CN107162424B - Ceramic whiteware high-performance glaze and preparation method thereof - Google Patents
Ceramic whiteware high-performance glaze and preparation method thereof Download PDFInfo
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- CN107162424B CN107162424B CN201710531462.XA CN201710531462A CN107162424B CN 107162424 B CN107162424 B CN 107162424B CN 201710531462 A CN201710531462 A CN 201710531462A CN 107162424 B CN107162424 B CN 107162424B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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Abstract
The invention discloses a kind of ceramic whiteware high-performance glaze and preparation method thereof, belong to domestic ceramics glaze technical field.Ceramic whiteware high-performance glaze of the invention is grouped as by following group: water mill potassium feldspar, kaolin burn talcum, dolomite, barium carbonate, calcining zinc oxide, water mill quartz, glaze paint stabilizer, coefficient of expansion regulator.The production method of ceramic whiteware high-performance glaze includes the following steps: stock, aging and glaze firing.Ceramic whiteware high-performance glaze obtained by raw material of the present invention, the melting temperature of its glaze is high, and its melt temperature scope is wide, reach 1290 ~ 1330 DEG C, glaze paint is small by kiln temperature influence of fluctuations, and glaze paint pin hole is few, glaze paint is bright smooth, glaze superficial expansivity is adjustable, so that ceramic body surface increases a stress, has reached in 200 DEG C ~ 20 DEG C indehiscent effects of rapid heat cycle.
Description
Technical field
The invention belongs to domestic ceramics glaze technical fields, and in particular to a kind of ceramic whiteware high-performance glaze and its preparation side
Method.
Background technique
Dahua ware is with a long history, after hardships in thousand, one of radiance is left in Chinese pottery history, in the world
For " Chinese white " word also just at the synonym of Dehua ceramic whiteware, " Chinese white " original text (BLANC DE CHINE) is method on ceramic history
Praise of the compatriots to Ming Dynasty's Dehua ceramic whiteware, for Dehua ceramic whiteware because its production is fine, quality heavily fortified point is close, and sparkling and crystal-clear as beautiful, glaze paint is moistened
Like rouge, therefore there are the laudatory titles such as " ivory white ", " lard white ware ", " goose down is white ", there is unique style in China's ceramic whiteware system, making pottery
It is occupied an important position in porcelain development history, there is the reputation of " oriental art " in the world.However, Dehua ceramic whiteware is used for domestic ceramics
Tea tableware in use, there are thermal shock resistances it is poor, melt temperature scope is narrow and pin hole is more the defects of.It is 140 DEG C~20 through excess temperature
DEG C rapid heat cycle cracking heat stability testing, and requirements of the national standard heat stability testing, temperature is 180 DEG C~20
DEG C a rapid heat cycle do not crack, and the heat stability testing of section port product, standard requirements are 200 DEG C~20 DEG C of temperature
A rapid heat cycle do not crack, especially big part product, so this defect limits Dehua ceramic whiteware and uses as tea tableware
Range.There is technical staff capturing this technical problem always, passes through heat stability testing portioned product by research of technique
180 DEG C~20 DEG C rapid heat cycles do not crack, but cannot stablize guarantee, and qualification rate is low, be still difficult to meet it is domestic and
International current standard.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of environmental protection and energy saving, raw material is easy to get, temperature of glaze firing
High ceramic whiteware high-performance glaze, is coated with the ceramic whiteware of high-performance glaze of the invention, and thermal shock resistance is strong, and it is prepared
The process of technique is novel, and process conditions are safely controllable.
The present invention adopts the following technical scheme:
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 20~
40wt%, 6~10wt% of kaolin, 8~15wt% of talcum, 0~3wt% of dolomite, 2~6wt% of barium carbonate, calcined oxide are burnt
5~9wt% of zinc, water mill 25~32wt% of quartz, glaze paint 3~6wt% of stabilizer, 5~15wt% of coefficient of expansion regulator.
Further, it is mainly made of following component according to weight percent: water mill potassium feldspar 23wt%, kaolin
10wt%, talcum 12wt%, dolomite 3wt%, barium carbonate 2wt%, calcining zinc oxide 5wt%, water mill quartz 32wt%, glaze are burnt
Face stabilizer 3wt%, coefficient of expansion regulator 10wt%, the above component sum total is 100wt%.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein and aging temperature is 30~40 DEG C,
The aging time is 6~7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1290~1330 DEG C, and constant temperature time is 60~120min.
Further, in a process of lapping described in step 1, according to primary proportion material: water=1:0.4~0.6 ratio
Example is ground, and milling time is 40~50min, and the primary sieving uses 200~280 mesh screens, described secondary ground
Cheng Zhong, expect according to secondary proportion: water=1:0.4~0.6 ratio is ground, and milling time is 30~40min, described secondary
Sieving uses 200~280 mesh screens, and the rate that tails over is 0.04~0.06%.
Further, temperature aging described in step 2 is 35 DEG C, and the aging time is 7 days.
Further, temperature of glaze firing described in step 3 is 1310 DEG C, constant temperature time 90min.
Further, the glaze paint stabilizer is one of zirconium silicate micro mist or zirconium oxide micro mist, and the glaze paint is stablized
The partial size of agent is 1~3 μm.
Further, the coefficient of expansion regulator is one kind of spodumene or petalite.
Further, the coefficient of expansion regulator is mainly made of following component according to weight percent: spodumene 40
~60wt%, 40~60wt% of petalite.
Compared with the prior art, the present invention has the following beneficial effects:
Using ceramic whiteware high-performance glaze obtained by raw material proportioning of the present invention, the melting temperature of glaze is high,
And its melt temperature scope is wide, reaches 1290~1330 DEG C, glaze paint is small by kiln temperature influence of fluctuations, and glaze paint pin hole is few, glaze paint
Bright smooth, glaze superficial expansivity is adjustable, so that ceramic body surface increases a stress, improves the thermal shock resistance of ceramic whiteware
Can, reach in 200 DEG C~20 DEG C indehiscent effects of rapid heat cycle.There is ceramic whiteware high-performance glaze of the invention to be made
It is that ceramic whiteware enters high-grade hotel and provides necessary condition with porcelain market, realizes the purpose of industrial upgrading, economic benefit
It is significant with social benefit, to be conducive to technological progress and the application development of ceramic whiteware industry.
Specific embodiment
Embodiment 1
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 20%, kaolinite
Native 6wt%, talcum 15wt%, barium carbonate 2%, calcining zinc oxide 9wt%, water mill quartz 30wt%, glaze paint stabilizer are burnt
3wt%, coefficient of expansion regulator 15wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer is zirconium silicate micro mist, and the coefficient of expansion regulator is spodumene.
Wherein, the partial size of the glaze paint stabilizer is 1 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.4 ratio is ground
Mill, milling time 40min, primary be sieved uses 200 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.4 ratio is ground, and milling time 30min, the secondary sieving uses 200 mesh screens, and the rate of tailing over is
0.04%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 30 DEG C, aging
Time be 6 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1290 DEG C, constant temperature time 60min.
Embodiment 2
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 25%, kaolinite
Native 6wt%, talcum 12wt%, barium carbonate 2%, calcining zinc oxide 7wt%, water mill quartz 32wt% are burnt, glaze paint stablizes 3wt%,
Coefficient of expansion regulator 13wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer is zirconium oxide micro mist, and the coefficient of expansion regulator is petalite.
Wherein, the partial size of the glaze paint stabilizer is 2 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.5 ratio is ground
Mill, milling time 45min, primary be sieved uses 250 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.5 ratio is ground, and milling time 35min, the secondary sieving uses 250 mesh screens, and the rate of tailing over is
0.05%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 35 DEG C, aging
Time be 7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1290 DEG C, constant temperature time 80min.
Embodiment 3
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 30%, kaolinite
Native 8wt%, burn talcum 8wt%, barium carbonate 4%, calcining zinc oxide 9wt%, water mill quartz 25wt%, glaze paint stabilizer 3wt%,
Coefficient of expansion regulator 13wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer be zirconium silicate micro mist, the coefficient of expansion regulator mainly by following component according to
Weight percent composition: spodumene 40wt%, petalite 60wt%.
Wherein, the partial size of the glaze paint stabilizer is 3 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.6 ratio is ground
Mill, milling time 50min, primary be sieved uses 280 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.6 ratio is ground, and milling time 40min, the secondary sieving uses 280 mesh screens, and the rate of tailing over is
0.06%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 40 DEG C, aging
Time be 7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1300 DEG C, constant temperature time 60min.
Embodiment 4
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 35%, kaolinite
Native 10wt%, talcum 10wt%, barium carbonate 2%, calcining zinc oxide 7wt%, water mill quartz 25wt%, glaze paint stabilizer are burnt
6wt%, coefficient of expansion regulator 5wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer be zirconium silicate micro mist, the coefficient of expansion regulator mainly by following component according to
Weight percent composition: spodumene 50wt%, petalite 50wt%.
Wherein, the partial size of the glaze paint stabilizer is 1 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.6 ratio is ground
Mill, milling time 50min, primary be sieved uses 280 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.6 ratio is ground, and milling time 40min, the secondary sieving uses 280 mesh screens, and the rate of tailing over is
0.05%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 35 DEG C, aging
Time be 7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1310 DEG C, constant temperature time 60min.
Embodiment 5
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 35%, kaolinite
Native 10wt%, talcum 10wt%, barium carbonate 2%, calcining zinc oxide 7wt%, water mill quartz 25wt%, glaze paint stabilizer are burnt
6wt%, coefficient of expansion regulator 5wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer be zirconium silicate micro mist, the coefficient of expansion regulator mainly by following component according to
Weight percent composition: spodumene 60wt%, petalite 40wt%.
Wherein, the partial size of the glaze paint stabilizer is 2 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.6 ratio is ground
Mill, milling time 50min, primary be sieved uses 280 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.6 ratio is ground, and milling time 40min, the secondary sieving uses 280 mesh screens, and the rate of tailing over is
0.04%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 35 DEG C, aging
Time be 7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1310 DEG C, constant temperature time 60min.
Embodiment 6
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 40%, kaolinite
Native 6wt%, talcum 12wt%, barium carbonate 2%, calcining zinc oxide 7wt%, water mill quartz 25wt%, glaze paint stabilizer are burnt
3wt%, coefficient of expansion regulator 5wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer is zirconium silicate micro mist, and the coefficient of expansion regulator is petalite.
Wherein, the partial size of the glaze paint stabilizer is 3 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.6 ratio is ground
Mill, milling time 50min, primary be sieved uses 280 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.6 ratio is ground, and milling time 40min, the secondary sieving uses 280 mesh screens, and the rate of tailing over is
0.04%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 35 DEG C, aging
Time be 7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1290 DEG C, constant temperature time 60min.
Embodiment 7
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 30%, kaolinite
Native 8wt%, talcum 10wt%, dolomite 1wt%, barium carbonate 4%, calcining zinc oxide 7wt%, water mill quartz 27wt%, glaze are burnt
Face stabilizer 3wt%, coefficient of expansion regulator 10wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer is zirconium oxide micro mist, the coefficient of expansion regulator are as follows: spodumene.
Wherein, the partial size of the glaze paint stabilizer is 1 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.6 ratio is ground
Mill, milling time 50min, primary be sieved uses 280 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.6 ratio is ground, and milling time 40min, the secondary sieving uses 280 mesh screens, and the rate of tailing over is
0.07%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 35 DEG C, aging
Time be 7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1300 DEG C, constant temperature time 60min.
Embodiment 8
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 20%, kaolinite
Native 10wt%, talcum 13wt%, barium carbonate 2%, calcining zinc oxide 5wt%, water mill quartz 32wt%, glaze paint stabilizer are burnt
6wt%, coefficient of expansion regulator 12wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer is zirconium oxide micro mist, and the coefficient of expansion regulator is spodumene.
Wherein, the partial size of the glaze paint stabilizer is 2 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.6 ratio is ground
Mill, milling time 50min, primary be sieved uses 280 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.6 ratio is ground, and milling time 40min, the secondary sieving uses 280 mesh screens, and the rate of tailing over is
0.04%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 35 DEG C, aging
Time be 7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1330 DEG C, constant temperature time 60min.
Embodiment 9
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 23%, kaolinite
Native 10wt%, talcum 12wt%, dolomite 3wt%, barium carbonate 2%, calcining zinc oxide 5wt%, water mill quartz 32wt%, glaze are burnt
Face stabilizer 3wt%, coefficient of expansion regulator 10wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer is zirconium silicate micro mist, and the coefficient of expansion regulator is spodumene.
Wherein, the partial size of the glaze paint stabilizer is 1 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.6 ratio is ground
Mill, milling time 50min, primary be sieved uses 280 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.6 ratio is ground, and milling time 40min, the secondary sieving uses 280 mesh screens, and the rate of tailing over is
0.04%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 35 DEG C, aging
Time be 7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1310 DEG C, constant temperature time 120min.
Embodiment 10
Ceramic whiteware high-performance glaze is mainly made of following component according to weight percent: water mill potassium feldspar 24%, kaolinite
Native 8wt%, talcum 10wt%, dolomite 1wt%, barium carbonate 4%, calcining zinc oxide 7wt%, water mill quartz 30wt%, glaze are burnt
Face stabilizer 6wt%, coefficient of expansion regulator 10wt%, the above component sum total is 100wt%.
Wherein, the glaze paint stabilizer is zirconium silicate micro mist, and the coefficient of expansion regulator is spodumene.
Wherein, the partial size of the glaze paint stabilizer is 1 μm.
The production method of ceramic whiteware high-performance glaze, includes the following steps:
Step 1: stock:
By the water mill potassium feldspar, kaolin, burn talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz according to
Sum total is that 100wt% is matched, and obtains once proportion material, then once match gained and expects once to be ground and primary mistake
Sieve, obtains an abrasive, then again matches the glaze paint stabilizer and coefficient of expansion regulator according to weight percent,
Then it is added in gained abrasive, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, obtains two
Secondary abrasive；
Wherein, in a process of lapping described in step 1, according to primary proportion material: water=1:0.6 ratio is ground
Mill, milling time 50min, primary be sieved uses 280 mesh screens, in the secondary process of lapping, according to secondary proportion
Material: water=1:0.6 ratio is ground, and milling time 40min, the secondary sieving uses 280 mesh screens, and the rate of tailing over is
0.04%
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 35 DEG C, aging
Time be 7 days.
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing
Degree is 1330 DEG C, constant temperature time 60min.
Ceramic whiteware high-performance glaze obtained by Examples 1 to 10 is subjected to performance detection, wherein
1, coefficient of expansion detection is tested at 25~861 DEG C；
2, measuring brightness method:
Measuring brightness whiteness detector test, whiteness detector (hollow cone) are called reflectance photometer, whiteness
Meter.It is primarily adapted for use in the whiteness measurement of the object or powder of achromaticity surfacing.It can accurately obtain and visual sense degree phase one
The whiteness value of cause.
3, the bronsted lowry acids and bases bronsted lowry of resistance to low concentration is detected with reference to GB/T4100-2006；
4, capacitive lead content is detected with reference to GB/T 3534-2002；
5, capacitive cadmium content is detected with reference to GB/T 3534-2002；
6, coefficient of friction is detected with reference to GB/T4100-2006；
7, glossiness is detected with reference to GB/T 15614-2015.
Acquired results are as shown in table 1:
Table 1: the testing result of 1~embodiment of embodiment, 10 gained ceramic whiteware high-performance glaze
As can be known from the above table, resulting ceramic whiteware high-performance glaze whiteness is high, and glaze paint is smooth, and anti-friction performance is strong, and cadmium lead contains
Measure low, the coefficient of expansion is between 155~168, and controllable execution is strong.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation
It is merely illustrated the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also has
Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention
It is defined by the appending claims and its equivalent thereof.
Claims (6)
1. ceramic whiteware high-performance glaze, which is characterized in that be made of following component according to weight percent: water mill potassium feldspar 20~
40 wt %, 6~10wt% of kaolin, 8~15wt% of talcum, 0~3wt% of dolomite, 2~6 wt % of barium carbonate, calcined oxide are burnt
5~9wt% of zinc, water mill 25~32wt% of quartz, glaze paint 3~6wt% of stabilizer, 5~15wt% of coefficient of expansion regulator；
The glaze paint stabilizer is one of zirconium silicate micro mist or zirconium oxide micro mist, and the partial size of the glaze paint stabilizer is 1 ~ 3 μ
m；
The coefficient of expansion regulator is one kind of spodumene or petalite.
2. ceramic whiteware high-performance glaze according to claim 1, which is characterized in that by following component according to weight percent
Composition: water mill potassium feldspar 23wt%, kaolin 10wt%, talcum 12wt%, dolomite 3wt%, barium carbonate 2wt%, calcining zinc oxide are burnt
5wt%, water mill quartz 32wt%, glaze paint stabilizer 3wt%, coefficient of expansion regulator 10wt%, the above component summation are 100wt%.
3. the production method of ceramic whiteware high-performance glaze described in claim 1, which comprises the steps of:
Step 1: stock:
By the water mill potassium feldspar, kaolin, talcum, dolomite, barium carbonate, calcining zinc oxide and water mill quartz are burnt according to total
It is matched with for 100 wt%, obtains once proportion material, then gained is once matched to material once grind and be once sieved,
An abrasive is obtained, is then again matched the glaze paint stabilizer and coefficient of expansion regulator according to weight percent, so
It is added in gained abrasive afterwards, obtains secondary proportion material, the secondary proportion material of gained is subjected to secondary grinding and secondary sieving, is obtained secondary
Abrasive；
Step 2: aging:
Secondary abrasive progress obtained by step 1 is aging, obtain aging pug, wherein aging temperature is 30 ~ 40 DEG C, aging
Time is 6 ~ 7 days；
Step 3: glaze firing:
Aging pug obtained by step 2 is fired by glaze, ceramic whiteware high-performance glaze is obtained, wherein the temperature of oxidizing atmosphere glaze firing is
1290 ~ 1330 DEG C, constant temperature time is 60 ~ 120min.
4. the production method of ceramic whiteware high-performance glaze according to claim 3, which is characterized in that one described in step 1
In secondary process of lapping, according to primary proportion material: water=1:0.4 ~ 0.6 ratio is ground, and milling time is 40 ~ 50min, institute
It states primary be sieved and uses 200 ~ 280 mesh screens, in the secondary process of lapping, expect according to secondary proportion: water=1:0.4 ~ 0.6
Ratio is ground, milling time be 30 ~ 40min, it is described it is secondary sieving use 200 ~ 280 mesh screens, tail over rate be 0.04 ~
0.06%。
5. the production method of ceramic whiteware high-performance glaze according to claim 3, which is characterized in that old described in step 2
Rotten temperature is 35 DEG C, and the aging time is 7 days.
6. the production method of ceramic whiteware high-performance glaze according to claim 3, which is characterized in that glaze described in step 3
Burning temperature is 1310 DEG C, constant temperature time 90min.
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| CN107298530A (en) * | 2017-08-16 | 2017-10-27 | 福建省德化县三峰陶瓷有限公司 | It is unleaded to prepare the unleaded method without boron metal-lustrous glaze ceramic without boron metal-lustrous glaze and with it |
| CN107673611B (en) * | 2017-10-25 | 2023-03-28 | 福建省德化县福金兴陶瓷有限责任公司 | Whitening glaze and preparation process thereof |
| CN107879624A (en) * | 2017-11-07 | 2018-04-06 | 广西壮族自治区黎塘工业瓷厂 | A kind of refractory ceramics glaze |
| CN108178516A (en) * | 2018-02-06 | 2018-06-19 | 福建工程学院 | A kind of preparation and application of ceramic color glaze |
| CN109095775B (en) * | 2018-08-22 | 2021-08-03 | 福建德化五洲陶瓷股份有限公司 | Transparent glaze suitable for high-strength white porcelain and preparation method thereof |
| CN110240477B (en) * | 2019-05-24 | 2022-04-05 | 福建省泉州龙鹏集团有限公司 | Preparation method of underglaze bone ash porcelain |
| CN110228992A (en) * | 2019-06-28 | 2019-09-13 | 福建泉州顺美集团有限责任公司 | A kind of high white pottery porcelain of high thermal stability and preparation method thereof |
| CN111153593A (en) * | 2020-01-18 | 2020-05-15 | 福建德化五洲陶瓷股份有限公司 | Transparent glaze suitable for high-strength magnesium porcelain, high-strength magnesium porcelain and preparation method thereof |
| CN111995382B (en) * | 2020-08-24 | 2022-05-06 | 蒙娜丽莎集团股份有限公司 | Mutton tallow jade ceramic tile and preparation method thereof |
| CN112897881A (en) * | 2021-01-15 | 2021-06-04 | 景德镇陶瓷大学 | High-temperature iron sand gold glaze and preparation method and application thereof |
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| CN101182238A (en) * | 2006-11-14 | 2008-05-21 | 霍炳祥 | Clear glaze and method for manufacturing same |
| CN101691309A (en) * | 2009-10-16 | 2010-04-07 | 醴陵联合陶瓷制品有限公司 | Preparation method of high-temperature high white ceramic glaze |
| CN102464488A (en) * | 2010-11-04 | 2012-05-23 | 福建省泉州龙鹏集团有限公司 | Medium-temperature oxidized high-whiteness blue-jade porcelain and preparation method thereof |
| CN104150966B (en) * | 2014-08-11 | 2015-09-16 | 景德镇市精业陶瓷有限公司 | A kind of preparation method of snowflake glaze decorative daily-use pottery and obtained product thereof |
| CN104261879A (en) * | 2014-09-23 | 2015-01-07 | 福建省德化县宏达陶瓷有限公司 | High-gloss transparent glaze formula for daily-use ceramics, as well as preparation method and using method of high-gloss transparent glaze formula |
| CN105330158B (en) * | 2015-10-30 | 2018-02-23 | 广东家美陶瓷有限公司 | A kind of glaze of dark ceramics and preparation method thereof |
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| CN105819690B (en) * | 2016-03-21 | 2018-08-28 | 江苏高淳陶瓷股份有限公司 | The preparation method of colour enamels porcelain in a kind of glaze |
| CN105967643B (en) * | 2016-05-05 | 2019-01-29 | 德化县如瓷生活文化有限公司 | Medium temperature top grade tableware for daily use porcelain and preparation method thereof |
| CN106007379A (en) * | 2016-05-23 | 2016-10-12 | 广东家美陶瓷有限公司 | Transparent glaze and preparation method thereof |
| CN106219981B (en) * | 2016-08-05 | 2018-10-30 | 福建省德化县杰艺陶瓷有限公司 | High white ceramic glaze thoroughly and the method for making high ceramic whiteware thoroughly with it |
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