CN107417249A - A kind of manufacture craft of in-glaze decoration blue and white porcelain - Google Patents

A kind of manufacture craft of in-glaze decoration blue and white porcelain Download PDF

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Publication number
CN107417249A
CN107417249A CN201710349573.9A CN201710349573A CN107417249A CN 107417249 A CN107417249 A CN 107417249A CN 201710349573 A CN201710349573 A CN 201710349573A CN 107417249 A CN107417249 A CN 107417249A
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parts
blue
porcelain
glaze
white
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Inventor
裴仕林
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Anhui Blue And White Fang Ci Industry Limited-Liability Co
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Anhui Blue And White Fang Ci Industry Limited-Liability Co
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Priority to CN201710349573.9A priority Critical patent/CN107417249A/en
Publication of CN107417249A publication Critical patent/CN107417249A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a kind of manufacture craft of in-glaze decoration blue and white porcelain, it is related to field of porcelain fabrication, comprises the following steps:Embryo material is made, and embryo material used is made up of the raw material including following parts by weight:30 50 parts of porcelain stone, 30 50 parts of kaolin, 5 10 parts of calcite, 8 15 parts of camwood knag, 37 parts of calcination of talc;Embryo processed is dried;Glazing is dried, and the raw material that glaze used includes following parts by weight forms:40 60 parts of feldspar, 30 50 parts of quartz, 8 15 parts of calcite, 15 parts of clay, 15 parts of porcelain powder, 15 parts of plant ash;Applique glazing;Loading of kiln is fired, the in-glaze decoration blue and white porcelain unique style produced of the present invention, and into colour-stable, outward appearance moistens the Guang months, and lively soft, exquisiteness is sparkling and crystal-clear, and mechanical resistant polishing machine and corrosion resistance are strong, simple production process, no toxic heavy metal dissolution, safety and environmental protection.

Description

A kind of manufacture craft of in-glaze decoration blue and white porcelain
Technical field
The present invention relates to field of porcelain fabrication, and in particular to a kind of manufacture craft of in-glaze decoration blue and white porcelain.
Background technology
Blue and white porcelain, blue and white porcelain, often referred to as blue and white also known as whitely, is one of main flow kind of Chinese porcelain, belongs to underglaze colour. It is original it is blue and white showed its trace in the Tang and Song Dynasty, having arrived the Yuan Dynasty tends to be ripe, and the Yuan Dynasty is with the development need of domestic and international trade, hard paste porcelain industry There is bigger progress compared with the Song Dynasty, wood-fired kiln famous at that time successfully burns out blue-and-white porcelain, and it makes pole exquisite and handed down from ancient times It is few, so it is abnormal precious.
Since the late Qing Dynasty, with production development and technological progress, start paster printing technology occurred.This technique starts from Japan, it is characterized in that cost is low, work efficiency is fast.Paster printing technology uses a variety of stamp means (such as flat stamping, wire mark, gravure), it Applique on glaze can be divided into, three kinds of applique under applique and glaze in glaze, applique is applique after glazing in glaze, is reglazed after applique, is mesh Preceding domestic porcelain, such as most common trailing on bottle, disk, bowl;Blue and white paster stamp is to be printed on ceramic paint under glaze On fiber tissue paper, this paper is sustained;Applique process is that ceramic paint is printed on film on glaze, and film is attached on ground paper and protected Deposit, this film for being loaded with cobalt material decorative pattern is peeled again when use, be affixed on white glaze porcelain, directly enter baking oven and bake.
Although the work efficiency of paster stamp is high, cost is low, and decorative pattern seems stiff relative to Freehandhand-drawing grain pattern, and translucency is poor, Sometimes it also occur that pattern folds, lacks the phenomenon of color, so also needing to update and replenishment of process, it is blue or green to improve paster stamp The quality of flower porcelain.
The content of the invention
(1) technical problem solved
In view of the shortcomings of the prior art, the invention provides a kind of manufacture craft of in-glaze decoration blue and white porcelain so that produces In-glaze decoration blue and white porcelain unique style, into colour-stable, simple production process, no toxic heavy metal dissolution safety and environmental protection.
(2) technical scheme
To realize object above, the present invention is achieved by the following technical programs:
A kind of manufacture craft of in-glaze decoration blue and white porcelain, comprises the following steps:
(1) embryo material makes:The raw material that embryo material used includes following parts by weight forms:Porcelain stone 30-50 parts, kaolin 30-50 Part, calcite 5-10 parts, camwood knag 8-15 parts, calcination of talc 3-7 parts, by above-mentioned raw materials grinding and sieving, clear water is added to stir 5- 30-50d is standing and soak for after 10h, takes the raw material centrifugal dehydration after precipitation, after room temperature is dried, then it is i.e. available by vacuum pugging The embryo material;
(2) embryo processed is dried:Idiosome is made in embryo material, after trimmed, in the environment of humidity 25-40%, 20-30 DEG C of temperature It is standby after naturally dry;
(3) glazing is dried:The raw material that glaze used includes following parts by weight forms:Feldspar 40-60 parts, quartzy 30-50 parts, Calcite 8-15 parts, clay 1-5 parts, porcelain powder 1-5 parts, plant ash 1-5 parts, by idiosome with the glaze glazing, obtained after drying Blue and white porcelain enamel germ;
(4) applique glazing:Binding agent is coated at blue and white porcelain enamel germ, blue and white marble paper is sticked with secondary color roasting decal method Afterwards, then with the glaze glazing, blue and white porcelain idiosome is obtained;
(5) loading of kiln is fired:Blue and white porcelain idiosome is put into kiln, after 1260-1280 DEG C is fired 5-10h, naturally cools to room Temperature, you can obtain the in-glaze decoration blue and white porcelain.
Preferably, it is 50-70 to cross sieve mesh number in the step (1).
Preferably, the rotating speed of centrifuge is 1000-3000r/min when being centrifuged in the step (1).
Preferably, drying temperature is 700-900 DEG C in the step (3).
Preferably, binding agent used is phenolic aldehyde system binding agent in the step (4).
Preferably, blue and white marble paper used is the blue and white marble paper of butyral film in the step (4).
(3) beneficial effect
The invention provides a kind of manufacture craft of in-glaze decoration blue and white porcelain, there is advantages below:
(1) glaze of the present invention adds porcelain powder on the basis of feldspar-calcite, improves hardness of glaze surface, reduces high temperature and glues Degree, the anti-wear performance of blue and white porcelain can not only be improved by adding plant ash, and can lift glaze paint color and luster and texture.
(2) by testing repeatedly, selected embryo material composition, traditional handicraft is combined with modern technologies, made embryo material Walk particle is homogeneous, and internal stress is released after centrifugation, and the tire matter surface obtained after firing is smooth, rich in moist gloss Texture.
(3) present invention softening melting of product glaze paint, oozes the granules of pigments on blue and white marble paper under conditions of high temperature rapid firing Enter in glaze, glaze face closure, pattern are just immersed in glaze after cooling, and outward appearance moistens the Guang months, lively soft, fine and smooth sparkling and crystal-clear, are quite had The effect of underglaze colour.Mechanical resistant polishing machine and corrosion resistance are strong, and more outer layer glaze wraps up granules of pigments simultaneously, also thoroughly solve Determine the harm of ware heavy metal.
(4) technique is simple, and production cost is low, is adapted to large-scale production.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one Divide embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making The every other embodiment obtained under the premise of creative work, belongs to the scope of protection of the invention.
Embodiment 1:
A kind of manufacture craft of in-glaze decoration blue and white porcelain, comprises the following steps:
(1) embryo material makes:The raw material that embryo material used includes following parts by weight forms:35 parts of porcelain stone, 40 parts of kaolin, Fang Xie 8 parts of stone, 10 parts of camwood knag, 5 parts of calcination of talc, 65 mesh sieves are crossed after above-mentioned raw materials are crushed, be standing and soak for after adding clear water stirring 8h 45d, the raw material centrifugal dehydration after precipitation is taken, centrifuge speed 2500r/min, after room temperature is dried, then by vacuum pugging is It can obtain the embryo material;
(2) embryo processed is dried:Idiosome is made in embryo material, after trimmed, is dried in the air naturally in the environment of humidity 30%, 27 DEG C of temperature It is standby after dry;
(3) glazing is dried:The raw material that glaze used includes following parts by weight forms:50 parts of feldspar, quartzy 40 parts, calcite 10 parts, 3 parts of clay, 1 part of porcelain powder, 3 parts of plant ash, by idiosome with the glaze glazing, blue and white porcelain enamel germ is obtained after drying, is dried Temperature is 800 DEG C;
(4) applique glazing:Phenolic aldehyde system binding agent is coated at blue and white porcelain enamel germ, contracting fourth is sticked with secondary color roasting decal method After the blue and white marble paper of aldehyde film, then with the glaze glazing, blue and white porcelain idiosome is obtained;
(5) loading of kiln is fired:Blue and white porcelain idiosome is put into kiln, after 1260 DEG C are fired 7h, naturally cools to room temperature, you can To the in-glaze decoration blue and white porcelain.
Embodiment 2:
(1) embryo material makes:The raw material that embryo material used includes following parts by weight forms:30 parts of porcelain stone, 30 parts of kaolin, Fang Xie 5 parts of stone, 8 parts of camwood knag, 7 parts of calcination of talc, 50 mesh sieves are crossed after above-mentioned raw materials are crushed, be standing and soak for after adding clear water stirring 6h 50d, the raw material centrifugal dehydration after precipitation is taken, centrifuge speed 3000r/min, after room temperature is dried, then by vacuum pugging is It can obtain the embryo material;
(2) embryo processed is dried:Idiosome is made in embryo material, after trimmed, is dried in the air naturally in the environment of humidity 25%, 20 DEG C of temperature It is standby after dry;
(3) glazing is dried:The raw material that glaze used includes following parts by weight forms:40 parts of feldspar, quartzy 50 parts, calcite 15 parts, 5 parts of clay, 1 part of porcelain powder, 3 parts of plant ash, by idiosome with the glaze glazing, blue and white porcelain enamel germ is obtained after drying, is dried Temperature is 850 DEG C;
(4) applique glazing:Phenolic aldehyde system binding agent is coated at blue and white porcelain enamel germ, contracting fourth is sticked with secondary color roasting decal method After the blue and white marble paper of aldehyde film, then with the glaze glazing, blue and white porcelain idiosome is obtained;
(5) loading of kiln is fired:Blue and white porcelain idiosome is put into kiln, after 1260 DEG C are fired 10h, naturally cools to room temperature, you can Obtain the in-glaze decoration blue and white porcelain.
Embodiment 3:
(1) embryo material makes:The raw material that embryo material used includes following parts by weight forms:50 parts of porcelain stone, 50 parts of kaolin, Fang Xie 10 parts of stone, 15 parts of camwood knag, 7 parts of calcination of talc, 70 mesh sieves are crossed after above-mentioned raw materials are crushed, be standing and soak for after adding clear water stirring 5h 30d, the raw material centrifugal dehydration after precipitation is taken, centrifuge speed 3000r/min, after room temperature is dried, then by vacuum pugging is It can obtain the embryo material;
(2) embryo processed is dried:Idiosome is made in embryo material, after trimmed, is dried in the air naturally in the environment of humidity 35%, 30 DEG C of temperature It is standby after dry;
(3) glazing is dried:The raw material that glaze used includes following parts by weight forms:40 parts of feldspar, quartzy 50 parts, calcite 15 parts, 5 parts of clay, 5 parts of porcelain powder, 5 parts of plant ash, by idiosome with the glaze glazing, blue and white porcelain enamel germ is obtained after drying, is dried Temperature is 900 DEG C;
(4) applique glazing:Phenolic aldehyde system binding agent is coated at blue and white porcelain enamel germ, contracting fourth is sticked with secondary color roasting decal method After the blue and white marble paper of aldehyde film, then with the glaze glazing, blue and white porcelain idiosome is obtained;
(5) loading of kiln is fired:Blue and white porcelain idiosome is put into kiln, after 1280 DEG C are fired 5h, naturally cools to room temperature, you can To the in-glaze decoration blue and white porcelain.
Embodiment 4:
(1) embryo material makes:The raw material that embryo material used includes following parts by weight forms:40 parts of porcelain stone, 35 parts of kaolin, Fang Xie 7 parts of stone, 12 parts of camwood knag, 3 parts of calcination of talc, 60 mesh sieves are crossed after above-mentioned raw materials are crushed, be standing and soak for after adding clear water stirring 10h 35d, the raw material centrifugal dehydration after precipitation is taken, centrifuge speed 1000r/min, after room temperature is dried, then by vacuum pugging is It can obtain the embryo material;
(2) embryo processed is dried:Idiosome is made in embryo material, after trimmed, is dried in the air naturally in the environment of humidity 40%, 25 DEG C of temperature It is standby after dry;
(3) glazing is dried:The raw material that glaze used includes following parts by weight forms:60 parts of feldspar, quartzy 30 parts, calcite 8 parts, 1 part of clay, 1 part of porcelain powder, 1 part of plant ash, by idiosome with the glaze glazing, blue and white porcelain enamel germ is obtained after drying, is dried Temperature is 700 DEG C;
(4) applique glazing:Phenolic aldehyde system binding agent is coated at blue and white porcelain enamel germ, contracting fourth is sticked with secondary color roasting decal method After the blue and white marble paper of aldehyde film, then with the glaze glazing, blue and white porcelain idiosome is obtained;
(5) loading of kiln is fired:Blue and white porcelain idiosome is put into kiln, after 1270 DEG C are fired 7h, naturally cools to room temperature, you can To the in-glaze decoration blue and white porcelain.
Embodiment 5:
(1) embryo material makes:The raw material that embryo material used includes following parts by weight forms:35 parts of porcelain stone, 50 parts of kaolin, Fang Xie 10 parts of stone, 15 parts of camwood knag, 3 parts of calcination of talc, 50 mesh sieves are crossed after above-mentioned raw materials are crushed, leaching is stood after adding clear water stirring 10h 45d is steeped, takes the raw material centrifugal dehydration after precipitation, centrifuge speed 3000r/min, after room temperature is dried, then by vacuum pugging It can obtain the embryo material;
(2) embryo processed is dried:Idiosome is made in embryo material, after trimmed, is dried in the air naturally in the environment of humidity 40%, 30 DEG C of temperature It is standby after dry;
(3) glazing is dried:The raw material that glaze used includes following parts by weight forms:60 parts of feldspar, quartzy 30 parts, calcite 15 parts, 1 part of clay, 5 parts of porcelain powder, 5 parts of plant ash, by idiosome with the glaze glazing, blue and white porcelain enamel germ is obtained after drying, is dried Temperature is 850 DEG C;
(4) applique glazing:Phenolic aldehyde system binding agent is coated at blue and white porcelain enamel germ, contracting fourth is sticked with secondary color roasting decal method After the blue and white marble paper of aldehyde film, then with the glaze glazing, blue and white porcelain idiosome is obtained;
(5) loading of kiln is fired:Blue and white porcelain idiosome is put into kiln, after 1280 DEG C are fired 10h, naturally cools to room temperature, you can Obtain the in-glaze decoration blue and white porcelain.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality Body or operation make a distinction with another entity or operation, and not necessarily require or imply and deposited between these entities or operation In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to Nonexcludability includes, so that process, method, article or equipment including a series of elements not only will including those Element, but also the other element including being not expressly set out, or it is this process, method, article or equipment also to include Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that Other identical element also be present in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (6)

1. a kind of manufacture craft of in-glaze decoration blue and white porcelain, it is characterised in that comprise the following steps:
(1) embryo material makes:The raw material that embryo material used includes following parts by weight forms:Porcelain stone 30-50 parts, kaolin 30-50 parts, side Stone 5-10 parts, camwood knag 8-15 parts, calcination of talc 3-7 parts are solved, by above-mentioned raw materials grinding and sieving, after adding clear water stirring 5-10h Be standing and soak for 30-50d, take precipitation after raw material centrifugal dehydration, after room temperature is dried, then by vacuum pugging i.e. can obtain the embryo Material;
(2) embryo processed is dried:Idiosome is made in embryo material, it is natural in the environment of humidity 25-40%, 20-30 DEG C of temperature after trimmed Dry rear standby;
(3) glazing is dried:The raw material that glaze used includes following parts by weight forms:Feldspar 40-60 parts, quartzy 30-50 parts, Fang Xie Stone 8-15 parts, clay 1-5 parts, porcelain powder 1-5 parts, plant ash 1-5 parts, by idiosome with the glaze glazing, obtained after drying blue and white Enamel embryo;
(4) applique glazing:Binding agent is coated at blue and white porcelain enamel germ, after sticking blue and white marble paper with secondary color roasting decal method, then With the glaze glazing, blue and white porcelain idiosome is obtained;
(5) loading of kiln is fired:Blue and white porcelain idiosome is put into kiln, after 1260-1280 DEG C is fired 5-10h, naturally cools to room temperature, i.e., It can obtain the in-glaze decoration blue and white porcelain.
2. the manufacture craft of in-glaze decoration blue and white porcelain as claimed in claim 1, it is characterised in that sieved in the step (1) Mesh number is 50-70.
3. the manufacture craft of in-glaze decoration blue and white porcelain as claimed in claim 1, it is characterised in that when being centrifuged in the step (1) The rotating speed of centrifuge is 1000-3000r/min.
4. the manufacture craft of in-glaze decoration blue and white porcelain as claimed in claim 1, it is characterised in that temperature is dried in the step (3) Spend for 700-900 DEG C.
5. the manufacture craft of in-glaze decoration blue and white porcelain as claimed in claim 1, it is characterised in that used viscous in the step (4) Knot agent is phenolic aldehyde system binding agent.
6. the manufacture craft of in-glaze decoration blue and white porcelain as claimed in claim 1, it is characterised in that green grass or young crops used in the step (4) Flower marble paper is the blue and white marble paper of butyral film.
CN201710349573.9A 2017-05-17 2017-05-17 A kind of manufacture craft of in-glaze decoration blue and white porcelain Pending CN107417249A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109516834A (en) * 2018-11-12 2019-03-26 苏州工业园区职业技术学院 A kind of wear-resistant and soda acid ceramic decoration method
CN113292359A (en) * 2021-06-18 2021-08-24 景德镇陶瓷大学 Antique blue and white material, preparation method thereof and antique blue and white porcelain comprising antique blue and white material
CN114907148A (en) * 2022-05-23 2022-08-16 孙赛华 Formula and processing method of over-glaze blue and white pigment
CN115677222A (en) * 2022-11-02 2023-02-03 福建省德化龙峰陶瓷有限公司 Antistatic antibacterial ceramic glaze and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109516834A (en) * 2018-11-12 2019-03-26 苏州工业园区职业技术学院 A kind of wear-resistant and soda acid ceramic decoration method
CN113292359A (en) * 2021-06-18 2021-08-24 景德镇陶瓷大学 Antique blue and white material, preparation method thereof and antique blue and white porcelain comprising antique blue and white material
CN114907148A (en) * 2022-05-23 2022-08-16 孙赛华 Formula and processing method of over-glaze blue and white pigment
CN115677222A (en) * 2022-11-02 2023-02-03 福建省德化龙峰陶瓷有限公司 Antistatic antibacterial ceramic glaze and manufacturing method thereof

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Application publication date: 20171201