CN107501528A - 石墨烯聚(5‑醛基吲哚)纳米复合材料的制备 - Google Patents

石墨烯聚(5‑醛基吲哚)纳米复合材料的制备 Download PDF

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CN107501528A
CN107501528A CN201710796580.3A CN201710796580A CN107501528A CN 107501528 A CN107501528 A CN 107501528A CN 201710796580 A CN201710796580 A CN 201710796580A CN 107501528 A CN107501528 A CN 107501528A
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graphene
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赵世芬
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Yantai Zhiben Intellectual Property Operation and Management Co Ltd
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
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    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
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    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
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Abstract

本发明涉及石墨烯聚(5‑醛基吲哚)纳米复合材料的制备，包括：首先，在0.5‑0.7mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积，沉积电压为‑1.8V，至此，化学还原的氧化石墨烯被修饰在了ITO导电玻璃上；然后，在含0.1‑0.3mol L‑1 TBATFB的乙腈溶液中采用一室三电极体系，工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃，使0.02‑0.04mol L‑1 5‑醛基吲哚1.35V的电压下进行电化学聚合，从而制备石墨烯聚(5‑醛基吲哚)纳米复合材料。

Description

石墨烯聚(5-醛基吲哚)纳米复合材料的制备
技术领域
本发明涉及石墨烯聚(5-醛基吲哚)纳米复合材料的制备，属于材料化学领域。
背景技术
顺应研究需要，各种电致变色材料也相继被发现，如聚噻吩、聚吡咯、聚咔唑等。聚吲哚家族因其独特优势得到了人们的关注，特别是热稳定性好、电致发光性能稳定、氧化还原活性高等。一般来说，在聚合难易程度上，导电聚合物单体中有反应活性功能基团的要比没有取代基团的更易反应；在电致变色性能上，一般由掺杂决定。为了改善其稳定性，近年来人们对该材料的研究主要集中在降低共轭聚合物的能带间隙上，其中一个常用方法是向聚合物中加入π共轭链，例如苯基或者噻吩基。
聚(5-醛基吲哚)分子中既有苯环也有吲哚环，苯环的加入使分子的共轭平面结构增大，这不仅有利于电子在三环系统中的苯环上传输，而且还使分子能带间隙降低，相应的聚合物具有良好的电致变色性能。高性能的电致变色材料仍然是科学家们的主要目标，到目前为止，没课题组做关于聚(5-醛基吲哚)/石墨烯电化学合成及其电致变色性能的研究。基于此，将尝试通过直接阳极氧化聚(5-醛基吲哚)单体和石墨烯，在电极表面电沉积得到聚(5-醛基吲哚)/石墨烯膜，并对聚合物的电致变色性能和动力学性能进行表征。
发明内容
本发明所要解决的技术问题是提供石墨烯聚(5-醛基吲哚)纳米复合材料的制备，技术方案如下：首先，在0.5-0.7mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积，沉积电压为-1.8V，至此，化学还原的氧化石墨烯被修饰在了ITO导电玻璃上；然后，在含0.1-0.3mol L-1TBATFB的乙腈溶液中采用一室三电极体系，工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃，使0.02-0.04mol L-15-醛基吲哚1.35V的电压下进行电化学聚合，从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
本发明的有益效果是：制备工艺简易环保，成本低，适用范围广。
具体实施方式
实施例1
首先，在0.5mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积，沉积电压为-1.8V，至此，化学还原的氧化石墨烯被修饰在了ITO导电玻璃上；然后，在含0.1mol L-1TBATFB的乙腈溶液中采用一室三电极体系，工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃，使0.02mol L-15-醛基吲哚1.35V的电压下进行电化学聚合，从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
实施例2
首先，在0.7mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积，沉积电压为-1.8V，至此，化学还原的氧化石墨烯被修饰在了ITO导电玻璃上；然后，在含0.3mol L-1TBATFB的乙腈溶液中采用一室三电极体系，工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃，使0.04mol L-15-醛基吲哚1.35V的电压下进行电化学聚合，从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
实施例3
首先，在0.6mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积，沉积电压为-1.8V，至此，化学还原的氧化石墨烯被修饰在了ITO导电玻璃上；然后，在含0.2mol L-1TBATFB的乙腈溶液中采用一室三电极体系，工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃，使0.03mol L-15-醛基吲哚1.35V的电压下进行电化学聚合，从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (2)

1.石墨烯聚(5-醛基吲哚)纳米复合材料的制备，其特征在于，包括：首先，在0.5-0.7mg/mL氧化石墨烯的水溶液中采用一室三电极体系中进行石墨烯的电化学沉积，沉积电压为-1.8V，至此，化学还原的氧化石墨烯被修饰在了ITO导电玻璃上；然后，在含0.1-0.3mol L-1TBATFB的乙腈溶液中采用一室三电极体系，工作电极为化学还原的氧化石墨烯修饰的ITO导电玻璃，使0.02-0.04mol L-15-醛基吲哚1.35V的电压下进行电化学聚合，从而制备石墨烯聚(5-醛基吲哚)纳米复合材料。
2.根据权利要求1所述的合成方法，其特征在于，所述反应温度为20-25度。
CN201710796580.3A 2017-09-06 2017-09-06 石墨烯聚(5‑醛基吲哚)纳米复合材料的制备 Withdrawn CN107501528A (zh)

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CN114388273A (zh) * 2022-01-07 2022-04-22 青海大学 一种花青素敏化的P5FIn/ITO纳米复合材料的制备方法及其应用
CN114806312A (zh) * 2022-04-15 2022-07-29 哈尔滨工程大学 聚吲哚改性氧化石墨烯/丙烯酸氟硼复合防污涂层的制备方法

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114388273A (zh) * 2022-01-07 2022-04-22 青海大学 一种花青素敏化的P5FIn/ITO纳米复合材料的制备方法及其应用
CN114388273B (zh) * 2022-01-07 2022-10-14 青海大学 一种花青素敏化的P5FIn/ITO纳米复合材料的制备方法及其应用
CN114806312A (zh) * 2022-04-15 2022-07-29 哈尔滨工程大学 聚吲哚改性氧化石墨烯/丙烯酸氟硼复合防污涂层的制备方法

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