CN107468586A - A kind of water outlet moisturizing element face frost and preparation method thereof - Google Patents
A kind of water outlet moisturizing element face frost and preparation method thereof Download PDFInfo
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- CN107468586A CN107468586A CN201710822627.9A CN201710822627A CN107468586A CN 107468586 A CN107468586 A CN 107468586A CN 201710822627 A CN201710822627 A CN 201710822627A CN 107468586 A CN107468586 A CN 107468586A
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- water outlet
- face frost
- element face
- moisturizing element
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Abstract
The invention belongs to the technical field of cosmetics, discloses a kind of water outlet moisturizing element face frost and preparation method thereof.The water outlet moisturizing element face frost is prepared by following raw material by weight percentage：Emulsifying agent 3%~7%, thickening property elastomer 1%~5%, silicone oil 0.5%~3.5%, grease 5%~10%, titanium dioxide 5%~8%, oil phase thickeners 1%~5%, NMF 15%~25%, PH conditioning agents 0.9%~1.5%, preservative 0.1%~0.8%, active component 1%~3%, deionized water surplus.The plain face frost of the present invention has good hand touch, and salubrious to moisten, ductility is good, and hides flaw whitening naturally, during smearing with silk slide as sliding and feel and go out the pleasant feeling of moistening water.The present invention can not only smear up to be brightened naturally, there is the skin sense of water outlet, moreover it is possible to the whitening for inherence of getting up and moisture-keeping efficacy.
Description
Technical field
The invention belongs to the technical field of cosmetics, and in particular to a kind of water outlet moisturizing element face frost and preparation method thereof.
Background technology
In recent years, as cosmetic art quickly develops the fast pace life with city white collar, a enjoy of being born
The plain face frost that masses pursue, the birth of plain face frost, plain face frost has started the wind of one plain face goddess within short a period of time
Cruelly, plain face frost is not only convenient for carrying, and also and the maximum difference of traditional skin care item is that they are the combinations of skin care item and color make-up
Body, not simple only traditional skin care product skin care, the function of moisturizing moisturizing, also with color make-up with whitening highlight the screening flaw
Function because containing titanium dioxide in plain face frost, also with certain physical sunscreen function.In so allegro work now
In making and living, everybody does a series of cumbersome basic nursings without the time of abundance and then made up again daytime, goes home at night again
Makeup removing.But it is quick for convenience, as long as plain face frost is smeared a little after carrying out most basic nursing, it is possible to U.S. a whole day, at night
Makeup removing can also not had to, directly use mildy wash wash clean.Here it is doting on for most of modern workplace peoples and " lazy woman "
Youngster.But the screening flaw effect of plain face frost is not to protrude very much, and maintenance function is also not special powerful, if above
Basic nursing moisturizing is not handled properly, it is easy to occur that face is dry and astringent or skin becomes it is obscure the problem of.
Current plain face frost patent only discloses five kinds of patents：Chinese patent application CN106474040A pearl essences face frost
And preparation method thereof；The plain face frost that a kind of whitenings of Chinese patent application CN106265390A highlight, Chinese patent application
A kind of cosmetic compositions containing black fruit fructus lycii extract of CN106265437A and plain face frost；Chinese patent application
A kind of water resistants of CN106265475A exempt from plain face frost and preparation method thereof of removing ornaments and formal dress；Chinese patent application CN104825371A is a kind of containing height
Plain face frost of concentration essence lotion and preparation method thereof；Wherein all it is not involved with water outlet moisturizing element face frost.
Therefore a plain face frost for being different from traditional Water-In-Oil is developed, there can be the skin sense that water moistens, it is not thick and heavy；Can also immediately and
Long-acting moisturizing, the water outlet moisturizing element face frost that and can hides the Water-In-Oil of flaw brilliant white naturally for a long time are extremely urgent.
The content of the invention
The shortcomings that in order to overcome prior art and deficiency, primary and foremost purpose of the invention are to provide a kind of water outlet moisturizing element face
Frost, the plain face frost have the effect of water outlet when smearing, skin sense water profit is salubrious, and ductility is good, holds the adornment time and grows, and from
Flaw whitening is so hidden, also with the sliding sense as silk cunning.
Another object of the present invention is to provide the preparation method of above-mentioned water outlet moisturizing element face frost.The present invention is using normal temperature breast
The mode (i.e. cold to match somebody with somebody method) of change, the energy is saved, simple to operate, environmental protection.The method that traditional plain face frost is typically emulsified using high temperature,
Power consumption is big, but the present invention uses normal temperature emulsifying manner, and product stability is improved while reducing and consuming energy.
The purpose of the present invention is achieved through the following technical solutions：
A kind of water outlet moisturizing element face frost, is prepared by following raw material by weight percentage：
The weight percentage sum of each raw material is 100%.
Preferably, the water outlet moisturizing element face frost, is prepared by following raw material by weight percentage：
The weight percentage sum of each raw material is 100%.
It is highly preferred that the water outlet moisturizing element face frost, is prepared by following raw material by weight percentage：
The weight percentage sum of each raw material is 100%.
The emulsifying agent is the mixed of lauryl KF-6028 and cross-linked polymer
Compound；The cross-linked polymer is dimethyl silicone polymer and KSG-210；
The lauryl KF-6028 (INCI names) is company of SHIN-ETSU HANTOTAI KF6038
(trade name)；
The dimethyl silicone polymer and KSG-210 are dimethyl silicone polymer
(and) KSG-210 (INCI names) is company of SHIN-ETSU HANTOTAI SSG-210SP (trade name).
The thickening property elastomer is Dimethicone/Vinyl Dimethicone cross-linked polymer/ring five
Dimethyl silicone polymer, company of SHIN-ETSU HANTOTAI KSG-15AP.
The silicone oil is dimethyl silicone polymer.
The grease is one or more kinds of mixtures in isohexadecane, Permethyl 99A, isononyl isononanoate.
The titanium dioxide is the titanium dioxide of silica and polydimethylsiloxane--modified, the preferably PARSOL from DSM
Titanium dioxide (titanium dioxide (and) silica (and) dimethyl silicone polymer) of TX silicon processing.
The oil phase thickeners are thickener A and thickener B, and thickener A is cyclomethicone, distearyl two
The BENTONE of the mixture of methyl amine hectorite and propene carbonate, i.e. ELEMENTIS companies (this company of Britain's hamming)
GEL VS-5PCV。
Thickener B is acrylate (class)/ethylhexyl acrylate/dimethyl silicone polymer methacrylate copolymers
Thing, the SSE-800SP of company of SHIN-ETSU HANTOTAI.
The NMF is glycerine, 1,2- propane diols, 1.3- butanediols, Sodium Hyaluronate, tara gum NMF, xylose
Alcohol radical glucoside and anhydro xylitol and xylitol (the Hao Bo Co., Ltds AQUAXYL xylitol NMF (commodity of Guangzhou hundred
Name)) in one or more kinds of mixtures.Such as (this product comes from Chinese Fu Ruida companies, trade name to Sodium Hyaluronate
For HA-TP), due to its own special molecular structure, (carboxyl and other polar groups in molecule can combine to form hydrogen with water
Key) moisture of 1000 times of own wt can be absorbed, make skin water profit full, smooth microgroove.Sodium Hyaluronate can be in skin simultaneously
Skin surface forms thin film, extends the moisturizing water lock ability of skin, helps elastic fibers and collagen to be in full of water
In the environment divided, skin is allowed to show more flexible；Tara gum NMF is Guangzhou Nuo Ran bio tech ltd
The spirit of Hydromanil 3D water locks, INCI are water and glycerine and tara gum, contain galactomannans and oligomeric sweet dew in product
Oligosaccharides plays instant moisturizing and lasting moisture-keeping efficacy, and the moisturizing ingredient of innovation is while water suction/water lock, with a kind of immediately rapid
And natural mode, hydrone is transported to skin deep layer.
The PH conditioning agents are one or two kinds of in sodium chloride, citric acid.
The preservative is methylisothiazolinone and Sensiva SC50, German Shu Mei EUXYL K220.
The active component is ginseng extract, and the production of Lang De companies of South Korea hundred, the main component of ginseng extract is soap
Glycosides (13 kinds of ginsenosides), amino acid, carbohydrate, vitamin (A, B1, B2, C) etc..Ginseng extract (ginseng extract) can stimulate
The biosynthesis of nucleic acid, protein and lipid.Ginseng extract has the work for suppressing LOX, suppressing tyrosinase activity
With.
The preparation method of the water outlet moisturizing element face frost, comprises the following steps：
(1) at normal temperatures, NMF, PH conditioning agents, active component, deionized water and preservative are mixed, obtains water
Phase mixture；
(2) by lauryl KF-6028 in titanium dioxide, silicone oil and emulsifying agent
Mix, grinding, obtain mixture；
(3) by dimethyl silicone polymer and poly dimethyl in thickening property elastomer, oil phase thickeners, grease and emulsifying agent
Siloxanes PEG-10/15 cross-linked polymers carry out homogeneous, obtain oil mixture；
(4) oil mixture in mixture in step (2) and step (3) is mixed, then under conditions of stirring, slowly
Aqueous mixture in step (1) is added, low speed homogeneous, is stirred, obtains water outlet moisturizing element face frost.
Mixed described in step (1) to stir and evenly mix, the rotating speed of stirring is 80~300r/min；Step is ground described in (2)
The rotating speed of mill is 50~80rpm, and the time of grinding is 25~35min；The condition of homogeneous described in step (3) be 3500~
3~5min of 4500rpm homogeneous；The condition of low speed homogeneous is described in step (4)：400~1000rpm homogeneous, 2~3min；It is all
The rotating speed of stirring is 400~800rpm, and the time to stir is 5~15min.
Each composition of the present invention, which cooperates, to interact, and wherein ginseng extract can play timely whitening effect, for a long time
Using can also play whitening spot-removing, long-acting moisturizing, bright color effect, the ginseng extract in formula, which has, to be suppressed fat oxygen and closes
Enzyme, the effect for suppressing tyrosinase activity；Silicone oil, the reasonable compounding of emulsifying agent effectively control water outlet speed and the globule it is big
It is small, secondly with reasonably combined, the fabulous greasy and spreadability improved when product is smeared of titanium dioxide and other materials.This hair
Bright plain face frost has good hand touch, and salubrious to moisten, ductility is good, and screening flaw whitening naturally, cunning during smearing as with silk cunning
Feel and go out the pleasant feeling of moistening water.Ginseng extract is coordinated to play from inside to outside white.The present invention can not only smear nature up
Brighten, there is the skin sense of water outlet, moreover it is possible to the whitening for inherence of getting up and moisture-keeping efficacy.
Compared with prior art, the present invention has advantages below and beneficial effect：The water outlet element face frost of the present invention has hand
Feel, salubrious to moisten, ductility is good, and hides flaw whitening naturally, during smearing with silk slide as sliding feel and go out the pleased of moistening water
Happy sense；Ginseng extract is coordinated to play from inside to outside white；The present invention can not only smear up to be brightened naturally, there is the skin of water outlet
Sense, moreover it is possible to the whitening for inherence of getting up and moisture-keeping efficacy.Therefore, each reasonable composition compounding of plain face of the invention frost, has fabulous guarantor
Wet effect and lasting moisturizing effect, while flaw whitening can also be hidden naturally.
In addition, the method for the present invention is simple, plain face frost can be prepared at normal temperatures, economic and environment-friendly, to greatest extent
The active component in formula in each working substance is protected not destroyed by high temperature, and the feel that can be out of the water is more preferable, more water profit
Smear skin sense.
Embodiment
The present invention is described in further detail with reference to specific embodiment, but embodiments of the present invention are not limited to
This.Raw material can reach from market employed in the present invention.Water outlet moisturizing element face frost formula is as shown in table 1 in embodiment 1~5
(dosage of each raw material is percetage by weight, each raw material weight percent and for 100%)：
The formula of water outlet moisturizing element face frost in the embodiment 1~5 of table 1
The preparation method of the water outlet moisturizing element face frost of embodiment 1~5, comprises the following steps：
(1) at normal temperatures, NMF, PH conditioning agents, active component, deionized water and preservative are mixed, obtains water
Phase mixture；Described to mix to stir and evenly mix, the rotating speed of stirring is 200r/min；
(2) by acrylate (class)/ethylhexyl acrylate/polydimethylsiloxanes in titanium dioxide, silicone oil, oil phase thickeners
Lauryl KF-6028 mixes in alkane methacrylate copolymer and emulsifying agent
It is even, grinding, obtain mixture；The rotating speed of the grinding is 60rpm, and the time of grinding is 30min；
(3) cyclomethicone in thickening property elastomer, oil phase thickeners/distearyl dimethyl lithium is covered de-
Dimethyl silicone polymer and dimethyl silicone polymer PEG-10/15 cross-linked polymerics in stone/propene carbonate, grease and emulsifying agent
Thing carries out homogeneous, obtains oil mixture；The condition of the homogeneous is 4000rpm homogeneous 3min；
(4) oil mixture in mixture in step (2) and step (3) is mixed, then under conditions of stirring, slowly
Aqueous mixture in step (1) is added, low speed homogeneous, is stirred, obtains water outlet moisturizing element face frost；The bar of the low speed homogeneous
Part is：500rpm homogeneous 3min；The rotating speed of all stirrings is 800rpm, and the time to stir is 10min.
Product made from embodiment 1~5 is detected：
First, Product Safety assesses (human body skin patch experimental result)
Evaluation method：
1) tested material：Plain face frost made from embodiment 1~5：Commercially available plain face frost product tested material as a control group；
2) negative control：Blank control；
3) subject：30 people, male 15 people, the people of female 15, age 18-30 year, meet volunteer's inclusion criteria；
4) closed patch method：From qualified patch material, tested material about 0.020g~0.025g is put into spot examination device
Interior, control wells are blank control (not putting any material), by added with the spot of tested material try device be pasted on non-stimulated adhesive tape it is tested
The back or forearm song side of person, is gently pressed with palm and is allowed to equably be pasted on skin, continues 24h；
5) record data：Tested material is removed after 24h, the 30min after tested material spot examination device is removed, is observed after impression disappearance
Dermoreaction, press《Cosmetics health specification》Dermoreaction grade scale records its result in (version in 2007)；
6) evaluation of result：Reaction result is recorded by skin adverse reaction grade scale (table 2)
The skin adverse reaction grade scale of table 2
7) assay：Cosmetics human body skin patch experimental result is as shown in table 3：
The human body skin patch test result of the embodiment 1~5 of table 3 and commercially available plain face frost：
Shown from the human skin patch result of table 3：In embodiment 1~5,20 subjects skins are all negative
React (grading system：0 grade).Foundation《Cosmetics health specification》(version in 2007) human skin patch criterion, sample
Product are to human body without skin adverse reaction.
Reference examples (domestic certain famous brand name element face frost) have 1 subject 1 order reaction occur.
2nd, moistening effect is assessed
With plain face frost made from embodiment 1~5：Commercially available plain face frost product tested material as a control group；Negative control：Blank
Control.
Tested crowd：30 adult female volunteers；Age is between 16 to 35 one full year of life；
Method of testing：Test at septum reset or so cheekbone, nose and pupil intersection or so cheek, temple and corners of the mouth intersection
Place's left and right sides is completed as pilot region, the test of same volunteer by same survey crew.
Search time：Whole research is scheduled to last 8h researcher and commented using preceding, 0h, 2h, 4h, 8h progress clinical test results
Estimate.
Testing standard：The measure of skin moisture content：The skin produced using German Courage+Khazaka (CK) company
Moisture tester Corneometer CM825 are surveyed 5 times and are averaged.
Test result is as shown in table 4.
The performance of keeping humidity test result of the embodiment 1~5 of table 4 and commercially available plain face frost
From test result as can be seen that the moistening effect of embodiment is best, the moistening effect of embodiment 1~5 is than commercially available sample
Product (domestic famous brand name element face frost) will get well.Therefore, each composition has what is mutually cooperateed with terms of moisturizing in the skin matrix
Act on and obtain preferable effect.
3rd, other performance detects
1) tested crowd：40 adult female volunteers；Age is between 16 to 35 one full year of life；
Method of testing：By the water outlet moisturizing element face frost of the gained of embodiment 2 and market (whitening element face frost 1 (brand 1), whitening
Plain face frost 2 (brand 2), whitening element face frost 3 (brand 3)) clinical trial evaluation is carried out, daily using once, product is commented
Valency.Standards of grading are：Spreadability is 10 points very well, preferably 8 points of spreadability, and spreadability is generally 6 points, and spreadability difference is 4 points；
Whitening effect is 10 points very well, preferably 8 points of whitening effect, and whitening effect is generally 6 points, and whitening effect difference is 4 points；Hold adornment effect
Fruit is very well 10 points, holds preferably 8 points of adornment effect, holds adornment effect and be generally 6 points, and it is 4 points to hold adornment effect difference；Mildy wash cleaning effect
Fruit is very well 10 points, and preferably 8 points of mildy wash cleaning performance, mildy wash cleaning performance is generally 6 points, and mildy wash cleaning performance is poor
For 4 points；Floating powder phenomenon is 10 points very well, floats preferably 8 points of powder phenomenon, and floating powder phenomenon is generally 6 points, and it is 4 points to float powder phenomenon difference.
Search time：30 days by a definite date clinical test results of whole research are assessed.Test result is as shown in table 5.
The embodiment 2 of table 5 and the performance test results of the plain face frost in market
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
- A kind of 1. water outlet moisturizing element face frost, it is characterised in that：It is prepared by following raw material by weight percentage：The thickening property elastomer is Dimethicone/Vinyl Dimethicone cross-linked polymer/ring five poly- two Methylsiloxane；The emulsifying agent is the mixing of lauryl KF-6028 and cross-linked polymer Thing；The cross-linked polymer is dimethyl silicone polymer and KSG-210；The active component is ginseng extract.
- 2. water outlet moisturizing element face frost according to claim 1, it is characterised in that：The silicone oil is dimethyl silicone polymer；The grease is one or more kinds of mixtures in isohexadecane, Permethyl 99A, isononyl isononanoate.
- 3. water outlet moisturizing element face frost according to claim 1, it is characterised in that：The titanium dioxide is silica and poly dimethyl silicon Siloxane modified titanium dioxide.
- 4. water outlet moisturizing element face frost according to claim 1, it is characterised in that：The oil phase thickeners are thickener A and increasing Thick dose of B, thickener A are the mixture of cyclomethicone, distearyl dimethyl amine hectorite and propene carbonate, That is the BENTONE GELVS-5PCV of ELEMENTIS companies；Thickener B is acrylate (class)/ethylhexyl acrylate/poly- two Methylsiloxane methacrylate copolymer, the SSE-800SP of company of SHIN-ETSU HANTOTAI；The NMF is glycerine, 1,2- propane diols, 1.3- butanediols, Sodium Hyaluronate, tara gum NMF, Xylitol-based One or more kinds of mixtures in the xylitol NMF of glucoside and anhydro xylitol and xylitol composition.
- 5. water outlet moisturizing element face frost according to claim 4, it is characterised in that：The tara gum NMF is that Guangzhou promise is right Bio tech ltd's Hydromanil 3D water locks spirit, the entitled water of INCI and glycerine and tara gum.
- 6. water outlet moisturizing element face frost according to claim 1, it is characterised in that：The PH conditioning agents are sodium chloride, citric acid Middle one or two；The preservative is methylisothiazolinone and Sensiva SC50, German Shu Mei EUXYL K220.
- 7. water outlet moisturizing element face frost according to claim 1, it is characterised in that：By following raw material system by weight percentage It is standby to form：
- 8. water outlet moisturizing element face frost according to claim 1, it is characterised in that：By following raw material system by weight percentage It is standby to form：The weight percentage sum of each raw material is 100%.
- 9. according to the preparation method of any one of the claim 1~8 water outlet moisturizing element face frost, it is characterised in that：Including as follows Step：(1) at normal temperatures, NMF, PH conditioning agents, active component, deionized water and preservative are mixed, obtains aqueous phase and mix Compound；(2) lauryl KF-6028 in titanium dioxide, silicone oil and emulsifying agent is mixed It is even, grinding, obtain mixture；(3) by dimethyl silicone polymer and polydimethylsiloxanes in thickening property elastomer, oil phase thickeners, grease and emulsifying agent Alkane PEG-10/15 cross-linked polymers carry out homogeneous, obtain oil mixture；(4) oil mixture in mixture in step (2) and step (3) is mixed, then under conditions of stirring, be slowly added to Aqueous mixture in step (1), low speed homogeneous, stirs, and obtains water outlet moisturizing element face frost.
- 10. the preparation method of water outlet moisturizing element face frost according to claim 9, it is characterised in that：Step mixes described in (1) To stir and evenly mix, the rotating speed of stirring is 80~300r/min；The rotating speed ground described in step (2) is 50~80rpm, and the time of grinding is 25~35min；The condition of homogeneous described in step (3) is 3500~4500rpm homogeneous, 3~5min；The condition of low speed homogeneous is described in step (4)：400~1000rpm homogeneous, 2~3min；The rotating speed of all stirrings is 400 ~800rpm, the time to stir are 5~15min.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108403483A (en) * | 2018-06-02 | 2018-08-17 | 杭州兰茜化妆品有限公司 | It is a kind of element face frost and its preparation process |
| CN108785174A (en) * | 2018-07-27 | 2018-11-13 | 大埔县通美实业有限公司 | A kind of plain face frost and preparation method thereof rich in grapefruit abstract |
| CN108852987A (en) * | 2018-07-27 | 2018-11-23 | 大埔县通美实业有限公司 | A kind of skin care item and preparation method thereof rich in grapefruit abstract |
| CN109316361A (en) * | 2018-10-10 | 2019-02-12 | 广州雷诺生物科技有限公司 | A kind of fullerene mineral are luxurious to dote on essence cream |
| CN111803430A (en) * | 2020-08-14 | 2020-10-23 | 广州致美日化科技有限公司 | Face-beautifying cream and preparation method thereof |
| CN111840203A (en) * | 2020-08-18 | 2020-10-30 | 广东丸美生物技术股份有限公司 | Anti-aging moisturizing face cream |
| CN115813786A (en) * | 2022-12-23 | 2023-03-21 | 安庆科思化学有限公司 | Water-resistant sunscreen composition with water outlet capacity and preparation method thereof |
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