CN107468596B - Pure natural active hair dye - Google Patents

Pure natural active hair dye Download PDF

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Publication number
CN107468596B
CN107468596B CN201710912838.1A CN201710912838A CN107468596B CN 107468596 B CN107468596 B CN 107468596B CN 201710912838 A CN201710912838 A CN 201710912838A CN 107468596 B CN107468596 B CN 107468596B
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agent
hair
freeze
mass
dried powder
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CN107468596A (en
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吴昊
张也
罗宇娟
万超群
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Shanxi Haosi Technology Co.,Ltd.
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Shanxi Lyvdikangmin Agricultural Development Co ltd
Shaanxi Normal University
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/002Preparations for repairing the hair, e.g. hair cure
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/004Preparations used to protect coloured hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/10Preparations for permanently dyeing the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/84Products or compounds obtained by lyophilisation, freeze-drying

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Abstract

The invention provides a pure plant coloring agent, which comprises an agent A and an agent B, wherein the agent A is plant active coloring freeze-dried powder, and the agent B is a traditional Chinese medicine extracting solution. The preparation A comprises lyophilized powder of Juglandis pericarpium Citri Reticulatae viride, lyophilized powder of Mori fructus, and lyophilized powder of rhizoma Zingiberis recens. The preparation B comprises various traditional Chinese medicines and the balance of deionized water according to different effects on hair. Mixing the agent A and the agent B, uniformly coating the mixture on clean hair, and keeping the temperature for half an hour. The hair dye adopts natural plants as main components of the hair dye, and does not contain any harmful components. In addition, the freeze drying technology is adopted to keep the activity of the effective dyeing components of the natural plants. Meanwhile, the nutrient components are added to promote the hair to absorb the nutrition, so that the hair is more smooth.

Description

Pure natural active hair dye
Technical Field
The invention relates to the field of hair dyes, in particular to a pure natural active hair dye, which maintains the activity of effective dyeing components of natural plants by utilizing a freeze drying technology.
Background
With the development of times, hair dyeing becomes fashionable, however, at present, most hair dyes are oxidation hair dyes, the main raw materials of the oxidation hair dyes are p-phenylenediamine compounds and benzenediols, the damage to hair keratin is quite large, the hair is easy to be damaged, and the hair is easy to be withered, crisp, split and shed after being frequently used. Some pure natural dyes destroy the active substances of the dyeing components due to improper extraction (drying and crushing). In order to solve the above problems, patent application 201010572862.3 discloses a natural hair dye composition. The method comprises freeze-drying natural melanin, radix Polygoni Multiflori, rhizoma Zingiberis, rhizoma bletilla, indigo naturalis, rhizoma Nardostachyos, nidus Vespae extract, carbon molecular sieve, etc. at critical point, grinding at 90-125 deg.C before freeze-drying raw materials, wherein the internal structure of effective components is changed during grinding at the temperature, and the raw materials are contacted with air sufficiently to destroy activity of dyeing components.
Disclosure of Invention
The invention aims to provide a pure natural active hair dye which is convenient to prepare aiming at the defects of the prior art.
The invention is realized by adopting the following technical scheme:
a pure natural active hair dye comprises agent A and agent B, wherein agent A is lyophilized powder of active plant dye, and agent B is Chinese medicinal extractive solution; wherein, the agent A has the function of coloring hair, and the agent B has the function of deeply nourishing hair roots and repairing hair. When used, the mixing ratio of the agent A and the agent B is 1:1 (weight ratio).
The agent A is composed of walnut green seedcase freeze-dried powder, mulberry freeze-dried powder and ginger freeze-dried powder in different proportions, and is agent A I;
the A agent I is a black dye and consists of the following freeze-dried powder in percentage by mass: 40-60% of walnut peel freeze-dried powder, 30-40% of mulberry freeze-dried powder and 10-30% of ginger freeze-dried powder;
in a preferred embodiment, the A agent I comprises the following freeze-dried powder in percentage by mass: 60% of walnut peel freeze-dried powder, 30% of mulberry freeze-dried powder and 10% of ginger freeze-dried powder.
The preparation method of the agent A comprises the following steps:
(a) cleaning fresh walnut green seedcases, mulberries and ginger, and respectively freezing and drying;
(b) freeze drying, pulverizing, and mixing the lyophilized powder at different ratios.
The agent B is divided into four types according to the hair effect, namely agent B I, agent B II, agent B III and agent B IV;
the agent B I can increase the flexibility of hair, enables the hair not to become brittle easily, is suitable for people with easily broken hair, and is prepared from the following components in percentage by mass: 10 to 30 percent of ginseng, 20 to 30 percent of astragalus root, 20 to 30 percent of phellodendron bark and 20 to 40 percent of Szechuan lovage rhizome; the surface layer of human hair is composed of numerous scales, the cuticle of normal hair is arranged in a roof scaly shape, and the hair skin of damaged hair is not arranged in a roof scaly shape any more, so that the hair becomes brittle and easy to break. While agent B deeply moistens and repairs scalp and improves the phenomenon of easy hair breakage. In a preferred embodiment, the agent B I comprises the following components in percentage by mass: 25% of ginseng, 25% of astragalus, 20% of phellodendron and 30% of ligusticum wallichii.
The agent B II can improve the alopecia problem and promote the hair regrowth, and is prepared from the following components in percentage by mass: 10-20% of peony, 10-30% of medlar, 10-20% of astragalus root and 50-70% of white mulberry root-bark; alopecia is mainly caused by damage to scalp tissues and hair follicle cells, while agent B II has the effects of activating scalp cells and stimulating hair follicles, thereby promoting hair regrowth. In a preferred embodiment, the agent B II comprises the following components in percentage by mass: 20% of Chinese herbaceous peony, 10% of Chinese wolfberry, 10% of astragalus root and 60% of white mulberry root-bark.
The agent B III is helpful for eliminating hair oil, relieving itching, removing dandruff and keeping scalp healthy, is suitable for oily hair, and is prepared from the following components in percentage by mass: 20 to 30 percent of tuber fleeceflower root, 10 to 20 percent of cacumen biotae, 10 to 20 percent of yerbadetajo herba ecliptae, 10 to 20 percent of salvia miltiorrhiza, 30 to 40 percent of mint and 10 to 20 percent of mung bean; the root of greasy hair and dandruff is the vigorous activity of the sebaceous glands on the head and the imbalance of the oil secretion of the scalp. The B preparation III uses Chinese medicinal materials such as cacumen Platycladi, semen Phaseoli Radiati, and herba Menthae to nourish hair root, regulate scalp oil secretion, and improve hair living environment. In a preferred embodiment, the agent B III comprises the following components in percentage by mass: 30% of polygonum multiflorum, 10% of cacumen biotae, 10% of eclipta, 10% of salvia miltiorrhiza, 30% of mint and 10% of mung bean.
The agent B and the agent IV have the effects of blackening and moistening hair, endow the hair with glossiness and soft and smooth feeling, are suitable for dry and withered hair, and are prepared from the following components in percentage by mass: 20 to 40 percent of angelica, 20 to 30 percent of Chinese honeylocust fruit, 10 to 20 percent of cacumen biotae, 20 to 30 percent of mint and 10 to 20 percent of medlar; the withered, yellow and lusterless hair is mainly caused by damaged hair small skin on the surface of hair, serious water loss and insufficient nutrition of hair follicle, so that the hair is atrophied. And the agent B and the agent IV repair hair small skins on the hair surface, provide enough nutrition for hair roots, and have the effects of blackening and moistening the hair. In a preferred embodiment, the agent B IV comprises the following components in percentage by mass: 30% of angelica sinensis, 25% of Chinese honeylocust fruit, 15% of cacumen biotae, 20% of mint and 10% of medlar.
The preparation method of the agent B comprises the following steps:
(a) cleaning the Chinese medicinal materials, oven drying, and pulverizing.
(b) According to different effects on hair, the crushed Chinese medicinal materials are mixed according to the mass percentage, put into a reaction kettle, added with deionized water and mixed uniformly, the weight ratio of water to the mixture is 2:1, and then kept at the constant temperature of 70 ℃ for 2 hours.
(c) Adding an ionic active agent and a thickening agent into the extracting solution; according to the extraction weight ratio, the extract: ionic active agent: the thickening agent is 100:40: 1.
Wherein the ionic active agent is polyethylene glycol, and the thickening agent is guar gum.
(d) And vacuum concentrating the extractive solution to obtain Chinese medicinal concentrated solution with concentration of 60-75%.
The hair dye preparation method adopts a vacuum freeze drying technology, and water frozen by fresh plants such as walnut green husks and mulberries is directly sublimated from ice solids into steam in a high-vacuum environment. Because the drying process is at very low temperature and basically isolates air, the biological, chemical and physical properties of the plants are stable, and the active substances in the raw materials are well preserved. Meanwhile, the vacuum freeze drying technology is thorough in dehydration, and the dried walnut green husks, the dried mulberries and the like are stable in properties and convenient to store for a long time. Finally, in the vacuum freeze drying process, the hair dyeing natural raw material has no surface hardening problem, and the interior of the hair dyeing natural raw material is formed into a porous sponge shape, so that the hair dyeing natural raw material has excellent rehydration property, and can recover the state before drying in a short time. As described above, the vacuum freeze-drying technique offers many advantages for the production of natural reactive colorants.
The functions of the raw materials used in the invention are as follows:
walnut green husk: the exocarpium Juglandis Immaturus contains exocarpium Citri Reticulatae viride pigment such as purpurin and green pigment.
And (3) mulberry fruit: the mulberry contains a large amount of nutrient substances required by human bodies and also contains hair blackening elements, so that the hair can be blackened and glossy.
Ginger: the ginger can prevent dandruff falling and hair falling, and protect scalp.
Polygonum multiflorum: has effects in regulating nerve and endocrine, nourishing hair root, promoting generation of hair melanin, blackening hair, and moistening hair.
Ginseng: ginseng radix has effects of dilating head capillary, increasing hair nutrition, improving hair toughness, and protecting hair from alopecia and breakage.
Ligusticum wallichii: the ligusticum wallichii is beneficial to improving the nutrition of the hair, expands the capillary vessels of the head, enables the hair to have good flexibility and function of difficult embrittlement, and keeps the hair smooth and glossy.
Chinese angelica: can dilate capillary vessels of scalp and promote blood circulation. The prepared radix Angelicae sinensis shampoo can prevent alopecia and moisten skin and hair. It also has effects in blackening and brightening hair, and preventing yellow hair and white hair.
Red sage root: promoting hair melanogenesis, improving white hair, yellow hair, and dry hair, and relieving itching and dandruff when combined with other natural medicines.
Astragalus root: has effects in dilating blood vessel, preventing and treating alopecia, and promoting hair growth.
Wolfberry fruit: can prevent alopecia and make hair black and bright.
The hair dye adopts natural plants as main components of the hair dye, and does not contain any harmful components. In addition, the freeze drying technology is adopted to keep the activity of the effective dyeing components of the natural plants. Meanwhile, the nutrient components are added to promote the hair to absorb the nutrition, so that the hair is more smooth.
Detailed Description
The following provides a detailed description of specific embodiments of the present invention.
Example 1
A natural active hair dye comprises agent A and agent B, wherein agent A is lyophilized powder of active plant dye, and agent B is Chinese medicinal extractive solution.
The preparation A is composed of walnut green seedcase freeze-dried powder, mulberry freeze-dried powder and ginger freeze-dried powder in different proportions, and is preparation A I; the following were used:
the A agent I consists of the following freeze-dried powder in percentage by mass: 60% of walnut peel freeze-dried powder, 30% of mulberry freeze-dried powder and 10% of ginger freeze-dried powder;
the preparation method of the agent A comprises the following steps: (a) cleaning fresh walnut green seedcase, mulberry and ginger, and respectively freeze-drying; (b) freeze drying, pulverizing, and mixing with the lyophilized powder.
The agent B is divided into four types according to the hair effect, namely agent B I, agent B II, agent B III and agent B IV; the following were used:
the agent B I can increase the flexibility of hair, enables the hair not to become brittle easily, is suitable for people with easily broken hair quality, and is prepared from the following freeze-dried powder in percentage by mass: 25% of ginseng, 25% of astragalus, 20% of phellodendron and 30% of ligusticum wallichii;
the agent B II can improve the alopecia problem and promote the hair regrowth, and is prepared from the following freeze-dried powder in percentage by mass: 20% of Chinese herbaceous peony, 10% of medlar, 10% of astragalus root and 60% of white mulberry root-bark;
the agent B III is helpful for eliminating hair oil, relieving itching, removing dandruff and keeping scalp healthy, is suitable for oily hair, and is prepared from the following freeze-dried powder in percentage by mass: 30% of polygonum multiflorum, 10% of cacumen biotae, 10% of eclipta, 10% of salvia miltiorrhiza, 30% of mint and 10% of mung bean;
the agent B IV has the effects of blackening and moistening hair, endows the hair with glossiness and soft and smooth feeling, is suitable for dry withered and yellow hair, and is prepared from the following freeze-dried powder in percentage by mass: 30% of angelica sinensis, 25% of Chinese honeylocust fruit, 15% of cacumen biotae, 20% of mint and 10% of medlar.
The preparation method of the agent B comprises the following steps: (a) cleaning various Chinese medicinal materials, oven drying, and pulverizing; (b) according to different effects on hair, the crushed Chinese medicinal materials are mixed according to a certain mass percentage, put into a reaction kettle, added with deionized water and mixed uniformly, the weight ratio of water to the mixture is 2:1, and then kept at the constant temperature of 70 ℃ for 2 hours; (c) adding 40% of ionic active agent and 1% of thickening agent into the extracting solution; (d) vacuum concentrating the extractive solution to obtain Chinese medicinal concentrated solution.
The user conditions of this example 1 are as follows: 100 patients with white hair and unhealthy hair were tested and divided into four groups on average. The first group of patients had fragile hair, the second group had severe hair loss problems, the third group had severe head oil, and the fourth group had dry, yellow and lusterless hair.
Figure GDA0002525292240000071
Mixing the agent A and the agent B at a ratio of 1:1, respectively applying on hair of patients with different hair qualities, keeping warm for half an hour, and cleaning to obtain black hair. After 1 application per month and 3 consecutive months, the first group had 21 patients with increased hair flexibility (84%), the second group had improved hair loss, 19 patients with increased hair mass (76%), the third group had a decrease in the rate of hair cuticle oil from 50% -60% to 6% -8% in 23 patients (92%), and the fourth group had 23 patients with smooth and bright hair (92%).
Through data analysis, the agent A plays a role in dyeing, and the agent B can play a role in repairing different hair qualities.
Example 2
A natural active hair dye comprises agent A and agent B, wherein agent A is lyophilized powder of active plant dye, and agent B is Chinese medicinal extractive solution.
The preparation A is composed of walnut green seedcase freeze-dried powder, mulberry freeze-dried powder and ginger freeze-dried powder in different proportions, and is preparation A I; the following were used:
the A agent I consists of the following freeze-dried powder in percentage by mass: 50% of walnut peel freeze-dried powder, 35% of mulberry freeze-dried powder and 15% of ginger freeze-dried powder;
the preparation method of the agent A comprises the following steps: (a) cleaning fresh walnut green seedcase, mulberry and ginger, and respectively freeze-drying; (b) freeze drying, pulverizing, and mixing with the lyophilized powder.
The agent B is divided into four types according to the hair effect, namely agent B I, agent B II, agent B III and agent B IV; the following were used:
the agent B I can increase the flexibility of hair, enables the hair not to become brittle easily, is suitable for people with easily broken hair quality, and is prepared from the following freeze-dried powder in percentage by mass: 10% of ginseng, 20% of astragalus, 30% of golden cypress and 40% of ligusticum wallichii;
the agent B II can improve the alopecia problem and promote the hair regrowth, and is prepared from the following freeze-dried powder in percentage by mass: 10% of Chinese herbaceous peony, 10% of medlar, 10% of astragalus root and 70% of white mulberry root-bark;
the agent B III is helpful for eliminating hair oil, relieving itching, removing dandruff and keeping scalp healthy, is suitable for oily hair, and is prepared from the following freeze-dried powder in percentage by mass: 20% of polygonum multiflorum, 15% of cacumen biotae, 10% of eclipta, 10% of salvia miltiorrhiza, 35% of mint and 10% of mung bean;
the agent B IV has the effects of blackening and moistening hair, endows the hair with glossiness and soft and smooth feeling, is suitable for dry withered and yellow hair, and is prepared from the following freeze-dried powder in percentage by mass: 20% of angelica sinensis, 20% of Chinese honeylocust fruit, 20% of cacumen biotae, 20% of mint and 20% of medlar.
The preparation method of the agent B comprises the following steps: (a) cleaning various Chinese medicinal materials, oven drying, and pulverizing; (b) according to different effects on hair, the crushed Chinese medicinal materials are mixed according to a certain mass percentage, put into a reaction kettle, added with deionized water and mixed uniformly, the weight ratio of water to the mixture is 2:1, and then kept at the constant temperature of 70 ℃ for 2 hours; (c) adding 40% of ionic active agent and 1% of thickening agent into the extracting solution; (d) vacuum concentrating the extractive solution to obtain Chinese medicinal concentrated solution.
Example 3
A natural active hair dye comprises agent A and agent B, wherein agent A is lyophilized powder of active plant dye, and agent B is Chinese medicinal extractive solution.
The preparation A is composed of walnut green seedcase freeze-dried powder, mulberry freeze-dried powder and ginger freeze-dried powder in different proportions, and is preparation A I; the following were used:
the A agent I consists of the following freeze-dried powder in percentage by mass: 40% of walnut peel freeze-dried powder, 30% of mulberry freeze-dried powder and 30% of ginger freeze-dried powder;
the preparation method of the agent A comprises the following steps: (a) cleaning fresh walnut green seedcase, mulberry and ginger, and respectively freeze-drying; (b) freeze drying, pulverizing, and mixing with the lyophilized powder.
The agent B is divided into four types according to the hair effect, namely agent B I, agent B II, agent B III and agent B IV; the following were used:
the agent B I can increase the flexibility of hair, enables the hair not to become brittle easily, is suitable for people with easily broken hair quality, and is prepared from the following freeze-dried powder in percentage by mass: 30% of ginseng, 20% of astragalus, 30% of phellodendron and 20% of ligusticum wallichii;
the agent B II can improve the alopecia problem and promote the hair regrowth, and is prepared from the following freeze-dried powder in percentage by mass: 10% of Chinese herbaceous peony, 20% of medlar, 20% of astragalus root and 50% of white mulberry root-bark;
the agent B III is helpful for eliminating hair oil, relieving itching, removing dandruff and keeping scalp healthy, is suitable for oily hair, and is prepared from the following freeze-dried powder in percentage by mass: 20% of polygonum multiflorum, 10% of cacumen biotae, 20% of eclipta, 10% of salvia miltiorrhiza, 30% of mint and 10% of mung bean;
the agent B IV has the effects of blackening and moistening hair, endows the hair with glossiness and soft and smooth feeling, is suitable for dry withered and yellow hair, and is prepared from the following freeze-dried powder in percentage by mass: 40% of angelica sinensis, 20% of Chinese honeylocust fruit, 10% of cacumen biotae, 20% of mint and 10% of medlar.
The preparation method of the agent B comprises the following steps: (a) cleaning various Chinese medicinal materials, oven drying, and pulverizing; (b) according to different effects on hair, the crushed Chinese medicinal materials are mixed according to a certain mass percentage, put into a reaction kettle, added with deionized water and mixed uniformly, the weight ratio of water to the mixture is 2:1, and then kept at the constant temperature of 70 ℃ for 2 hours; (c) adding 40% of ionic active agent and 1% of thickening agent into the extracting solution; (d) vacuum concentrating the extractive solution to obtain Chinese medicinal concentrated solution.
It should be noted that modifications and applications may occur to those skilled in the art without departing from the spirit and scope of the invention as defined by the appended claims. Components not specifically described in the embodiments of the present invention can be implemented by the prior art.

Claims (1)

1. A pure natural active hair dye is characterized in that: comprises agent A and agent B, wherein the agent A is plant active staining lyophilized powder, and the agent B is Chinese medicinal extractive solution; the mixing ratio of the agent A to the agent B is 1: 1;
the agent A is a black dye and consists of the following freeze-dried powder in percentage by mass: 60% of walnut peel freeze-dried powder, 30% of mulberry freeze-dried powder and 10% of ginger freeze-dried powder;
the agent B is agent B I, agent B II, agent B III and agent B IV respectively;
the agent B I is prepared from the following components in percentage by mass: 25% of ginseng, 25% of astragalus, 20% of phellodendron and 30% of ligusticum wallichii;
the B agent II is prepared from the following components in percentage by mass: 20% of Chinese herbaceous peony, 10% of medlar, 10% of astragalus root and 60% of white mulberry root-bark;
the B agent III is prepared from the following components in percentage by mass: 30% of polygonum multiflorum, 10% of cacumen biotae, 10% of eclipta, 10% of salvia miltiorrhiza, 30% of mint and 10% of mung bean;
the agent B and the agent IV are prepared from the following components in percentage by mass: 30% of angelica sinensis, 25% of Chinese honeylocust fruit, 15% of cacumen biotae, 20% of mint and 10% of medlar;
the preparation method of the agent A comprises the following steps:
(a) cleaning fresh walnut green seedcases, mulberries and ginger, and respectively freezing and drying;
(b) freeze drying, pulverizing, and mixing with the lyophilized powder;
the preparation method of the agent B comprises the following steps:
(a) cleaning the Chinese medicinal materials, oven drying, and pulverizing;
(b) mixing the crushed Chinese medicinal materials according to different effects on hair by mass percent, putting the mixture into a reaction kettle, adding deionized water, uniformly mixing, wherein the weight ratio of water to the mixture is 2:1, and then keeping the temperature at 70 ℃ for 2 hours;
(c) adding 40% of ionic active agent and 1% of thickening agent into the extracting solution according to the weight ratio of the extracting solution; the ionic active agent is polyethylene glycol, and the thickening agent is guar gum;
(d) and vacuum concentrating the extracting solution to obtain the traditional Chinese medicine concentrated solution.
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Publication number Priority date Publication date Assignee Title
CN109758389A (en) * 2018-10-29 2019-05-17 武威福民汇科技开发有限公司 A kind of processing method of green peel of walnut day hair dye
CN111803388B (en) * 2020-07-20 2023-08-11 西安幸福未来化妆品有限公司 Pure natural hair dye powder and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103735453A (en) * 2013-12-21 2014-04-23 姜波 Health maintaining type herbaceous plant hair dye
CN106691939A (en) * 2017-01-13 2017-05-24 浙江百寿堂药业有限公司 Enzyme traditional Chinese medicine hair care cream

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103735453A (en) * 2013-12-21 2014-04-23 姜波 Health maintaining type herbaceous plant hair dye
CN106691939A (en) * 2017-01-13 2017-05-24 浙江百寿堂药业有限公司 Enzyme traditional Chinese medicine hair care cream

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