CN107467450A - Selenium-rich water and preparation method thereof - Google Patents
Selenium-rich water and preparation method thereof Download PDFInfo
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- CN107467450A CN107467450A CN201710704812.8A CN201710704812A CN107467450A CN 107467450 A CN107467450 A CN 107467450A CN 201710704812 A CN201710704812 A CN 201710704812A CN 107467450 A CN107467450 A CN 107467450A
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- 239000011669 selenium Substances 0.000 title claims abstract description 173
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 151
- 229910052711 selenium Inorganic materials 0.000 title claims abstract description 138
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title claims abstract description 120
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 229940065287 selenium compound Drugs 0.000 claims abstract description 60
- 150000003343 selenium compounds Chemical class 0.000 claims abstract description 60
- 229930003231 vitamin Natural products 0.000 claims abstract description 28
- 235000013343 vitamin Nutrition 0.000 claims abstract description 28
- 239000011782 vitamin Substances 0.000 claims abstract description 28
- 229940088594 vitamin Drugs 0.000 claims abstract description 28
- 150000003722 vitamin derivatives Chemical class 0.000 claims abstract description 28
- 239000011573 trace mineral Substances 0.000 claims abstract description 19
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 19
- 102000008114 Selenoproteins Human genes 0.000 claims description 49
- 108010074686 Selenoproteins Proteins 0.000 claims description 49
- 241000222336 Ganoderma Species 0.000 claims description 41
- 229920001282 polysaccharide Polymers 0.000 claims description 14
- 239000005017 polysaccharide Substances 0.000 claims description 14
- -1 selenium polysaccharide Chemical class 0.000 claims description 12
- 230000009514 concussion Effects 0.000 claims description 11
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 10
- 238000005119 centrifugation Methods 0.000 claims description 10
- 108010059892 Cellulase Proteins 0.000 claims description 9
- 229940106157 cellulase Drugs 0.000 claims description 9
- 108090000790 Enzymes Proteins 0.000 claims description 8
- 102000004190 Enzymes Human genes 0.000 claims description 8
- 230000009849 deactivation Effects 0.000 claims description 8
- 229940088598 enzyme Drugs 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 238000002386 leaching Methods 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 238000000605 extraction Methods 0.000 claims description 6
- 229910052712 strontium Inorganic materials 0.000 claims description 6
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical group [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 6
- 238000002604 ultrasonography Methods 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
- 230000015556 catabolic process Effects 0.000 claims description 3
- 238000006731 degradation reaction Methods 0.000 claims description 3
- 239000011630 iodine Substances 0.000 claims description 3
- 229910052740 iodine Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 1
- 230000001256 tonic effect Effects 0.000 abstract description 10
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 9
- 201000010099 disease Diseases 0.000 abstract description 7
- 235000020188 drinking water Nutrition 0.000 abstract description 7
- 239000003651 drinking water Substances 0.000 abstract description 7
- 230000036541 health Effects 0.000 abstract description 6
- 150000003342 selenium Chemical class 0.000 abstract description 6
- 230000002708 enhancing effect Effects 0.000 abstract description 5
- 230000002265 prevention Effects 0.000 abstract description 4
- 239000013589 supplement Substances 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 230000003138 coordinated effect Effects 0.000 abstract description 3
- 230000036039 immunity Effects 0.000 abstract description 3
- 230000001988 toxicity Effects 0.000 abstract description 3
- 231100000419 toxicity Toxicity 0.000 abstract description 3
- 230000003712 anti-aging effect Effects 0.000 abstract description 2
- 235000011649 selenium Nutrition 0.000 description 111
- 241000196324 Embryophyta Species 0.000 description 18
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 14
- 239000002994 raw material Substances 0.000 description 11
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
- 239000008280 blood Substances 0.000 description 8
- 210000004369 blood Anatomy 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229930003427 Vitamin E Natural products 0.000 description 7
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 7
- 235000019165 vitamin E Nutrition 0.000 description 7
- 239000011709 vitamin E Substances 0.000 description 7
- 229940046009 vitamin E Drugs 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- FDKWRPBBCBCIGA-UHFFFAOYSA-N 2-azaniumyl-3-$l^{1}-selanylpropanoate Chemical compound [Se]CC(N)C(O)=O FDKWRPBBCBCIGA-UHFFFAOYSA-N 0.000 description 4
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 4
- RJFAYQIBOAGBLC-BYPYZUCNSA-N Selenium-L-methionine Chemical compound C[Se]CC[C@H](N)C(O)=O RJFAYQIBOAGBLC-BYPYZUCNSA-N 0.000 description 4
- RJFAYQIBOAGBLC-UHFFFAOYSA-N Selenomethionine Natural products C[Se]CCC(N)C(O)=O RJFAYQIBOAGBLC-UHFFFAOYSA-N 0.000 description 4
- 229930003268 Vitamin C Natural products 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000002354 daily effect Effects 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229960002718 selenomethionine Drugs 0.000 description 4
- 235000019154 vitamin C Nutrition 0.000 description 4
- 239000011718 vitamin C Substances 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 201000011510 cancer Diseases 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 240000008397 Ganoderma lucidum Species 0.000 description 2
- 235000001637 Ganoderma lucidum Nutrition 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 238000010170 biological method Methods 0.000 description 2
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- 239000011785 micronutrient Substances 0.000 description 2
- 235000013369 micronutrients Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QWWVBNODQCWBAZ-WHFBIAKZSA-N (2r)-2-amino-3-[(2r)-2-carboxy-2-(methylamino)ethyl]sulfanylpropanoic acid Chemical compound CN[C@H](C(O)=O)CSC[C@H](N)C(O)=O QWWVBNODQCWBAZ-WHFBIAKZSA-N 0.000 description 1
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- AUNGANRZJHBGPY-UHFFFAOYSA-N D-Lyxoflavin Natural products OCC(O)C(O)C(O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 1
- 206010039921 Selenium deficiency Diseases 0.000 description 1
- 229930003451 Vitamin B1 Natural products 0.000 description 1
- 229930003471 Vitamin B2 Natural products 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000001093 anti-cancer Effects 0.000 description 1
- 238000009534 blood test Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 208000026106 cerebrovascular disease Diseases 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000004064 dysfunction Effects 0.000 description 1
- 235000006694 eating habits Nutrition 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 201000005577 familial hyperlipidemia Diseases 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000014106 fortified food Nutrition 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000012946 outsourcing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003359 percent control normalization Methods 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000001243 protein synthesis Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229960003495 thiamine Drugs 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
- 230000014616 translation Effects 0.000 description 1
- 235000010374 vitamin B1 Nutrition 0.000 description 1
- 239000011691 vitamin B1 Substances 0.000 description 1
- 235000019164 vitamin B2 Nutrition 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/38—Other non-alcoholic beverages
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/15—Vitamins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/16—Inorganic salts, minerals or trace elements
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Mycology (AREA)
- Inorganic Chemistry (AREA)
- Medicines Containing Plant Substances (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The invention provides selenium-rich water and preparation method thereof, is related to drinking water technical field.The selenium-rich water is mainly made up of 900 1100 parts of 0.0001 0.001 parts of organic selenium compounds and water, Se content is reasonable in the selenium-rich water, people just reach the selenium element that supplement needed by human body is wanted during drinking water, do not need extra tonic or build up one's health by taking tonic, supply Se scientific, this selenium-rich water is drunk for a long time, enhancing body immunity function, enhancing solution toxicity, anti-aging can be reached, reach physical fitness, the purpose of the disease that disappears diseases prevention；Meanwhile be used cooperatively by water soluble vitamin and/or trace element with organic selenium compounds, so as to produce coordinated effect, the physiologically active of organic selenium compounds can be promoted to further enhance, more conducively absorption of human body.Present invention also offers the preparation method of selenium-rich water, and the preparation method is simple and easy, is suitable for industrially mass producing.
Description
Technical field
The present invention relates to drinking water technical field, in particular to selenium-rich water and preparation method thereof.
Background technology
Selenium is referred to as " king of anticancer " in body trace element by scientist, and scientific research is found, the height of blood selenium level
The low generation with cancer is closely bound up.And substantial amounts of experiment case study data and it was verified that human body selenium deficiency will result in important device
The dysfunction of official, cause the generation of many serious diseases, such as：Malignant tumour, cardiovascular and cerebrovascular diseases etc..
Market now how regional to the country is investigated, it is found that selenium-rich product is a lot, such as：Rice, water fruits and vegetables, protect
Strong product etc., but these products be rarely fulfilled that human body that National Nutrient association announces daily must intake requirement.And
This extra tonic or the form built up one's health by taking tonic, are not very convenient.
In view of this, it is special to propose the present invention to solve above-mentioned technical problem.
The content of the invention
The present invention first purpose be to provide a kind of selenium-rich water, the selenium-rich water is mainly obtained by organic selenium compounds and water
Arrive, Se content is reasonable in the selenium-rich water, and people just reach the selenium element that supplement needed by human body is wanted during drinking water, it is not necessary to
Extra tonic is built up one's health by taking tonic, and supply Se scientific, drinks this selenium-rich water for a long time, physical fitness can be reached, disappear disease diseases prevention the effect of.
Second object of the present invention is to provide a kind of preparation method of selenium-rich water, and the preparation method is simple and easy, fits
Together in industrial large-scale production.
In order to realize the above-mentioned purpose of the present invention, spy uses following technical scheme：
The present invention provides a kind of selenium-rich water, and the selenium-rich water is mainly made up of the component of following parts by weight：Organic selenizing
Compound 0.0001-0.001 parts and water 900-1100 parts.
Further, the selenium-rich water is mainly made up of the component of following parts by weight：Organic selenium compounds 0.00012-
0.0008 part and water 950-1050 parts.
Further, the selenium-rich water is mainly made up of the component of following parts by weight：Organic selenium compounds 0.00012-
0.0008 part and 1000 parts of water.
Further, the organic selenium compounds are selenium polysaccharide and/or selenoprotein.
Further, the organic selenium compounds are Ganoderma lucidumyogurt.
Further, the Ganoderma lucidumyogurt is that gained is extracted from Se-rich lucid ganoderma mycelium, specifically by Se-rich lucid ganoderma
Mycelium is added in leaching liquor, and after cellulase degradation, heat up enzyme deactivation, centrifugation, that is, obtains Ganoderma lucidumyogurt；
Preferably, the extraction of the Ganoderma lucidumyogurt is that Se-rich lucid ganoderma mycelium is added in alkaline aqueous solution, Xiang Qi
Middle addition 0.2-0.4% cellulase is digested, and enzymolysis time 1-3h, is digested after 86-90 DEG C of enzyme deactivation, 300-
500r/min centrifuges 10-20min, obtains Ganoderma lucidumyogurt.
Further, the organic selenium compounds exist in the form of selenoprotein；
The selenoprotein is that gained is extracted from Se-enriched yeast, and specifically Se-enriched yeast is added in leaching liquor, is shaken
Ultrasound, centrifugation, obtains selenoprotein.
Further, the organic selenium compounds exist in the form of plant selenoprotein；
The plant selenoprotein is that gained is extracted from plant.
Further, the selenium-rich water also includes water soluble vitamin 0.005-0.05 parts；
Preferably, the selenium-rich water also includes micro- 0.00005-0.0001 parts, and the trace element is selected from strontium, zinc
Or a kind of in iodine or at least two combination.
Present invention also offers a kind of preparation method of selenium-rich water, comprise the following steps：
By the organic selenium compounds of formula ratio, optionally water soluble vitamin and optionally trace element is added to formula ratio
Water in be well mixed, obtain selenium-rich water.
Compared with prior art, selenium-rich water provided by the invention and preparation method thereof has the advantages that：
(1) the invention provides a kind of selenium-rich water, mainly obtained by organic selenium compounds and water, Se content in the selenium-rich water
Rationally, people just reach the selenium element wanted of supplement needed by human body during drinking water, it is not necessary to and extra tonic is built up one's health by taking tonic,
Supply Se scientific, this selenium-rich water is drunk for a long time, can reach enhancing body immunity function, enhancing solution toxicity, anti-aging, reach
Physical fitness, the purpose of the disease that disappears diseases prevention.
(2) selenium-rich water provided by the invention, suitable various people drink, and drink for a long time better.
(3) selenium-rich water provided by the invention, coordinated by water soluble vitamin and/or trace element with organic selenium compounds
Use, so as to produce coordinated effect, the physiologically active of organic selenium compounds can be promoted to further enhance, more conducively human body is inhaled
Receive.
(4) the invention provides a kind of preparation method of selenium-rich water, the preparation method is simple and easy, is suitable for industrial big
Large-scale production.
Embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the present invention.It is unreceipted specific in embodiment
Condition person, the condition suggested according to normal condition or manufacturer are carried out.Agents useful for same or the unreceipted production firm person of instrument, it is
The conventional products that can be obtained by commercially available purchase.
According to an aspect of the invention, there is provided a kind of selenium-rich water, is mainly made up of the component of following parts by weight：Have
Machine selenium compound 0.0001-0.001 parts and water 900-1100 parts.
The invention provides a kind of selenium-rich water, mainly being obtained by organic selenium compounds and water, the selenium-rich water Se content is reasonable,
People just reach the selenium element wanted of supplement needed by human body during drinking water, it is not necessary to which extra tonic is built up one's health by taking tonic, science
Selenium-supply, drink this selenium-rich water for a long time, physical fitness can be reached, disappear disease diseases prevention the effect of.
In general, the existence form of selenium has two kinds of inorganic selenium and Organic Selenium.It is organic in the present invention compared with inorganic selenium
Toxicity of Selenium Compounds is low, Small side effects, more conducively absorption of human body.
The typical but non-limiting parts by weight of organic selenium compounds be 0.0001 part, 0.0002 part, 0.0003 part,
0.0004 part, 0.0005 part, 0.0006 part, 0.0007 part, 0.0008 part, 0.0009 part or 0.001 part.
Due to this selenium-rich water, to be used as drinking water or beverage directly for human consumption, so water uses mineral water or pure
Water.
The typical but non-limiting parts by weight of water be 900 parts, 920 parts, 940 parts, 950 parts, 960 parts, 980 parts, 1000
Part, 1020 parts, 1040 parts, 1050 parts, 1060 parts, 1080 parts or 1100 parts.
" mainly by ... be made " of the present invention, it is intended that it can also include other components in addition to the component, this
Other a little components assign the selenium-rich water different characteristics.In addition, " mainly by ... be made " of the present invention, may be used also
With replace with enclosed " for " or " by ... form ".
As a kind of preferred embodiment of the present invention, selenium-rich water is mainly made up of the component of following parts by weight：Organic selenizing
Compound 0.00012-0.0008 parts and water 950-1050 parts.
As a kind of preferred embodiment of the present invention, selenium-rich water is mainly made up of the component of following parts by weight：Organic selenizing
1000 parts of compound 0.00012-0.0008 parts and water.
Pass through the further restriction to each raw material dosage in selenium-rich water so that the proportioning of organic selenium compounds and water more section
Learn.
As a kind of preferred embodiment of the present invention, organic selenium compounds are selenium polysaccharide and/or selenoprotein.
Selenium is the essential trace elements of the human body.Polysaccharide is natural biological macromolecular substances, and it is almost present in all biologies
It is the main matter and constituent of organism energy in body.And the selenium polysaccharide for combining both together not only has inorganic selenium
Activity, various physiological functions also with polysaccharide, and be more conducive to be absorbed by organisms utilization.
As a kind of preferred embodiment of the present invention, organic selenium compounds are Ganoderma lucidumyogurt.
Organic selenium compounds are typically using biological method extraction gained.Ganoderma lucidumyogurt is also to pass through in the present invention
Biological method extracts gained from Se-rich lucid ganoderma mycelium, and specifically Se-rich lucid ganoderma mycelium is added in leaching liquor, passes through
After crossing cellulase degradation, heat up enzyme deactivation, centrifugation, that is, obtains Ganoderma lucidumyogurt.
Preferably, the extraction of Ganoderma lucidumyogurt is that a certain amount of Se-rich lucid ganoderma mycelium is added in alkaline aqueous solution,
The cellulase for adding 0.2-0.4%wt thereto is digested, and enzymolysis time 1-3h, is digested after 86-90 DEG C of enzyme deactivation,
300r/min-500r/min centrifuges 10-20min, obtains Ganoderma lucidumyogurt.
Wherein, the dosage of cellulase is 0.2%, 0.25%, 0.3%, 0.35% or 0.4%.
Enzymolysis time typical but non-limiting such as 1h, 1.5h, 2h, 2.5h or 3h.
Typical but non-limiting hydrolysis temperature is 86 DEG C, 87 DEG C, 88 DEG C, 89 DEG C or 90 DEG C.
During centrifugation typical but non-limiting rotating speed be 300r/min, 350r/min, 400r/min, 450r/min or
500r/min。
Typical but non-limiting centrifugation time is 10min, 12min, 14min, 15min, 16min, 18min or 20min.
Restriction to each technological parameter in the extraction process of Ganoderma lucidumyogurt so that the recovery rate of Ganoderma lucidumyogurt is in
Higher level.
The not only above-mentioned selenium polysaccharide of the existence form of organic selenium compounds, can also be selenoprotein.Selenoprotein is broadly divided into
Two classes：(1) selenoprotein containing selenocystein.In most cases, selenocystein is that carrying selenium element is most important
Mode, selenocystein are also referred to as the 21st amino acid because of its importance, in mammalian body participate in protein groups into, so
In this case the selenoprotein namely albumen containing selenocystein；(2) selenoprotein containing selenomethionine.Selenium is with selenium first
Methyllanthionine or selenomethionine are that main reference state is present in grain.Although selenomethionine participate in protein synthesis be probably with
Machine process, but the albumen containing selenomethionine is also referred to as selenoprotein.
As a kind of preferred embodiment of the present invention, organic selenium compounds exist in the form of selenoprotein；
Selenoprotein is that gained is extracted from Se-enriched yeast, and specifically Se-enriched yeast is added in leaching liquor, concussion ultrasound,
Centrifugation, obtains selenoprotein.
Specifically, Se-enriched yeast is added in leaching liquor, concussion ultrasound, centrifugation, selenoprotein is obtained.Further, will
Se-enriched yeast is added in alkaline solution and extracted, and 4-6h is shaken in 200r/min-300r/min oscillator, and in concussion
Period, which takes out, to be carried out ultrasonic 1-2 times, ultrasonic time 20-40min, and concussion centrifuges after terminating, and takes supernatant to obtain selenoprotein.
Typical but non-limiting concussion speed is 200r/min, 220r/min, 250r/min, 260r/min, 280r/
Min or 300r/min.
The typical but non-limiting concussion time is 4h, 4.5h, 5h, 5.5h or 6h.
Typical but non-limiting ultrasonic time be 20min, 22min, 24min, 25min, 26min, 28min, 30min,
32min, 34min, 35min, 36min, 38min or 40min.
As a kind of preferred embodiment of the present invention, organic selenium compounds exist in the form of plant selenoprotein.
Plant selenoprotein is that gained is extracted from plant.Plant selenoprotein is easily soluble in water, is easily absorbed by the body, human body
Absorption rate is up to more than 90%, and the biological value of plant selenoprotein is higher relative to animal selenoprotein.According to GB14880-
2012《National food safety standard-food enrichment uses standard》, plant selenoprotein and any edible raw material are arranged in pairs or groups, added
Work goes out selenium-enriched food, selenium-rich beverage, selemium nutrition replenishers and health food, cosmetics.
It should be noted that organic selenium compounds can be any one in two kinds of selenium polysaccharide and selenoprotein, can also
It is two kinds of combination.
Preferably, organic compound is the combination of selenium polysaccharide and selenoprotein.Selenium polysaccharide and selenoprotein are used cooperatively, relatively
There is the effect of more preferable scavenging hydroxyl, enhancing immunity of organism activity in inorganic selenium.
Now, the proportioning between selenium polysaccharide and selenoprotein can be any proportioning.Matched between selenium polysaccharide and selenoprotein
Preferably (1-5):(1-5), more preferably (1-4):(1-4), more preferably (1-3):(1-3).
As a kind of preferred embodiment of the present invention, selenium-rich water also includes water soluble vitamin.Water soluble vitamin is can be
The one group of vitamin dissolved in water, the indispensable micronutrient of human body, to health and maintain the normal function of body non-
It is often important, it should take in right amount daily.
The parts by weight of water soluble vitamin are 0.005-0.05 parts.The typical but non-limiting weight of water soluble vitamin
Number be 0.005 part, 0.01 part, 0.015 part, 0.02 part, 0.025 part, 0.03 part, 0.035 part, 0.04 part, 0.045 part or
0.05 part.
Water soluble vitamin is mainly selected from one kind in vitamin B1, vitamin B2, vitamin C and vitamin E or extremely
Few two kinds combination, preferably vitamin C and/or vitamin E.
In the present invention, water soluble vitamin and organic selenium compounds is compound, the selenium-rich water of gained can reach safe benefit
The effect of selenium, supplemented with vitamin.
When water soluble vitamin elects vitamin E as, organic selenium compounds also have with vitamin E cooperates with oxidation resistant work
With.
As a kind of preferred embodiment of the present invention, selenium-rich water also includes micro- 0.00005-0.0001 parts, described micro-
A kind of in strontium, zinc or iodine of secondary element or at least two combination.
The typical but non-limiting parts by weight of trace element are 0.005 part, 0.006 part, 0.008 part, 0.01 part,
0.012 part, 0.015 part, 0.016 part, 0.018 part or 0.020 part.
In addition, for different crowds, Se content might have different demands.Such as：, can be with every for cancer patient
It drinks the 500ml selenium-rich waters that Se content is 400 μ g；For cardiovascular patient, it is 300 μ g's that can drink Se content daily
500ml selenium-rich waters；For children, the 500ml selenium-rich waters that Se content is 50 μ g can be drunk daily；For sportsman, during match
The 500ml selenium-rich waters that Se content is 250 μ g can be drunk.
Present invention also offers a kind of preparation method of selenium-rich water, comprise the following steps：
By the organic selenium compounds of formula ratio, optionally water soluble vitamin and optionally trace element is added to formula ratio
Water in be well mixed, obtain selenium-rich water.
The preparation method is simple and easy, is suitable for industrially mass producing.
With reference to specific embodiment and comparative example, the invention will be further described.
Embodiment 1
A kind of selenium-rich water, it is made up of the component of following parts by weight：1000 parts of 0.0001 part of organic selenium compounds and water.
Wherein, organic selenium compounds are Ganoderma lucidumyogurt, and the extracting method of Ganoderma lucidumyogurt is as follows：By a certain amount of selenium-rich
Ganoderma lucidum mycelium is added in alkaline aqueous solution, and the cellulase of addition 0.3% is digested thereto, enzymolysis time 2h,
Enzymolysis 400r/min centrifugation 15min, obtains Ganoderma lucidumyogurt after 86 DEG C of enzyme deactivations.
Embodiment 2
A kind of selenium-rich water, it is made up of the component of following parts by weight：1000 parts of 0.0001 part of organic selenium compounds and water.
Wherein, organic selenium compounds are selenoprotein, and the extracting method of selenoprotein is as follows：It is molten that Se-enriched yeast is added to alkalescence
Extracted in liquid, and 4h is shaken in 250r/min oscillator, and taken out during concussion and carry out ultrasound 2 times, ultrasonic time
30min, concussion centrifuge after terminating, and take supernatant to obtain selenoprotein.
Embodiment 3
A kind of selenium-rich water, it is made up of the component of following parts by weight：1000 parts of 0.0001 part of organic selenium compounds and water.
Wherein, organic selenium compounds are plant selenoprotein, and selenium is contained purchased from Hubei.
Embodiment 4
A kind of selenium-rich water, it is made up of the component of following parts by weight：1000 parts of 0.0001 part of organic selenium compounds and water.
Wherein, organic selenium compounds are the mixture of Ganoderma lucidumyogurt and plant selenoprotein, Ganoderma lucidumyogurt and Selenium in Plants
The weight ratio of albumen is 2:1.As described in Example 1, plant selenoprotein contains selenium to the extracting method of Ganoderma lucidumyogurt purchased from Hubei.
Embodiment 5
A kind of selenium-rich water, it is made up of the component of following parts by weight：0.0005 part of organic selenium compounds, trace element
0.00005 part and 900 parts of water.
Wherein, organic selenium compounds are Ganoderma lucidumyogurt, and the extracting method of Ganoderma lucidumyogurt is as follows：By a certain amount of selenium-rich
Ganoderma lucidum mycelium is added in alkaline aqueous solution, and the cellulase of addition 0.4% is digested thereto, enzymolysis time 3h,
Enzymolysis 300r/min centrifugation 10min, obtains Ganoderma lucidumyogurt after 88 DEG C of enzyme deactivations；Trace element is Zn-ef ficiency.
Embodiment 6
A kind of selenium-rich water, it is made up of the component of following parts by weight：0.0006 part of organic selenium compounds, trace element
0.00007 part and 950 parts of water.
Wherein, organic selenium compounds are selenoprotein, and the extracting method of selenoprotein is as follows：It is molten that Se-enriched yeast is added to alkalescence
Extracted in liquid, and 5h is shaken in 300r/min oscillator, and taken out during concussion and carry out ultrasound 2 times, ultrasonic time
40min, concussion centrifuge after terminating, and take supernatant to obtain selenoprotein；Trace element is the mixing of Zn-ef ficiency and I, and zinc is first
The proportioning of element and I is 3:1.
Embodiment 7
A kind of selenium-rich water, it is made up of the component of following parts by weight：1050 parts of 0.0008 part of organic selenium compounds and water.
Wherein, organic selenium compounds are Ganoderma lucidumyogurt, and extracting method is as described in Example 5.
Embodiment 8
A kind of selenium-rich water, 0.005 part of water soluble vitamin is added on the basis of the selenium-rich water raw material of embodiment 7, it is water-soluble
Vitamin is specially vitamin C, and remaining raw material and dosage are same as Example 7.
Embodiment 9
A kind of selenium-rich water, 0.03 part of water soluble vitamin, water soluble vitamin are added on the basis of the selenium-rich water raw material of embodiment 7
Raw element is specially vitamin C, and remaining raw material and dosage are same as Example 7.
Embodiment 10
A kind of selenium-rich water, it is made up of the component of following parts by weight：1100 parts of 0.001 part of organic selenium compounds and water.
Wherein, organic selenium compounds are Ganoderma lucidumyogurt and plant selenoprotein, and the extracting method of Ganoderma lucidumyogurt is as implemented
Shown in example 1, the outsourcing of plant selenoprotein contains selenium from Hubei, and the weight ratio of Ganoderma lucidumyogurt and plant selenoprotein is 1:3.
Embodiment 11
A kind of selenium-rich water, except the weight of Ganoderma lucidumyogurt and plant selenoprotein ratio is 0.5:3, remaining raw material and dosage
It is same as in Example 10.
Embodiment 12
A kind of selenium-rich water, 0.05 part of water soluble vitamin is added on the basis of the selenium-rich water raw material of embodiment 10, it is water-soluble
Vitamin is specially vitamin E, and remaining raw material and dosage are same as in Example 10.
Embodiment 13
A kind of selenium-rich water, 0.0001 part of trace element, trace element are added on the basis of the selenium-rich water raw material of embodiment 10
For the combination of strontium and zinc, the amount ratio of trace element strontium and zinc is 2:1.
Comparative example 1
A kind of selenium-rich water, except the parts by weight of organic selenium compounds are down into 0.00005 part, remaining raw material and dosage
It is same as Example 5.
The preparation method for the selenium-rich water that embodiment 1-13 and comparative example 1 provide comprises the following steps：
By the organic selenium compounds of formula ratio, optionally water soluble vitamin and optionally trace element is added to formula ratio
Water in be well mixed, obtain selenium-rich water.
In order to verify the effect of above-described embodiment and comparative example, spy carries out following test.
Experimental example 1
The selenium, vitamin and micronutrient levels of selenium-rich water in embodiment 1-13 and comparative example 1 are detected, examined
It is as shown in table 1 to survey result：
1 each embodiment of table and comparative example content detection
From table 1 it follows that Se content is in higher level in the selenium-rich water of various embodiments of the present invention.
Wherein, embodiment 2-4 is the control experiment of embodiment 1, and four differences are the tool of organic selenium compounds
Body species is different.It can be seen from the data in Table 1 that when organic selenium compounds are with Ganoderma lucidumyogurt either plant selenoprotein or two
In the presence of the form of the mixture of person, Se content level is higher in selenium-rich water.
Embodiment 8 and embodiment 9 are the control experiment of embodiment 7.It can be seen from the data in Table 1 that when in selenium-rich water
During added with water soluble vitamin, the Se content in selenium-rich water has to be raised by a small margin, and with the increasing of water soluble vitamin dosage
More, the lifting of Se content becomes apparent.This is certain mainly due to this between water soluble vitamin and organic selenium compounds be present
Synergy, water soluble vitamin can promote the physiologically active of organic selenium compounds.
Embodiment 11-13 is the control experiment of embodiment 10.Compared with Example 10, changed in embodiment 11 organic
The weight proportion of selenium polysaccharide and selenoprotein in selenium compound, vitamin E is added in embodiment 12, dimension is with the addition of in embodiment 13
Raw plain E and trace element strontium and zinc.From table 1 it follows that vitamin E and/trace element add, be advantageous in selenium-rich water
The release of Se content in organic selenium compounds.
This experimental example is also tested as a control group from mineral water, and the Se content in mineral water is only 0.001mg/kg, selenium
Contents level is relatively low, can not meet needed for human normal.
Experimental example 2
Selenium-rich water of the present invention is tested in hyperlipemia, 500 hyperlipemic patients are divided into experimental group
And control group.Specifically, four groups of component of experiment, every group of 100 people, one group of 100 people of control group.Experimental group one drinks embodiment 10
Selenium-rich water, experimental group two drink the selenium-rich water of embodiment 11, and experimental group three drinks the selenium-rich water of embodiment 12, and experimental group four is drunk
The selenium-rich water of embodiment 13.In the case where eating habit is constant, experimental group drinks selenium-rich water 500ml, control group for each person every day
Drinking mineral water for each person every day, after half a year, blood test blood fat is carried out to 500 patients, concrete outcome is shown in Table 2.Wherein have
Efficiency is：Rate and blood-lipid decreased number/every group of total number of persons × 100%.
2 each experimental group of table and control group Blood Lipid situation
| Test group | Rate and blood-lipid decreased number | The constant number of blood fat | Blood fat rises number | It is efficient |
| Experimental group one | 71 | 22 | 7 | 71% |
| Experimental group two | 68 | 26 | 6 | 68% |
| Experimental group three | 76 | 20 | 4 | 76% |
| Experimental group four | 80 | 17 | 3 | 80% |
| Control group | 12 | 55 | 33 | 12% |
By table 2, it is apparent that hyperlipemic patients in each experimental group, have personnel more than half taking the present invention
Blood fat is decreased obviously after selenium-rich water.On the contrary, control group is almost without significant change, or even blood fat also occur further for some patientss
Elevated phenomenon.It can be seen that this selenium-rich water also has certain blood fat reducing function.
Finally it should be noted that：Various embodiments above is merely illustrative of the technical solution of the present invention, rather than its limitations；To the greatest extent
The present invention is described in detail with reference to foregoing embodiments for pipe, it will be understood by those within the art that：Its according to
The technical scheme described in foregoing embodiments can so be modified, either which part or all technical characteristic are entered
Row equivalent substitution；And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology
The scope of scheme.
Claims (10)
1. a kind of selenium-rich water, it is characterised in that the selenium-rich water is mainly made up of the component of following parts by weight：Organic Selenium chemical combination
Thing 0.0001-0.001 parts and water 900-1100 parts.
2. selenium-rich water according to claim 1, it is characterised in that the selenium-rich water is mainly by the component of following parts by weight
It is made：Organic selenium compounds 0.00012-0.0008 parts and water 950-1050 parts.
3. selenium-rich water according to claim 1, it is characterised in that the selenium-rich water is mainly by the component of following parts by weight
It is made：1000 parts of organic selenium compounds 0.00012-0.0008 parts and water.
4. according to the selenium-rich water described in claim 1-3 any one, it is characterised in that the organic selenium compounds are selenium polysaccharide
And/or selenoprotein.
5. according to the selenium-rich water described in claim 1-3 any one, it is characterised in that the organic selenium compounds are glossy ganoderma selenium
Polysaccharide.
6. selenium-rich water according to claim 5, it is characterised in that the Ganoderma lucidumyogurt is from Se-rich lucid ganoderma mycelium
Se-rich lucid ganoderma mycelium, is specifically added in leaching liquor by extraction gained, and after cellulase degradation, heat up enzyme deactivation, from
The heart, that is, obtain Ganoderma lucidumyogurt；
Preferably, the extraction of the Ganoderma lucidumyogurt is that Se-rich lucid ganoderma mycelium is added in alkaline aqueous solution, is added thereto
The cellulase for entering 0.2-0.4% is digested, and enzymolysis time 1-3h, is digested after 86-90 DEG C of enzyme deactivation, 300-500r/min
10-20min is centrifuged, obtains Ganoderma lucidumyogurt.
7. according to the selenium-rich water described in claim 1-3 any one, it is characterised in that the organic selenium compounds are with selenoprotein
Form exist；
The selenoprotein is that gained is extracted from Se-enriched yeast, and specifically Se-enriched yeast is added in leaching liquor, concussion ultrasound,
Centrifugation, obtains selenoprotein.
8. according to the selenium-rich water described in claim 1-3 any one, it is characterised in that the organic selenium compounds are with Selenium in Plants
The form of albumen is present；
The plant selenoprotein is that gained is extracted from plant.
9. according to the selenium-rich water described in claim 1-3 any one, it is characterised in that the selenium-rich water also includes water soluble vitamin
Raw plain 0.005-0.05 parts；
Preferably, the selenium-rich water also includes micro- 0.00005-0.0001 parts, and the trace element is selected from strontium, zinc or iodine
In it is a kind of or at least two combination.
10. the preparation method of the selenium-rich water described in claim 1-9 any one, it is characterised in that comprise the following steps：
By the organic selenium compounds of formula ratio, optionally water soluble vitamin and the optionally micro- water for being added to formula ratio
In be well mixed, obtain selenium-rich water.
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