CN107439562A - A kind of medicament composition and its application containing Tebuconazole and four chlorantraniliproles - Google Patents
A kind of medicament composition and its application containing Tebuconazole and four chlorantraniliproles Download PDFInfo
- Publication number
- CN107439562A CN107439562A CN201710825170.7A CN201710825170A CN107439562A CN 107439562 A CN107439562 A CN 107439562A CN 201710825170 A CN201710825170 A CN 201710825170A CN 107439562 A CN107439562 A CN 107439562A
- Authority
- CN
- China
- Prior art keywords
- tebuconazole
- chlorantraniliproles
- medicament
- rice
- medicament composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a kind of medicament composition for containing four chlorantraniliproles and Tebuconazole, it is made up of the chlorantraniliprole of active ingredient four and Tebuconazole and its auxiliary agent, four described chlorantraniliproles and Tebuconazole medicament composition indoor biometricses are 4 to the synergic ratio of false smut and rice leaf roller:1‑1:4.Field experiment is shown, the different dosage forms of two kinds of medicament compositions show good preventive effect to false smut and rice leaf roller, this medicament composition has synergistic effect notable, preventive effect is good, dosage is low, to environment and target organismses safety, the features such as being controlled a medicine more, there is good synergistic effect to preventing and treating rice pest especially false smut and rice leaf roller, have good effect to the resistance to the action of a drug, the reduction dosage of medicament to slowing down pest and disease damage.
Description
Technical field
The present invention relates to plant pest management field, and in particular to a kind of medicament containing Tebuconazole and four chlorantraniliproles
Composition and its production and use.
Background technology
Tebuconazole（Tebuconazole）, chemical name：(RS) -1- (4- chlorphenyls) -4,4- dimethyl -3-（1H-1,
2,4 triazol-1-yl methyl）Amyl- 3- alcohol, belongs to triazole bactericidal agent.Efficiently, wide spectrum, there is protection, treat and root out three big work(
Can, there are permeability and systemic activity, available for cauline leaf spraying, seed treatment, soil treatment.
Four chlorantraniliproles belong to ryanodine receptor activator insecticides, for low toxicity, broad spectrum pesticide, available for preventing and treating rice
The lepidoptera pests such as leaf-roller, striped rice borer, diamondback moth.
Rice leaf roller, belong to lepidoptera pyralidae, also known as scrape blue or green worm, be distributed in national paddy fields, with it is pregnant,
Heading stage damage loss is maximum, is one of primary pest of rice crop, has a strong impact on the quality and yield of rice.In recent years,
Rice leaf roller is to conventional dose（Such as organic phosphates, chrysanthemum esters and anabasine）The high-caliber resistance to the action of a drug is shown,
Prevent and treat more and more difficult.
Rice green smut, also known as pseudo- smut, paddy blossom disease and blue or green powder disease, is fungal disease, is the main disease on rice
One of evil, happens occasionally in China Hebei, the Yangtze river basin and southern each province paddy fields, once occurring, has a strong impact on rice
Yield and quality, seriously ill plot can underproduction 30%-60%.
It is mostly single dispenser to prevent and treat rice leaf roller and false smut in the market, add spraying times and dispenser into
This, the preventing and treating time of rice leaf roller and false smut approaches, so, cnaphalocrocis is prevented and treated while being badly in need of safe and efficient in production
The medicament of snout moth's larva and false smut.
In order to adapt to the actual demand in Rice Production, wasted also for the multiple dispenser of crops insecticide, bactericide is reduced
The problem of manpower and materials, Tebuconazole and four chlorantraniliproles compounding have been carried out to false smut and the Toxicity Determination of rice leaf roller
And field medicine effect test, it is found that Tebuconazole and four chlorantraniliproles compounding have certain synergy to rice leaf roller and false smut and made
With crop field effect shows that both are administered simultaneously, and have good preventive effect to rice leaf roller and false smut.So both avoid desinsection
The waste of manpower and materials, can also give full play to the effect of medicament caused by agent, bactericide repeat dispenser.Reducing dosage
Meanwhile ecological disruption and environmental pollution are effectively reduced, and rice yield and quality can be improved；Tebuconazole and tetrachloro worm in the present invention
Acid amides belongs to low toxicity, to people and animals, beneficial organism, Environmental security；It can administer or delay the resistance to the action of a drug of the disease pest to single medicament.
The content of the invention
The present invention provides a kind of medicament composition containing Tebuconazole and four chlorantraniliproles, can prevent and treat the rice on rice simultaneously
A variety of pest and disease damages such as leaf-roller, false smut and banded sclerotial blight, solves the multiple dispenser of bactericide, insecticide in Rice Production
Problem.Sprayed once early stage in Rice Heading, can effectively prevent and treat the harm of the pest and disease damage such as rice leaf roller and false smut on rice,
Cost of labor and drug cost when can reduce the applications of pesticide, have the characteristics of economic, efficient, environmentally friendly.
The technical scheme of the use of the present invention is as follows：
A kind of medicament composition containing Tebuconazole and four chlorantraniliproles, it is characterised in that：By active ingredient Tebuconazole and tetrachloro worm
Acid amides forms, and the mass ratio of the Tebuconazole and four chlorantraniliproles is (1-4):(1-32).
The described medicament composition containing Tebuconazole and four chlorantraniliproles, it is characterised in that：Penta in the composition pesticide
The mass ratio of azoles alcohol and four chlorantraniliproles is 4:1-1:4.
Described medicament composition, it is characterised in that：The quality of Tebuconazole and four chlorantraniliproles in the medicament composition
Than for 1:1-1:4.
The described medicament composition containing Tebuconazole and four chlorantraniliproles, it is characterised in that：The agent of the medicament composition
Type is missible oil, suspending agent, water-dispersible granules, wettable powder, aqueous emulsion, micro-capsule suspension.
Application of the described medicament composition containing Tebuconazole and four chlorantraniliproles on preventing and treating rice pest.
The mass ratio of Tebuconazole and four chlorantraniliproles is 4 in medicament composition of the present invention:1-1:32, both total amounts
Shared preparation ratio is unlimited.
The medicament composition of the present invention compared with prior art, produces following beneficial effect：（1）Said composition is to rice rice
Bent disease has preferable synergistic effect, can reduce the dosage of medicament.（2）The insecticidal bactericide both has quick-acting, has again longer
Lasting effect, multiple diseases and insect pest can be prevented and treated simultaneously.One medicine is controlled more, and saving of labor saves this, solves crop middle and later periods dispenser inconvenience
The problem of.（3）The insecticidal bactericide toxicity is low, while effectively preventing and treating pest and disease damage, reduces environmental pollution.（4）The medicament
Composition cost is low, prepares simply, easy to utilize.
The innovation of the present invention is to be found that the synergistic effect in terms of Tebuconazole and four chlorantraniliproles preventing and treating false smut
And the synergistic effect of Tebuconazole and four chlorantraniliproles preventing and treating planthopper.By Tebuconazole and four chlorantraniliprole certain proportion mixtures,
Reduce the usage amount of medicament in the case where preventive effect does not decline.
Toxicity Determination is as shown in the table.Indoor biometricses use mycelial growth rate method and drop method.
Tebuconazole and four chlorantraniliproles compounding are as shown in the table to the Toxicity Determination result of rice green smut
The Tebuconazole of table 1 and four chlorantraniliproles compound the Toxicity Determination to false smut
Note：CTC calculated values set four chlorantraniliprole EC50For 5000mg/L.
By upper table as can be seen that Tebuconazole has fine indoor virulence, EC to rice green smut50For 0.084mg/L, kill
After the chlorantraniliprole of worm agent four is compounded with it, institute's test ratio shows good synergistic effect.Illustrate the chlorantraniliprole of insecticide four
After being compounded with Tebuconazole, not only without Tebuconazole is weakened to the preventive effect of false smut, good synergistic effect is served on the contrary.
Tebuconazole and four chlorantraniliproles compounding are as shown in the table to the Toxicity Determination of rice leaf roller
The chlorantraniliprole of table 2 four compounds the Toxicity Determination to rice leaf roller with Tebuconazole
Note：CTC calculated values setting Tebuconazole LC50For 5000mg/L.
It can be seen from Table 2 that four chlorantraniliproles and Tebuconazole are 4:1-1:Co-toxicity coefficient is all higher than in 4 proportions
120, synergistic effect is notable, wherein 1:2 synergistic effects are the most obvious, and coefficient of synergism illustrates four chlorantraniliproles and penta up to 193.16
After azoles alcohol compounding, not only without preventive effect of the pymetrozine to rice leaf roller is weakened, serve within the specific limits on the contrary well
Synergistic effect.
（Four）Invention embodiment：
The composition pesticide of the present invention for containing four chlorantraniliproles and Tebuconazole can be processed into missible oil, suspending agent, moisture and dissipate
Property granula, wettable powder and microemulsion, can be specifically described by example 1, example 2, example 3, example 4 and example 5, but
Not limited to this.
Example 1：
Four chlorantraniliproles 15% are taken, Tebuconazole 15%, ethanol 30% is added, dimethylbenzene 20%, agriculture is added after high-speed stirred is well mixed
Newborn 602# 5%g, TX-10 4%g, dimethylbenzene supply 100%, are configured to missible oil.
Example 2：
Take four chlorantraniliproles 15%, Tebuconazole 15%, sodium lignin sulfonate 5%, styrene phenol formaldehyde resin APEO
2.4%, BY140 3%, xanthans 0.2%, aluminium-magnesium silicate 2%, ethylene glycol 5%, octanol 0.01%, mended with water and arrive 100g, uniformly mixing
After put into sand mill, be ground to below 5 microns of particle diameter, suspending agent be made.
Example 3：
Take four chlorantraniliproles 15%, Tebuconazole 15%, Methyl fatty acid amides benzene sulfonic acid sodium salt 5%, sodium methylene bis-naphthalene sulfonate 5%, sulfuric acid
Ammonium 5%, White Carbon black 25%, polyethylene glycol 3%, light weight calcium are mended to 100%.Active compound and auxiliary agent are crushed to grain through micro jet
5 μm of footpath, obtains female powder, is granulated, dries after female powder and Aqueous Solutions of Polyethylene Glycol are sufficiently mixed, sieving, so as to which water dispersible be made
Granula.
Example 4：
Take four chlorantraniliproles 15%, Tebuconazole 15%, Morwet D-425（Huntsman companies）5%, the contracting of alkyl naphthalene sulfonic acid sodium formaldehyde
Compound 2.5%, ammonium sulfate 5%, light weight calcium are mended to 100%, are uniformly crushed after mixing through airslide disintegrating mill, wettable powder is made.
Example 5：
Four chlorantraniliproles 15% are taken, Tebuconazole 15%, are dissolved in the in the mixed solvent containing 20% cyclohexanone and 10%DMF, add 5%
By140 and 2.8% agriculture breast 602#, is uniformly mixed, above-mentioned solution is slowly poured into water, under 100-300r/min rotating speeds
It is sufficiently stirred, water complements to 100%, and microemulsion is made.
Above-mentioned raw materials are commercially available qualified products.
Above-mentioned preparation field test has been subjected to prove its drug effect.Experimental arrangement is in Changfeng County Gang Ji experimental plots, test area
1400m2, Routine Management, other any medicaments are not sprayed during experiment, before rice cut 10-12 days spray pesticides, experiment set
3 groups of repetitions, random district's groups arrangement.Preventing and treating rice leaf roller and false smut field efficacy see the table below.
By upper table as can be seen that the mix preparation of four chlorantraniliproles and Tebuconazole under 6.0mg/L concentration for the treatment of 7 days it is right
The preventive effect of rice leaf roller has good prevention effect more than 90%, and the preventive effect of four chlorantraniliprole single doses is only
78.72%, significant difference；25 days preventive effects to false smut are more than 85% after processing, and the preventive effect of Tebuconazole single dose is 82.43%.
The present invention is by four chlorantraniliproles and Tebuconazole in proportion 4:1-1:4 are fabricated to missible oil, wettable powder, water dispersible
The preparation such as granula and suspending agent, water spray, atomizing can both be entered after can also adding suitable adjuvants with machineries such as hot mist machine, aircrafts
The extensive spraying of row.
Claims (4)
- A kind of 1. medicament composition containing Tebuconazole and four chlorantraniliproles, it is characterised in that：Its is effective for described medicament composition Composition is Tebuconazole and four chlorantraniliproles, and the mass ratio of the Tebuconazole and four chlorantraniliproles is 4:1-1:4.
- 2. the medicament composition according to claim 1 containing Tebuconazole and four chlorantraniliproles, it is characterised in that：The medicament The mass ratio of Tebuconazole and four chlorantraniliproles is 2 in composition:1-1:2.
- 3. the medicament composition according to claim 1 containing Tebuconazole and four chlorantraniliproles, it is characterised in that：The medicament The formulation of composition is missible oil, suspending agent, water-dispersible granules, wettable powder, aqueous emulsion, micro-capsule suspension.
- 4. the medicament composition according to claim 1 containing Tebuconazole and four chlorantraniliproles is on preventing and treating rice pest Using.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710825170.7A CN107439562A (en) | 2017-09-14 | 2017-09-14 | A kind of medicament composition and its application containing Tebuconazole and four chlorantraniliproles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710825170.7A CN107439562A (en) | 2017-09-14 | 2017-09-14 | A kind of medicament composition and its application containing Tebuconazole and four chlorantraniliproles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107439562A true CN107439562A (en) | 2017-12-08 |
Family
ID=60495499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710825170.7A Pending CN107439562A (en) | 2017-09-14 | 2017-09-14 | A kind of medicament composition and its application containing Tebuconazole and four chlorantraniliproles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107439562A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114467601A (en) * | 2022-01-19 | 2022-05-13 | 广东省林业科学研究院 | Prevention and control method for cinnamon bivalve leaf roller moths |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104798798A (en) * | 2014-01-26 | 2015-07-29 | 沈阳化工研究院有限公司 | Binary composition and application thereof |
| CN105532672A (en) * | 2014-11-03 | 2016-05-04 | 中化农化有限公司 | Composition containing SYP9080 and triazole bactericide, and application thereof |
-
2017
- 2017-09-14 CN CN201710825170.7A patent/CN107439562A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104798798A (en) * | 2014-01-26 | 2015-07-29 | 沈阳化工研究院有限公司 | Binary composition and application thereof |
| CN105532672A (en) * | 2014-11-03 | 2016-05-04 | 中化农化有限公司 | Composition containing SYP9080 and triazole bactericide, and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114467601A (en) * | 2022-01-19 | 2022-05-13 | 广东省林业科学研究院 | Prevention and control method for cinnamon bivalve leaf roller moths |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102258043A (en) | Germicide composition containing protioconazole | |
| CN102342285B (en) | Sterilization disease-resistant composition and suspension seed coating agent thereof | |
| CN104396974B (en) | Pesticide composition containing thifluzamide and chlorantraniliprole as well as application of pesticide composition | |
| CN102388911A (en) | Suspension seed coating formulation | |
| CN103858886A (en) | Sterilizing composition containing isopyrazam | |
| CN102342284B (en) | Sterilization disease-resistant composition and suspension seed coating agent thereof | |
| CN101632382A (en) | Pesticide composition containing flusilazole and tebuconazole and application thereof | |
| CN107439562A (en) | A kind of medicament composition and its application containing Tebuconazole and four chlorantraniliproles | |
| CN103651452A (en) | Bactericidal composition containing octyl trichlamide and carbendazim and application of bactericidal composition | |
| CN107006479A (en) | A kind of bactericidal composition containing SYP-3375 Yu fluorobenzene ether amide | |
| CN104430387B (en) | Insecticidal bactericide containing azoxystrobin and pymetrozine and application thereof | |
| CN106332893A (en) | Pesticide composition | |
| CN102823599B (en) | Bactericidal composition containing kresoxim-methyl and difenoconazole and application | |
| CN106804597A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide | |
| CN105638670B (en) | A kind of bactericidal composition containing fluorine bacterium azoles and oxazole | |
| CN105284815B (en) | A kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax | |
| CN103478156A (en) | MCPA (2-methyl-4-chloro-phenoxyacetic acid)-isoproturon herbicide and production method thereof | |
| CN104686522B (en) | A kind of bactericidal composition of fluorine-containing azoles ring bacterium amine and fluazinam | |
| US11484031B2 (en) | Seed coating agent for preventing and treating wheat rot disease | |
| CN101416629A (en) | Bactericide agent composition containing kresoxim-methyl and epoxiconazole | |
| CN106900722A (en) | A kind of composition pesticide | |
| CN105265444A (en) | Pesticide composition containing pyraflufen-ethyl and trifloxystrobin | |
| CN107333780B (en) | Bactericidal composition and application thereof | |
| CN110495461A (en) | A kind of bactericidal composition containing coumoxystrobin and probenazole | |
| CN106804596A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Rynaxypyr |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171208 |