CN107501528A - 石墨烯聚(5‑醛基吲哚)纳米复合材料的制备 - Google Patents
石墨烯聚(5‑醛基吲哚)纳米复合材料的制备 Download PDFInfo
- Publication number
- CN107501528A CN107501528A CN201710796580.3A CN201710796580A CN107501528A CN 107501528 A CN107501528 A CN 107501528A CN 201710796580 A CN201710796580 A CN 201710796580A CN 107501528 A CN107501528 A CN 107501528A
- Authority
- CN
- China
- Prior art keywords
- graphene
- poly
- composite material
- indoles
- nano composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/11—Homopolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/14—Side-groups
- C08G2261/142—Side-chains containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
- C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
- C08G2261/3241—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more nitrogen atoms as the only heteroatom, e.g. carbazole
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/44—Electrochemical polymerisation, i.e. oxidative or reductive coupling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
本发明涉及石墨烯聚(5‑醛基吲哚)纳米复合材料的制备,包括:首先,在0.5‑0.7mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积,沉积电压为‑1.8V,至此,化学还原的氧化石墨烯被修饰在了ITO导电玻璃上;然后,在含0.1‑0.3mol L‑1 TBATFB的乙腈溶液中采用一室三电极体系,工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃,使0.02‑0.04mol L‑1 5‑醛基吲哚1.35V的电压下进行电化学聚合,从而制备石墨烯聚(5‑醛基吲哚)纳米复合材料。
Description
技术领域
本发明涉及石墨烯聚(5-醛基吲哚)纳米复合材料的制备,属于材料化学领域。
背景技术
顺应研究需要,各种电致变色材料也相继被发现,如聚噻吩、聚吡咯、聚咔唑等。聚吲哚家族因其独特优势得到了人们的关注,特别是热稳定性好、电致发光性能稳定、氧化还原活性高等。一般来说,在聚合难易程度上,导电聚合物单体中有反应活性功能基团的要比没有取代基团的更易反应;在电致变色性能上,一般由掺杂决定。为了改善其稳定性,近年来人们对该材料的研究主要集中在降低共轭聚合物的能带间隙上,其中一个常用方法是向聚合物中加入π共轭链,例如苯基或者噻吩基。
聚(5-醛基吲哚)分子中既有苯环也有吲哚环,苯环的加入使分子的共轭平面结构增大,这不仅有利于电子在三环系统中的苯环上传输,而且还使分子能带间隙降低,相应的聚合物具有良好的电致变色性能。高性能的电致变色材料仍然是科学家们的主要目标,到目前为止,没课题组做关于聚(5-醛基吲哚)/石墨烯电化学合成及其电致变色性能的研究。基于此,将尝试通过直接阳极氧化聚(5-醛基吲哚)单体和石墨烯,在电极表面电沉积得到聚(5-醛基吲哚)/石墨烯膜,并对聚合物的电致变色性能和动力学性能进行表征。
发明内容
本发明所要解决的技术问题是提供石墨烯聚(5-醛基吲哚)纳米复合材料的制备,技术方案如下:首先,在0.5-0.7mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积,沉积电压为-1.8V,至此,化学还原的氧化石墨烯被修饰在了ITO导电玻璃上;然后,在含0.1-0.3mol L-1TBATFB的乙腈溶液中采用一室三电极体系,工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃,使0.02-0.04mol L-15-醛基吲哚1.35V的电压下进行电化学聚合,从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
本发明的有益效果是:制备工艺简易环保,成本低,适用范围广。
具体实施方式
实施例1
首先,在0.5mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积,沉积电压为-1.8V,至此,化学还原的氧化石墨烯被修饰在了ITO导电玻璃上;然后,在含0.1mol L-1TBATFB的乙腈溶液中采用一室三电极体系,工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃,使0.02mol L-15-醛基吲哚1.35V的电压下进行电化学聚合,从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
实施例2
首先,在0.7mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积,沉积电压为-1.8V,至此,化学还原的氧化石墨烯被修饰在了ITO导电玻璃上;然后,在含0.3mol L-1TBATFB的乙腈溶液中采用一室三电极体系,工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃,使0.04mol L-15-醛基吲哚1.35V的电压下进行电化学聚合,从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
实施例3
首先,在0.6mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积,沉积电压为-1.8V,至此,化学还原的氧化石墨烯被修饰在了ITO导电玻璃上;然后,在含0.2mol L-1TBATFB的乙腈溶液中采用一室三电极体系,工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃,使0.03mol L-15-醛基吲哚1.35V的电压下进行电化学聚合,从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
以上所述仅为本发明的较佳实施例,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (2)
1.石墨烯聚(5-醛基吲哚)纳米复合材料的制备,其特征在于,包括:首先,在0.5-0.7mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积,沉积电压为-1.8V,至此,化学还原的氧化石墨烯被修饰在了ITO导电玻璃上;然后,在含0.1-0.3mol L-1TBATFB的乙腈溶液中采用一室三电极体系,工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃,使0.02-0.04mol L-15-醛基吲哚1.35V的电压下进行电化学聚合,从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
2.根据权利要求1所述的合成方法,其特征在于,所述反应温度为20-25度。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710796580.3A CN107501528A (zh) | 2017-09-06 | 2017-09-06 | 石墨烯聚(5‑醛基吲哚)纳米复合材料的制备 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710796580.3A CN107501528A (zh) | 2017-09-06 | 2017-09-06 | 石墨烯聚(5‑醛基吲哚)纳米复合材料的制备 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107501528A true CN107501528A (zh) | 2017-12-22 |
Family
ID=60694937
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710796580.3A Withdrawn CN107501528A (zh) | 2017-09-06 | 2017-09-06 | 石墨烯聚(5‑醛基吲哚)纳米复合材料的制备 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107501528A (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114388273A (zh) * | 2022-01-07 | 2022-04-22 | 青海大学 | 一种花青素敏化的P5FIn/ITO纳米复合材料的制备方法及其应用 |
CN114806312A (zh) * | 2022-04-15 | 2022-07-29 | 哈尔滨工程大学 | 聚吲哚改性氧化石墨烯/丙烯酸氟硼复合防污涂层的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105037422A (zh) * | 2015-06-26 | 2015-11-11 | 苏州大学 | 一种吲哚膦酸酯衍生物的制备方法 |
CN105223249A (zh) * | 2015-10-16 | 2016-01-06 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种用于血清素检测的化学传感器的制备方法 |
CN106366084A (zh) * | 2016-08-29 | 2017-02-01 | 陕西理工大学 | 一种三重对称三氮杂纳米石墨烯分子及其制备方法 |
-
2017
- 2017-09-06 CN CN201710796580.3A patent/CN107501528A/zh not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105037422A (zh) * | 2015-06-26 | 2015-11-11 | 苏州大学 | 一种吲哚膦酸酯衍生物的制备方法 |
CN105223249A (zh) * | 2015-10-16 | 2016-01-06 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种用于血清素检测的化学传感器的制备方法 |
CN106366084A (zh) * | 2016-08-29 | 2017-02-01 | 陕西理工大学 | 一种三重对称三氮杂纳米石墨烯分子及其制备方法 |
Non-Patent Citations (2)
Title |
---|
GUANGMING NIE ET AL.: "Electrochemiluminescence Biosensor Based on Conducting Poly(5-formylindole) for Sensitive Detection of Ramos Cells", 《BIOMACROMOLECULES》 * |
张琳: "基于石墨烯/聚(6-羧基吲哚)复合材料的生物传感器研制及应用", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114388273A (zh) * | 2022-01-07 | 2022-04-22 | 青海大学 | 一种花青素敏化的P5FIn/ITO纳米复合材料的制备方法及其应用 |
CN114388273B (zh) * | 2022-01-07 | 2022-10-14 | 青海大学 | 一种花青素敏化的P5FIn/ITO纳米复合材料的制备方法及其应用 |
CN114806312A (zh) * | 2022-04-15 | 2022-07-29 | 哈尔滨工程大学 | 聚吲哚改性氧化石墨烯/丙烯酸氟硼复合防污涂层的制备方法 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Sharma et al. | Recent trends and developments in conducting polymer nanocomposites for multifunctional applications | |
Wu et al. | Large-Area Polyimide/SWCNT Nanocable Cathode for Flexible Lithium-Ion Batteries. | |
Gao et al. | Research progress of ionic liquids-based gels in energy storage, sensors and antibacterial | |
CN102629684B (zh) | 聚苯胺-石墨烯复合材料薄膜及其制备方法、电池、电子书 | |
Sonia et al. | Composite supercapacitor electrodes made of activated carbon/PEDOT: PSS and activated carbon/doped PEDOT | |
CN109036864B (zh) | 一种纳米硫化镍-石墨烯复合电极材料的制备方法及应用 | |
CN103570944B (zh) | 含有巯基的聚苯胺及其制备方法 | |
CN112552896A (zh) | 一种电致变色导电聚合物复合薄膜及器件制备方法 | |
Mehmood et al. | Polyaniline/graphene nanocomposites as counter electrode materials for platinum free dye-sensitized solar cells (DSSCSs) | |
CN107501528A (zh) | 石墨烯聚(5‑醛基吲哚)纳米复合材料的制备 | |
CN103811802A (zh) | 一种聚合物锂离子电池及其制造方法 | |
Nada et al. | Irreversible and self-healing electrically conductive hydrogels made of bio-based polymers | |
CN106290508B (zh) | 一种双酚a电聚合膜功能化碳纳米管/硫化镉复合电极及其制备方法和应用 | |
CN103477461B (zh) | 太阳能电池用电极体及其制造方法、具备该电极体的太阳能电池 | |
Khalid et al. | Ionically conducting and environmentally safe gum Arabic as a high-performance gel-like electrolyte for solid-state supercapacitors | |
CN106252099A (zh) | 一种超级电容器 | |
Duan et al. | A novel hydrogel electrolyte for all-climate high-performance flexible zinc-ion hybrid capacitors within temperature range from− 50 to 100° C | |
Imperiyka et al. | Preparation and Characterization of Polymer Electrolyte of Glycidyl Methacrylate‐Methyl Methacrylate‐LiClO4 Plasticized with Ethylene Carbonate | |
Li et al. | Performance enhancement of gel polymer electrolytes using sulfonated poly (ether ether ketone) for supercapacitors | |
CN107221449B (zh) | 一种超级电容器的电极材料及其制备方法 | |
CN107694353A (zh) | 乙基纤维素与离子液体气体分离膜的制备方法 | |
CN110491679B (zh) | 氧化石墨烯-聚噻吩复合材料和基于该材料的超级电容器 | |
Ma et al. | Efficient dye-sensitized solar cells made from high catalytic ability of polypyrrole@ platinum counter electrode | |
CN103396532B (zh) | 三苯乙烯衍生物发光薄膜的制备方法 | |
CN103035414B (zh) | 一种染料敏化太阳能电池对电极及其制备方法和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171222 |
|
WW01 | Invention patent application withdrawn after publication |