CN107418695A - 一种有色金属防锈切削液及其制备方法 - Google Patents

一种有色金属防锈切削液及其制备方法 Download PDF

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CN107418695A
CN107418695A CN201710634501.9A CN201710634501A CN107418695A CN 107418695 A CN107418695 A CN 107418695A CN 201710634501 A CN201710634501 A CN 201710634501A CN 107418695 A CN107418695 A CN 107418695A
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王诗斌
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Chaohu Pengyuan Metal Pipe Co Ltd
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Abstract

一种有色金属防锈切削液及其制备方法,主要包括以下组分制备而成:硫化脂肪酸钠4‑6份,高碳酸钾皂8‑14份,茶叶30‑40份,动物肝脏50‑60份,玉米淀粉40‑60份,防锈油剂60‑70份,酒精90‑110份,环已烷4‑6份,0.5%碳酸钠水溶液4‑6份,钝化液9‑11份,环烷酸锌19‑21份,改性添加剂5‑15份,低级醚6‑10份,清洁剂90‑120份。配置方便,成本低,无危害,节水,不伤手,清洗过程安全简单,清洗效果好,无腐蚀效果,对人类卫生健康影响小,天然除锈剂,擦拭,用水冲洗即可,制备简便,安全无毒,对金属具有良好的除锈功能。

Description

一种有色金属防锈切削液及其制备方法
技术领域:
本发明涉及有色金属制造领域,具体涉及一种有色金属防锈切削液及其制备方法。
背景技术:
有色金属可分为重金属(如铜,铅,锌),轻金属(如铝,镁),贵金属(如金,银,铂)及稀有金属(如钨,钼,锗,锂,镧,铀)。有色金属是国民经济,人民日常生活及国防工业,科学技术发展必不可少的基础材料和重要的战略物资。农业现代化,工业现代化,国防和科学技术现代化都离不开有色金属。例如飞机,导弹,火箭,卫星,核潜艇等尖端武器以及原子能,电视,通讯,雷达,电子计算机等尖端技术所需的构件或部件大都是由有色金属中的轻金属和烯有金属制成的;此外,没有镍,钴,钨,钼,钒,铌等有色金属也就没有合金钢的生产。有色金属在某些用途(如电力工业等)上,使用量也是相当可观的。现在世界上许多国家,尤其是工业发达国家,竞相发展有色金属工业,增加有色金属的战略储备。
随着工业的发展,技术不断的进步,有色金属在切削的同时,切削面温度可达600-800℃,同时伴有大量切屑和粉末,对有色金属切削研究的深入,多在切削的过程中添加切削液,降低切削面温度,减少变形发黑,和毛刺,但是切削后,切削面被冲洗,易出现锈迹,因此,需要研制一种防锈切削液。
发明内容:
本发明所要解决的技术问题在于克服现有技术的缺陷,提供一种有色金属防锈切削液及其制备方法。
本发明所要解决的技术问题采用以下技术方案来实现。
一种有色金属防锈切削液,其特征在于:主要包括以下组分制备而成:硫化脂肪酸钠4-6份,高碳酸钾皂8-14份,茶叶30-40份,动物肝脏50-60份,玉米淀粉40-60份,防锈油剂60-70份,酒精90-110份,环已烷4-6份,0.5%碳酸钠水溶液4-6份,钝化液9-11份,环烷酸锌19-21份,改性添加剂5-15份,低级醚6-10份,清洁剂90-120份。
主要包括以下组分制备而成:硫化脂肪酸钠4份,高碳酸钾皂8份,茶叶30份,动物肝脏50份,玉米淀粉40份,防锈油剂60份,酒精90份,环已烷4份,0.5%碳酸钠水溶液4份,钝化液9份,环烷酸锌19份,改性添加剂5份,低级醚6份,清洁剂90份。
主要包括以下组分制备而成:硫化脂肪酸钠6份,高碳酸钾皂14份,茶叶40份,动物肝脏60份,玉米淀粉60份,防锈油剂70份,酒精110份,环已烷6份,0.5%碳酸钠水溶液6份,钝化液11份,环烷酸锌21份,改性添加剂15份,低级醚10份,清洁剂120份。
一种有色金属防锈切削液制备方法,其特征在于:包括以下步骤制备而成:
取硫化脂肪酸钠加入到500份水内,进行蒸馏,收集蒸馏液;
将动物肝脏放入蒸馏液中,同时添加酒精,点燃,直至酒精燃烧殆尽;
取高碳酸钾皂加入其中,再铺上茶叶,静置3天;
取环已烷浸入防锈油剂中,加热至80~90℃,约30~40min;
将茶叶取出,放入上述加热的混合物中浸泡,然后浸入0.5%碳酸钠水溶液中约5min;
将上述混合物,固液分离,400目过滤,所得滤液倒入由钝化液中,加热至80~90℃,约5~1Omin,得到A组分,备用;
取环烷酸锌、改性添加剂、低级醚加入到玉米淀粉中,用泵将磨好的浆液打入大缸内,加入酸浆,充分搅拌,至pH值为5.2左右,静止30分钟的时;
等待充分沉淀后,再把粉面上的清水倒掉,将大缸内淀粉层撬起并搅匀,然后,把这些浓浆泵入到150-180目的细筛上进行第二次过滤,方法与粗滤相同,把经过第二次过滤的浆水泵入缸内,加入等量的清洁剂,充分搅拌,300℃加热,混合3小时;
然后静置,使淀粉充分沉淀,到450-580目的细筛上进行过滤,得到B组分;
将A组分和B组分混合,加入盐20-30份,搅拌,蒸馏,所得蒸馏液即为产品。
所述的钝化液为50%的10%亚硝酸酸钠水溶液和50%的0.5%碳酸钠水溶液组成。
所述的清洁剂为苯甲酸钠10%,二异丙基萘磺酸钠20%,助剂5%份,硼酸5%,尼泊金甲酯10%,柚子汁50%与90℃加热混合制备所得。
所述的防锈油剂由羟基乙叉二磷酸HEDP、聚丙烯酸PAA、片碱NaOH、苯并三氮唑、亚硫酸钠、水和其他助剂组成,
具体配比为:羟基乙叉二磷酸HEDP占所述除锈剂制备方法总质量百分比20-25%、聚丙烯酸PAA占所述除锈剂制备方法总质量百分比15-20%、水占所述除锈剂制备方法总质量百分比40-60%、片碱NaOH占所述除锈剂制备方法总质量百分比2-5%、苯并三氮唑占所述除锈剂制备方法总质量百分比0.1-0.5%、亚硫酸钠占所述除锈剂制备方法总质量百分比1.5-2.5%,其他助剂占所述除锈剂制备方法总质量百分比2-15%。
本发明的有益效果在于:
利用动物肝脏和茶叶原本的清洁效果,配合利用玉米淀粉制备的B组分,含有大量除锈因子,通过清洁剂吸附在金属表面,有效降低切削面生锈的发生,配置方便,成本低,无危害,节水,不伤手,清洗过程安全简单,清洗效果好,无腐蚀效果,对人类卫生健康影响小,天然除锈剂,擦拭,用水冲洗即可,制备简便,安全无毒,对金属具有良好的除锈功能。
具体实施方式:
为了使本发明实现的技术手段,创作特征,达成目的与功效易于明白了解,下面结合具体实施例,进一步阐述本发明。
实施例1:一种有色金属防锈切削液,主要包括以下组分制备而成:硫化脂肪酸钠4份,高碳酸钾皂8份,茶叶30份,动物肝脏50份,玉米淀粉40份,防锈油剂60份,酒精90份,环已烷4份,0.5%碳酸钠水溶液4份,钝化液9份,环烷酸锌19份,改性添加剂5份,低级醚6份,清洁剂90份。
一种有色金属防锈切削液制备方法,包括以下步骤制备而成:
取硫化脂肪酸钠加入到500份水内,进行蒸馏,收集蒸馏液;
将动物肝脏放入蒸馏液中,同时添加酒精,点燃,直至酒精燃烧殆尽;
取高碳酸钾皂加入其中,再铺上茶叶,静置3天;
取环已烷浸入防锈油剂中,加热至80~90℃,约30~40min;
将茶叶取出,放入上述加热的混合物中浸泡,然后浸入0.5%碳酸钠水溶液中约5min;
将上述混合物,固液分离,400目过滤,所得滤液倒入由钝化液中,加热至80~90℃,约5~1Omin,得到A组分,备用;
取环烷酸锌、改性添加剂、低级醚加入到玉米淀粉中,用泵将磨好的浆液打入大缸内,加入酸浆,充分搅拌,至pH值为5.2左右,静止30分钟的时;
等待充分沉淀后,再把粉面上的清水倒掉,将大缸内淀粉层撬起并搅匀,然后,把这些浓浆泵入到150-180目的细筛上进行第二次过滤,方法与粗滤相同,把经过第二次过滤的浆水泵入缸内,加入等量的清洁剂,充分搅拌,300℃加热,混合3小时;
然后静置,使淀粉充分沉淀,到450-580目的细筛上进行过滤,得到B组分;
将A组分和B组分混合,加入盐20-30份,搅拌,蒸馏,所得蒸馏液即为产品。
钝化液为50%的10%亚硝酸酸钠水溶液和50%的0.5%碳酸钠水溶液组成。
清洁剂为苯甲酸钠10%,二异丙基萘磺酸钠20%,助剂5%份,硼酸5%,尼泊金甲酯10%,柚子汁50%与90℃加热混合制备所得。
防锈油剂由羟基乙叉二磷酸HEDP、聚丙烯酸PAA、片碱NaOH、苯并三氮唑、亚硫酸钠、水和其他助剂组成,
具体配比为:羟基乙叉二磷酸HEDP占所述除锈剂制备方法总质量百分比20%、聚丙烯酸PAA占所述除锈剂制备方法总质量百分比15%、水占所述除锈剂制备方法总质量百分比58%、片碱NaOH占所述除锈剂制备方法总质量百分比5%、苯并三氮唑占所述除锈剂制备方法总质量百分比0.5%、亚硫酸钠占所述除锈剂制备方法总质量百分比1.5%,其他助剂占所述除锈剂制备方法总质量百分比2-15%。
对比现有的切削液:
通过数据可知本法制备的切削液有效降低切削面生锈的发生,配置方便,成本低,无危害,节水,不伤手,清洗过程安全简单,清洗效果好,无腐蚀效果。
实施例2:一种有色金属防锈切削液,
主要包括以下组分制备而成:硫化脂肪酸钠6份,高碳酸钾皂14份,茶叶40份,动物肝脏60份,玉米淀粉60份,防锈油剂70份,酒精110份,环已烷6份,0.5%碳酸钠水溶液6份,钝化液11份,环烷酸锌21份,改性添加剂15份,低级醚10份,清洁剂120份。
一种有色金属防锈切削液制备方法,包括以下步骤制备而成:
取硫化脂肪酸钠加入到500份水内,进行蒸馏,收集蒸馏液;
将动物肝脏放入蒸馏液中,同时添加酒精,点燃,直至酒精燃烧殆尽;
取高碳酸钾皂加入其中,再铺上茶叶,静置3天;
取环已烷浸入防锈油剂中,加热至80~90℃,约30~40min;
将茶叶取出,放入上述加热的混合物中浸泡,然后浸入0.5%碳酸钠水溶液中约5min;
将上述混合物,固液分离,400目过滤,所得滤液倒入由钝化液中,加热至80~90℃,约5~1Omin,得到A组分,备用;
取环烷酸锌、改性添加剂、低级醚加入到玉米淀粉中,用泵将磨好的浆液打入大缸内,加入酸浆,充分搅拌,至pH值为5.2左右,静止30分钟的时;
等待充分沉淀后,再把粉面上的清水倒掉,将大缸内淀粉层撬起并搅匀,然后,把这些浓浆泵入到150-180目的细筛上进行第二次过滤,方法与粗滤相同,把经过第二次过滤的浆水泵入缸内,加入等量的清洁剂,充分搅拌,300℃加热,混合3小时;
然后静置,使淀粉充分沉淀,到450-580目的细筛上进行过滤,得到B组分;
将A组分和B组分混合,加入盐20-30份,搅拌,蒸馏,所得蒸馏液即为产品。
钝化液为50%的10%亚硝酸酸钠水溶液和50%的0.5%碳酸钠水溶液组成。
清洁剂为苯甲酸钠10%,二异丙基萘磺酸钠20%,助剂5%份,硼酸5%,尼泊金甲酯10%,柚子汁50%与90℃加热混合制备所得。
防锈油剂由羟基乙叉二磷酸HEDP、聚丙烯酸PAA、片碱NaOH、苯并三氮唑、亚硫酸钠、水和其他助剂组成,
具体配比为:羟基乙叉二磷酸HEDP占所述除锈剂制备方法总质量百分比25%、聚丙烯酸PAA占所述除锈剂制备方法总质量百分比20%、水占所述除锈剂制备方法总质量百分比47%、片碱NaOH占所述除锈剂制备方法总质量百分比5%、苯并三氮唑占所述除锈剂制备方法总质量百分比0.5%、亚硫酸钠占所述除锈剂制备方法总质量百分比2.5%,其他助剂占所述除锈剂制备方法总质量百分比2-15%。
对比现有的切削液:
通过数据可知本法制备的切削液有效降低切削面生锈的发生,配置方便,成本低,无危害,节水,不伤手,清洗过程安全简单,清洗效果好,无腐蚀效果。
以上显示和描述了本发明的基本原理,主要特征和本发明的优点。本行业的技术人员应该了解,本发明不受上述实施例的限制,上述实施例和说明书中描述的只是说明本发明的原理,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (7)

1.一种有色金属防锈切削液,其特征在于:主要包括以下组分制备而成:硫化脂肪酸钠4-6份,高碳酸钾皂8-14份,茶叶30-40份,动物肝脏50-60份,玉米淀粉40-60份,防锈油剂60-70份,酒精90-110份,环已烷4-6份,0.5%碳酸钠水溶液4-6份,钝化液9-11份,环烷酸锌19-21份,改性添加剂5-15份,低级醚6-10份,清洁剂90-120份。
2.根据权利要求1中所述的一种有色金属防锈切削液,其特征在于:主要包括以下组分制备而成:硫化脂肪酸钠4份,高碳酸钾皂8份,茶叶30份,动物肝脏50份,玉米淀粉40份,防锈油剂60份,酒精90份,环已烷4份,0.5%碳酸钠水溶液4份,钝化液9份,环烷酸锌19份,改性添加剂5份,低级醚6份,清洁剂90份。
3.根据权利要求1中所述的一种有色金属防锈切削液,其特征在于:主要包括以下组分制备而成:硫化脂肪酸钠6份,高碳酸钾皂14份,茶叶40份,动物肝脏60份,玉米淀粉60份,防锈油剂70份,酒精110份,环已烷6份,0.5%碳酸钠水溶液6份,钝化液11份,环烷酸锌21份,改性添加剂15份,低级醚10份,清洁剂120份。
4.根据权利要求1中所述的一种有色金属防锈切削液,其特征在于:所述的钝化液为50%的10%亚硝酸酸钠水溶液和50%的0.5%碳酸钠水溶液组成。
5.根据权利要求1中所述的一种有色金属防锈切削液,其特征在于:所述的清洁剂为苯甲酸钠10%,二异丙基萘磺酸钠20%,助剂5%份,硼酸5%,尼泊金甲酯10%,柚子汁50%与90℃加热混合制备所得。
6.根据权利要求1中所述的一种有色金属防锈切削液,其特征在于:所述的防锈油剂由羟基乙叉二磷酸HEDP、聚丙烯酸PAA、片碱NaOH、苯并三氮唑、亚硫酸钠、水和其他助剂组成,
具体配比为:羟基乙叉二磷酸HEDP占所述除锈剂制备方法总质量百分比20-25%、聚丙烯酸PAA占所述除锈剂制备方法总质量百分比15-20%、水占所述除锈剂制备方法总质量百分比40-60%、片碱NaOH占所述除锈剂制备方法总质量百分比2-5%、苯并三氮唑占所述除锈剂制备方法总质量百分比0.1-0.5%、亚硫酸钠占所述除锈剂制备方法总质量百分比1.5-2.5%,其他助剂占所述除锈剂制备方法总质量百分比2-15%。
7.一种有色金属防锈切削液制备方法,其特征在于:包括以下步骤制备而成:
取硫化脂肪酸钠加入到500份水内,进行蒸馏,收集蒸馏液;
将动物肝脏放入蒸馏液中,同时添加酒精,点燃,直至酒精燃烧殆尽;
取高碳酸钾皂加入其中,再铺上茶叶,静置3天;
取环已烷浸入防锈油剂中,加热至80~90℃,约30~40min;
将茶叶取出,放入上述加热的混合物中浸泡,然后浸入0.5%碳酸钠水溶液中约5min;
将上述混合物,固液分离,400目过滤,所得滤液倒入由钝化液中,加热至80~90℃,约5~1Omin,得到A组分,备用;
取环烷酸锌、改性添加剂、低级醚加入到玉米淀粉中,用泵将磨好的浆液打入大缸内,加入酸浆,充分搅拌,至pH值为5.2左右,静止30分钟的时;
等待充分沉淀后,再把粉面上的清水倒掉,将大缸内淀粉层撬起并搅匀,然后,把这些浓浆泵入到150-180目的细筛上进行第二次过滤,方法与粗滤相同,把经过第二次过滤的浆水泵入缸内,加入等量的清洁剂,充分搅拌,300℃加热,混合3小时;
然后静置,使淀粉充分沉淀,到450-580目的细筛上进行过滤,得到B组分;
将A组分和B组分混合,加入盐20-30份,搅拌,蒸馏,所得蒸馏液即为产品。
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104789324A (zh) * 2015-04-29 2015-07-22 青岛德翕拓创高新技术有限公司 一种有色金属加工切削液
CN105018949A (zh) * 2015-08-06 2015-11-04 潘桂枝 一种适于钢材精密零件的除锈剂及其除锈工艺
CN105755491A (zh) * 2014-12-14 2016-07-13 王欣欣 一种中性除油除锈剂
CN106929873A (zh) * 2017-04-05 2017-07-07 罗碧贤 金属水管内壁除锈剂及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105755491A (zh) * 2014-12-14 2016-07-13 王欣欣 一种中性除油除锈剂
CN104789324A (zh) * 2015-04-29 2015-07-22 青岛德翕拓创高新技术有限公司 一种有色金属加工切削液
CN105018949A (zh) * 2015-08-06 2015-11-04 潘桂枝 一种适于钢材精密零件的除锈剂及其除锈工艺
CN106929873A (zh) * 2017-04-05 2017-07-07 罗碧贤 金属水管内壁除锈剂及其制备方法

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