CN105819690B - The preparation method of colour enamels porcelain in a kind of glaze - Google Patents
The preparation method of colour enamels porcelain in a kind of glaze Download PDFInfo
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- CN105819690B CN105819690B CN201610162838.XA CN201610162838A CN105819690B CN 105819690 B CN105819690 B CN 105819690B CN 201610162838 A CN201610162838 A CN 201610162838A CN 105819690 B CN105819690 B CN 105819690B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
The present invention relates to a kind of preparation methods of colour enamels porcelain in glaze, it is spare first to prepare crystalline ceramics glaze, it is made further according to selected type, examination patch radian version marble paper, decoration flower face, colour enamels decorative position picture making and the output of the respective film, then decoration flower face pattern halftone is made, colour enamels decorates halftone, using decoration flower face pattern halftone, face pattern is spent in printed decoration on water transfer base stock, colour enamels decorative layer is printed on the pattern of decoration flower face using colour enamels decoration halftone to cover on decoration flower face pattern and colour enamels decorative layer using cover oil, decal paper for ceramic ware is made, decal paper for ceramic ware is attached on porcelain, and it is dried, porcelain is finally put into color roasting in decoration firing kiln, to obtain the final product.The colour enamels colorant and white ceramic glaze of porcelain of the present invention can combine well, do not occur to shell glaze and glaze splits phenomenon, colour enamels colorant prevents the heavy metal in colorant to be precipitated, can be used as the domestic ceramics contacted with food in glaze.
Description
Technical field
The present invention relates to a kind of preparation methods of colour enamels porcelain in glaze, belong to the manufacture technology field of porcelain.
Background technology
Colour enamels is one of ware decoration technique, is derived from painted enamel skill and technique.Use the porcelain of colour enamels decoration technique
It is often simply called colour enamels.Colour enamels has drawn the skill and technique of copper painted enamel, on the tire of porcelain, with the description of various enamel color materials
At a kind of new overglaze color porcelain.Colour enamels has long history, is referred to as the enamel of " faience queen " " government porcelain kiln in government porcelain kiln "
Faience, although it has, porcelain is fine and smooth, color material is dignified, lovely luster is beautiful, painter is exquisite, there is the features such as embossment texture on surface,
But its current manufacture craft still continues to use the artificial Freehandhand-drawing technique of traditional low temperature overglaze color, and the low temperature glaze in the technique is enameled pool
It is bright-coloured, the heavy metal of the easy precipitation such as lead, cadmium is added in colorant, therefore cannot act as the dress of the domestic ceramics contacted with food
Decorations.
Invention content
Present invention aim to address the domestic ceramicses that low temperature overglaze color may not apply to contact with food in the prior art
Deficiency, provide a kind of preparation method of colour enamels porcelain in glaze, colour enamels porcelain can serve as contacting with food in glaze obtained
Domestic ceramics, and porcelain porcelain is bright in colour, picture embossment sense is apparent.
Technical solution
Colour enamels is different from traditional colour enamels in glaze, is to add one layer on the colorant of pattern again on former white ceramic glaze thoroughly
Bright glaze, pattern color also can completely be shown, and the colour for being present in glaze is known as in-glaze decoration, in addition transparent glaze layer is passing through
Surface bulge is generated after crossing 820~880 DEG C of heating, has the essential characteristic of colour enamels picture embossment texture, with this technology
Enamel color ceramic membranelle marble paper is made, is attached on Bone China after 820~880 DEG C of decoration firings, the colour enamels china color and luster of production is fresh
Gorgeous, picture embossment sense is obviously, it can be achieved that the industrialized mass production of enamel color ceramic.Specific technical solution is as follows：
The preparation method of colour enamels porcelain, includes the following steps in a kind of glaze：
(1) crystalline ceramics glaze is prepared：Fineness is taken to be not more than 25~34 parts of the feldspar powder of 325 mesh, fineness is not more than 325
18~28.5 parts of purpose silica flour, fineness are not more than the calcite in powder of 250 mesh no more than 8~15 parts of the talcum powder of 250 mesh, fineness
12~18.5 parts, 1~7 part of zinc oxide, 6~12 parts of strontium carbonate, 5~12 parts of boric acid, 3~8 parts of potassium nitrate, it is high again after mixing
Temperature melting, be then placed in quenching in water and frit be made, frit is crushed, be made fineness no more than 250 targeted fine powders it is spare, it is above-mentioned
Number is parts by weight；
(2) it is made according to selected type, examination patch radian version marble paper, decoration flower face, colour enamels decorative position picture making
And respectively film output；
(3) decoration flower face pattern halftone is made, colour enamels decorates halftone；
(4) pattern halftone printed decoration on water transfer base stock in decoration flower face is used to spend face pattern；
(5) the crystalline ceramics glaze of step (1) is mixed with varnish by 10: 6.5-8 weight ratio convex as colour enamels
Layer pigment prints colour enamels decorative layer using colour enamels decoration halftone on the pattern of decoration flower face；
(6) it is covered on the decoration flower face pattern of step (4) and the colour enamels decorative layer of step (5), is made using cover oil
At decal paper for ceramic ware, decal paper for ceramic ware is attached on porcelain, and is dried；
(7) porcelain is put into decoration firing kiln color roasting to get colour enamels porcelain in glaze.
Colour enamels decoration halftone in step (3) is prepared as follows：
A. screen frame is tilted 70-80 ° of placement, printing faces outwardly, and is first coated with 3 photosensitive pastes in printing surface, then scrapes falling
Face is coated with 2 photosensitive pastes, and halftone is put into drying box and is dried；
B. after photosensitive paste drying, then in printing surface 3 photosensitive pastes of coating, shaving 1 photosensitive paste of coating then is being fallen, is being put
Enter in drying box and dries；
C. step b is repeated totally 4 times.
Further, in step (3), decoration flower face pattern halftone shines system, colour enamels decoration website using the grenadine of 200 mesh
Version shines system using the grenadine of 120 mesh, and grenadine used is polyester grenadine, such as the Smart grenadine of Japan's production, makes net
Used photosensitive paste is 6000B oiliness photosensitive pastes in Japanese village when version.
Further, in step (4), the 14 serial nothings that pigment used in the pattern of face is produced by Fu Lu companies are spent in printed decoration
Lead ceramic paint and varnish 80820 are allocated according to 10: 6.5-8 weight ratio.
Further, in step (5), the method for colour enamels decorative layer is printed on the pattern of decoration flower face is：First by colour enamels
Convex layer pigment is printed onto on the pattern of decoration flower face, the natural air drying at 20-35 DEG C, then repeats convex layer of colour enamels of printing
Pigment, the natural air drying at 20-35 DEG C.Further, in step (6), the cover oil is the envelope of German Heraeus Inc.'s production
Face oil Y406.
Further, in step (7), color roasting temperature is 820~880 DEG C, time 2.5-4h.
Advantageous effect：
In the glaze of the present invention in the preparation process of colour enamels porcelain, on marble paper pattern plus layer of transparent glaze has been printed, it should
Clear frit is naturally raised after decoration firing, produces the artistic effect as embossment, and can be fine with colour enamels colorant and white ceramic glaze
Ground combines, and does not occur to shell glaze and glaze splits phenomenon；The colour enamels colorant of colour enamels porcelain prevents the weight in colorant in glaze in glaze
Metal is precipitated, and the ceramic product of production disclosure satisfy that the technology requirement of domestic ceramics, the technical indicator that product reaches are water absorption rate
Less than 0.5%, 180 DEG C to 20 DEG C hydrothermal exchanges of thermal shock resistance are not split once, and lead release is less than 0.5mg/L, and quantity of cadmium release is small
In 0.1mg/L.
Specific implementation mode
The present invention is further explained in the light of specific embodiments.
Explanation：In following embodiments, the feldspar powder used is the Pingjiang River feldspar powder of 325 mesh of fineness；Silica flour is fineness 325
Purpose Fengyang silica flour；Talcum powder is that talcum powder is produced in Haicheng City of 250 mesh of fineness；Calcite in powder is that the Xuancheng side of 250 mesh of fineness solves
Mountain flour；Grenadine used is the Smart grenadine of Japan's production when making halftone, and photosensitive paste is that 6000B oiliness is photosensitive in Japanese village
Slurry；Varnish is the varnish 80820 of Fu Lu companies production；Cover oil is the cover oil Y406 of German Heraeus Inc.；Printing
The 14 series leadless ceramic paints and varnish 80820 that pigment used in the pattern of decoration flower face is produced by Fu Lu companies according to
10: 6.5-8 weight ratio is allocated；The convex layer pigment of colour enamels presses 10: 6.5-8 by crystalline ceramics glaze and varnish 80820
Weight ratio mix.
Embodiment 1
Prepare crystalline ceramics glaze：Take 28 parts of feldspar powder, 22 parts of silica flour, 11 parts of talcum powder, 14 parts of calcite in powder, oxidation
3 parts of zinc, 8 parts of strontium carbonate, 7 parts of boric acid, 5 parts of potassium nitrate be uniformly mixed after after 1400 DEG C of meltings into the water quenching be made it is molten
Block, frit is fitted into bobbing machine mill, water, high alumina ballstone are added, and frit is ground into the glaze slip that fineness is more than 325 mesh, crosses 250
Mesh sieves, and is then dried through 80~110 DEG C, and powder is made and crosses 250 mesh sieve.
It is made according to selected type, examination patch radian version marble paper, after selected type radian, size are suitable, decoration flower face, enamel
Thinkling sound's color equipment adorns position picture making and the output of the respective film；Make decoration flower face pattern halftone, colour enamels decorates halftone, decoration flower
Face pattern halftone shines system using the grenadine of 200 mesh, and colour enamels decorates halftone and shines system, enamel using the grenadine of 120 mesh
Color equipment decorations halftone is prepared as follows：A. screen frame is tilted 70-80 ° of placement, printing faces outwardly, and is first coated with 3 in printing surface
Then secondary photosensitive paste is falling shaving 2 photosensitive pastes of coating, halftone is put into drying box and is dried；B. after photosensitive paste drying, then
3 photosensitive pastes are coated in printing surface, then shaving 1 photosensitive paste of coating is being fallen, is being put into drying box and dries；C. step b is repeated
Totally 4 times.
The convex layer pigment of pigment colour enamels used in colour enamels is toasted into 15min at a temperature of 110 DEG C in oven, dries its water
Part；Using decoration flower face pattern halftone, face pattern is spent in printed decoration on water transfer base stock, is being filled using colour enamels decoration halftone
Colour enamels decorative layer is printed on the pattern of decoration face, the method for colour enamels decorative layer is printed on the pattern of decoration flower face is：First by enamel
The color convex layer pigment of thinkling sound is printed onto on the pattern of decoration flower face, and natural wind is dried at 25 DEG C, then repeats colour enamels of printing
Convex layer pigment, natural wind is dried at 25 DEG C.It is covered on above-mentioned decoration flower face pattern and colour enamels decorative layer using cover oil,
Decal paper for ceramic ware is made.
Certified decal paper for ceramic ware is cut, redundance is cut off, the marble paper sheared is put into and fills clear water
Basin in impregnated, impregnate 2 to 3min after take out, be put into vessel and prepare applique, product is put into clean hot water into
Row cleaning；Soaked marble paper is attached on ceramic product, positive position is put, marble paper is struck off with Cowhells scraping article, it cannot there are gas
Steep in marble paper in the following, with cloth by product and marble paper surface water and rubber erasers it is clean, will stick colored ceramic product enter it is roasting
Flower kiln decoration firing, 860 DEG C of color roasting 3h to get.
Embodiment 2
Prepare crystalline ceramics glaze：Take 30 parts of feldspar powder, 24 parts of silica flour, 8 parts of talcum powder, 16 parts of calcite in powder, oxidation
5 parts of zinc, 10 parts of strontium carbonate, 6 parts of boric acid, 3 parts of potassium nitrate be uniformly mixed after after 1450 DEG C of meltings into the water quenching be made it is molten
Block, frit is fitted into bobbing machine mill, water, high alumina ballstone are added, and frit is ground into the glaze slip that fineness is more than 325 mesh, crosses 250
Mesh sieves, and is then dried through 80~110 DEG C, and powder is made and crosses 250 mesh sieve.
It is made according to selected type, examination patch radian version marble paper, after selected type radian, size are suitable, decoration flower face, enamel
Thinkling sound's color equipment adorns position picture making and the output of the respective film；Make decoration flower face pattern halftone, colour enamels decorates halftone, decoration flower
Face pattern halftone shines system using the grenadine of 200 mesh, and colour enamels decorates halftone and shines system, enamel using the grenadine of 120 mesh
Color equipment decorations halftone is prepared as follows：A. screen frame is tilted 70-80 ° of placement, printing faces outwardly, and is first coated with 3 in printing surface
Then secondary photosensitive paste is falling shaving 2 photosensitive pastes of coating, halftone is put into drying box and is dried；B. after photosensitive paste drying, then
3 photosensitive pastes are coated in printing surface, then shaving 1 photosensitive paste of coating is being fallen, is being put into drying box and dries；C. step b is repeated
Totally 4 times.
Pigment used in colour enamels and the convex layer pigment of colour enamels are toasted at a temperature of 115 DEG C at 120 DEG C in oven
15min dries its moisture content；Using decoration flower face pattern halftone, face pattern is spent in printed decoration on water transfer base stock, using enamel
Color equipment decorations halftone prints colour enamels decorative layer on the pattern of decoration flower face, and colour enamels decorative layer is printed on the pattern of decoration flower face
Method is：First the convex layer pigment of colour enamels is printed onto on the pattern of decoration flower face, natural wind is dried at 26 DEG C, then repeats print
A convex layer pigment of colour enamels is brushed, natural wind is dried at 26 DEG C.Above-mentioned decoration flower face pattern and enamel are covered using cover oil
In thinkling sound's coloured silk decorative layer, decal paper for ceramic ware is made.
Certified decal paper for ceramic ware is cut, redundance is cut off, the marble paper sheared is put into and fills clear water
Basin in impregnated, impregnate 2 to 3min after take out, be put into vessel and prepare applique, product is put into clean hot water into
Row cleaning；Soaked marble paper is attached on ceramic product, positive position is put, marble paper is struck off with Cowhells scraping article, it cannot there are gas
Steep in marble paper in the following, with cloth by product and marble paper surface water and rubber erasers it is clean, will stick colored ceramic product enter it is roasting
Flower kiln decoration firing, 840 DEG C of color roasting 3h to get.
Embodiment 3
Prepare crystalline ceramics glaze：Take 34 parts of feldspar powder, 20 parts of silica flour, 12 parts of talcum powder, 15 parts of calcite in powder, oxidation
1 part of zinc, 10 parts of strontium carbonate, 9 parts of boric acid, 7 parts of potassium nitrate be uniformly mixed after after 1450 DEG C of meltings into the water quenching be made it is molten
Block, frit is fitted into bobbing machine mill, water, high alumina ballstone are added, and frit is ground into the glaze slip that fineness is more than 325 mesh, crosses 250
Mesh sieves, and is then dried through 80~110 DEG C, and powder is made and crosses 250 mesh sieve.
It is made according to selected type, examination patch radian version marble paper, after selected type radian, size are suitable, decoration flower face, enamel
Thinkling sound's color equipment adorns position picture making and the output of the respective film；Make decoration flower face pattern halftone, colour enamels decorates halftone, decoration flower
Face pattern halftone shines system using the grenadine of 200 mesh, and colour enamels decorates halftone and shines system, enamel using the grenadine of 120 mesh
Color equipment decorations halftone is prepared as follows：A. screen frame is tilted 70-80 ° of placement, printing faces outwardly, and is first coated with 3 in printing surface
Then secondary photosensitive paste is falling shaving 2 photosensitive pastes of coating, halftone is put into drying box and is dried；B. after photosensitive paste drying, then
3 photosensitive pastes are coated in printing surface, then shaving 1 photosensitive paste of coating is being fallen, is being put into drying box and dries；C. step b is repeated
Totally 4 times.
Pigment used in colour enamels and the convex layer pigment of colour enamels are toasted into 15min at a temperature of 120 DEG C in oven, dried
Its moisture content；Using decoration flower face pattern halftone, face pattern is spent in printed decoration on water transfer base stock, and halftone is decorated using colour enamels
Colour enamels decorative layer is printed on the pattern of decoration flower face, the method for colour enamels decorative layer is printed on the pattern of decoration flower face is：First
The convex layer pigment of colour enamels is printed onto on the pattern of decoration flower face, natural wind is dried at 30 DEG C, then repeats enamel of printing
The color convex layer pigment of thinkling sound, natural wind is dried at 30 DEG C.Above-mentioned decoration flower face pattern and colour enamels decoration are covered using cover oil
On layer, decal paper for ceramic ware is made.
Certified decal paper for ceramic ware is cut, redundance is cut off, the marble paper sheared is put into and fills clear water
Basin in impregnated, impregnate 2 to 3min after take out, be put into vessel and prepare applique, product is put into clean hot water into
Row cleaning；Soaked marble paper is attached on ceramic product, positive position is put, marble paper is struck off with Cowhells scraping article, it cannot there are gas
Steep in marble paper in the following, with cloth by product and marble paper surface water and rubber erasers it is clean, will stick colored ceramic product enter it is roasting
Flower kiln decoration firing, 830 DEG C of color roasting 4h to get.
Performance test
10 sets of tableware, including 10 inch square positions, 12 inch fish disks are respectively made by embodiment 1-3 implementations, 8.5 inch are flat
Disk, 9 inch soup bowls, 5-8 inch bowl, 12 ounces of cups carry out water absorption rate, thermal shock resistance and lead-indium alloy test, wherein absorbing water respectively
The test method of rate refers to GB/T3299-1996《Domestic ceramics water absorption rate measures legislation》, the test method reference of thermal shock resistance
GB/T3298-2008《Domestic ceramics protests that thermal shock resistance measures legislation》, Lead and cadmium weight testing method is with reference to GB/T3534-
2002《Domestic ceramics lead-indium alloy measures legislation》.
Test result see the table below：
。
Claims (4)
1. the preparation method of colour enamels porcelain in a kind of glaze, which is characterized in that include the following steps：
(1) crystalline ceramics glaze is prepared：Fineness is taken to be not more than 25~34 parts of the feldspar powder of 325 mesh, fineness is not more than the stone of 325 mesh
18~28.5 parts of English powder, fineness no more than 8~15 parts of the talcum powder of 250 mesh, fineness no more than 250 mesh calcite in powder 12~
18.5 parts, 1~7 part of zinc oxide, 6~12 parts of strontium carbonate, 5~12 parts of boric acid, 3~8 parts of potassium nitrate, high temperature melting again after mixing
Melt, be then placed in quenching in water and frit is made, frit is crushed, be made fineness no more than 250 targeted fine powders it is spare, above-mentioned number
It is parts by weight；
(2) it is made according to selected type, examination patch radian version marble paper, decoration flower face, colour enamels decorative position picture making and each
It is exported from the film；
(3) decoration flower face pattern halftone is made, colour enamels decorates halftone；
(4) pattern halftone printed decoration on water transfer base stock in decoration flower face is used to spend face pattern；
(5) the crystalline ceramics glaze of step (1) is mixed with varnish by 10: 6.5-8 weight ratio and is used as the convex layer face of colour enamels
Material prints colour enamels decorative layer using colour enamels decoration halftone on the pattern of decoration flower face；
(6) it is covered on the decoration flower face pattern of step (4) and the colour enamels decorative layer of step (5) using cover oil, pottery is made
Porcelain decal paper, decal paper for ceramic ware is attached on porcelain, and is dried；
(7) porcelain is put into decoration firing kiln color roasting to get colour enamels porcelain in glaze；
In step (3), decoration flower face pattern halftone using 200 mesh grenadine shine system, colour enamels decorate halftone using
The grenadine of 120 mesh shines system, and grenadine used is polyester grenadine；
In step (4), the 14 series leadless ceramic paints that pigment is produced by Fu Lu companies used in the pattern of face are spent in printed decoration
It is allocated according to 10: 6.5-8 weight ratio with varnish 80820；
In step (6), the cover oil is the cover oil Y406 of German Heraeus Inc.'s production.
2. the preparation method of colour enamels porcelain in glaze as described in claim 1, which is characterized in that the colour enamels in step (3)
Decoration halftone is prepared as follows：
A. screen frame is tilted 70-80 ° of placement, printing faces outwardly, and is first coated with 3 photosensitive pastes in printing surface, is then falling shaving painting
2 photosensitive pastes of cloth, halftone are put into drying box and are dried；
B. after photosensitive paste drying, then in printing surface 3 photosensitive pastes of coating, shaving 1 photosensitive paste of coating then is being fallen, is being put into baking
It is dried in dry case；
C. step b is repeated totally 4 times.
3. the preparation method of colour enamels porcelain in glaze as described in claim 1, which is characterized in that in step (5), in decoration flower
The method of colour enamels decorative layer is printed on the pattern of face is：First the convex layer pigment of colour enamels is printed onto on the pattern of decoration flower face, in 20-
Then natural air drying at 35 DEG C repeats convex layer pigment of colour enamels of printing, the natural air drying at 20-35 DEG C.
4. the preparation method of colour enamels porcelain in glaze as described in any one of claims 1 to 3, which is characterized in that step (7)
In, color roasting temperature is 820~880 DEG C, time 2.5-4h.
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106277787B (en) * | 2016-08-23 | 2018-11-30 | 宜兴市方卫明均陶艺术研究所 | A kind of anticracking colour enamels and preparation method thereof |
| CN107162424B (en) * | 2017-07-03 | 2019-01-29 | 福建德化五洲陶瓷股份有限公司 | Ceramic whiteware high-performance glaze and preparation method thereof |
| CN108178517A (en) * | 2018-02-07 | 2018-06-19 | 山西巨彩昇宇文化传媒股份有限公司 | A kind of thread weaving enamel glaze |
| CN108546081B (en) * | 2018-04-27 | 2021-05-14 | 孙劲松 | Firing method of porcelain body painting enamel |
| CN111254751B (en) * | 2020-02-24 | 2024-04-02 | 惠达卫浴股份有限公司 | Ceramic water transfer printing label paper and manufacturing method thereof |
| CN112552069B (en) * | 2020-12-17 | 2022-06-07 | 唐山福来瓷科技有限公司 | Production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional code or one-dimensional code |
| CN113547869B (en) * | 2021-08-04 | 2022-10-04 | 德化县新佳兴印刷有限公司 | In-glaze color paper and preparation method thereof |
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| CN102602216A (en) * | 2012-03-09 | 2012-07-25 | 斯达高瓷艺发展（深圳）有限公司 | Method for manufacturing enamel painted porcelain |
| CN105293909A (en) * | 2015-11-10 | 2016-02-03 | 福建省德化铭丰金花纸有限公司 | In-glaze decoration embossment base material, in-glaze decoration stained paper manufactured through in-glaze decoration embossment base material and manufacturing technology of in-glaze decoration embossment base material |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102602216A (en) * | 2012-03-09 | 2012-07-25 | 斯达高瓷艺发展（深圳）有限公司 | Method for manufacturing enamel painted porcelain |
| CN105293909A (en) * | 2015-11-10 | 2016-02-03 | 福建省德化铭丰金花纸有限公司 | In-glaze decoration embossment base material, in-glaze decoration stained paper manufactured through in-glaze decoration embossment base material and manufacturing technology of in-glaze decoration embossment base material |
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| CN105819690A (en) | 2016-08-03 |
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