CN107459432A - A kind of grape special fertilizer material and preparation method thereof - Google Patents
A kind of grape special fertilizer material and preparation method thereof Download PDFInfo
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- CN107459432A CN107459432A CN201710938525.3A CN201710938525A CN107459432A CN 107459432 A CN107459432 A CN 107459432A CN 201710938525 A CN201710938525 A CN 201710938525A CN 107459432 A CN107459432 A CN 107459432A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
- C05F17/20—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation using specific microorganisms or substances, e.g. enzymes, for activating or stimulating the treatment
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
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Abstract
The present invention provides a kind of grape special fertilizer material and preparation method thereof, and it is prepared comprising following raw material by compound bacteria-fermented：The sugarcane tip, sugarcane top, molasses, rainbow conk, pine needle meal, humic acid, calcium chloride.Utilize the steam blasting pretreatment sugarcane tip, sugarcane top, improve Lignin degradation rate, further lignin degrading and cellulose are handled by courage amic acid ionic liquid again, improve compound bacteria-fermented efficiency, containing nutriments such as crude protein and crude fat in compound bacteria-fermented product, nutrition content in fertilizer is improved.Fertilizer technique prepared by the present invention is simple, and cost is low, and protein content is high, has fine development prospect.
Description
Technical field
The invention belongs to technical field of fertilizer production, more particularly to one kind prepares grape special fertilizer material using by-product from sugarcane
And preparation method thereof.
Background technology
The safety of soil environment problem that China faces at present becomes increasingly conspicuous.Nothing is destroyed or be contaminated to soil environment
Influence can be brought to the ecological functions of soil by doubting, in some instances it may even be possible to lose soil system collapse, function.Soil pollution does not only result in
The reduction of soil quality and productivity, and cause the decline of water, gas environmental quality, serious soil pollution will be injured directly
Ecological safety, food security and human-body safety；Although at present in peripheral doses, chemical remediation and the engineering technology of pollution environment
Aspect has certain progress, and forms some practical techniques.But these restorative procedures often break the thing of meeting contaminated site
Rationality matter, or even the secondary pollution of environment can be caused, the reparation for soil pollution is not inherently improved and solved.
Conceding the land to forestry has become a kind of national conditions, however, on the soil that soil has deteriorated, many plants are difficult to grow.Plant is sought
Nutrient solution can effectively improve the fertility for deteriorating soil, improve the resistance against diseases of plant, can make soil of the plant faster in deterioration
Upper quick healthy growth.
Guangxi possesses abundant Sugarcane Industry, but the remaining raw material majority of cane sugar manufacture can not be utilized, and cause material
It is discarded, or even pollution environment.China there are about the large-scale sugar refinery of family more than 500, annual sugarcane caused main by-product after rolling sugar at present
Nearly ten million ton of product-bagasse, and only fraction is used for papermaking and pressing plate, it is most of to be used as fuel, waste very big, some areas
Bagasse even turns into reluctant rubbish, it would be highly desirable to develops.Because bagasse nutritive value is low, palatability is poor, so long
Feed has seldom been used directly as since phase.Bagasse typically contains lignin 22% ~ 24%, and crude protein 1.5% ~ 2.0%, crude fat 0.4% ~
0.8%.In the processing of bagasse, chemical method is although easy and effective, but costly or pollution environment.Sugarcane toppers leaf is tight at present
Weight is superfluous, and utilization rate is low, and most of sugarcane tip, sugarcane top are all incinerated, and not only cause environmental pollution, and wastes fertilizer money
Source.
Number of patent application CN201510838465.9, muscat grape kind special slow release compound fertilizer and its preparation side
Method, the fertilizer include the outer layer covers layer and internal layer fertiliser granulates being made up of natural polymer coated fertilizer, the fertiliser granulates
It is mixed with and is formed by following components：Urea, calcium superphosphate, Diammonium phosphate (DAP), potassium chloride, fermentation of organic material, agricultural rare-earth, borax
Or boric acid, copper sulphate, zinc sulfate, magnesium sulfate, ferric nitrate, ammonium molybdate, compound sodium nitrophenolate, polyglutamic acid, diatomite or kaolin.Should
Fertilizer disclosure satisfy that during grape normal growth to the demand of various nutrients containing comprehensive nutritional ingredient is enriched, strengthen grape
Disease resistance, winter resistance, improve fruit quality；With good slow release effect, the loss of fertilizer nutrient is effectively reduced, improves fertilizer
Expect utilization rate；The natural polymer coated fertilizer of selection possesses good biodegradability, ecological pollution will not be caused, to ring
Border has friendly effect.Patent of invention CN201410000616.9, a kind of fructus crataegi pinnatifidae organic fertilizer special and preparation method thereof,
Disclose a kind of fructus crataegi pinnatifidae organic fertilizer special and its manufacture method, it is characterised in that：Mainly by following raw material components and again
Amount number is made：300 parts of dry silkworm excrement, peanut meal powder 10-20 parts, peanut shell meal 20-40 parts, microbial bacterial agent 0.5-1.5 parts,
Tea seed episperm carbon granule 4-8 parts, sugarcane ash 20-40 parts, pulverized limestone 1-6 parts.Preparation method continuous production device, reduce granulation of fertilizer and
Liquid drying process, method simply easily operate, good product quality, and operation recruitment is few, reduces production cost；Fertilizer nutrient knot
Structure is reasonable, has the effect of release and release control fertilizer, water conservation and improved soil, reduces the loss of fertilizer, improve the utilization rate of fertilizer, can be full
The nutrient requirement of sufficient fructus crataegi pinnatifidae tree, yield can be improved, improving quality, hawthorn can be eaten raw, delicious, and astringent taste is few, storage period
It is long, there is preferable economic benefit, ecological benefits and social benefit.
In the prior art, prepare converted products using sugarcane toppers, sugarcane top and prepare the rare report of fertilizer.
The content of the invention
For in the prior art, by-product from sugarcane utilization rate is low, it is few to prepare fertilizer technology using sugarcane toppers, sugarcane top as raw material
Present situation, the present invention provides a kind of prepares grape special fertilizer material and preparation method thereof using the sugarcane tip, sugarcane leaf converted products.
Grape special fertilizer material of the present invention is prepared by following weight fraction than component raw material by fermentation：The sugarcane tip 50 ~ 100
Part, 50 ~ 100 parts of sugarcane top, 20 ~ 50 parts of molasses, 10 ~ 15 parts of rainbow conk, 5 ~ 10 parts of pine needle meal, 20 ~ 30 parts of humic acid, calcium chloride 50
~ 60 parts.
Rainbow conk powder is added in compound bacterium culture medium, variegated inulinase can generate laccase with the lichen bacillus ferments rainbow conk,
Laccase can effectively facilitate the degraded of cellulose and lignin.
It is volatile oil that pine needle, which contains various bioactivators and nutritional ingredient wherein main pharmacodynamics composition, while is also contained
Abundant trace element, unrighted acid, plant hormone etc., pine needle meal is big directly as fertilizer additive dosage, this
Invention is fermented pine needle meal as compound bacterium culture medium, cellulose point wherein caused by bacillus licheniformis and aspergillus versicolor
Solution enzyme can degrade to pine needle meal, the active material of pine needle meal is effectively discharged, and compared with directly adding pine needle meal, make
Small with dosage, active material utilization is higher.
The compound bacteria of the present invention is fermented to plurality of raw materials, improves feed nutrition material content, on the other hand, is fermented generation
The synergy of compound bacteria can be improved by thanking to a large amount of consumption of thing, improve the metabolic activity intensity of microorganism, improve fermentation efficiency.
The present invention also provides the preparation method of the grape special fertilizer material, is prepared by following steps：
A. pretreatment of raw material
（1）The sugarcane tip, sugarcane leaf are taken, cleans, is crushed to obtain raw material disintegrating slag using pulverizer, is then fed into the progress of steam blasting machine
Explosion treatment, obtain bagasse powder；
（2）Bagasse powder is added in the ionic liquid of its quality 5 ~ 8%, heating stirring is protected to 60 ~ 80 DEG C under nitrogen protection
Warm 10min, 5 ~ 10% solid acid catalyst is then added, is heated to 180 ~ 200 DEG C, it is mixed that degraded is obtained after 3 ~ 5h of reaction time
Compound；
The ionic liquid is made up of courage acyl cation and amino acid anion, and its water content is 50 ~ 80%；
（3）Treat that degradation of mixture is cooled to 50 ~ 60 DEG C, the warm water of isometric 50 ~ 60 DEG C of addition, mix, under 17000rpm from
15 ~ 20min of the heart, residue are washed with deionized 2 ~ 3 times, collect all supernatants, are rotated under vacuum, after removing moisture, add
Add new bagasse to be handled, the supernatant after all revolvings and residue are well mixed after 4 ~ 5 batches and obtain mixed liquor；
B. fermenting raw materials
（1）60 ~ 80 parts of mixed liquor of gained is taken, the molasses of its quality 15 ~ 20% is sprayed, adds 6 ~ 12 parts of rainbow conk powder, pine needle meal 5 ~ 10
Part, 6 ~ 12 parts of analysis for soybean powder, 20 ~ 40 parts of mannitol, 2 ~ 4 parts of potassium dihydrogen phosphate, 0.6 ~ 1.2 part of calcium chloride, magnesium sulfate 0.6 ~ 1.2
Part, it is well mixed, regulation pH is 7.2 ~ 7.3, and inoculation compound bacteria carries out 72 ~ 80h of fermentation, and control fermentation temperature enters at 40 ~ 50 DEG C
Row compost fermentation, carry out turning over fertilizer guarantee temperature when fermentation temperature is more than 50 DEG C no more than 50 DEG C, obtain converted products；
The compound bacteria is quick bacillus flavus, blown-ball Azotobacter, bacillus licheniformis, aspergillus versicolor；
（2）20 ~ 30 parts of humic acid is taken, 50 ~ 60 parts of calcium chloride, adds converted products, after being well mixed, produces grape special fertilizer
Material.
As a further improvement on the present invention, the Steam explosion treatment is divided into two benches progress, and first stage explosion is steamed
Steam pressure is 1.2 ~ 1.6MPa, and pressure hold time is 200 ~ 240s；Second stage steam blasting steam pressure is 2 ~ 2.8MPa,
Pressure hold time is 140 ~ 160s.
The sugarcane tip, sugarcane leaf utilization rate focus primarily upon the separation of lignin and cellulose, can effectively be made using steam blasting
Partial lignin and cellulose separation.In intermediate pressure section（1.2~1.6MPa）, pressure hold time makes in the range of 200 ~ 240s, sharp
Can separate most of lignin and cellulose with steam blasting；In high pressure section（2~2.8MPa）, when pressure hold time is 140
During ~ 160s, the separating effect of pentose and hexose is optimal, improves glucide content.This technique is first with low pressure stage steam
Explosion separates the lignin and cellulose of macromolecular, then carries out glucide separation by high pressure section steam blasting, can reduce wood
Quality and cellulosic structure to sugar from inhibition, make the glucide content after separation higher.
As a further improvement on the present invention, amino acid anion is lysine anion, sweet ammonia in the ionic liquid
It is a kind of in acid anion, alanine anion, methionine anion.
The anion of ionic liquid can with the interaction of hydrogen bond between cellulose, and then destroy microcrystalline cellulose crystal
Structure, so as to reach the separation of lignin and cellulose.Conventional ion liquid is expensive, toxicity is big, not easily biological-degradable, and
It is difficult to removed completely from cellulose and lignocellulosic, and the ionic liquid residued in cellulose and lignocellulosic component
Follow-up polysaccharide enzymolysis process can be had a negative impact again.Courage amic acid ionic liquid has that raw material is renewable, degradable, nothing
The outstanding performance such as toxicity, can effectively lignin degrading and cellulose, the component in ionic liquid is absorbable material, is reduced
The labour cost of downstream separation.
As a further improvement on the present invention, the preparation method of the solid acid is as follows：
A. in air atmosphere, by 250 DEG C of calcining 2h of MCM-41 molecular sieves, 350 DEG C is then heated to, continues to calcine 2h, finally
550 DEG C of calcining 4h are warming up to, are sealed after cooling standby；
B. the MCM-41 molecular sieves after calcining are invaded into bubble 24h in the 1mol/L concentrated sulfuric acid, after 105 DEG C of drying, forged at 300 DEG C
4h is burnt, obtains H2SO4/ MCM-41 molecular sieve solid acid catalysts.
Solid acid have can be easily separated, post-process simply, the spy such as etching apparatus, environment-friendly and catalytic selectivity be not high
Point, for molecular sieve carried type solid acid due to having the characteristics that superior heat endurance, acidity are adjustable, mesoporous MCM-41 is a kind of new
The molecular sieve of type, it is regularly arranged in order with stable skeleton structure, duct, and there is higher specific surface area（1000m2/g）
With big adsorption capacity（0.7ml/g）, the vacancy of bulky molecular catalysis material has been filled up, but because its acidity is relatively low, it usually needs
Load acid.Sulfuric acid catalysis lignin has very high degradation rate, goes out H after sulfuric acid acidifying2SO4/ MCM-41 contains acidic site simultaneously
Separation is more easily than with very high catalytic activity, and liquid-phase reaction system.
As a further improvement on the present invention, the quick bacillus flavus, blown-ball Azotobacter inoculum concentration are respectively 2 ~ 4%, ground
Clothing bacillus, aspergillus versicolor inoculum concentration are respectively 4 ~ 8%.
The lichen bacillus ferments can produce cellulase, and then decomposition of cellulose, but cellobiose can suppress cellulose
The activity of enzyme；Quick bacillus flavus and blown-ball Azotobacter can be grown using cellobiose, so as to release cellobiose to fibre
Tie up the inhibitory action of plain enzyme；Aspergillus versicolor can improve cellulase activity, and effectively suppress varied bacteria growing.
During fixed nitrogen, the ammonia of formation has toxic action to Nitrogen Fixation System for quick bacillus flavus and blown-ball Azotobacter,
After the amount for the nitrogen that diazotroph is fixed can meet nitrogen-fixing bacteria nutrition itself, metabolic demand, Nitrogen Fixation System, fixed nitrogen effect may turn off
Rate will become very low；Bacillus licheniformis can utilize the nitrogen that nitrogen-fixing bacteria are fixed, and release the influence of nitrogen so that fixed nitrogen
Systems stay is carried out, and sufficient nitrogen can make the vigorous growth of bacillus licheniformis, improve its degradation efficiency to cellulose.
As a further improvement on the present invention, the molasses brix is 40 ~ 50Bx, and sugar content is 30 ~ 35%.
The molasses of high concentration can suppress the growth of microorganism, and 40 ~ 50Bx, the molasses of sugar content 30 ~ 35% are quick yellow bars
Four kinds of bacterium, blown-ball Azotobacter, bacillus licheniformis, aspergillus versicolor preferable growth conditions of bacterium.
Advantages of the present invention：
1st, sugarcane discarded object is handled using steam blasting and ionic liquid, efficiently separates lignin and cellulose, improved polysaccharide and contain
Amount；
2nd, compound cooperative fermentation, the content of nutriment in feed, consumption energy of the plurality of raw materials to fermentating metabolism product are improved
The metabolism of compound bacteria is effectively improved, so as to improve fermentation efficiency；
3rd, the present invention carries out the grape fertilizer of fermentation preparation using the sugarcane tip, sugarcane leaf, can not only improve soil beneficial microorganism number
Amount, increases soil fertility, and then promotes grape growth, and another aspect raw material sources are wide, and cost is low, realize resource reutilization.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A. pretreatment of raw material
（1）The sugarcane tip, sugarcane leaf are taken, cleans, is crushed to obtain raw material disintegrating slag using pulverizer, is then fed into the progress of steam blasting machine
Explosion treatment, obtain bagasse powder；
The Steam explosion treatment is divided into two benches progress, and first stage explosion steam pressure is 1.6MPa, pressure hold time
For 200s；Second stage steam blasting steam pressure is 2.8MPa, pressure hold time 140s.
（2）Bagasse powder is added in the ionic liquid of its quality 5 ~ 8%, heating stirring is protected to 80 DEG C under nitrogen protection
Warm 10min, 10% solid acid catalyst is then added, 200 DEG C is heated to, degradation of mixture is obtained after reaction time 5h；
The ionic liquid is made up of courage acyl cation and glycine anion, and its water content is 80%；
（3）Treat that degradation of mixture is cooled to 60 DEG C, the warm water of isometric 60 DEG C of addition, mix, centrifuged under 17000rpm
20min, residue are washed with deionized 3 times, collect all supernatants, are rotated under vacuum, after removing moisture, add new sweet
Bagasse is handled, and is well mixed the supernatant after all revolvings and residue after 5 batches and is obtained mixed liquor；
B. fermenting raw materials
（1）80 parts of mixed liquor of gained is taken, the molasses of its quality 20% is sprayed, adds 12 parts of rainbow conk powder, 10 parts of pine needle meal, analysis for soybean powder
12 parts, 40 parts of mannitol, 4 parts of potassium dihydrogen phosphate, 1.2 parts of calcium chloride, 1.2 parts of magnesium sulfate, it is well mixed, regulation pH is 7.3, is connect
Kind compound bacteria carries out fermentation 80h, and control fermentation temperature carries out compost fermentations at 50 DEG C, turned over when fermentation temperature is more than 50 DEG C
Fertilizer ensures that temperature is no more than 50 DEG C, obtains converted products；
The molasses brix is 50Bx, sugar content 30%.
The compound bacteria is quick bacillus flavus, blown-ball Azotobacter, bacillus licheniformis, aspergillus versicolor；It is described quick yellow
Color bacillus, blown-ball Azotobacter inoculum concentration are respectively 4%, and bacillus licheniformis, aspergillus versicolor inoculum concentration are respectively 8%；
（2）20 parts of humic acid is taken, 50 parts of calcium chloride, adds converted products, after being well mixed, produces grape special fertilizer material.
In the fertilizer that the present embodiment is prepared into, total protein content 34%；Crude fiber content is 19%, and amino acid content is
1.4%；Vineland is applied fertilizer with the present embodiment fertilizer, sugared content improves 6 ~ 8% in grape fruit, and vintage is 2.2 ~ 2.6 tons/
Mu.
Embodiment 2
A. pretreatment of raw material
（1）The sugarcane tip, sugarcane leaf are taken, cleans, is crushed to obtain raw material disintegrating slag using pulverizer, is then fed into the progress of steam blasting machine
Explosion treatment, obtain bagasse powder；
The Steam explosion treatment is divided into two benches progress, and first stage explosion steam pressure is 1.2MPa, pressure hold time
For 240s；Second stage steam blasting steam pressure is 2MPa, pressure hold time 160s.
（2）Bagasse powder is added in the ionic liquid of its quality 5%, heating stirring is to 60 DEG C under nitrogen protection, insulation
10min, 5% solid acid catalyst is then added, 180 DEG C is heated to, degradation of mixture is obtained after reaction time 3h；
The ionic liquid is made up of courage acyl cation and alanine anion, and its water content is 50%；
（3）Treat that degradation of mixture is cooled to 50 DEG C, the warm water of isometric 50 DEG C of addition, mix, centrifuged under 17000rpm
15min, residue are washed with deionized 2 times, collect all supernatants, are rotated under vacuum, after removing moisture, add new sweet
Bagasse is handled, and is well mixed the supernatant after all revolvings and residue after 4 batches and is obtained mixed liquor；
B. fermenting raw materials
（1）60 parts of mixed liquor of gained is taken, the molasses of its quality 15% is sprayed, adds 6 parts of rainbow conk powder, 5 parts of pine needle meal, analysis for soybean powder 6
Part, 20 parts of mannitol, 2 parts of potassium dihydrogen phosphate, 0.6 part of calcium chloride, 0.6 part of magnesium sulfate, it is well mixed, regulation pH is 7.2, inoculation
Compound bacteria carries out fermentation 72h, and control fermentation temperature carries out compost fermentation at 40 DEG C, carries out turning over fertilizer when fermentation temperature is more than 50 DEG C
Ensure that temperature is no more than 50 DEG C, obtain converted products；
The molasses brix is 40Bx, sugar content 35%.
The compound bacteria is quick bacillus flavus, blown-ball Azotobacter, bacillus licheniformis, aspergillus versicolor；It is described quick yellow
Color bacillus, blown-ball Azotobacter inoculum concentration are respectively 2%, and bacillus licheniformis, aspergillus versicolor inoculum concentration are respectively 4%；
（2）30 parts of humic is taken, 60 parts of calcium chloride, adds converted products, after being well mixed, produces grape special fertilizer material.
In the fertilizer that the present embodiment is prepared into, total protein content 34%；Crude fiber content is 19%, and amino acid content is
1.8%.Vineland is applied fertilizer with the present embodiment fertilizer, sugared content improves 5 ~ 7% in grape fruit, and vintage is 2 ~ 2.2 tons/
Mu.
Embodiment 3
A. pretreatment of raw material
（1）The sugarcane tip, sugarcane leaf are taken, cleans, is crushed to obtain raw material disintegrating slag using pulverizer, is then fed into the progress of steam blasting machine
Explosion treatment, obtain bagasse powder；
The Steam explosion treatment is divided into two benches progress, and first stage explosion steam pressure is 1.4MPa, pressure hold time
For 220s；Second stage steam blasting steam pressure is 2.2MPa, pressure hold time 150s.
（2）Bagasse powder is added in the ionic liquid of its quality 6%, heating stirring is to 65 DEG C under nitrogen protection, insulation
10min, 6% solid acid catalyst is then added, 180 DEG C is heated to, degradation of mixture is obtained after reaction time 4h；
The ionic liquid is made up of courage acyl cation and lysine anion, and its water content is 60%；
（3）Treat that degradation of mixture is cooled to 50 DEG C, the warm water of isometric 50 DEG C of addition, mix, centrifuged under 17000rpm
20min, residue are washed with deionized 3 times, collect all supernatants, are rotated under vacuum, after removing moisture, add new sweet
Bagasse is handled, and is well mixed the supernatant after all revolvings and residue after 4 batches and is obtained mixed liquor；
B. fermenting raw materials
（1）60 parts of mixed liquor of gained is taken, the molasses of its quality 16% is sprayed, adds 8 parts of rainbow conk powder, 8 parts of pine needle meal, analysis for soybean powder 8
Part, 30 parts of mannitol, 3 parts of potassium dihydrogen phosphate, 1 part of calcium chloride, 1 part of magnesium sulfate, it is well mixed, regulation pH is 7.2, and inoculation is compound
Bacterium carries out fermentation 80h, and control fermentation temperature carries out compost fermentation at 50 DEG C, carries out turning over fertile guarantee when fermentation temperature is more than 50 DEG C
Temperature is no more than 50 DEG C, obtains converted products；
The molasses brix is 40Bx, sugar content 32%.
The compound bacteria is quick bacillus flavus, blown-ball Azotobacter, bacillus licheniformis, aspergillus versicolor；It is described quick yellow
Color bacillus, blown-ball Azotobacter inoculum concentration are respectively 2%, and bacillus licheniformis, aspergillus versicolor inoculum concentration are respectively 4%；
（2）25 parts of humic acid is taken, 55 parts of calcium chloride, adds converted products, after being well mixed, produces grape special fertilizer material.
In the feed that the present embodiment is prepared into, total protein content 35%；Crude fiber content is 14%, and amino acid content is
1.7%.Vineland is applied fertilizer with the present embodiment fertilizer, sugared content improves 7 ~ 9% in grape fruit, and vintage is 2.3 ~ 2.7 tons/
Mu.
Contrast experiment
Universal grape special-purpose control-release fertilizer, the big ecological engineering Co., Ltd production of Shandong Nintaus, model PT20-10-15.
The grape special fertilizer material that embodiment 1 ~ 3 is prepared.
For trying grape variety：Yellow sand king.
Dose be for 50 kilograms every mu, fertilizing method be after grape harvesting in autumn direct motion dig 40 centimetres of depths, 20 lis
The wide ditch of rice, apply in ditch after disposably fertilizer is mixed with part soil, watered after earthing.Fertilization effect such as table 1.
Each grape fertilizer fertilization effect of table 1
It can be seen that by table 1, grape special fertilizer material prepared by the present invention can effectively improve probiotics quantity in soil, improve grape
Yield and sugared content.The grape special fertilizer material cost of material of the present invention is low, and preparation method is simple.
The above embodiment of the present invention scheme is only the description of the invention and can not limit the present invention, in the power with the present invention
Any change in sharp claim suitable implication and scope, is all considered to be and is included within the scope of the claims.
Claims (7)
1. a kind of grape special fertilizer material, it is characterised in that be prepared by following weight fraction than component raw material by fermentation：Sugarcane
50 ~ 100 parts of the tip, 50 ~ 100 parts of sugarcane top, 20 ~ 50 parts of molasses, 10 ~ 15 parts of rainbow conk, 5 ~ 10 parts of pine needle meal, 20 ~ 30 parts of humic acid,
50 ~ 60 parts of calcium chloride.
2. a kind of preparation method of grape special fertilizer material, it is characterised in that be prepared by following steps：
A. pretreatment of raw material
（1）The sugarcane tip, sugarcane leaf are taken, cleans, is crushed to obtain raw material disintegrating slag using pulverizer, is then fed into the progress of steam blasting machine
Explosion treatment, obtain bagasse powder；
（2）Bagasse powder is added in the ionic liquid of its quality 5 ~ 8%, heating stirring is protected to 60 ~ 80 DEG C under nitrogen protection
Warm 10min, the solid acid catalyst of bagasse silty amount 5 ~ 10% is then added, be heated to 180 ~ 200 DEG C, after 3 ~ 5h of reaction time
Obtain degradation of mixture；
The ionic liquid is made up of courage acyl cation and amino acid anion, and its water content is 50 ~ 80%；
（3）Treat that degradation of mixture is cooled to 50 ~ 60 DEG C, the warm water of isometric 50 ~ 60 DEG C of addition, mix, under 17000rpm from
15 ~ 20min of the heart, residue are washed with deionized 2 ~ 3 times, collect supernatant, are rotated under vacuum, and after removing moisture, addition is new
Bagasse handled, the supernatant after all revolvings and residue are well mixed after 4 ~ 5 batches, obtain mixed liquor；
B. fermenting raw materials
（1）60 ~ 80 parts of mixed liquor of gained is taken, the molasses of its quality 15 ~ 20% is sprayed, adds 6 ~ 12 parts of rainbow conk powder, pine needle meal 5 ~ 10
Part, 6 ~ 12 parts of analysis for soybean powder, 20 ~ 40 parts of mannitol, 2 ~ 4 parts of potassium dihydrogen phosphate, 0.6 ~ 1.2 part of calcium chloride, magnesium sulfate 0.6 ~ 1.2
Part, it is well mixed, regulation pH is 7.2 ~ 7.3, and inoculation compound bacteria carries out 72 ~ 80h of fermentation, and control fermentation temperature enters at 40 ~ 50 DEG C
Row compost fermentation, carry out turning over fertilizer guarantee temperature when fermentation temperature is more than 50 DEG C no more than 50 DEG C, obtain converted products；
The compound bacteria is quick bacillus flavus, blown-ball Azotobacter, bacillus licheniformis, aspergillus versicolor；
（2）20 ~ 30 parts of humic acid is taken, 50 ~ 60 parts of calcium chloride, adds converted products, after being well mixed, produces grape special fertilizer
Material.
A kind of 3. preparation method of grape special fertilizer material according to claim 2, it is characterised in that：At the steam blasting
Reason is divided into two benches progress, and first stage explosion steam pressure is 1.2 ~ 1.6MPa, and pressure hold time is 200 ~ 240s；Second
Stage steam explosion steam pressure is 2 ~ 2.8MPa, and pressure hold time is 140 ~ 160s.
A kind of 4. preparation method of grape special fertilizer material according to claim 2, it is characterised in that：The solid acid catalysis
The preparation method of agent is as follows：
A. in air atmosphere, by 250 DEG C of calcining 2h of MCM-41 molecular sieves, 350 DEG C is then heated to, continues to calcine 2h, finally
550 DEG C of calcining 4h are warming up to, are sealed after cooling standby；
B. the MCM-41 molecular sieves after calcining are invaded into bubble 24h in the 1mol/L concentrated sulfuric acid, after 105 DEG C of drying, forged at 300 DEG C
4h is burnt, obtains H2SO4/ MCM-41 molecular sieve solid acid catalysts.
A kind of 5. preparation method of grape special fertilizer material according to claim 2, it is characterised in that：The quick yellow bar
Bacterium, blown-ball Azotobacter inoculum concentration are respectively 2 ~ 4%, and bacillus licheniformis, aspergillus versicolor inoculum concentration are respectively 4 ~ 8%.
A kind of 6. preparation method of grape special fertilizer material according to claim 2, it is characterised in that：The molasses brix is
40 ~ 50Bx, sugar content are 30 ~ 35%.
A kind of 7. preparation method of grape special fertilizer material according to claim 2, it is characterised in that：In the ionic liquid
Amino acid anion is a kind of in lysine anion, glycine anion, alanine anion, methionine anion.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109265201A (en) * | 2018-11-21 | 2019-01-25 | 山东农业大学 | Using animal wool lysate as the bio-feritlizer of effective component and preparation method and application |
| CN109627122A (en) * | 2019-01-17 | 2019-04-16 | 山东省农业科学院作物研究所 | A kind of biogas residue farmland compound fertilizer and preparation method thereof |
| CN111574311A (en) * | 2020-04-29 | 2020-08-25 | 河北科技大学 | Environment-friendly enzyme and preparation method and application thereof |
| CN118324586A (en) * | 2024-04-15 | 2024-07-12 | 山东沃力生物科技集团有限公司 | Absorption-promoting amino acid fertilizer, preparation method and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160037772A1 (en) * | 2014-08-08 | 2016-02-11 | Mario Miguel Guerrero Mendez | Increasing abiotic stress tolerance in plants |
| CN106365893A (en) * | 2016-08-28 | 2017-02-01 | 铜仁市万山区山地葡萄科技有限公司 | Preparation method of special organic fertilizer for grapes |
| CN106588489A (en) * | 2016-12-21 | 2017-04-26 | 广西浩昌敏再生资源利用有限公司 | Special chemical fertilizer capable of improving grape fruit quality |
| CN106831233A (en) * | 2017-01-03 | 2017-06-13 | 青岛农业大学 | Biological organic soil that a kind of utilization compost product improvement foundation pit earth is obtained and preparation method thereof |
| CN107018852A (en) * | 2017-03-28 | 2017-08-08 | 陆川县巨丰种植园 | A kind of high-yield planting method of grape |
-
2017
- 2017-10-11 CN CN201710938525.3A patent/CN107459432A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160037772A1 (en) * | 2014-08-08 | 2016-02-11 | Mario Miguel Guerrero Mendez | Increasing abiotic stress tolerance in plants |
| CN106365893A (en) * | 2016-08-28 | 2017-02-01 | 铜仁市万山区山地葡萄科技有限公司 | Preparation method of special organic fertilizer for grapes |
| CN106588489A (en) * | 2016-12-21 | 2017-04-26 | 广西浩昌敏再生资源利用有限公司 | Special chemical fertilizer capable of improving grape fruit quality |
| CN106831233A (en) * | 2017-01-03 | 2017-06-13 | 青岛农业大学 | Biological organic soil that a kind of utilization compost product improvement foundation pit earth is obtained and preparation method thereof |
| CN107018852A (en) * | 2017-03-28 | 2017-08-08 | 陆川县巨丰种植园 | A kind of high-yield planting method of grape |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109265201A (en) * | 2018-11-21 | 2019-01-25 | 山东农业大学 | Using animal wool lysate as the bio-feritlizer of effective component and preparation method and application |
| CN109627122A (en) * | 2019-01-17 | 2019-04-16 | 山东省农业科学院作物研究所 | A kind of biogas residue farmland compound fertilizer and preparation method thereof |
| CN111574311A (en) * | 2020-04-29 | 2020-08-25 | 河北科技大学 | Environment-friendly enzyme and preparation method and application thereof |
| CN118324586A (en) * | 2024-04-15 | 2024-07-12 | 山东沃力生物科技集团有限公司 | Absorption-promoting amino acid fertilizer, preparation method and application |
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Application publication date: 20171212 |