达嗪钠60份、吲哚美辛钾4份、助悬剂14份、矫味剂3份,活性多肽1.5份。
活性多肽的氨基酸序列为SCASRRCSFRCRAGRCKGYACRSFGRRSRICKCFRC。
实施例3:
一种羽绒服用抗菌防潮羽绒的加工工艺,抗菌防潮羽绒的成分包括家禽羽毛99份、鹅绒16份、苎麻纤维39份、整理液9份、蛋白降解液5份、三甲铵乙内酯2.3份、纳米三氧化二铁2.3份、海藻纤维纺丝液2.6份、山梨醇0.5份、水3份,抗菌剂4份。
一种羽绒服用抗菌防潮羽绒的加工工艺,包括以下步骤:
1)按配方量称取家禽羽毛、鹅绒混合后,对其在200℃的环境下进行高压灭菌,冷却后在酒精中浸泡4小时,再用清水漂洗,然后在100℃的环境下对其进行烘干,最后研磨成粉末状备用;
2)在整理液中加入研磨好的羽毛粉搅拌均匀,在95℃环境下预烘1h,然后再在120-150℃的温度下进行烘干去溶剂,获得改性羽毛粉;
3)将改性羽毛粉加到蛋白降解液中,密封置于90℃下45min,然后用纱布去除残渣,得到羽毛角蛋白溶液备用;
4)按配方量加入三甲铵乙内酯、纳米三氧化二铁、海藻纤维纺丝液、山梨醇、水混合搅拌均匀,再将苎麻纤维经碱液浸泡后再经黄化处理成纤维素磺酸酯溶液,后加入三甲铵乙内酯混合溶液搅拌均匀,然后和备用羽毛蛋白溶液混合进行湿法纺丝得到羽毛蛋白粘胶丝;
5)将得到的羽毛蛋白粘胶丝先后进行凝固浴处理、酸洗、水洗烘干得到蛋白羽毛纤维备用;
6)将得到的蛋白羽毛纤维浸渍到抗菌剂中,烘干处理后得到抗菌透气蛋白羽毛纤维,再将羽毛纤维做出人工羽绒。
蛋白降解液含有尿素8份、偏重亚硫酸钾0.5份、十二烷基硫酸钠0.4份、水3份。
整理液包括硅烷偶联剂kh5906-份、丙酮溶液56份。
抗菌剂为一种抗菌纤维浸渍组合物,其主要组分按重量份计为:液体橡胶15份、异氰酸酯20份、单硬脂酸甘油酯9份、尼泊金乙酯2.5份、增塑剂19份、二氧化钛1份、超细二氧化硅9份、催化剂3份、三聚磷酸钠0.4份,抗菌增效剂3份。
抗菌增效剂,包括磺胺氯达嗪钠60份、吲哚美辛钾4份、助悬剂16份、矫味剂3份,活性多肽1.5份。
活性多肽的氨基酸序列为SCASRRCSFRCRAGRCKGYACRSFGRRSRICKCFRC。
本发明的操作步骤中的常规操作为本领域技术人员所熟知,在此不进行赘述。
以上所述的实施例对本发明的技术方案进行了详细说明,应理解的是以上所述仅为本发明的具体实施例,并不用于限制本发明,凡在本发明的原则范围内所做的任何修改、补充或类似方式替代等,均应包含在本发明的保护范围之内。
序列表
<110> 海盐派特普科技有限公司
<120> 一种羽绒服用抗菌防潮羽绒的加工工艺
<160> 1
<170> SIPOSequenceListing 1.0
<210> 1
<211> 36
<212> PRT
<213> 人工合成(Mytilus coruscus)
<400> 1
Ser Cys Ala Ser Arg Arg Cys Ser Phe Arg Cys Arg Ala Gly Arg Cys
1 5 10 15
Lys Gly Tyr Ala Cys Arg Ser Phe Gly Arg Arg Ser Arg Ile Cys Lys
20 25 30
Cys Phe Arg Cys
35

Claims (7)

1.一种羽绒服用抗菌防潮羽绒的加工工艺,其特征在于:所述的抗菌防潮羽绒成分包括家禽羽毛80-110份、鹅绒12-17份、苎麻纤维35-55份、整理液8-10份、蛋白降解液4-7份、三甲铵乙内酯0.5-3.5份、纳米三氧化二铁0.2-2.3份、海藻纤维纺丝液2.2-3.8份、山梨醇0.1-0.8份、水2-4份,抗菌剂1-4份。
2.根据权利要求1所述的一种羽绒服用抗菌防潮羽绒的加工工艺,其特征在于:包括以下步骤:
1)按配方量称取家禽羽毛、鹅绒混合后,对其在150-200℃的环境下进行高压灭菌,冷却后在酒精中浸泡4-8小时,再用清水漂洗,然后在80-100℃的环境下对其进行烘干,最后研磨成粉末状备用;
2)在整理液中加入研磨好的羽毛粉搅拌均匀,在90-95℃环境下预烘1-1.5h,然后再在120-150℃的温度下进行烘干去溶剂,获得改性羽毛粉;
3)将改性羽毛粉加到蛋白降解液中,密封置于90-100℃下30-45min,然后用纱布去除残渣,得到羽毛角蛋白溶液备用;
4)按配方量加入三甲铵乙内酯、纳米三氧化二铁、海藻纤维纺丝液、山梨醇、水混合搅拌均匀,再将苎麻纤维经碱液浸泡后再经黄化处理成纤维素磺酸酯溶液,后加入三甲铵乙内酯混合溶液搅拌均匀,然后和备用羽毛蛋白溶液混合进行湿法纺丝得到羽毛蛋白粘胶丝;
5)将得到的羽毛蛋白粘胶丝先后进行凝固浴处理、酸洗、水洗烘干得到蛋白羽毛纤维备用;
6)将得到的蛋白羽毛纤维浸渍到抗菌剂中,烘干处理后得到抗菌透气蛋白羽毛纤维,再将羽毛纤维做出人工羽绒。
3.根据权利要求2所述的一种羽绒服用抗菌防潮羽绒的加工工艺,其特征在于:所述步骤3的蛋白降解液含有尿素4-8份、偏重亚硫酸钾0.1-0.5份、十二烷基硫酸钠0.02-0.4份、水2-4份。
4.根据权利要求2所述的一种羽绒服用抗菌防潮羽绒的加工工艺,其特征在于:所述步骤2的整理液包括硅烷偶联剂kh5906-9份、丙酮溶液55-60份。
5.根据权利要求1所述的一种羽绒服用抗菌防潮羽绒的加工工艺,其特征在于:所述的抗菌剂为一种抗菌纤维浸渍组合物,其主要组分按重量份计为:液体橡胶15-55份、异氰酸酯20-30份、单硬脂酸甘油酯9-21份、尼泊金乙酯1-2.5份、增塑剂12-19份、二氧化钛1-7份、超细二氧化硅2-9份、催化剂1-6份、三聚磷酸钠0.2-0.9份,抗菌增效剂1-6份。
6.根据权利要求5所述的一种羽绒服用抗菌防潮羽绒的加工工艺,其特征在于:所述抗菌增效剂,其主要组分按重量份计为:磺胺氯达嗪钠58-60份、吲哚美辛钾1-6份、助悬剂12-20份、矫味剂1-6份,活性多肽1-2份。
7.根据权利要求6所述的一种羽绒服用抗菌防潮羽绒的加工工艺,其特征在于:所述的活性多肽的氨基酸序列为SCASRRCSFRCRAGRCKGYACRSFGRRSRICKCFRC。
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CN114431689A (zh) * 2021-11-24 2022-05-06 吉祥三宝高科纺织有限公司 一种对婴童头部和颈部具有防护功能的护型枕
CN114431689B (zh) * 2021-11-24 2023-07-21 吉祥三宝高科纺织有限公司 一种对婴童头部和颈部具有防护功能的护型枕

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