CN107418778A - 一种无色素无香精洗衣片及其制备方法 - Google Patents

一种无色素无香精洗衣片及其制备方法 Download PDF

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CN107418778A
CN107418778A CN201710617251.8A CN201710617251A CN107418778A CN 107418778 A CN107418778 A CN 107418778A CN 201710617251 A CN201710617251 A CN 201710617251A CN 107418778 A CN107418778 A CN 107418778A
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parts
essence
pigment
laundry sheet
sodium
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钱钢
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Connaught Environmental Protection Technology (suzhou) Co Ltd
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Abstract

本发明公开了一种无色素无香精洗衣片，按照质量份数包括以下组分：十二醇聚氧乙烯米硫酸钠1‑10份、椰油酰胺丙基甜菜碱0.1‑3份、粘合剂3‑10份、茶皂素1‑10份、α‑烯基磺酸钠5‑15份、防腐剂0.1‑0.3份、填充料10‑15份、润滑剂0.2‑0.3份、非离子表面活性剂6‑8份、螯合剂0.2‑0.5份、氢氧化钠0.01‑1.0份、丙二醇甲醚醋酸酯5‑8份、去离子水30‑80份；本发明提供的洗衣片中无色素无香精，适宜婴幼儿衣物的清洗；本发明提供的洗衣片的制备方法简单，易于实现。

Description

一种无色素无香精洗衣片及其制备方法
技术领域
本发明属于化工技术领域，特别涉及一种无色素无香精洗衣片及其制备方法。
背景技术
洗衣片与传统方式相比，大大提高了产品的去污能力 ,无磷，无添加，不伤手，洗衣片遇水后即可迅速分解溶化，释放纳米级洁净小分子，更深层更彻底地净化沉积在衣服上的顽渍。
此外，现有技术中的洗衣片，含有色素和香精，不适宜婴幼儿衣物的清洗。色素与香精对婴幼儿产生伤害，故急需一种无色素无香精的洗衣片。
发明内容
本发明提供一种无色素无香精洗衣片及其制备方法，以解决现有技术中洗衣片中含有色素和香精，不适宜婴幼儿衣物清洗的问题。
为实现上述目的，本发明采用的技术方案为：
一种无色素无香精洗衣片，按照质量份数包括以下组分：十二醇聚氧乙烯米硫酸钠1-10份、椰油酰胺丙基甜菜碱0.1-3份、粘合剂3-10份、茶皂素1-10份、α-烯基磺酸钠5-15份、防腐剂0.1-0.3份、填充料10-15份、润滑剂0.2-0.3份、非离子表面活性剂6-8份、螯合剂0.2-0.5份、氢氧化钠0.01-1.0份、丙二醇甲醚醋酸酯5-8份、去离子水30-80份。
所述粘合剂为羧甲基纤维素钠、瓜尔胶、纤维素、麦牙糊精、糖类、聚乙二醇和聚乙烯醇中的一种或多种以任意比例的混合物。
所述非离子表面活性剂为烷氧基化表面活性剂或聚氧乙烯-聚氧丙烯嵌段聚合物中的一种。
所述填充料为滑石粉、高岭土、藻类土、淀粉、硅石、尼龙中的一种或多种以任意比例的混合物。
所述润滑剂为硬脂酸镁、二氧化硅、氢化植物油、棕榈酸异丙酯、甘油、矿油中的一种或多种以任意比例的混合物。
所述螯合剂为焦磷酸钠或乙二胺四乙酸二钠。
所述防腐剂为异噻唑啉酮。
所述洗衣片的厚度为0.5-1.0cm。
一种无色素无香精洗衣片的制备方法，包括以下步骤：
反应釜中加入去离子水和丙二醇甲醚醋酸酯，加热至50-60℃，向去离子水中加入二醇聚氧乙烯米硫酸钠和椰油酰胺丙基甜菜碱，搅拌均匀，再向其中加入茶皂素、非离子表面活性剂，加热至70-90℃，搅拌均匀，再向其中加入α-烯基磺酸钠，加热至90-95℃，再向其中加入填充料、粘合剂和润滑剂，搅拌均匀，自然降温至60-80℃，再向其中加入螯合剂，搅拌均匀，自然降温至50-60℃，继续搅拌隔夜后，加热至70-80℃，再向其中加入防腐剂，自然冷却至室温，再向其中加入氢氧化钠，调节PH至6-8，搅拌均匀后倒入模板，再将模板置于烘干筒中进行烘干，得到洗衣片。
倒入模板前，模板预热至30-50℃、烘干筒的烘干温度为50-60℃，烘干时间为2-3h、烘干筒的转速为10-15转/min。
与现有技术相比，本发明具有以下优点：
本发明提供的洗衣片中无色素无香精，适宜婴幼儿衣物的清洗；本发明提供的洗衣片的制备方法简单，易于实现。
具体实施方式
下面结合实施例对本发明作更进一步的说明。
实施例1
一种无色素无香精洗衣片，按照质量份数包括以下组分：十二醇聚氧乙烯米硫酸钠1份、椰油酰胺丙基甜菜碱0.1份、粘合剂羧甲基纤维素钠3份、茶皂素1份、α-烯基磺酸钠5份、防腐剂异噻唑啉酮0.1份、填充料滑石粉10份、润滑剂硬脂酸镁0.2份、非离子表面活性剂烷氧基化表面活性剂6份、螯合剂焦磷酸钠0.2份、氢氧化钠0.01份、丙二醇甲醚醋酸酯5份、去离子水30份，所述洗衣片的厚度为0.5cm。
一种无色素无香精洗衣片的制备方法，包括以下步骤：
反应釜中加入去离子水和丙二醇甲醚醋酸酯，加热至50℃，向去离子水中加入二醇聚氧乙烯米硫酸钠和椰油酰胺丙基甜菜碱，搅拌均匀，再向其中加入茶皂素、非离子表面活性剂，加热至70℃，搅拌均匀，再向其中加入α-烯基磺酸钠，加热至90，再向其中加入填充料、粘合剂和润滑剂，搅拌均匀，自然降温至60℃，再向其中加入螯合剂，搅拌均匀，自然降温至50℃，继续搅拌隔夜后，加热至70℃，再向其中加入防腐剂，自然冷却至室温，再向其中加入氢氧化钠，调节PH至6，搅拌均匀后倒入模板，倒入模板前，模板预热至30℃，再将模板置于烘干筒中进行烘干，烘干温度为50℃，烘干时间为2h、烘干筒的转速为10转/min，得到洗衣片。
实施例2
一种无色素无香精洗衣片，按照质量份数包括以下组分：十二醇聚氧乙烯米硫酸钠5份、椰油酰胺丙基甜菜碱2份、粘合剂瓜尔胶8份、茶皂素1-10份、α-烯基磺酸钠5-15份、防腐剂异噻唑啉酮0.2份、填充料高岭土3份、润滑剂二氧化硅0.25份、非离子表面活性剂烷氧基化表面活性剂7份、螯合剂焦磷酸钠0.3份、氢氧化钠0.5份、丙二醇甲醚醋酸酯6份、去离子水50份，所述洗衣片的厚度为0.8cm。
一种无色素无香精洗衣片的制备方法，包括以下步骤：
反应釜中加入去离子水和丙二醇甲醚醋酸酯，加热至55℃，向去离子水中加入二醇聚氧乙烯米硫酸钠和椰油酰胺丙基甜菜碱，搅拌均匀，再向其中加入茶皂素、非离子表面活性剂，加热至80℃，搅拌均匀，再向其中加入α-烯基磺酸钠，加热至93℃，再向其中加入填充料、粘合剂和润滑剂，搅拌均匀，自然降温至65℃，再向其中加入螯合剂，搅拌均匀，自然降温至55℃，继续搅拌隔夜后，加热至75℃，再向其中加入防腐剂，自然冷却至室温，再向其中加入氢氧化钠，调节PH至7，搅拌均匀后倒入模板，倒入模板前，模板预热至35℃，再将模板置于烘干筒中进行烘干，烘干温度为55，烘干时间为2.5h、烘干筒的转速为13转/min，得到洗衣片。
实施例3
一种无色素无香精洗衣片，按照质量份数包括以下组分：十二醇聚氧乙烯米硫酸钠10份、椰油酰胺丙基甜菜碱3份、粘合剂纤维素10份、茶皂素10份、α-烯基磺酸钠15份、防腐剂异噻唑啉酮0.3份、填充料藻类土15份、润滑剂氢化植物油0.3份、非离子表面活性剂聚氧乙烯-聚氧丙烯嵌段聚合物8份、螯合剂乙二胺四乙酸二钠0.5份、氢氧化钠1.0份、丙二醇甲醚醋酸酯8份、去离子水80份，所述洗衣片的厚度为1.0cm。
一种无色素无香精洗衣片的制备方法，包括以下步骤：
反应釜中加入去离子水和丙二醇甲醚醋酸酯，加热至60℃，向去离子水中加入二醇聚氧乙烯米硫酸钠和椰油酰胺丙基甜菜碱，搅拌均匀，再向其中加入茶皂素、非离子表面活性剂，加热至90℃，搅拌均匀，再向其中加入α-烯基磺酸钠，加热至95℃，再向其中加入填充料、粘合剂和润滑剂，搅拌均匀，自然降温至80℃，再向其中加入螯合剂，搅拌均匀，自然降温至60℃，继续搅拌隔夜后，加热至80℃，再向其中加入防腐剂，自然冷却至室温，再向其中加入氢氧化钠，调节PH至8，搅拌均匀后倒入模板，倒入模板前，模板预热至50℃，再将模板置于烘干筒中进行烘干，烘干温度为60℃，烘干时间为3h、烘干筒的转速为15转/min，得到洗衣片。
实施例4
一种无色素无香精洗衣片，按照质量份数包括以下组分：十二醇聚氧乙烯米硫酸钠10份、椰油酰胺丙基甜菜碱3份、粘合剂（羧甲基纤维素钠、瓜尔胶、纤维素、麦牙糊精、糖类各2份）10份、茶皂素10份、α-烯基磺酸钠15份、防腐剂异噻唑啉酮0.3份、填充料（滑石粉、高岭土、藻类土、淀粉、硅石各3份）15份、润滑剂（硬脂酸镁、二氧化硅、氢化植物油各0.1份）0.3份、非离子表面活性剂聚氧乙烯-聚氧丙烯嵌段聚合物8份、螯合剂乙二胺四乙酸二钠0.5份、氢氧化钠1.0份、丙二醇甲醚醋酸酯8份、去离子水80份，所述洗衣片的厚度为1.0cm。
一种无色素无香精洗衣片的制备方法，包括以下步骤：
反应釜中加入去离子水和丙二醇甲醚醋酸酯，加热至60℃，向去离子水中加入二醇聚氧乙烯米硫酸钠和椰油酰胺丙基甜菜碱，搅拌均匀，再向其中加入茶皂素、非离子表面活性剂，加热至90℃，搅拌均匀，再向其中加入α-烯基磺酸钠，加热至95℃，再向其中加入填充料、粘合剂和润滑剂，搅拌均匀，自然降温至80℃，再向其中加入螯合剂，搅拌均匀，自然降温至60℃，继续搅拌隔夜后，加热至80℃，再向其中加入防腐剂，自然冷却至室温，再向其中加入氢氧化钠，调节PH至8，搅拌均匀后倒入模板，倒入模板前，模板预热至50℃，再将模板置于烘干筒中进行烘干，烘干温度为60℃，烘干时间为3h、烘干筒的转速为15转/min，得到洗衣片。
实施例5
一种无色素无香精洗衣片，按照质量份数包括以下组分：十二醇聚氧乙烯米硫酸钠10份、椰油酰胺丙基甜菜碱3份、粘合剂（聚乙二醇和聚乙烯醇各5份）10份、茶皂素10份、α-烯基磺酸钠15份、防腐剂异噻唑啉酮0.3份、填充料（淀粉、硅石、尼龙各5份）15份、润滑剂（氢化植物油、棕榈酸异丙酯、甘油各0.1份）0.3份、非离子表面活性剂聚氧乙烯-聚氧丙烯嵌段聚合物8份、螯合剂乙二胺四乙酸二钠0.5份、氢氧化钠1.0份、丙二醇甲醚醋酸酯8份、去离子水80份，所述洗衣片的厚度为1.0cm。
一种无色素无香精洗衣片的制备方法，包括以下步骤：
反应釜中加入去离子水和丙二醇甲醚醋酸酯，加热至60℃，向去离子水中加入二醇聚氧乙烯米硫酸钠和椰油酰胺丙基甜菜碱，搅拌均匀，再向其中加入茶皂素、非离子表面活性剂，加热至90℃，搅拌均匀，再向其中加入α-烯基磺酸钠，加热至95℃，再向其中加入填充料、粘合剂和润滑剂，搅拌均匀，自然降温至80℃，再向其中加入螯合剂，搅拌均匀，自然降温至60℃，继续搅拌隔夜后，加热至80℃，再向其中加入防腐剂，自然冷却至室温，再向其中加入氢氧化钠，调节PH至8，搅拌均匀后倒入模板，倒入模板前，模板预热至50℃，再将模板置于烘干筒中进行烘干，烘干温度为60℃，烘干时间为3h、烘干筒的转速为15转/min，得到洗衣片。
实施例6
一种无色素无香精洗衣片，按照质量份数包括以下组分：十二醇聚氧乙烯米硫酸钠1份、椰油酰胺丙基甜菜碱0.1份、粘合剂（羧甲基纤维素钠1份、聚乙二醇0.5份和聚乙烯醇1.5份）3份、茶皂素1份、α-烯基磺酸钠5份、防腐剂异噻唑啉酮0.1份、填充料（藻类土3份、淀粉2份、硅石1份、尼龙4份）10份、润滑剂（棕榈酸异丙酯0.1份、甘油0.05份、矿油0.05份）0.2份、非离子表面活性剂烷氧基化表面活性剂6份、螯合剂焦磷酸钠0.2份、氢氧化钠0.01份、丙二醇甲醚醋酸酯5份、去离子水30份，所述洗衣片的厚度为0.5cm。
一种无色素无香精洗衣片的制备方法，包括以下步骤：
反应釜中加入去离子水和丙二醇甲醚醋酸酯，加热至50℃，向去离子水中加入二醇聚氧乙烯米硫酸钠和椰油酰胺丙基甜菜碱，搅拌均匀，再向其中加入茶皂素、非离子表面活性剂，加热至70℃，搅拌均匀，再向其中加入α-烯基磺酸钠，加热至90，再向其中加入填充料、粘合剂和润滑剂，搅拌均匀，自然降温至60℃，再向其中加入螯合剂，搅拌均匀，自然降温至50℃，继续搅拌隔夜后，加热至70℃，再向其中加入防腐剂，自然冷却至室温，再向其中加入氢氧化钠，调节PH至6，搅拌均匀后倒入模板，倒入模板前，模板预热至30℃，再将模板置于烘干筒中进行烘干，烘干温度为50℃，烘干时间为2h、烘干筒的转速为10转/min，得到洗衣片。
以上所述仅是本发明的优选实施方式，应当指出：对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (10)

1.一种无色素无香精洗衣片，其特征在于，按照质量份数包括以下组分：十二醇聚氧乙烯米硫酸钠1-10份、椰油酰胺丙基甜菜碱0.1-3份、粘合剂3-10份、茶皂素1-10份、α-烯基磺酸钠5-15份、防腐剂0.1-0.3份、填充料10-15份、润滑剂0.2-0.3份、非离子表面活性剂6-8份、螯合剂0.2-0.5份、氢氧化钠0.01-1.0份、丙二醇甲醚醋酸酯5-8份、去离子水30-80份。
2.根据权利要求1所述的无色素无香精洗衣片，其特征在于，所述粘合剂为羧甲基纤维素钠、瓜尔胶、纤维素、麦牙糊精、糖类、聚乙二醇和聚乙烯醇中的一种或多种以任意比例的混合物。
3.根据权利要求1所述的无色素无香精洗衣片，其特征在于：所述非离子表面活性剂为烷氧基化表面活性剂或聚氧乙烯-聚氧丙烯嵌段聚合物中的一种。
4.根据权利要求1所述的无色素无香精洗衣片，其特征在于，所述填充料为滑石粉、高岭土、藻类土、淀粉、硅石、尼龙中的一种或多种以任意比例的混合物。
5.根据权利要求1所述的无色素无香精洗衣片，其特征在于，所述润滑剂为硬脂酸镁、二氧化硅、氢化植物油、棕榈酸异丙酯、甘油、矿油中的一种或多种以任意比例的混合物。
6.根据权利要求1所述的无色素无香精洗衣片，其特征在于，所述螯合剂为焦磷酸钠或乙二胺四乙酸二钠。
7.根据权利要求1所述的无色素无香精洗衣片，其特征在于，所述防腐剂为异噻唑啉酮。
8.根据权利要求1所述的无色素无香精洗衣片，其特征在于：所述洗衣片的厚度为0.5-1.0cm。
9.根据权利要求1-8任一所述的无色素无香精洗衣片的制备方法，其特征在于，包括以下步骤：
反应釜中加入去离子水和丙二醇甲醚醋酸酯，加热至50-60℃，向去离子水中加入二醇聚氧乙烯米硫酸钠和椰油酰胺丙基甜菜碱，搅拌均匀，再向其中加入茶皂素、非离子表面活性剂，加热至70-90℃，搅拌均匀，再向其中加入α-烯基磺酸钠，加热至90-95℃，再向其中加入填充料、粘合剂和润滑剂，搅拌均匀，自然降温至60-80℃，再向其中加入螯合剂，搅拌均匀，自然降温至50-60℃，继续搅拌隔夜后，加热至70-80℃，再向其中加入防腐剂，自然冷却至室温，再向其中加入氢氧化钠，调节PH至6-8，搅拌均匀后倒入模板，再将模板置于烘干筒中进行烘干，得到洗衣片。
10.根据权利要求9所述的无色素无香精洗衣片的制备方法，其特征在于，倒入模板前，模板预热至30-50℃、烘干筒的烘干温度为50-60℃，烘干时间为2-3h、烘干筒的转速为10-15转/min。
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