CN107494568A - Prevent and treat compound synergistic bactericidal composition and its application of tomato and pear tree Major Diseases - Google Patents
Prevent and treat compound synergistic bactericidal composition and its application of tomato and pear tree Major Diseases Download PDFInfo
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- CN107494568A CN107494568A CN201710692451.XA CN201710692451A CN107494568A CN 107494568 A CN107494568 A CN 107494568A CN 201710692451 A CN201710692451 A CN 201710692451A CN 107494568 A CN107494568 A CN 107494568A
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- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000030833 cell death Effects 0.000 description 1
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical class [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 230000002438 mitochondrial effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 244000039328 opportunistic pathogen Species 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229960005486 vaccine Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of compound synergistic bactericidal composition and its application for preventing and treating tomato and pear tree Major Diseases, the composition pesticide active component includes fluorine azoles bacterium acyl azanol and active component B；Wherein active component B includes one kind in methoxy acrylic bactericide, ergosterol synthetic inhibitor, substituted aniline series bactericidal agent, bacillus subtilis (Bacillus subtilis) BAB 1.Composition pesticide of the present invention is applied to the preventing and treating of the Major Diseases such as gray mold, early blight, leaf mold, gray leaf spot, scab, ring spot and the black spot of tomato and pear tree; its quick-acting and lasting effect are good; mechanism of action is novel and site is more; the drug-fast occurrence and development of pathogen can effectively be delayed, to disease not only with protective effect but also with good therapeutic action.The compound synergic composite reagent amount is few, effectively reduces pollution of the medicament to fruit and environment.
Description
Technical field
The invention belongs to technical field of pesticide, more particularly to a kind of compound synergistic bactericidal combination for preventing and treating fruits and vegetables Major Diseases
Thing and application.
Background technology
Fluorine azoles bacterium acyl azanol (adepidyntm) belongs to succinate dehydrogenase inhibitors series bactericidal agent, and its mode of action is logical
Cross and the Complex II (succinate dehydrogenase) of mitochondrial respiratory chain is worked, the energetic supersession of cell is influenceed, so as to suppress target
The spore germination of fungi, germ tube and mycelial growth are marked, shows good protection and therapeutic action.The bactericide has efficiently low
The features such as malicious, have to a variety of pathogens such as Botrytis, Septoria, Cercospora leaf spot, Alternaria and Venturia
Good activity.
Methoxy acrylic bactericide mechanism of action is novel, mainly acts on mitochondrial respiratory chain cpd III, with
Qo sites on fungal cytochrome b combine, and prevent electron transmission between cytochrome b and C1 and suppress mitochondrial respiratory effect,
Mitochondria is seted to ultimately result in cell death from producing and providing the energy (ATP) needed for cell eubolism, suppress pathogen
Spore germination, the formation of mycelial growth and spore, there is protection and therapeutic action
Ergosterol synthetic inhibitor series bactericidal agent SYP-Z048, Imazalil sulfate and natamycin, mechanism of action are only
Spy, structure is novel, has the characteristics of efficient, wide spectrum and security are good, has remarkable preventive effect to gray mold.Substituted benzene amine is sterilized
Agent fluazinam is a kind of protective fungicide of broad-spectrum high efficacy, to Botrytis cinerea, interlink spore genus, Phytophthora, Plasmopara, nuclear disk
The germ disease such as Pseudomonas and Venturia also has good activity.
Biocontrol microorganisms bacillus subtilis (Bacillus subtilis) BAB-1 is protected by Hebei Prov. Academy of Agricultural ＆. Forest Sciences plant
Shield research institute screening obtain, there is good preventive effect to various plants fungal disease, on July 6th, 2007, be preserved in China it is micro-
Biological inoculum preservation administration committee common micro-organisms center, deposit number are CGMCC No.2099.Classification system is：
Bacillus subtilis BAB-1 (hereinafter referred to as BAB-1).BAB-1 is for bacillus subtilis (Bacillus subtilis)
Disclosed in Chinese patent CN101148650A, the bacterial strain have efficiently, antimicrobial spectrum it is wide, using it is simple, cost is low, dirty without environment
The features such as dye, the preventing and treating available for graw mold of tomato and leaf mold.
So far there is not yet utilizing fluorine azoles bacterium acyl azanol and methoxy acrylic bactericide, ergosterol synthetic inhibitor
SYP-Z048, Imazalil sulfate and natamycin and biocontrol agent bacillus subtilis BAB-1 develop mixture preventing and treating tomato (leaf
Mildew, early blight, gray leaf spot and gray mold) and pear tree (scab, ring spot and black spot) Major Diseases report.
The content of the invention
Fluorine azoles bacterium acyl azanol has higher resistance risk, and long-term use may bring resistance to produce, and drug effect decline etc. is asked
Topic, to delay the generation of the drug resistance, preventive effect is improved, reduce dosage, composition pesticide proposed by the present invention is containing active
Composition A (fluorine azoles bacterium acyl azanol) and active component B (methoxy acrylic bactericide, ergosterol synthetic inhibitor, substitution
Aniline fungicides fluazinam and bacillus subtilis BAB-1) and appropriate auxiliary agent.Composition pesticide of the present invention can be used for preventing
Control tomato and pear tree Major Diseases.
First purpose of the present invention is to provide a kind of compound synergistic bactericidal combination for preventing and treating tomato and pear tree Major Diseases
Thing, its active component include fluorine azoles bacterium acyl azanol and active component B；Wherein active component B kills including methoxy acrylic
Microbial inoculum, ergosterol synthetic inhibitor, substituted aniline series bactericidal agent, bacillus subtilis (Bacillus subtilis) BAB-1
In one kind.
Further, the methoxy acrylic bactericide includes Fluoxastrobin, pyraclostrobin, Enestroburin, azoles
Any of amine bacterium ester, kresoxim-methyl, ZEN 90160, SYP-3375, chlorine pyridine bacterium fat, trifloxystrobin, alkene oxime amine etc. are several.
Further, the ergosterol synthetic inhibitor includes SYP-Z048, Imazalil sulfate and natamycin etc.
Any of or it is several.
Further, substituted aniline series bactericidal agent is including fluazinam etc..Further, the bacillus subtilis BAB-1
For its zymotic fluid or its lyophilized bacterium powder or its metabolite；It is preferred that the total viable count of the zymotic fluid is 7 × 109~1 ×
1010CFU/mL；It is preferred that the total viable count of the lyophilized bacterium powder is 1.8 × 1010~2.4 × 1010CFU/g。
The two kinds of active components of the compound synergic composition pesticide of fluorine-containing azoles bacterium acyl azanol of the present invention when in use, its
Proportioning is not particularly limited, and the two is respectively provided with obvious synergistic effect with arbitrary proportion compounding use.
In order to preferably play drug effect, in above-mentioned compound synergistic bactericidal composition, preferably fluorine azoles bacterium acyl azanol and the work
Property composition B weight ratio is (1-10):(1-10), more preferably (1-4):(1-4), much further preferably from (1-2):
(1-2).I.e. when two active components are with said ratio compounding use, there is more preferably synergistic effect.
In order to give full play to the drug effect of above-mentioned compound synergistic bactericidal composition, this can be made in any one above-mentioned composition
Various formulations known to field, such as wettable powder, suspending agent, oil suspending agent.In various formulations, the preferred weight of active component
Amount percentage is 1%-80%, further preferred 30%-60%, most preferably 45%.
When above-mentioned composition pesticide is made into specific formulation, used auxiliary agent is auxiliary agent commonly used in the art, be may be selected from
One or more combinations in wetting agent, dispersant, suspension aids, binding agent (thickener), anti-bubble auxiliary agent, disintegrant.
Specifically, the present invention provides a kind of Wettable pesticide powder, and the Wettable pesticide powder is by including such as the following group
Divide what is be prepared：Fluorine azoles bacterium acyl azanol, active component B, wetting agent, dispersant, filler.
The Wettable pesticide powder is preferably prepared by the component including following parts by weight：10-30 part fluorine azoles bacterium acyls
Azanol, 10-30 part active component B, 1-10 part wetting agents, 1-10 part dispersants, filler complement to 100 parts.
In the above-mentioned Wettable pesticide powder, the wetting agent is preferably AEO (JFC), dodecane
One or more of combinations in base benzene sulfonic acid sodium salt, APES formaldehyde condensation product sulfonate (SOPA)；
The dispersant is preferably naphthalene sulfonic acid-formaldehyde condensation product sodium salt (NNO), lignosulfite, sodium lignin sulfonate
Salt (M-9), 4- oleoyls-methoxy benzenesulfonic acid sodium salt (LS), sanlose (CMC), APES
(OP-10), one or more combinations in ethylene glycol monobutyl ether, polyoxyethanyl alkyl ether, NPE；
The filler is preferably one or more in white carbon, kaolin, precipitated calcium carbonate, diatomite, bentonite
Combination.
The wettable powder is more preferably prepared by the component including following parts by weight：21-24 part fluorine azoles bacterium acyl hydroxyls
Amine, 21-24 part active component B, 5-8 part APES formaldehyde condensation product sulfonate, 3-5 part polyoxyethanyl alkyl
Ether, diatomite complement to 100 parts.
It is further preferred that the wettable powder is prepared by the component including following parts by weight：22.96 part 98%
Fluorine azoles bacterium acyl azanol, 23.32 part of 96.5% active component B (preferably azoles amine bacterium ester), 6 parts of pelopon As, 4 parts of wood
Quality sulfonate sodium, 43.72 parts of precipitated calcium carbonates.
Invention also provides the preparation method of any one above-mentioned Wettable pesticide powder to be：By fluorine azoles bacterium acyl hydroxyl
Amine, the active component B (such as kresoxim-methyl), wetting agent, dispersant, filler are well mixed, and are then crushed, and are crossed 325 mesh sieves, that is, are made
Into 42%-48% fluorine azoles bacterium acyl azanol active component B (such as kresoxim-methyl) Wettable pesticide powder.
The present invention also provides a kind of suspension pesticide, and the suspension pesticide including following component by being prepared：
10-30 part fluorine azoles bacterium acyl azanols, 10-30 part active component B, 3-5 parts emulsifying agent, 2-3 parts wetting agent, 3-5 parts preservative, 0.5
~3 parts of stabilizers, 0.5~2 part of defoamer, 1~3 part of antifreezing agent, water complement to 100 parts.
In the suspension pesticide, the emulsifying agent is preferably alkyl naphthalene sulfonic acid salt, alkylphenol-formaldehyde resin polyoxy second
Alkene ether, Span60, one kind in triphenoethyl benzene phenol polyoxy in alkene oxygen ethylene block polymer or Tween-60
It is or two or more；
The wetting agent is preferably alkylphenol-polyethenoxy base ether phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products
Sulfate, alkyl sulfate, phenethyl phenol polyoxyethylene groups ether phosphate, sodium alkyl sulfonate or one kind in naphthalene sulfonate or two
More than kind；
The preservative is preferably more than one or both of benzoic acid, formaldehyde or sodium benzoate；
The stabilizer is preferably more than one or both of epoxy chlorine alkane or triphenyl phosphate；
The defoamer is preferably organosilicon；
The antifreezing agent is preferably more than one or both of propane diols, ethylene glycol, glycerine, urea or inorganic salts.
The suspension pesticide is more preferably prepared by the component including following parts by weight：21-24 part fluorine azoles bacterium acyl hydroxyls
Amine, 21-24 part active components B (preferably azoles amine bacterium ester or natamycin), 3-5 part alkyl naphthalene sulfonic acids salt, 2-4 part dodecyls
Sodium sulfonate, 3-5 parts sodium benzoate, 2-3 part epoxy chlorine alkane, 0.5-1 parts organosilicon, 1-3 parts glycerine, water complement to 100 parts.
It is further preferred that the suspending agent is prepared by the component including following parts by weight：22.96 part 98%
Fluorine azoles bacterium acyl azanol；22.50 parts of active component B (preferably natamycin)；4 parts of alkyl phenol formaldehyde resin polyoxyethylene ethers, 3 part ten
Dialkyl sulfonates, 4 parts of sodium benzoates, 2 parts of epoxy chlorine alkane, 0.5 part of organosilicon, 1 part of propane diols and 40.04 parts of water.
Invention also provides the preparation method of any one above-mentioned suspension pesticide to be：By fluorine azoles bacterium acyl azanol, work
Property composition B, emulsifying agent, wetting agent, stabilizer, defoamer, antifreezing agent, water and abrasive media mixed grinding, are homogeneously suspended
Liquid, decoction is separated with abrasive media, that is, 42%-48% fluorine azoles bacterium acyl azanol active component B (such as azoles amine bacterium ester) are made
Suspension pesticide.
Present invention simultaneously provides a kind of oil suspending agent agricultural chemicals, the oil suspending agent agricultural chemicals is by being prepared including following component
's：Fluorine azoles bacterium acyl azanol, the active component B, wetting dispersing agent, viscosity-controlling agent oil base etc. form.
The oil suspending agent agricultural chemicals is preferably prepared by the component including following parts by weight：5-10 part fluorine azoles bacterium acyl azanols,
5-10 part active component B, 10-20 part wetting dispersing agents, 1-2 part viscosity-controlling agents, oil base complement to 100 parts.
In the oil suspending agent agricultural chemicals, wetting dispersing agent is preferably：The methyl esters emulsifier YUS-EC2200 of this grease of bamboo, ore deposit
Thing emulsifier YUS-135B, vegetable oil emulsifier YUS-110；Methyl esters emulsifier VO/02N, mineral oil emulsion agent MO/P；First
Ester oil emulsifier 1577 or B1579, vegetable oil emulsifier 1573；Oily suspension aids SOD (there is outstanding emulsification to make methyl esters oil
With)；Silicone oil and white oil emulsifying agent C13/3；One or both of methyl esters emulsifier OF-8712-70 or OF-7812-70 etc.
More than.
The viscosity-controlling agent is：Organobentonite, aluminium-magnesium silicate, gas-phase silica etc.；
The oil base is：Methyl oleate, vegetable oil (soybean oil, rapeseed oil and corn oil etc.), mineral oil etc..
Preferably, the oil suspending agent agricultural chemicals is prepared by the component including following parts by weight：5.1 parts of fluorine azoles bacterium acyl hydroxyls
Amine, 5.1 parts of active component B (preferably Imazalil sulfate), 10 parts of vegetable oil emulsifiers, 1 part of organobentonite, soybean oil are supplied
To 100 parts.
Second object of the present invention is to provide the compound synergic pesticide combination of any one above-mentioned fluorine-containing azoles bacterium acyl azanol
Thing or the application containing its preparation in tomato and the preventing and treating of pear tree Major Diseases.
The disease is included in gray mold, early blight, leaf mold, gray leaf spot, scab, ring spot and black spot etc.
It is one or more.
The compound synergic composition pesticide of fluorine-containing azoles bacterium acyl azanol of the present invention or containing its preparation be applied to tomato and
The preventing and treating of gray mold, early blight, leaf mold, gray leaf spot, scab, ring spot and the black spot of pear tree etc..
The compound synergic composition pesticide of fluorine-containing azoles bacterium acyl azanol of the present invention or the quick-acting containing its preparation and hold
Effect property is good, and mechanism of action is novel and site is more, can effectively delay the drug-fast occurrence and development of pathogen, not only have to disease
Protective effect and there is good therapeutic action.Further, by adding this area routine into the bactericidal composition
Auxiliary agent is made into the conventional formulation in this area and novel form oil suspending agent is more conducive to active component and plays drug effect.The Bactericidal composite
The preparation technology of thing is simple, and cost is low, and dosage is low, and diseases prevention spectrum is wide, and biological safety is high, remarkable in economical benefits.The compound sterilizing
Agent preparation technology is simple, and cost is low, and diseases prevention spectrum is wide, and biological safety is high, remarkable in economical benefits, effectively reduces chemical pesticide
Dosage, the compounded combination adapted to current double reduce-administration plans.
Embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.It is unreceipted specific in embodiment
Technology or condition person, carried out according to the technology or condition described by document in the art, or according to product description.It is used
Reagent or the unreceipted production firm person of instrument are the conventional products that can be commercially available by regular distributor or pass through ability
Domain conventional meanses are prepared.
The unit of weight being related in following examples can be gram, kilogram, ton, or its multiple.
Embodiment 1
A kind of composition pesticide, the formulation of the composition pesticide is wettable powder, and the wettable powder is by such as
What lower component was prepared：22.96 part of 98% fluorine azoles bacterium acyl azanol, 23.32 part of 96.5% azoles amine bacterium ester, 6 parts of detergent alkylates
Sulfonate sodium, 4 parts of lignin sulfonic acid sodium salts, 43.72 parts of precipitated calcium carbonates.
The wettable powder is more preferably prepared by the component including following parts by weight：22.96 part of 98% fluorine azoles bacterium
Acyl azanol, 22.96 part of 98% kresoxim-methyl, 5 parts of APES formaldehyde condensation product sulfonate, 4 parts of polyoxyethanyl alkyl
Ether, 45.08 parts of diatomite.
Embodiment 2-6
Composition pesticide, preparation method is with embodiment 1, the difference is that following components：
Embodiment 7-12
Composition pesticide, preparation method is with embodiment 1, the difference is that following components：
Embodiment 13
A kind of composition pesticide, the formulation of the composition pesticide is wettable powder, and the wettable powder is by such as
What lower component was prepared：The fluorine azoles bacterium acyl azanol active compound of mass concentration 98%：20.41 parts；Bacillus subtilis BAB-1 is freezed
(total viable count is 2.0 × 10 to bacterium powder10CFU/g)：40 parts；Dispersant sanlose：3 parts；Wetting agent：Dodecyl
Sodium sulfonate：4.5 part；Filler precipitated calcium carbonate：32.09 parts.Being matched somebody with somebody with this, 20% fluorine azoles bacterium acyl hydroxyl can be made as stated above
The CFU/ grams of bacillus subtilis BAB-1 wettable powder of amine 8,000,000,000.
Embodiment 14
A kind of composition pesticide, the formulation of the composition pesticide is suspending agent, and the suspending agent is by following component system
For what is obtained：22.96 part of 98% fluorine azoles bacterium acyl azanol；23.32 part of 96.5% azoles amine bacterium ester；4 parts of alkylphenol-formaldehyde resin polyoxies
Vinethene, 3 parts of dodecyl sodium sulfates, 4 parts of sodium benzoates, 2 parts of epoxy chlorine alkane, 0.5 part of organosilicon, 1 part of propane diols and 39.22
Part water.
Embodiment 15-25
Composition pesticide, it is formulated as shown in the table respectively：
Embodiment 26
A kind of composition pesticide, the formulation of the composition pesticide is oil suspending agent, and the oil suspending agent is by following component system
For what is obtained：5.1 part of 98% fluorine azoles bacterium acyl azanol；5.1 part of 98% Imazalil sulfate；10 parts of mineral oil emulsion agent YUS-
135B, 1 part of organobentonite, soybean oil complement to 100 parts.
Embodiment 27-33
Composition pesticide, it is formulated as shown in the table respectively：
Embodiment 34
In order to further verify that the bactericidal composition of the present invention has good bactericidal effect, carried out below by way of test example
Illustrate, length is limited, and the present invention, which only records, has convictive formula and experiment.
In tests below example, 200g/L fluorine azoles bacterium acyl azanol suspending agents (autogamy)；250g/L Fluoxastrobins suspending agent (commercially available)
20% azoles amine bacterium ester suspending agent (commercially available)；25% pyraclostrobin missible oil (commercially available), 50% trifloxystrobin water dispersible granule (commercially available)；
25% Enestroburin missible oil (commercially available)；22.5% ZEN 90160 missible oil (commercially available)；20% SYP-3375 suspending agent (commercially available)；5%
Alkene oxime amine missible oil (commercially available)；25% SYP-Z048 missible oil (commercially available)；25% chlorine pyridine bacterium fat missible oil (self-control)；75% imazalil sulphur
Hydrochlorate soluble granule (commercially available)；50% fluazinam missible oil (commercially available)；8×109CFU/mL bacillus subtilis BAB-1 zymotic fluids
(Inst. of Plant Protection, Hebei-Prov. Academy of Agricultural and Forestry Scie's offer).
The compounding test medicine being related in tests below example has the formula in above example to prepare.
Test example one：Fluorine azoles bacterium acyl azanol is from different fungicide compoundings to tomato and the co-toxicity of pear tree Major Diseases
It is sick to causing fruits and vegetables Major Diseases from different fungicide compoundings that fluorine azoles bacterium acyl azanol is studied using conventional methods
The co-toxicity of opportunistic pathogen
For trying cause of disease bacteria strain：Tomato (botrytis cinerea, early vaccine, grey tikka and leaf mycete) and pear tree (black star germ, wheel line
Bacterium and blackspot bacterium) provided by Inst. of Plant Protection, Hebei-Prov. Academy of Agricultural and Forestry Scie.Strains tested is carried out using PDA culture medium pre-
Culture.Wherein described PDA culture medium is potato 200g, glucose 20g, agar 10g, distilled water 1000mL.
Reagent agent will be dissolved in acetone respectively, after the mother liquor that concentration is 10000 μ g/mL is made, by different quality ratio
(10:1、8:1：6:1、4:1、2:1、1:1、1:2、1:4、1:6、1:8、1:10) mix, obtain the mixed liquor of different ratio.Then
It is serially diluted with sterilized water, 1 is pressed with culture medium：9 ratio mixing, the drug containing PDA plate of series concentration is respectively prepared.
Preculture bacterial strain edge, which is beaten, takes a diameter of 5mm bacteria cakes, and face down is connected to drug containing flat board center, incubated as at 24 DEG C,
When control bacterium colony extends to 80% or so of culture dish, using the diameter of each processing of crossing method measurement and control.Profit
EC is calculated with dps softwares50And coefficient correlation.
The calculating of inhibiting rate：
Inhibiting rate (%)=[(control colony growth amount-processing colony growth amount germination rate)/control colony growth amount] ×
100%
The mixed coefficient of synergism of medicament is calculated with reference to Wadley formula：
SR=EC50(th)/EC50(ob)
A, b represent two kinds of bactericide shared ratio in the mixture in above formula；EC50And EC (A)50(B) A and B is represented respectively
Actual observation EC50Value, EC50(th) represent that two kinds of bactericide of A, B press a:The mixed theoretical EC of b50Value, EC50(ob) it is A, B
Two kinds of bactericide press a:The mixed actual observation EC of b50Value.SR>1.5, synergy；SR<0.5, antagonism；SR between 0.5 and 1.5 it
Between represent summation action.
Experimental result is shown in Table 1-21.
Co-toxicity of the fluorine azoles bacterium acyl azanol of table 1 with azoxystrobin compound to botrytis cinerea
As known from Table 1, the mycelial growth of botrytis cinerea is shown after fluorine azoles bacterium acyl azanol is mixed with Fluoxastrobin
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows significant synergistic effect,
Wherein when the proportioning of fluorine azoles bacterium acyl azanol and Fluoxastrobin is 1:Synergistic effect is most obvious when 1, coefficient of synergism 6.28.
The fluorine azoles bacterium acyl azanol of table 2 compounds the co-toxicity to botrytis cinerea with pyraclostrobin
As known from Table 2, to the equal table of mycelial growth of botrytis cinerea after fluorine azoles bacterium acyl azanol is mixed with pyraclostrobin
Reveal good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, its
In when the proportioning of fluorine azoles bacterium acyl azanol and pyraclostrobin be 1:Synergistic effect is most obvious when 2, coefficient of synergism 7.69.
The fluorine azoles bacterium acyl azanol of table 3 compounds the co-toxicity to botrytis cinerea with Enestroburin
As known from Table 3, the mycelial growth of botrytis cinerea is showed after fluorine azoles bacterium acyl azanol is mixed with Enestroburin
Go out good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein
When the proportioning of fluorine azoles bacterium acyl azanol and Enestroburin is 1:Synergistic effect is most obvious when 1, coefficient of synergism 8.86.
The fluorine azoles bacterium acyl azanol of table 4 compounds the co-toxicity to botrytis cinerea with azoles amine bacterium ester
As known from Table 4, the mycelial growth of botrytis cinerea is showed after fluorine azoles bacterium acyl azanol is mixed with azoles amine bacterium ester
Go out good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein
When the proportioning of fluorine azoles bacterium acyl azanol and azoles amine bacterium ester is 1:Synergistic effect is most obvious when 1, coefficient of synergism 6.65.
The fluorine azoles bacterium acyl azanol of table 5 compounds the co-toxicity to botrytis cinerea with Imazalil sulfate
As known from Table 5, it is equal to the mycelial growth of botrytis cinerea after fluorine azoles bacterium acyl azanol is mixed with Imazalil sulfate
Good inhibitory action is shown, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect,
Wherein when the proportioning of fluorine azoles bacterium acyl azanol and azoles amine bacterium ester is 1:Synergistic effect is most obvious when 1, coefficient of synergism 1.99.
The fluorine azoles bacterium acyl azanol of table 6 compounds the co-toxicity to tomato early blight bacterium with kresoxim-methyl
As known from Table 6, the mycelial growth of tomato early blight bacterium is shown after fluorine azoles bacterium acyl azanol is mixed with kresoxim-methyl
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein when
The proportioning of fluorine azoles bacterium acyl azanol and kresoxim-methyl is 1:Synergistic effect is most obvious when 1, coefficient of synergism 4.36.
The fluorine azoles bacterium acyl azanol of table 7 compounds the co-toxicity to tomato early blight bacterium with fluazinam
As known from Table 7, the mycelial growth of tomato early blight bacterium is shown after fluorine azoles bacterium acyl azanol is mixed with fluazinam
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein when
The proportioning of fluorine azoles bacterium acyl azanol and fluazinam is 1:Synergistic effect is most obvious when 2, coefficient of synergism 2.65.
The fluorine azoles bacterium acyl azanol of table 8 compounds the co-toxicity to tomato early blight bacterium with SYP-Z048
As known from Table 8, the mycelial growth of tomato early blight bacterium is showed after fluorine azoles bacterium acyl azanol is mixed with SYP-Z048
Go out good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein
When the proportioning of fluorine azoles bacterium acyl azanol and SYP-Z048 is 1:Synergistic effect is most obvious when 1, coefficient of synergism 4.35.
The fluorine azoles bacterium acyl azanol of table 9 compounds the co-toxicity to tomato bastard indigo plaque with natamycin
As known from Table 9, the mycelial growth of tomato bastard indigo plaque is showed after fluorine azoles bacterium acyl azanol is mixed with natamycin
Go out good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein
When the proportioning of fluorine azoles bacterium acyl azanol and natamycin is 1:Synergistic effect is most obvious when 1, coefficient of synergism 1.83.
The fluorine azoles bacterium acyl azanol of table 10 compounds the co-toxicity to tomato bastard indigo plaque with fluazinam
As known from Table 10, the mycelial growth of tomato bastard indigo plaque is shown after fluorine azoles bacterium acyl azanol is mixed with fluazinam
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein when
The proportioning of fluorine azoles bacterium acyl azanol and fluazinam is 1:Synergistic effect is most obvious when 1, coefficient of synergism 1.70.
The fluorine azoles bacterium acyl azanol of table 11 compounds the co-toxicity to Fulvia fulva with Enestroburin
As known from Table 11, the mycelial growth of Cladosporium fulvum is shown after fluorine azoles bacterium acyl azanol is mixed with Enestroburin
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein when
The proportioning of fluorine azoles bacterium acyl azanol and Enestroburin is 1:Synergistic effect is most obvious when 1, coefficient of synergism 1.85.
The fluorine azoles bacterium acyl azanol of table 12 compounds the co-toxicity to Fulvia fulva with SYP-3375
As known from Table 12, the mycelial growth of Cladosporium fulvum is shown after fluorine azoles bacterium acyl azanol is mixed with SYP-3375
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein when
The proportioning of fluorine azoles bacterium acyl azanol and SYP-3375 is 1:Synergistic effect is most obvious when 1, coefficient of synergism 1.81.
The fluorine azoles bacterium acyl azanol of table 13 compounds the co-toxicity to pear cucumerinum with ZEN 90160
As known from Table 13, the mycelial growth of pear cucumerinum is shown after fluorine azoles bacterium acyl azanol is mixed with ZEN 90160
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein when
The proportioning of fluorine azoles bacterium acyl azanol and ZEN 90160 is 1:Synergistic effect is most obvious when 4, coefficient of synergism 5.05.
The fluorine azoles bacterium acyl azanol of table 14 compounds the co-toxicity to pear cucumerinum with SYP-3375
As known from Table 14, the mycelial growth of pear cucumerinum is shown after fluorine azoles bacterium acyl azanol is mixed with SYP-3375
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein when
The proportioning of fluorine azoles bacterium acyl azanol and SYP-3375 is 1:Synergistic effect is most obvious when 1, coefficient of synergism 5.25.
The fluorine azoles bacterium acyl azanol of table 15 compounds the co-toxicity to pear cucumerinum with chlorine pyridine bacterium fat
As known from Table 15, the mycelial growth of pear cucumerinum is shown after fluorine azoles bacterium acyl azanol is mixed with chlorine pyridine bacterium fat
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein when
The proportioning of fluorine azoles bacterium acyl azanol and chlorine pyridine bacterium fat is 1:Synergistic effect is most obvious when 1, coefficient of synergism 5.32.
The fluorine azoles bacterium acyl azanol of table 16 compounds the co-toxicity to black rot of pear bacterium with trifloxystrobin
As known from Table 16, the mycelial growth of black rot of pear bacterium is shown after fluorine azoles bacterium acyl azanol is mixed with trifloxystrobin good
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein working as fluorine
The proportioning of azoles bacterium acyl azanol and trifloxystrobin is 1:Synergistic effect is most obvious when 1, coefficient of synergism 9.42.
The fluorine azoles bacterium acyl azanol of table 17 compounds the co-toxicity to black rot of pear bacterium with SYP-Z048
As known from Table 17, the mycelial growth of black rot of pear bacterium is shown after fluorine azoles bacterium acyl azanol is mixed with SYP-Z048
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein when
The proportioning of fluorine azoles bacterium acyl azanol and trifloxystrobin is 1:Synergistic effect is most obvious when 1, coefficient of synergism 2.54.
The fluorine azoles bacterium acyl azanol of table 18 compounds the co-toxicity to pears blackspot bacterium with pyraclostrobin
As known from Table 18, the mycelial growth of Pear black spot bacterium is showed after fluorine azoles bacterium acyl azanol is mixed with pyraclostrobin
Go out good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein
When the proportioning of fluorine azoles bacterium acyl azanol and pyraclostrobin is 1:Synergistic effect is most obvious when 1, coefficient of synergism 6.02.
The fluorine azoles bacterium acyl azanol of table 19 compounds the co-toxicity to pears blackspot bacterium with fluazinam
As known from Table 19, the mycelial growth of Pear black spot bacterium is shown after fluorine azoles bacterium acyl azanol is mixed with fluazinam good
Good inhibitory action, it is each to match (1~10):The coefficient of synergism of (1~10) is all higher than 1.5, shows synergistic effect, wherein working as fluorine
The proportioning of azoles bacterium acyl azanol and fluazinam is 1:Synergistic effect is most obvious when 1, coefficient of synergism 3.93.
The fluorine azoles bacterium acyl azanol of table 20 compounds the co-toxicity to pears blackspot bacterium with natamycin
As known from Table 20, the mycelial growth of Pear black spot bacterium is shown after fluorine azoles bacterium acyl azanol is mixed with natamycin
Good inhibitory action, it is each to match (1~6):The coefficient of synergism of (1~6) is all higher than 1.5, shows synergistic effect, wherein working as fluorine
The proportioning of azoles bacterium acyl azanol and natamycin is 1:Synergistic effect is most obvious when 1, coefficient of synergism 1.72.
The fluorine azoles bacterium acyl azanol of table 21 compounds the co-toxicity to botrytis cinerea with bacillus subtilis BAB-1
Note：Bacillus subtilis BAB-1 is its zymotic fluid in table 21, by Inst. of Plant Protection, Hebei-Prov. Academy of Agricultural and Forestry Scie
There is provided, living bacteria count is 8 × 109CFU/mL。
As known from Table 21, to the mycelia of botrytis cinerea after fluorine azoles bacterium acyl azanol is mixed with bacillus subtilis BAB-1
Growth shows good inhibitory action, each to match (1~4):The coefficient of synergism of (1~4) is all higher than 1.5, shows synergy
Effect, wherein when fluorine azoles bacterium acyl azanol and bacillus subtilis BAB-1 proportionings are 2:Synergistic effect is most obvious when 1, coefficient of synergism
For 1.80.
Test example two：The field efficacy of fluorine azoles bacterium acyl azanol and different bactericide and its complex preparation to graw mold of tomato
According to medicine inspecting institute of the Ministry of Agriculture《Pesticide field efficacy medicine test criterion》GB/T17980-2000 " bactericidal agent for preventing and treating vegetable ash
Mildew test of pesticide effectiveness criterion " is tested.Experimental plot is located at Hebei province Baoding Xushui County Gao Lin villages and small towns White Tower paving village, in tomato
Gray mold sporadicly starts to spray first time medicine, continuous use 3 times, medication interval 7 days, 7 days investigation field hairs after last medication
State of an illness condition, calculate disease index and prevention effect.
The fluorine azoles bacterium acyl azanol of table 22 is with other bactericide and its complex preparation to graw mold of tomato field controling test
Experiment is as can be seen that 45% fluorine azoles bacterium acyl azanol Fluoxastrobin wettable powder, 20% fluorine azoles bacterium acyl azanol are phonetic
Bacterium ester oil suspension, 45% fluorine azoles bacterium acyl azanol pyraclostrobin wettable powder, 45% fluorine azoles bacterium acyl azanol pyrazoles ether bacterium
Ester wettable powder, 45% fluorine azoles bacterium acyl azanol azoles amine bacterium ester wettable powder, 45% fluorine azoles bacterium acyl azanol SYP-Z048
Wettable powder, 10% fluorine azoles bacterium acyl azanol SYP-Z048 oil suspending agent, 45% fluorine azoles bacterium acyl azanol Imazalil sulfate oil
CFU/ grams of bacillus subtilis BAB-1 wettable powder of suspension and 20% fluorine azoles bacterium acyl azanol 8,000,000,000 under test dose to kind
Solanum cinerea shows good prevention effect, compared with its single dose, in the case where dosage reduces, to the preventive effect of gray mold
Still better than its single dose, and crop and other beneficial organisms are had no adverse effects under test dose.
Test example three：The field efficacy of fluorine azoles bacterium acyl azanol and different bactericide and its complex preparation to leaf muld of tomato
According to medicine inspecting institute of the Ministry of Agriculture《Pesticide field efficacy medicine test criterion》GB/T17980.111-2004 " bactericidal agent for preventing and treating kind
Eggplant leaf mold field control effectiveness test criterion " is tested.Experimental plot is located at village of Pang Gezhuang of Hebei province Baoding Dingxing County, in tomato
Start to spray first time medicine, continuous use 3 times, medication interval 7 days, 7 days investigation fields after last medication when leaf mold sporadicly occurs
Incidence, calculate disease index and prevention effect.
The fluorine azoles bacterium acyl azanol of table 23 is with other bactericide and its complex preparation to leaf muld of tomato field controling test
Experiment as can be seen that fluorine azoles bacterium acyl azanol from it is different it is bactericide compounded after there is good preventing and treating to leaf muld of tomato
Effect, its single dose is above to the preventive effect of leaf mold, and dosage significantly reduces compared with single dose, to making under test dose
Thing and other beneficial organisms have no adverse effects.
Test example four：The field efficacy of fluorine azoles bacterium acyl azanol and different bactericide and its complex preparation to early blight of tomato
According to medicine inspecting institute of the Ministry of Agriculture《Pesticide field efficacy medicine test criterion》GB/T17980.31-2000 " bactericidal agent for preventing and treating kind
Eggplant early blight and late blight field control effectiveness test criterion " is tested.
Experimental plot is located at Cangzhou, Hebei Province Suning County Shi Su towns, starts spray when early blight of tomato sporadicly occurs for the first time
Medicine, continuous use 3 times, medication interval 7 days, 7 days investigation field incidences after last medication, calculate disease index and preventing and treating effect
Fruit.
The fluorine azoles bacterium acyl azanol of table 24 is with other bactericide and its complex preparation to early blight of tomato field controling test
| Medicament | Dosage (ga.i./hm2) | Preventive effect (%) |
| 45% fluorine azoles bacterium acyl azanol Fluoxastrobin suspending agent | 150 | 91.5 |
| 45% fluorine azoles bacterium acyl azanol pyraclostrobin suspending agent | 150 | 92.2 |
| 45% fluorine azoles bacterium acyl azanol fluazinam suspending agent | 180 | 90.7 |
| 10% fluorine azoles bacterium acyl azanol fluazinam oil suspending agent | 150 | 92.3 |
| 45% fluorine azoles bacterium acyl azanol chlorfenapyr suspending agent | 120 | 93.4 |
| 45% fluorine azoles bacterium acyl azanol azoles amine bacterium ester suspending agent | 150 | 88.6 |
| 45% fluorine azoles bacterium acyl azanol SYP-Z048 suspending agent | 150 | 89.8 |
| 200g/L fluorine azoles bacterium acyl azanol suspending agents | 200 | 79.4 |
| 250g/L Fluoxastrobin suspending agents | 300 | 75.1 |
| 25% pyraclostrobin missible oil | 250 | 72.5 |
| 20% azoles amine bacterium ester suspending agent | 250 | 73.2 |
| 25% SYP-Z048 missible oil | 400 | 80.3 |
| 50% fluazinam missible oil | 260 | 70.2 |
| 22.5% ZEN 90160 missible oil | 150 | 79.8 |
Experiment as can be seen that fluorine azoles bacterium acyl azanol from it is different it is bactericide compounded after there is good preventing and treating to early blight of tomato
Effect, its single dose is above to the preventive effect of early blight, and dosage significantly reduces compared with single dose, to making under test dose
Thing and other beneficial organisms have no adverse effects.
Test example five：The field efficacy of fluorine azoles bacterium acyl azanol and different bactericide and its complex preparation to Tomato gray leaf spot
Experimental plot is located at little Sai villages all over the city of Hebei province, starts to spray first time medicine when tomato ash tikka sporadicly occurs, continuously
Medication 3 times, medication interval 10 days, 10 days investigation field incidences, calculate disease index and prevention effect after last medication.
The fluorine azoles bacterium acyl azanol of table 25 is with other bactericide and its complex preparation to tomato ash tikka field controling test
| Medicament | Dosage (ga.i./hm2) | Preventive effect (%) |
| 45% fluorine azoles bacterium acyl azanol Fluoxastrobin suspending agent | 120 | 90.1 |
| 45% fluorine azoles bacterium acyl azanol pyraclostrobin suspending agent | 120 | 93.2 |
| 45% fluorine azoles bacterium acyl azanol fluazinam suspending agent | 120 | 92.0 |
| 45% fluorine azoles bacterium acyl azanol SYP-Z048 suspending agent | 120 | 91.2 |
| 10% fluorine azoles bacterium acyl azanol SYP-Z048 oil suspending agent | 100 | 93.5 |
| 45% fluorine azoles bacterium acyl azanol natamycin oil suspending agent | 150 | 92.3 |
| 200g/L fluorine azoles bacterium acyl azanol suspending agents | 200 | 81.2 |
| 250g/L Fluoxastrobin suspending agents | 300 | 76.9 |
| 25% pyraclostrobin missible oil | 250 | 79.4 |
| 25% SYP-Z048 missible oil | 400 | 82.2 |
| 50% fluazinam missible oil | 260 | 79.8 |
| Natamycin | 240 | 72.4 |
Experiment as can be seen that fluorine azoles bacterium acyl azanol with it is different it is bactericide compounded after to Tomato gray leaf spot have well prevent
Effect is controlled, its single dose is above to the preventive effect of gray leaf spot, and dosage significantly reduces compared with single dose, under test dose
Crop and other beneficial organisms are had no adverse effects.
Test example six：The field efficacy of fluorine azoles bacterium acyl azanol and different bactericide and its complex preparation to pear scab
According to medicine inspecting institute of the Ministry of Agriculture《Pesticide field efficacy medicine test criterion》GB/T17980.24-2000 " bactericidal agent for preventing and treating pears
Scab field control effectiveness test criterion " is tested
Experimental plot is located at Hebei province Botou City great Hu villages village, starts to spray first time medicine when pear scab occurs, continuous to use
Medicine 3 times, medication interval 30 days, 20 days investigation field incidences, calculate disease index and prevention effect after last medication.
The fluorine azoles bacterium acyl azanol of table 26 is with other bactericide and its complex preparation to pear scab field controling test
Experiment as can be seen that fluorine azoles bacterium acyl azanol with it is different it is bactericide compounded after there is good preventing and treating effect to pear scab
Fruit, its single dose is above to the preventive effect of pear scab, and dosage significantly reduces compared with single dose, to making under test dose
Thing and other beneficial organisms have no adverse effects.
Test example seven：The field efficacy of fluorine azoles bacterium acyl azanol and different bactericide and its complex preparation to pears wheel line
According to medicine inspecting institute of the Ministry of Agriculture《Pesticide field efficacy medicine test criterion》GB/T17980.118-2004 " bactericidal agent for preventing and treating apples
Fruit ring spot field control effectiveness test criterion " is tested
Experimental plot is located at Bei little Chen villages of Xinji City of Hebei province, 10 days spray first time medicines, continuous use 4 after pear tree is thanked and spent
Secondary, medication interval 30 days, 14 days investigation field incidences, calculate disease index and prevention effect after last medication.
The fluorine azoles bacterium acyl azanol of table 27 is with other bactericide and its complex preparation to black rot of pear field controling test
Experiment as can be seen that fluorine azoles bacterium acyl azanol with it is different it is bactericide compounded after there is good preventing and treating effect to black rot of pear
Fruit, its single dose is above to the preventive effect of ring spot, and dosage significantly reduces compared with single dose, lasting period length, in experiment agent
Crop and other beneficial organisms are had no adverse effects under amount.
Test example eight：The field efficacy of fluorine azoles bacterium acyl azanol and different bactericide and its complex preparation to Pear black spot
Experimental plot is located at Hebei province Zhao County Xie village, starts to use first time medicine, continuous use 3 when pears pears blackspot is sporadicly fallen ill
Secondary, medication interval 20 days, 14 days investigation field incidences, calculate disease index and prevention effect after last medication.
The fluorine azoles bacterium acyl azanol of table 28 is with other bactericide and its complex preparation to Pear black spot field controling test
Experiment as can be seen that fluorine azoles bacterium acyl azanol with it is different it is bactericide compounded after there is good preventing and treating effect to Pear black spot
Fruit, its single dose is above to the preventive effect of black spot, and dosage significantly reduces compared with single dose, lasting period length, in experiment agent
Crop and other beneficial organisms are had no adverse effects under amount.
Although above the present invention is made to retouch in detail with general explanation, embodiment and experiment
State, but on the basis of the present invention, it can be made some modifications or improvements, this is apparent to those skilled in the art
's.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, are belonged to claimed
Scope.
Claims (10)
1. a kind of compound synergistic bactericidal composition for preventing and treating tomato and pear tree Major Diseases, its active component include fluorine azoles bacterium acyl hydroxyl
Amine and active component B；Wherein active component B includes methoxy acrylic bactericide, ergosterol synthetic inhibitor, substitution
One kind in aniline fungicides, bacillus subtilis (Bacillus subtilis) BAB-1；
Preferably, the methoxy acrylic bactericide include Fluoxastrobin, pyraclostrobin, Enestroburin, azoles amine bacterium ester,
Any of kresoxim-methyl, ZEN 90160, SYP-3375, chlorine pyridine bacterium fat, trifloxystrobin, alkene oxime amine are several；And/or
The ergosterol synthetic inhibitor includes any of SYP-Z048, Imazalil sulfate, natamycin or several；
And/or
The substituted aniline series bactericidal agent includes fluazinam；And/or the bacillus subtilis BAB-1 be its zymotic fluid or its
Lyophilized bacterium powder or its metabolite；It is preferred that the total viable count of the zymotic fluid is 7 × 109~1 × 1010CFU/mL；It is it is preferred that described
The total viable count of lyophilized bacterium powder is 1.8 × 1010~2.4 × 1010CFU/g。
2. preventing and treating tomato according to claim 1 and the compound synergistic bactericidal composition of pear tree Major Diseases, its feature exist
In the weight ratio of fluorine azoles bacterium acyl azanol and the active component B is (1-10):(1-10), it is preferably (1-4):(1-4), enters one
Step is preferably (1-2):(1-2).
3. the pesticidal preparations of the compound synergistic bactericidal composition containing claim 1 or 2；Preferably, the pesticidal preparations is can
WP, suspending agent or oil suspending agent；And/or
Preferably, the percentage by weight of active component is 1%-80%, preferably 30%-70% in the pesticidal preparations, more excellent
Select 45%-60%.
4. pesticidal preparations according to claim 3, it is wettable powder, it is characterised in that the wettable powder is
By what is be prepared including following component：10-30 part fluorine azoles bacterium acyl azanols, 10-30 part active component B, 1-10 part wetting agents, 1-
10 parts of dispersants, filler complement to 100 parts；
Preferably, the wetting agent be AEO, pelopon A, APES,
One or more of combinations in formaldehyde condensate sulfonate；And/or
The dispersant is naphthalene sulfonic acid-formaldehyde condensation product sodium salt, lignosulfite, lignin sulfonic acid sodium salt, 4- oleoyls-first
Epoxide benzene sulfonic acid sodium salt, sanlose, APES, ethylene glycol monobutyl ether, polyoxyethanyl alkyl
One or more combinations in ether, NPE；And/or
The filler is one or more combinations in white carbon, kaolin, precipitated calcium carbonate, diatomite, bentonite.
5. pesticidal preparations according to claim 4, it is characterised in that the wettable powder is by including following parts by weight
Component be prepared：21-24 part fluorine azoles bacterium acyl azanols, 21-24 part active component B, 5-8 part neopelexes
Salt, 3-5 part lignin sulfonic acid sodium salts, precipitated calcium carbonate complement to 100 parts；
Preferably, the wettable powder is prepared by the component including following parts by weight：22.96 part of 98% fluorine azoles bacterium
Acyl azanol, 23.32 part of 96.5% active component B, 6 parts of pelopon As, 4 parts of lignin sulfonic acid sodium salts, 43.72 parts
Precipitated calcium carbonate.
6. pesticidal preparations according to claim 3, it is suspending agent, it is characterised in that the suspending agent is by including such as
What lower component was prepared：10-30 part fluorine azoles bacterium acyl azanols, 10-30 active components B, 3-5 part emulsifying agent, 2-3 parts wetting agent,
3-5 parts preservative, 0.5~3 part of stabilizer, 0.5~2 part of defoamer, 1~3 part of antifreezing agent, water complement to 100 parts；
Preferably, the emulsifying agent is alkyl naphthalene sulfonic acid salt, alkyl phenol formaldehyde resin polyoxyethylene ether, anhydrous sorbitol tristearin
In acid esters, triphenoethyl benzene phenol polyoxy more than one or both of alkene oxygen ethylene block polymer or Tween-60；And/or
The wetting agent be alkylphenol-polyethenoxy base ether phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate,
It is more than one or both of alkyl sulfate, phenethyl phenol polyoxyethylene groups ether phosphate, sodium alkyl sulfonate or naphthalene sulfonate；
And/or
So-called preservative is more than one or both of benzoic acid, formaldehyde or sodium benzoate；And/or
The stabilizer is more than one or both of epoxy chlorine alkane or triphenyl phosphate；And/or
The defoamer is organosilicon；And/or
The antifreezing agent is more than one or both of propane diols, ethylene glycol, glycerine, urea or inorganic salts.
7. pesticidal preparations according to claim 6, it is characterised in that the suspending agent is the group by including following parts by weight
Divide what is be prepared：21-24 part fluorine azoles bacterium acyl azanols, 21-24 part active component B, 3-5 part alkylphenol-formaldehyde resin polyoxyethylene
Ether, 2-4 part dodecyl sodium sulfates, 3-5 parts sodium benzoate, 2-3 part epoxy chlorine alkane, 0.5-1 parts organosilicon, 1-3 parts propane diols,
Water complements to 100 parts；
The suspending agent is prepared by the component including following parts by weight：22.96 part of 98% fluorine azoles bacterium acyl azanol；
22.50 part active component B；4 parts of alkyl phenol formaldehyde resin polyoxyethylene ethers, 3 parts of dodecyl sodium sulfates, 4 parts of sodium benzoates, 2
Part epoxy chlorine alkane, 0.5 part of organosilicon, 1 part of propane diols and 40.04 parts of water.
8. pesticidal preparations according to claim 3, it is oil suspending agent, it is characterised in that the oil suspending agent is by including such as
What lower component was prepared：5-10 part fluorine azoles bacterium acyl azanols, 5-10 part active component B, 10-20 part wetting dispersing agents, 1-2 parts stick
Conditioning agent is spent, oil base complements to 100 parts；
Preferably, the wetting dispersing agent is：The methyl esters emulsifier YUS-EC2200, mineral oil emulsion agent YUS- of this grease of bamboo
135B, vegetable oil emulsifier YUS-110；Methyl esters emulsifier VO/02N, mineral oil emulsion agent MO/P；Methyl esters emulsifier 1577
Or B1579, vegetable oil emulsifier 1573；Oily suspension aids SOD；Silicone oil and white oil emulsifying agent C13/3；Methyl esters emulsifier OF-
It is more than one or both of 8712-70 or OF-7812-70；And/or
The viscosity-controlling agent is：It is more than one or both of organobentonite, aluminium-magnesium silicate, gas-phase silica；And/or
The oil base is：It is more than one or both of methyl oleate, vegetable oil, mineral oil.
9. pesticidal preparations according to claim 8, it is oil suspending agent, it is characterised in that the oil suspending agent agricultural chemicals by including
The component of following parts by weight is prepared：5.1 parts of fluorine azoles bacterium acyl azanols, 5.1 parts of active component B, 10 parts of vegetable oil emulsifiers, 1
Part organobentonite, soybean oil complement to 100 parts.
10. the pesticidal preparations described in compound synergistic bactericidal composition or claim any one of 3-9 described in claim 1 or 2
Application in tomato and the preventing and treating of pear tree Major Diseases；
Preferably, the disease is included in gray mold, early blight, leaf mold, gray leaf spot, scab, ring spot, black spot
It is one or more.
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| CN202010197233.0A Active CN111296460B (en) | 2017-08-14 | 2017-08-14 | Compound synergistic bactericidal composition for preventing and treating main diseases of tomatoes and pears and application thereof |
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|---|---|---|---|---|
| CN108142422A (en) * | 2018-02-02 | 2018-06-12 | 深圳诺普信农化股份有限公司 | Bactericidal composition |
| CN108142423A (en) * | 2018-02-02 | 2018-06-12 | 深圳诺普信农化股份有限公司 | Bactericidal composition and its application |
| CN108294013A (en) * | 2018-02-02 | 2018-07-20 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing fluorine azoles bacterium acyl azanol and its application |
| CN109156477A (en) * | 2018-09-14 | 2019-01-08 | 河北省农林科学院植物保护研究所 | Application of the bacillus subtilis BAB-1 in prevention and treatment leaf muld of tomato |
| CN109566624A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN109566640A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN110195033A (en) * | 2019-06-05 | 2019-09-03 | 中国农业科学院蔬菜花卉研究所 | One bacillus subtilis and the application in the prevention and treatment of S. lycopersici leaf spot |
| CN110679597A (en) * | 2019-11-18 | 2020-01-14 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Medicament composition for preventing and treating macadimia nut gray mold |
| CN114271278A (en) * | 2021-12-30 | 2022-04-05 | 上海绿泽生物科技有限责任公司 | Yield-increasing pesticide composition and application thereof |
| CN114766483A (en) * | 2022-05-20 | 2022-07-22 | 青岛海利尔生物科技有限公司 | Sterilization composition containing bronopol and application thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103081917A (en) * | 2013-01-17 | 2013-05-08 | 湖南农大海特农化有限公司 | Fluxapyroxad-fluazinam sterilization composition |
| CN105028483A (en) * | 2015-07-27 | 2015-11-11 | 河北省农林科学院植物保护研究所 | Compound bactericide containing bacillus subtilis BAB-1 and boscalid and application thereof |
| CN106857540A (en) * | 2017-04-17 | 2017-06-20 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol and triazole bactericidal agent |
| CN107006480A (en) * | 2017-04-20 | 2017-08-04 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol |
| CN108419804A (en) * | 2017-02-13 | 2018-08-21 | 中化作物保护品有限公司 | A kind of bactericidal composition and its application |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR083112A1 (en) * | 2010-10-01 | 2013-01-30 | Syngenta Participations Ag | METHOD FOR CONTROLLING PHYTOPATHOGEN DISEASES AND COMPOSITIONS USEFUL FUNGICIDES FOR SUCH CONTROL |
| CN102067858A (en) * | 2011-01-18 | 2011-05-25 | 河北省农林科学院植物保护研究所 | Compound bactericide for mainly treating grey mold of fruits and vegetables |
-
2017
- 2017-08-14 CN CN202010197233.0A patent/CN111296460B/en active Active
- 2017-08-14 CN CN201710692451.XA patent/CN107494568B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103081917A (en) * | 2013-01-17 | 2013-05-08 | 湖南农大海特农化有限公司 | Fluxapyroxad-fluazinam sterilization composition |
| CN105028483A (en) * | 2015-07-27 | 2015-11-11 | 河北省农林科学院植物保护研究所 | Compound bactericide containing bacillus subtilis BAB-1 and boscalid and application thereof |
| CN108419804A (en) * | 2017-02-13 | 2018-08-21 | 中化作物保护品有限公司 | A kind of bactericidal composition and its application |
| CN106857540A (en) * | 2017-04-17 | 2017-06-20 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol and triazole bactericidal agent |
| CN107006480A (en) * | 2017-04-20 | 2017-08-04 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109566624A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN109566640A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN108142422A (en) * | 2018-02-02 | 2018-06-12 | 深圳诺普信农化股份有限公司 | Bactericidal composition |
| CN108142423A (en) * | 2018-02-02 | 2018-06-12 | 深圳诺普信农化股份有限公司 | Bactericidal composition and its application |
| CN108294013A (en) * | 2018-02-02 | 2018-07-20 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing fluorine azoles bacterium acyl azanol and its application |
| CN109156477A (en) * | 2018-09-14 | 2019-01-08 | 河北省农林科学院植物保护研究所 | Application of the bacillus subtilis BAB-1 in prevention and treatment leaf muld of tomato |
| CN110195033A (en) * | 2019-06-05 | 2019-09-03 | 中国农业科学院蔬菜花卉研究所 | One bacillus subtilis and the application in the prevention and treatment of S. lycopersici leaf spot |
| CN110679597B (en) * | 2019-11-18 | 2021-08-06 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Medicament composition for preventing and treating macadimia nut gray mold |
| CN110679597A (en) * | 2019-11-18 | 2020-01-14 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Medicament composition for preventing and treating macadimia nut gray mold |
| CN113661998A (en) * | 2019-11-18 | 2021-11-19 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Energy metabolism repressor for resisting gray mold |
| CN113661998B (en) * | 2019-11-18 | 2022-11-11 | 山东康惠植物保护有限公司 | Energy metabolism repressor for resisting gray mold |
| CN114271278A (en) * | 2021-12-30 | 2022-04-05 | 上海绿泽生物科技有限责任公司 | Yield-increasing pesticide composition and application thereof |
| CN114271278B (en) * | 2021-12-30 | 2023-09-08 | 上海绿泽生物科技有限责任公司 | Pesticide composition for increasing yield and application thereof |
| CN114766483A (en) * | 2022-05-20 | 2022-07-22 | 青岛海利尔生物科技有限公司 | Sterilization composition containing bronopol and application thereof |
| CN114766483B (en) * | 2022-05-20 | 2024-02-09 | 青岛海利尔生物科技有限公司 | Sterilization composition containing bronopol and application thereof |
| CN116420724A (en) * | 2023-04-19 | 2023-07-14 | 宁波三江益农化学有限公司 | Pesticide composition, pesticide, preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111296460B (en) | 2021-08-06 |
| CN111296460A (en) | 2020-06-19 |
| CN107494568B (en) | 2021-04-06 |
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