CN107502467A - 一种具有抗再沉积功能的透明液体洗涤剂组合物及制法 - Google Patents
一种具有抗再沉积功能的透明液体洗涤剂组合物及制法 Download PDFInfo
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- CN107502467A CN107502467A CN201710776686.7A CN201710776686A CN107502467A CN 107502467 A CN107502467 A CN 107502467A CN 201710776686 A CN201710776686 A CN 201710776686A CN 107502467 A CN107502467 A CN 107502467A
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- liquid detergent
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- 239000003599 detergent Substances 0.000 title claims abstract description 34
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims description 12
- 238000005406 washing Methods 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 17
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 102000004190 Enzymes Human genes 0.000 claims abstract description 16
- 108090000790 Enzymes Proteins 0.000 claims abstract description 16
- 239000006081 fluorescent whitening agent Substances 0.000 claims abstract description 15
- 239000003755 preservative agent Substances 0.000 claims abstract description 15
- 230000002335 preservative effect Effects 0.000 claims abstract description 15
- 238000003756 stirring Methods 0.000 claims description 20
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 7
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 7
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- -1 sodium alkyl benzene Chemical class 0.000 claims description 5
- 229920000881 Modified starch Polymers 0.000 claims description 4
- 239000004368 Modified starch Substances 0.000 claims description 4
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 4
- 235000019426 modified starch Nutrition 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical group O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- 238000007046 ethoxylation reaction Methods 0.000 claims 1
- 238000003860 storage Methods 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 description 8
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 229940124274 edetate disodium Drugs 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- CVOFKRWYWCSDMA-UHFFFAOYSA-N 2-chloro-n-(2,6-diethylphenyl)-n-(methoxymethyl)acetamide;2,6-dinitro-n,n-dipropyl-4-(trifluoromethyl)aniline Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl.CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O CVOFKRWYWCSDMA-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 101150096185 PAAS gene Proteins 0.000 description 1
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- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
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Abstract
一种具有抗再沉积功能的透明液体洗涤剂组合物的重量百分比组成为阴离子表面活性剂11.0～16.0wt%；非离子表面活性剂4.0～8.0wt%；抗再沉积剂0.5～3.0wt%；洗涤助剂0.5～5.0wt%；荧光增白剂0.01～0.1wt%；防腐剂0.01～0.1wt%；洗涤用酶0.01～1.0wt%；其余为水。本发明具有溶解性和透明性好、不分层，储存稳定性好的优点。
Description
技术领域
本发明属于一种具有抗再沉积功能的透明液体洗涤剂组合物及制备方法。
背景技术
液体洗涤剂始于二十世纪四十年代末；七、八十年代得到较快发展和普及；到了九十年代，伴随着科学技术的进步，液体洗涤剂的品种和功能不断变化，在洗涤用品中所占的比例快速上升。液体洗涤剂由活性成分和辅助成分构成。活性成分一般为表面活性剂，是洗涤过程中去除污垢的主要成分；而辅助成分主要由各种助剂组成，如螯合剂、增稠剂、防腐剂、酶制剂和抗再沉积剂等，主要起到降低水中Ca2+和Mg2+的浓度、稳定洗涤液的pH值和调节洗涤液的粘稠度等作用。
织物多次洗涤后由于污垢在织物表面的沉积使得织物表面硬化、色泽暗淡以及织物的使用寿命降低，在洗涤剂中添加抗再沉积剂能够有效的解决这些问题。抗再沉积剂是指能够防止洗涤下来的污垢再次沉淀于被洗物上，将污垢悬浮于洗涤剂中的物质。抗再沉积剂有两个作用：一是抗污垢沉积，抗再沉积剂能够将污垢包围起来，分散在水中，防止了污垢和织物的吸附接触；二是抗无机盐沉积，抗再沉积剂能够螯合无机盐离子，减少了无机盐晶核的形成和晶体的生长，从而降低了不溶性无机盐在织物表面的沉积。因此开发具有抗再沉积性能的洗涤剂，对于洗涤后织物的颜色、织物的手感及织物的使用寿命都具有重要的现实意义。
现有技术将抗再沉积剂加入到液体洗涤剂中，洗涤剂的溶解性和透明性变差，致使洗涤剂分层。
发明内容
本发明提供一种加入抗再沉积剂的洗涤剂溶解性和透明性无变化，洗涤剂无分层的具有抗再沉积功能的透明液体洗涤剂组合物及制备方法。
本发明是包含一种抗再沉积剂的液体洗涤剂组合物，其液体洗涤剂组合物外观浅黄色透明、具有优异的抗再沉积性能。
本发明具有抗再沉积功能的透明液体洗涤剂组合物，其重量百分比组成如下：
a)阴离子表面活性剂11.0～16.0wt％；
b)非离子表面活性剂4.0～8.0wt％；
c)抗再沉积剂0.5～3.0wt％；
d)洗涤助剂0.5～5.0wt％；
e)荧光增白剂0.01～0.1wt％；
f)防腐剂0.01～0.1wt％；
g)洗涤用酶0.01～1.0wt％；
h)其余为水。
如上所述的阴离子表面活性剂包括：烷基苯磺酸钠(LAS)、脂肪酸甲酯磺酸盐(MES)、脂肪醇聚氧乙烯醚硫酸盐(AES)、α-烯基磺酸盐(AOS)或脂肪醇聚氧乙烯醚羧酸盐(AEC)中的两种。
如上所述的的非离子表面活性剂包括：烷基糖苷APG(C12－14)、脂肪醇聚氧乙烯醚(AEO7或AEO9)、脂肪酸甲酯乙氧基化物(FMEE)或改性油脂乙氧基化物中的一种。
如上所述的抗再沉积剂包括：聚乙烯吡咯烷酮(PVP)、羧甲基纤维素钠(CMC)、聚丙烯酸钠(PAA)、聚乙烯醇(PVA)、改性淀粉中的任意两种组成的混合物。
如上所述的洗涤助剂包括柠檬酸钠、碳酸钠、层状硅酸钠、单乙醇胺、三乙醇胺、乙二胺四乙酸二钠(EDTA)中的一种或两种组成的混合物。
本发明制备方法包括如下步骤：
在30～80℃下，将洗涤助剂和抗再沉积剂加入水中，充分搅拌至上述物料全部溶解，然后在300～1000r/min的搅拌速度下，加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后，加入荧光增白剂，继续搅拌30～50min，冷却至室温，加入洗涤用酶和防腐剂，继续搅拌60～240min，至产品呈均匀透明状态，即得到所要的液体洗涤剂组合物。
本发明与现有技术相比具有如下优点：
1.本发明的液体洗涤剂的溶解性和透明性好、不分层，储存稳定性好。
2.复配抗再沉积剂的抗再沉积性能优于单一抗再沉积剂。
具体实施方式
实施例1
a)阴离子表面活性剂LAS占8.0wt％，MES占3.0wt％；
b)非离子表面活性剂AEO7占4.0wt％；
c)聚乙烯醇PVA占0.5wt％；
d)羧甲基纤维素钠CMC占0.5wt％；
e)碳酸钠占0.4wt％；
f)柠檬酸钠占0.1wt％；
g)荧光增白剂占0.01wt％；
h)防腐剂占0.03wt％；
i)洗涤用酶占0.5wt％；
j)其余为水。
制备方法为：30℃下，将洗涤助剂和抗再沉积剂加入水中，充分搅拌至上述物料全部溶解，然后在400r/min的搅拌速度下，加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后，加入荧光增白剂，继续搅拌45min，冷却至室温，加入洗涤用酶和防腐剂，继续搅拌240min，至产品呈均匀透明状态，即得到所要的液体洗涤剂组合物。
实施例2
a)阴离子表面活性剂MES占11.0wt％，AES占5.0wt％；
b)非离子表面活性剂AEO9占8.0wt％；
c)聚乙烯吡咯烷酮PVP占2.0wt％；
d)聚丙烯酸钠PAAS占0.5wt％；
e)碳酸钠占4.0wt％；
f)乙二胺四乙酸二钠EDTA占1.0wt％；
g)荧光增白剂占0.04wt％；
h)防腐剂占0.07wt％；
i)洗涤用酶占0.01wt％；
j)其余为水。
制备方法为：60℃下，将洗涤助剂和抗再沉积剂加入水中，充分搅拌至上述物料全部溶解，然后在800r/min的搅拌速度下，加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后，加入荧光增白剂，继续搅拌35min，冷却至室温，加入洗涤用酶和防腐剂，继续搅拌160min，至产品呈均匀透明状态，即得到所要的液体洗涤剂组合物。
实施例3
a)阴离子表面活性剂MES占10.0wt％，AOS占3.0wt％；
b)非离子表面活性剂APG(C12～14)占6.0wt％；
c)聚乙烯醇PVA占1.5wt％；
d)聚丙烯酸钠PAA占0.5wt％；
e)碳酸钠占1.5wt％；
f)层状硅酸钠占1.0wt％；
g)荧光增白剂占0.08wt％；
h)防腐剂占0.01wt％；
i)洗涤用酶占0.3wt％；
j)其余为水。
制备方法为：55℃下，将洗涤助剂和抗再沉积剂加入水中，充分搅拌至上述物料全部溶解，然后在600r/min的搅拌速度下，加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后，加入荧光增白剂，继续搅拌50min，冷却至室温，加入洗涤用酶和防腐剂，继续搅拌200min，至产品呈均匀透明状态，即得到所要的液体洗涤剂组合物。
实施例4
a)阴离子表面活性剂LAS占7.0wt％，AEC占5.0wt％；
b)非离子表面活性剂FMEE占5.0wt％；
c)聚乙烯吡咯烷酮PVP占2.5wt％；
d)改性淀粉占0.5wt％；
e)碳酸钠占1.0wt％；
f)单乙醇胺占0.5wt％；
g)荧光增白剂占0.1wt％；
h)防腐剂占0.05wt％；
i)洗涤用酶占0.7wt％；
j)其余为水。
制备方法为：40℃下，将洗涤助剂和抗再沉积剂加入水中，充分搅拌至上述物料全部溶解，然后在1000r/min的搅拌速度下，加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后，加入荧光增白剂，继续搅拌40min，冷却至室温，加入洗涤用酶和防腐剂，继续搅拌120min，至产品呈均匀透明状态，即得到所要的液体洗涤剂组合物。
实施例5
a)阴离子表面活性剂MES占9.0wt％，AEC占5.0wt％；
b)非离子表面活性剂改性油脂乙氧基化物占7.0wt％；
c)羧甲基纤维素钠CMC占0.4wt％；
d)改性淀粉占0.1wt％；
e)碳酸钠占1.5wt％；
f)三乙醇胺占2.0wt％；
g)荧光增白剂占0.05wt％；
h)防腐剂占0.1wt％；
i)洗涤用酶占1.0wt％；
j)其余为水。
制备方法为：80℃下，将洗涤助剂和抗再沉积剂加入水中，充分搅拌至上述物料全部溶解，然后在300r/min的搅拌速度下，加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后，加入荧光增白剂，继续搅拌30min，冷却至室温，加入洗涤用酶和防腐剂，继续搅拌60min，至产品呈均匀透明状态，即得到所要的液体洗涤剂组合物。
Claims (7)
1.一种具有抗再沉积功能的透明液体洗涤剂组合物，其特征在于重量百分比组成如下：
a）阴离子表面活性剂11.0～16.0wt%；
b）非离子表面活性剂4.0～8.0wt%；
c）抗再沉积剂0.5～3.0wt%；
d）洗涤助剂0.5～5.0wt%；
e）荧光增白剂0.01～0.1wt%；
f）防腐剂0.01～0.1wt%；
g）洗涤用酶0.01～1.0wt%；
h）其余为水。
2.如权利要求1所述的一种具有抗再沉积功能的透明液体洗涤剂组合物，其特征在于所述的阴离子表面活性剂为烷基苯磺酸钠、脂肪酸甲酯磺酸盐、脂肪醇聚氧乙烯醚硫酸盐、α-烯基磺酸盐、脂肪醇聚氧乙烯醚羧酸盐中的两种。
3.如权利要求1所述的一种具有抗再沉积功能的透明液体洗涤剂组合物，其特征在于所述的的非离子表面活性剂包括：烷基糖苷APG、脂肪醇聚氧乙烯醚、脂肪酸甲酯乙氧基化物或改性油脂乙氧基化物中的一种。
4.如权利要求3所述的一种具有抗再沉积功能的透明液体洗涤剂组合物，其特征在于所述的烷基糖苷为C12－14的烷基糖苷、脂肪醇聚氧乙烯醚为AEO7或AEO9。
5.如权利要求1所述的一种具有抗再沉积功能的透明液体洗涤剂组合物，其特征在于所述的抗再沉积剂为聚乙烯吡咯烷酮、羧甲基纤维素钠、聚丙烯酸钠、聚乙烯醇、改性淀粉中的任意两种组成的混合物。
6.如权利要求1所述的一种具有抗再沉积功能的透明液体洗涤剂组合物，其特征在于所述的洗涤助剂为柠檬酸钠、碳酸钠、层状硅酸钠、单乙醇胺、三乙醇胺、乙二胺四乙酸二钠中的一种或两种组成的混合物。
7.如权利要求1－6任一项所述的一种具有抗再沉积功能的透明液体洗涤剂组合物的制备方法，其特征在于包括如下步骤：
在30～80℃下，将洗涤助剂和抗再沉积剂加入水中，充分搅拌至上述物料全部溶解，然后在300～1000r/min的搅拌速度下，加入非离子表面活性剂和阴离子表面活性剂，搅拌均匀后，加入荧光增白剂，继续搅拌30～50min，冷却至室温，加入洗涤用酶和防腐剂，继续搅拌60～240min，至产品呈均匀透明状态，即得到所要的液体洗涤剂组合物。
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Application publication date: 20171222 |