WO2019085190A1 - 一种氧化石墨烯高保水抑菌面膜基布的制备方法 - Google Patents
一种氧化石墨烯高保水抑菌面膜基布的制备方法 Download PDFInfo
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- WO2019085190A1 WO2019085190A1 PCT/CN2017/116977 CN2017116977W WO2019085190A1 WO 2019085190 A1 WO2019085190 A1 WO 2019085190A1 CN 2017116977 W CN2017116977 W CN 2017116977W WO 2019085190 A1 WO2019085190 A1 WO 2019085190A1
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- graphene oxide
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- fiber web
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- layer fiber
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
- D04H1/43835—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/524—Preservatives
Definitions
- the invention relates to the field of textile and beauty products, in particular to a preparation method of a graphene oxide high water retention bacteriostatic mask base cloth.
- the mask is becoming more and more popular among consumers.
- the patch mask is mainly made of mask base fabric and nutritional essence.
- the conventional mask base fabric is usually opened and mixed with polyester staple fiber and viscose staple fiber, and then formed by cross-laying and then hydroentangled.
- an antiseptic antibacterial agent In order to control the bacterial growth on the mask for a long time, an antiseptic antibacterial agent must be artificially added to the nutritional essence.
- the added antiseptic antibacterial agent inhibits the proliferation of skin cells and has an adverse effect on the skin tissue that is contacted. This may cause the mask to have a certain degree of irritating effect on the skin when used, and even the skin. It causes irritation damage and even allergies.
- Graphene oxide (GO) has good antibacterial properties.
- Hu W et al., Shanghai Institute of Applied Physics, Chinese Academy of Sciences published an article in ACS Nano to study the antibacterial properties of graphene oxide (GO) and reduced graphene oxide (RGO) for the first time.
- GO and RGO are effective in inhibiting the growth of Escherichia coli and have little cytotoxicity.
- Graphene can react with the phospholipid molecules on the bacterial cell membrane to form a strong dispersion interaction, so that the phospholipid molecules on the cell membrane can be directly extracted on a large scale, and the bacteria are killed, thereby effectively playing an antibacterial effect.
- the present invention provides a method for preparing a graphene oxide high water retention bacteriostatic mask base fabric.
- a method for preparing a graphene oxide high water retention bacteriostatic mask base fabric wherein the base fabric consists of The nutrient layer fiber web and the hydrophobic skeleton layer fiber web are composited, and the nutrient layer fiber web is prepared by uniformly blending the graphene oxide nylon fiber and the biomass fiber through a spunlace nonwoven fabric process;
- the hydrophobic skeleton layer fiber web is prepared by subjecting the graphene oxide nylon fiber to a spunlace nonwoven fabric process.
- the graphene oxide nylon fiber accounts for 10-20% of the total weight of the nutrient layer fiber web
- the biomass fiber accounts for 80-90% of the total weight of the nutrient layer fiber web.
- the graphene oxide nylon fiber is made of graphene oxide as a raw material, and the percentage of graphene in the graphene oxide nylon fiber is 0.5-0.9%.
- the graphene oxide nylon fiber has a specification of 7.22 - 8.33 tex (65 - 75 D) / 36 F.
- biomass fiber is one or more of viscose, aloe fiber, copper ion fiber, seaweed fiber, hemp fiber or regenerated cellulose fiber.
- the nutrient layer fiber web is subjected to hydrophilic finishing, and the moisture wicking and decontaminating finishing agent is formulated into a 10-15% solution, and the nutrient layer fiber web is sprayed by 80 ° C infrared drying to increase the nutrient layer fiber.
- the hydrophilic, wicking and decontaminating ability of the net is subjected to hydrophilic finishing, and the moisture wicking and decontaminating finishing agent is formulated into a 10-15% solution, and the nutrient layer fiber web is sprayed by 80 ° C infrared drying to increase the nutrient layer fiber.
- the graphene oxide high water-retaining antibacterial mask base cloth of the invention has good skin-friendly property, antibacterial property, moisture retention property, simple structure, high production efficiency, low cost and safer use.
- the mask base fabric does not need preservatives, meets the requirements of green, ecological, environmental protection and health, and can obtain a relatively better facial skin care effect.
- the biomass fiber is used as a carrier of the nutrient solution and the guarantee of high water retention
- the hydrophilic layer of the nutrient layer fiber network is used to enhance the hydrophilicity, perspiration and decontamination ability of the nutrient layer fiber web
- the graphene oxide nylon fiber provides the nutrient solution.
- the antibacterial and antiseptic function while the linearity of the graphene oxide nylon fiber in the hydrophobic skeleton layer fiber network is small, forming a thin capillary tube, and the nutrient layer fiber web forms a thick capillary tube, and the fiber layer from the hydrophobic skeleton layer to the nutrient layer is formed therebetween.
- the single guide wetness of the net Conducive to increasing the nutrient layer fiber network Moisturizing and nutrient delivery efficiency to the face.
- a method for preparing a graphene oxide high water retention bacteriostatic mask base fabric wherein the base fabric is composed of a nutrient layer fiber web and a hydrophobic skeleton layer fiber web, wherein the nutrient layer fiber web is a graphene oxide nylon fiber and The biomass fiber is uniformly blended and prepared by a spunlace nonwoven fabric process; the hydrophobic skeleton layer fiber web is prepared by subjecting the graphene oxide nylon fiber to a spunlace nonwoven fabric process.
- the graphene oxide nylon fiber accounts for 20% of the total weight of the nutrient layer fiber web, and the biomass fiber accounts for 80% of the total weight of the nutrient layer fiber web.
- the graphene oxide nylon fiber is made of graphene oxide as a raw material, and the percentage of the graphene weight in the graphene oxide nylon fiber is 0.5%.
- the graphite oxide nylon fiber has a specification of 7.22 tex (65D) / 36F.
- the biomass fiber is one or more of viscose, aloe fiber, copper ion fiber, seaweed fiber, hemp fiber or regenerated cellulose fiber.
- the nutrient layer fiber web is subjected to hydrophilic finishing, and the moisture wicking and decontaminating finishing agent is formulated into a 10% solution, and the nutrient layer fiber web is sprayed by 80 ° C infrared drying to increase the hydrophilicity of the nutrient layer fiber web. Perspiration and decontamination ability.
- a method for preparing a graphene oxide high water retention bacteriostatic mask base fabric wherein the base fabric is composed of a nutrient layer fiber web and a hydrophobic skeleton layer fiber web, wherein the nutrient layer fiber web is a graphene oxide nylon fiber and The biomass fiber is uniformly blended and prepared by a spunlace nonwoven fabric process; the hydrophobic skeleton layer fiber web is prepared by subjecting the graphene oxide nylon fiber to a spunlace nonwoven fabric process.
- the graphene oxide nylon fiber accounts for 10% of the total weight of the nutrient layer fiber web, and the biomass fiber accounts for 90% of the total weight of the nutrient layer fiber web.
- the graphene oxide nylon fiber is made of graphene oxide, and the percentage content of graphene in the graphene oxide nylon fiber is 0.9%.
- the graphite oxide nylon fiber has a specification of 8.33 tex (75D) / 36F.
- the biomass fiber is one or more of viscose, aloe fiber, copper ion fiber, seaweed fiber, hemp fiber or regenerated cellulose fiber.
- the nutrient layer fiber web is subjected to hydrophilic finishing, the moisture wicking and easy decontamination finishing agent is formulated into a 15% solution, and the nutrient layer fiber web is sprayed by 80 ° C infrared drying to increase the hydrophilicity of the nutrient layer fiber web. Perspiration and decontamination ability.
- a method for preparing a graphene oxide high water retention bacteriostatic mask base fabric wherein the base fabric is composed of a nutrient layer fiber web and a hydrophobic skeleton layer fiber web, wherein the nutrient layer fiber web is a graphene oxide nylon fiber and The biomass fiber is uniformly blended and prepared by a spunlace nonwoven fabric process; the hydrophobic skeleton layer fiber web is prepared by subjecting the graphene oxide nylon fiber to a spunlace nonwoven fabric process.
- the graphene oxide nylon fiber accounts for 14% of the total weight of the nutrient layer fiber web, and the biomass fiber accounts for 87% of the total weight of the nutrient layer fiber web.
- the graphene oxide nylon fiber is made of graphene oxide, and the percentage content of graphene in the graphene oxide nylon fiber is 0.7%.
- the graphite oxide nylon fiber has a specification of 7.86 tex (69D) / 36F.
- the biomass fiber is one or more of viscose, aloe fiber, copper ion fiber, seaweed fiber, hemp fiber or regenerated cellulose fiber.
- the nutrient layer fiber web is subjected to hydrophilic finishing, the moisture wicking and easy decontamination finishing agent is formulated into a 13% solution, and the nutrient layer fiber web is sprayed by 80 ° C infrared drying to increase the hydrophilicity of the nutrient layer fiber web. Perspiration and decontamination ability.
- the graphene oxide high water retention bacteriostatic mask base fabric of the invention has good skin-friendly property, antibacterial property and moisture retention property, simple structure, high production efficiency, low cost and safer use.
- the mask base fabric does not need preservatives, meets the requirements of green, ecological, environmental protection and health, and can obtain a relatively better facial skin care effect.
- the biomass fiber is used as a carrier of the nutrient solution and the guarantee of high water retention
- the hydrophilic layer of the nutrient layer fiber network is used to enhance the hydrophilicity, perspiration and decontamination ability of the nutrient layer fiber web
- the graphene oxide nylon fiber provides the nutrient solution.
- the antibacterial and antiseptic function while the linearity of the graphene oxide nylon fiber in the hydrophobic skeleton layer fiber network is small, forming a thin capillary tube, and the nutrient layer fiber web forms a thick capillary tube, and the fiber layer from the hydrophobic skeleton layer to the nutrient layer is formed therebetween.
- the single guide wetness of the net It is beneficial to increase the moisture retention of the nutrient layer fiber web and the nutrient delivery efficiency to the face.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Medicinal Preparation (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Nonwoven Fabrics (AREA)
Abstract
一种氧化石墨烯高保水抑菌面膜基布的制备方法,所述基布由营养层纤维网和疏水骨架层纤维网复合而成,所述的营养层纤维网是将氧化石墨烯锦纶纤维与生物质纤维均匀共混,经过水刺无纺布工艺制备而成;所述的疏水骨架层纤维网是将氧化石墨烯锦纶纤维经过水刺无纺布工艺制备而成。氧化石墨烯高保水抑菌面膜基布亲肤性、抗菌性、保湿性性好,结构简单,生产效率高、成本低,使用更加安全。面膜基布无需采用防腐剂,符合绿色、生态、环保、健康的要求,能够获得相对更好的面部养颜护肤效果。
Description
本发明涉及纺织和美妆用品领域,具体涉及一种氧化石墨烯高保水抑菌面膜基布的制备方法。
面膜正越来越受到消费者的喜爱,贴式面膜主要由面膜基布,营养精华液制成。常规面膜基布通常采用涤纶短纤和粘胶短纤开松混和,然后经交叉铺网成形,再经水刺缠结制成。为了长时间控制面膜上细菌繁殖,营养精华液中必须人为添加防腐抗菌剂。但所加的防腐抗菌剂对皮肤细胞增殖进行抑制,对接触的皮肤组织造成不良影响,这有可能使得面膜在使用的时候会不同程度存在对皮肤产生一定刺激作用、兹生细菌,甚至对皮肤产生刺激损害,以至发生过敏现象等情况。
因此为了提高面膜使用的安全性,需要在面膜基布的原材料选择上进行改进,使面膜基布自身具有一定的抗菌功能。氧化石墨烯(GO)具有良好的抗菌性能。2010年中国科学院上海应用物理研究所Hu W等人在ACS Nano发表文章,首次研究了氧化石墨烯(GO)、还原氧化石墨烯(RGO)的抗菌性能。GO、RGO能够有效地抑制大肠埃希菌的生长,并且细胞毒性很小。石墨烯可以与细菌细胞膜上的磷脂分子发生很强的色散相互作用,因而能够大规模直接抽取细胞膜上的磷脂分子,将细菌杀死,有效起到抗菌作用。
发明内容
发明目的:本发明提供一种氧化石墨烯高保水抑菌面膜基布的制备方法。
技术方案:一种氧化石墨烯高保水抑菌面膜基布的制备方法,所述基布由
营养层纤维网和疏水骨架层纤维网复合而成,所述的营养层纤维网是将氧化石墨烯锦纶纤维与生物质纤维均匀共混,经过水刺无纺布工艺制备而成;所述的疏水骨架层纤维网是将氧化石墨烯锦纶纤维经过水刺无纺布工艺制备而成。
进一步的,所述的氧化石墨烯锦纶纤维占营养层纤维网总重量的10-20%,生物质纤维占营养层纤维网总重量的80-90%。
进一步的,所述的氧化石墨烯锦纶纤维为以氧化石墨烯为原料,所述的氧化石墨烯锦纶纤维中石墨烯重量的百分比含量为0.5-0.9%。
进一步的,所述的氧化石墨烯锦纶纤维规格为7.22-8.33tex(65-75D)/36F。
进一步的,所述的生物质纤维为粘胶、芦荟纤维、铜离子纤维、海藻纤维、麻浆纤维或再生纤维素纤维中的一种或几种。
进一步的,所述的营养层纤维网进行亲水整理,将吸湿排汗易去污整理剂配制成10-15%的溶液,对营养层纤维网进行喷涂80℃红外烘干,增加营养层纤维网的亲水、排汗、去污能力。
有益效果:本发明中的氧化石墨烯高保水抑菌面膜基布亲肤性、抗菌性、保湿性性好,结构简单,生产效率高、成本低,使用更加安全。面膜基布无需采用防腐剂,符合绿色、生态、环保、健康的要求,能够获得相对更好的面部养颜护肤效果。
本发明中生物质纤维作为营养液的载体及高保水的保障,对营养层纤维网进行亲水整理增进营养层纤维网的亲水、排汗、去污能力,氧化石墨烯锦纶纤维提供营养液的抗菌、防腐功能,同时疏水骨架层纤维网中氧化石墨烯锦纶纤维线密度小,形成较细毛细管,营养层纤维网形成较粗毛细管,两者间形成由疏水骨架层纤维网向营养层纤维网的单向导湿性。有利于增加营养层纤维网的
保湿性及向面部的营养输送效率。
下面将对本发明实施例中的技术方案进行清楚、完整地描述,以使本领域的技术人员能够更好的理解本发明的优点和特征,从而对本发明的保护范围做出更为清楚的界定。本发明所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例,基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例1
一种氧化石墨烯高保水抑菌面膜基布的制备方法,所述基布由营养层纤维网和疏水骨架层纤维网复合而成,所述的营养层纤维网是将氧化石墨烯锦纶纤维与生物质纤维均匀共混,经过水刺无纺布工艺制备而成;所述的疏水骨架层纤维网是将氧化石墨烯锦纶纤维经过水刺无纺布工艺制备而成。
所述的氧化石墨烯锦纶纤维占营养层纤维网总重量的20%,生物质纤维占营养层纤维网总重量的80%。
所述的氧化石墨烯锦纶纤维为以氧化石墨烯为原料,所述的氧化石墨烯锦纶纤维中石墨烯重量的百分比含量为0.5%。
所述的氧化石墨烯锦纶纤维规格为7.22tex(65D)/36F。
所述的生物质纤维为粘胶、芦荟纤维、铜离子纤维、海藻纤维、麻浆纤维或再生纤维素纤维中的一种或几种。
所述的营养层纤维网进行亲水整理,将吸湿排汗易去污整理剂配制成10%的溶液,对营养层纤维网进行喷涂80℃红外烘干,增加营养层纤维网的亲水、排汗、去污能力。
实施例2
一种氧化石墨烯高保水抑菌面膜基布的制备方法,所述基布由营养层纤维网和疏水骨架层纤维网复合而成,所述的营养层纤维网是将氧化石墨烯锦纶纤维与生物质纤维均匀共混,经过水刺无纺布工艺制备而成;所述的疏水骨架层纤维网是将氧化石墨烯锦纶纤维经过水刺无纺布工艺制备而成。
所述的氧化石墨烯锦纶纤维占营养层纤维网总重量的10%,生物质纤维占营养层纤维网总重量的90%。
所述的氧化石墨烯锦纶纤维为以氧化石墨烯为原料,所述的氧化石墨烯锦纶纤维中石墨烯重量的百分比含量为0.9%。
所述的氧化石墨烯锦纶纤维规格为8.33tex(75D)/36F。
所述的生物质纤维为粘胶、芦荟纤维、铜离子纤维、海藻纤维、麻浆纤维或再生纤维素纤维中的一种或几种。
所述的营养层纤维网进行亲水整理,将吸湿排汗易去污整理剂配制成15%的溶液,对营养层纤维网进行喷涂80℃红外烘干,增加营养层纤维网的亲水、排汗、去污能力。
实施例3
一种氧化石墨烯高保水抑菌面膜基布的制备方法,所述基布由营养层纤维网和疏水骨架层纤维网复合而成,所述的营养层纤维网是将氧化石墨烯锦纶纤维与生物质纤维均匀共混,经过水刺无纺布工艺制备而成;所述的疏水骨架层纤维网是将氧化石墨烯锦纶纤维经过水刺无纺布工艺制备而成。
所述的氧化石墨烯锦纶纤维占营养层纤维网总重量的14%,生物质纤维占营养层纤维网总重量的87%。
所述的氧化石墨烯锦纶纤维为以氧化石墨烯为原料,所述的氧化石墨烯锦纶纤维中石墨烯重量的百分比含量为0.7%。
所述的氧化石墨烯锦纶纤维规格为7.86tex(69D)/36F。
所述的生物质纤维为粘胶、芦荟纤维、铜离子纤维、海藻纤维、麻浆纤维或再生纤维素纤维中的一种或几种。
所述的营养层纤维网进行亲水整理,将吸湿排汗易去污整理剂配制成13%的溶液,对营养层纤维网进行喷涂80℃红外烘干,增加营养层纤维网的亲水、排汗、去污能力。
本发明中的氧化石墨烯高保水抑菌面膜基布亲肤性、抗菌性、保湿性性好,结构简单,生产效率高、成本低,使用更加安全。面膜基布无需采用防腐剂,符合绿色、生态、环保、健康的要求,能够获得相对更好的面部养颜护肤效果。
本发明中生物质纤维作为营养液的载体及高保水的保障,对营养层纤维网进行亲水整理增进营养层纤维网的亲水、排汗、去污能力,氧化石墨烯锦纶纤维提供营养液的抗菌、防腐功能,同时疏水骨架层纤维网中氧化石墨烯锦纶纤维线密度小,形成较细毛细管,营养层纤维网形成较粗毛细管,两者间形成由疏水骨架层纤维网向营养层纤维网的单向导湿性。有利于增加营养层纤维网的保湿性及向面部的营养输送效率。
Claims (6)
- 一种氧化石墨烯高保水抑菌面膜基布的制备方法,其特征在于:所述基布由营养层纤维网和疏水骨架层纤维网复合而成,所述的营养层纤维网是将氧化石墨烯锦纶纤维与生物质纤维均匀共混,经过水刺无纺布工艺制备而成;所述的疏水骨架层纤维网是将氧化石墨烯锦纶纤维经过水刺无纺布工艺制备而成。
- 根据权利要求1所述的氧化石墨烯高保水抑菌面膜基布的制备方法,其特征在于:所述的氧化石墨烯锦纶纤维占营养层纤维网总重量的10-20%,生物质纤维占营养层纤维网总重量的80-90%。
- 根据权利要求2所述的氧化石墨烯高保水抑菌面膜基布的制备方法,其特征在于:所述的氧化石墨烯锦纶纤维为以氧化石墨烯为原料,所述的氧化石墨烯锦纶纤维中石墨烯重量的百分比含量为0.5-0.9%。
- 根据权利要求3所述的氧化石墨烯高保水抑菌面膜基布的制备方法,其特征在于:所述的氧化石墨烯锦纶纤维规格为7.22-8.33tex(65-75D)/36F。
- 根据权利要求1所述的氧化石墨烯高保水抑菌面膜基布的制备方法,其特征在于:所述的生物质纤维为粘胶、芦荟纤维、铜离子纤维、海藻纤维、麻浆纤维或再生纤维素纤维中的一种或几种。
- 根据权利要求1所述的氧化石墨烯高保水抑菌面膜基布的制备方法,其特征在于:所述的营养层纤维网进行亲水整理,将吸湿排汗易去污整理剂配制成10-15%的溶液,对营养层纤维网进行喷涂80℃红外烘干,增加营养层纤维网的亲水、排汗、去污能力。
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