CN112552069B - Production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional code or one-dimensional code - Google Patents
Production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional code or one-dimensional code Download PDFInfo
- Publication number
- CN112552069B CN112552069B CN202011502283.1A CN202011502283A CN112552069B CN 112552069 B CN112552069 B CN 112552069B CN 202011502283 A CN202011502283 A CN 202011502283A CN 112552069 B CN112552069 B CN 112552069B
- Authority
- CN
- China
- Prior art keywords
- dimensional code
- printing
- ink
- temperature
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
- C04B37/003—Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/10—Watermarks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/12—Transfer pictures or the like, e.g. decalcomanias
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/20—Uniting glass pieces by fusing without substantial reshaping
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/07—Glass compositions containing silica with less than 40% silica by weight containing lead
- C03C3/072—Glass compositions containing silica with less than 40% silica by weight containing lead containing boron
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K17/00—Methods or arrangements for effecting co-operative working between equipments covered by two or more of main groups G06K1/00 - G06K15/00, e.g. automatic card files incorporating conveying and reading operations
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K19/06009—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking
- G06K19/06018—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking one-dimensional coding
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K19/06009—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking
- G06K19/06037—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking multi-dimensional coding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention provides a production process of a ceramic or glass bonded high-temperature-resistant fired two-dimensional code or one-dimensional code, which relates to the technical field of artware production processes.A high-temperature-resistant transparent coating frit is printed on water transfer paper by using a 100-mesh screen with 500 meshes, the coating melting point is 500-mesh, an ultrafine coating solution block and stained paper ink mixing oil are uniformly mixed according to the ratio of 1:0.4 to prepare solution block ink, an ink press with the pressure of 50-100MPa is used for uniformly rolling the solution block ink, then the printing is carried out, and the solution block ink is placed into a drying box and dried at the temperature of 45 ℃ for half an hour; the baked two-dimensional code or one-dimensional code is already fused on the surface of the ware, is not afraid of knife scraping and water bubble and is always fused with the ware; the two-dimensional code or the one-dimensional code produced by the process is a flow code or a special code provided by a database, so that the processing efficiency of the two-dimensional code or the one-dimensional code of the ceramic or glass product is improved, and the market demand of batch production is met; has high practical value.
Description
Technical Field
The invention relates to the technical field of artware processes, in particular to a production process of a ceramic-pasted high-temperature-resistant fired two-dimensional code or one-dimensional code.
Background
Ceramics are a generic term for ceramics and porcelain. As early as one thousand years before the ceramic making technology is mastered in Europe, China can manufacture quite exquisite chinaware (Chinese people invented pottery early in the era of 2000 neolithic stoneware 8000 before the Youguan, from the development history of Chinese ceramics, the term "ceramic" is generally divided into two, namely, pottery and porcelain, clay and porcelain products with a matrix not densely sintered are generally called pottery, whether colored or white, wherein the part with higher sintering temperature and better sintering degree is called "pottery", one part for glazing is called "glaze pottery", relatively speaking, clay or porcelain products with higher sintering temperature, more compact sintering degree and excellent glaze color quality are called "porcelain", the development of Chinese traditional ceramics has been over a quite long history period, various and special processes, so the classification of Chinese traditional ceramics considers the technical hard indexes, the traditional habitual classification method is also considered comprehensively, and the change of ancient and modern scientific knowledge is combined, so that the classification conclusion that most ceramic materials are oxides, nitrides, borides, carbides and the like can be more effectively drawn. Common ceramic materials are clay, alumina, kaolin, and the like. Ceramic materials generally have a high hardness but a poor plasticity. Besides the use of food and decoration, the utility model also plays an important role in the development of science and technology. The ceramic raw material is extracted from a large amount of clay which is the original resource of the earth. The clay has toughness, can be plasticized when meeting water at normal temperature, can be slightly dried for carving, and can be completely dried for grinding; the pottery can be made into pottery and can be filled with water when the pottery is burnt to 700 ℃; when the material is burnt to 1230 ℃, the material is vitrified, and can completely absorb no water, resist high temperature and resist corrosion. The flexibility of its usage has been applied to various creativity in today's cultural science and technology.
The high-tech computer network technology is widely used in the production process of ceramic or glass, and each ceramic or glass product is provided with a certificate which symbolizes the identity from production to delivery: two-dimensional codes or one-dimensional codes. If the paper code is easy to lose or destroy, the paper code is burnt out and cannot be stored permanently when finally put into a kiln, and then the paper code is checked and verified
It is very troublesome. The invention patent of patent publication No. CN109551912A discloses a production process for pasting a high-temperature-resistant fired two-dimensional code or one-dimensional code on a ceramic green body, although the ceramic pasted high-temperature-resistant two-dimensional code or one-dimensional code can be obtained, only a mode of naturally airing for 11-13 hours is provided in the process, the processing efficiency is low, the market demand of batch production of ceramic or glass products cannot be met, and the two-dimensional code or the one-dimensional code fused on the surface of a ware is not resistant to knife scraping and water bubbles, so that the production process needs to be improved, the production efficiency is improved, and the market demand of batch production of the ceramic or glass products is met.
Disclosure of Invention
The invention aims to provide a production process of a ceramic-bonded or glass-bonded high-temperature-resistant fired two-dimensional code or one-dimensional code, and aims to solve the problem that the production efficiency of the ceramic-bonded high-temperature-resistant fired two-dimensional code or one-dimensional code in the prior art is low.
In order to achieve the purpose, the invention provides the following technical scheme to realize the purpose:
a ceramic bonding or glass pasting high-temperature-resistant firing two-dimensional code or one-dimensional code production process is characterized in that: the method comprises the following steps:
s1, printing high-temperature-resistant transparent coating frit on water transfer paper by using a 100-plus 500-mesh screen, uniformly mixing superfine coating frit and stained paper ink mixing oil according to a ratio of 1:0.2-0.5 to prepare frit ink, then uniformly rolling the frit ink by using an ink press with a pressure of 50-100MPa, printing, and then putting into a drying box to dry at a temperature of 45 ℃ for half an hour;
s2, generating a template of a two-dimensional code or a one-dimensional code to be printed by using computer software, or a pipeline code, a database code, a fixed code and a website code;
s3, cutting the dried water transfer paper into A4 or A3 paper, and printing a two-dimensional code or a one-dimensional code template to be printed in the production of computer software on the coating of the cut water transfer paper by a laser printer;
s4, printing a coating on the printing surface of the printed water transfer paper by using a 100-mesh screen and a 500-mesh screen again;
s5, mixing the superfine soluble block with stained paper ink mixing oil according to the ratio of 1:0.2-0.5 to prepare soluble block ink, and then rolling the soluble block ink uniformly by using an ink press with the pressure of 50-100 MPa;
s6, fully printing the rolled solution block ink on water transfer paper printed with two-dimensional codes or one-dimensional codes by using a 100-mesh and 500-mesh screen mesh, and then drying the water transfer paper in a drying box at the drying temperature of about 45 ℃ for half an hour;
s7, printing the pattern paper cover oil on the dried water transfer paper by using a 50-80 mesh silk screen, and drying for half an hour at the temperature of 45 ℃ by using a drying box;
s8, cutting the produced two-dimensional code or one-dimensional code water transfer paper into single bodies, immersing the single bodies in water for half a minute to remove the film, sticking the one-dimensional code or the two-dimensional code after the film removal on ceramic or glass, extruding water by a scraper to enable the one-dimensional code or the two-dimensional code to be tightly attached to the surface of a device, airing the device and then putting the device into a kiln; the baking temperature is 500-800 ℃; the baked two-dimensional code or one-dimensional code is already fused on the surface of the utensil, is not afraid of scraping and water bubble and is always fused with the utensil;
the toner for the toner cartridge of the laser printer mainly comprises the following components in percentage by mass: 20-30% of FeO crystal particles PLGMENT, 50-60% of polyacrylate-styrene copolymer, 10-20% of charge regulator CCA, a fluidizing agent SiO2 with a slightly larger proportion than that of the 20-30% of FeO crystal particles PLGMENT, and the like, and polyethylene/polypropylene paraffin; the iron content in the carbon powder is high, after printing, a two-dimensional code or a one-dimensional code is pasted in the next procedure, wherein in the high-temperature firing process, the iron element and oxygen generate a chemical reaction to generate ferroferric oxide 3Fe +2O2 ═ Fe3O4, and the ferroferric oxide is black and is stuck on the surface of the ceramic to be permanently stored and scanned;
the superfine frit is prepared by grinding 20-36.5% of SiO2, 3.5% of Al2O3, 5% of k2O 2% of Na2O, 20-40% of PbO and 40-13% of B2O3 by mass molecule number, sieving with a 200-mesh sieve, then putting into a ball mill, grinding into powder, and sieving with a 1000-mesh sieve.
Preferably: the carbon powder in the laser printer is printed by adopting Fe2O 3-containing ultrafine carbon powder.
Preferably: the glue-containing surface printing layer surface of the water transfer printing paper is a printing surface during laser printing.
Preferably: the printing coating adopts transparent or white or semitransparent frit, and the fineness of the frit is about 2000 meshes.
Preferably: the printing coating is prepared by printing a high-temperature-resistant transparent coating frit through a 100-sand 500-mesh screen, and the melting point temperature of the printing coating is 500-sand 800 ℃.
Preferably: and in the S5, the superfine soluble block and the stained paper ink mixing oil are uniformly mixed according to the mass ratio of 1:0.4 to prepare the soluble block ink.
The invention has the beneficial effects that:
printing a high-temperature-resistant transparent coating frit on water transfer paper by using a 100-500-mesh screen, wherein the coating melting point is 500-800 ℃, uniformly mixing an ultrafine coating frit and stained paper ink mixing oil according to the ratio of 1:0.4 to prepare a frit ink, uniformly rolling the frit ink by using an ink press with the pressure of 50-100MPa, printing, putting into a drying box, and drying at the temperature of 45 ℃ for half an hour; the baked two-dimensional code or one-dimensional code is already fused on the surface of the ware, is not afraid of knife scraping and water bubble and is always fused with the ware; the two-dimensional code or the one-dimensional code produced by the process is a flow code or a special code provided by a database, and a unique two-dimensional code or one-dimensional code of a permanent identity card is pasted for each ceramic or glass product, so that the ceramic or glass product is subjected to more than ten production processes in the production process of ceramic or glass, such as kiln entering, firing, kiln discharge, finished product inspection, packaging, warehouse entry registration, delivery, sale and the like, and each process saves a large amount of manpower to register by scanning the two-dimensional code or the one-dimensional code pasted on the surface of the ceramic or glass, reduces artificial errors in the production process, improves the processing efficiency of the two-dimensional code or the one-dimensional code of the ceramic or glass product, and meets the market demand of batch production; has high practical value.
Drawings
FIG. 1 is a flow chart of a production process of a ceramic or glass pasted high-temperature-resistant fired two-dimensional code or one-dimensional code according to the invention
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be further described with reference to the following embodiments. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. The conditions in the embodiments can be further adjusted according to specific conditions, and simple modifications of the method of the present invention based on the concept of the present invention are within the scope of the present invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
A production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional codes or one-dimensional codes comprises the following steps:
s1, printing high-temperature-resistant transparent coating frits on water transfer printing paper by using a 500-mesh screen, uniformly mixing superfine coating frits and stained paper ink mixing oil according to a ratio of 1:0.4 to prepare frit ink, rolling the frit ink uniformly by using an ink press with a pressure of 100MPa, printing, putting into a drying box after printing, and drying at a temperature of 45 ℃ for half an hour;
s2, generating a two-dimensional code or one-dimensional code template to be printed by using computer software;
s3, cutting the dried water transfer paper into A4 paper, printing a designed two-dimensional code or one-dimensional code template on the cut water transfer paper by using a laser printer, printing carbon powder in the laser printer by using Fe2O 3-containing superfine carbon powder, and taking the glue-containing surface of the water transfer paper as a printing surface during printing;
s4, printing a coating on the printing surface of the printed water transfer paper by using a 300-mesh screen, wherein the printing coating is prepared by selecting an ultrafine dissolving block with a melting point of 800 ℃ and passing through a 800-mesh screen;
s5, uniformly mixing the superfine soluble block and the stained paper ink mixing oil according to the mass ratio of 1:0.4 of the superfine soluble block to the stained paper ink mixing oil to prepare soluble block ink, and then uniformly rolling the soluble block ink by using an ink press with the pressure of 50 MPa;
s6, fully printing the rolled solution block ink on water transfer paper printed with two-dimensional codes or one-dimensional codes by using a 300-mesh silk screen, and drying for half an hour at 45 ℃;
s7, printing the paper seal oil on the dried water transfer paper by using a 60-mesh silk screen, and drying for half an hour at 45 ℃.
S8, cutting the produced two-dimensional code or one-dimensional code water transfer paper into single bodies, immersing the single bodies in water for half a minute to remove the film, sticking the one-dimensional code or the two-dimensional code after the film removal on ceramic or glass, extruding water by a scraper to enable the one-dimensional code or the two-dimensional code to be tightly attached to the surface of a device, airing the device and then putting the device into a kiln; the baking temperature is 500-800 ℃; the baked two-dimensional code or one-dimensional code is already fused on the surface of the utensil, and after the hundred-grid test, the two-dimensional code or the one-dimensional code is soaked in normal-temperature water for 96 hours and is soaked in boiled water at the high temperature of 100 ℃ for 96 hours, the two-dimensional code or the one-dimensional code is not afraid of scraping and water bubbles and is always fused with the utensil.
Example 2
A ceramic or glass pasting high-temperature-resistant firing two-dimensional code or one-dimensional code production process comprises the following steps:
s1, printing high-temperature-resistant transparent coating frits on water transfer printing paper by using a 500-mesh screen, uniformly mixing superfine coating frits and stained paper ink mixing oil according to a ratio of 1:0.4 to prepare frit ink, rolling the frit ink uniformly by using an ink press with a pressure of 100MPa, printing, putting into a drying box after printing, and drying at a temperature of 45 ℃ for half an hour;
s2, generating a two-dimensional code or one-dimensional code template to be printed by using computer software;
s3, cutting the dried water transfer paper into A3 paper, printing a designed two-dimensional code or one-dimensional code template on the cut water transfer paper by using a laser printer, printing carbon powder in the laser printer by using Fe2O 3-containing superfine carbon powder, and taking the glue-containing surface of the water transfer paper as a printing surface during printing;
s4, printing a coating on the printing surface of the printed water transfer paper by using a 300-mesh screen, wherein the printing coating is prepared by selecting an 800-DEG melting point superfine dissolving block and passing through an 800-mesh screen;
s5, uniformly mixing the superfine soluble block and the stained paper ink mixing oil according to the mass ratio of 1:0.4 of the superfine soluble block to the stained paper ink mixing oil to prepare soluble block ink, and then uniformly rolling the soluble block ink by using an ink press with the pressure of 50 MPa;
s6, fully printing the rolled solution block ink on water transfer paper printed with two-dimensional codes or one-dimensional codes by using a 300-mesh silk screen, and drying for half an hour at 45 ℃ after printing;
and S7, printing the pattern paper cover oil on the dried water transfer paper by using a 60-mesh silk screen, and drying for half an hour at 45 ℃.
S8, cutting the produced two-dimensional code or one-dimensional code water transfer paper into single bodies, immersing the single bodies in water for half a minute to remove the film, sticking the one-dimensional code or the two-dimensional code after the film removal on ceramic or glass, extruding water by a scraper to enable the one-dimensional code or the two-dimensional code to be tightly attached to the surface of a device, airing the device and then putting the device into a kiln; the baking temperature is 500-800 ℃; the baked two-dimensional code or one-dimensional code is already fused on the surface of the ware, is not afraid of knife scraping and water bubble and is always fused with the ware;
in the example 2, the articles are tightly attached to each other after being soaked in water at normal temperature for 96 hours and in boiled water at high temperature of 100 ℃ for 96 hours in the same Baige test as in the example 1, and the articles are not afraid of scraping and water soaking.
Example 3
A production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional codes or one-dimensional codes comprises the following steps:
s1, printing high-temperature-resistant transparent coating frits on water transfer paper by using a 500-mesh screen, uniformly mixing superfine coating frits and stained paper ink mixing oil according to a ratio of 1:0.4 to prepare the frit ink, rolling the frit ink uniformly by using an ink press with the pressure of 100MPa, printing, putting into a drying box after the printing is finished, and drying at the temperature of 45 ℃ for half an hour;
s2, generating a two-dimensional code or one-dimensional code template to be printed by using computer software;
s3, cutting the dried water transfer paper into A4 paper, printing a designed two-dimensional code or one-dimensional code template on the cut water transfer paper by using a laser printer, printing carbon powder in the laser printer by using Fe2O 3-containing superfine carbon powder, and taking the glue-containing surface of the water transfer paper as a printing surface during printing;
s4, printing a coating on the printing surface of the printed water transfer paper by using a 300-mesh screen, wherein the printing coating is prepared by selecting an 800-DEG melting point superfine dissolving block and passing through an 800-mesh screen;
s5, uniformly mixing the superfine soluble block and the stained paper ink mixing oil according to the mass ratio of 1:0.4 of the superfine soluble block to the stained paper ink mixing oil to prepare soluble block ink, and then uniformly rolling the soluble block ink by using an ink press with the pressure of 50 MPa;
s6, fully printing the rolled solution block ink on water transfer paper printed with two-dimensional codes or one-dimensional codes by using a 200-mesh silk screen, and drying for half an hour at 45 ℃;
and S7, printing the pattern paper cover oil on the dried water transfer printing paper by using a 60-mesh silk screen, and drying for half an hour.
S8, cutting the produced two-dimensional code or one-dimensional code water transfer paper into single bodies, immersing the single bodies in water for half a minute to remove the film, sticking the one-dimensional code or the two-dimensional code after the film removal on ceramic or glass, extruding water by a scraper to enable the one-dimensional code or the two-dimensional code to be tightly attached to the surface of a device, airing the device and then putting the device into a kiln; the baking temperature is 500-800 ℃; the baked two-dimensional code or one-dimensional code is already fused on the surface of the utensil, the two-dimensional code or one-dimensional code fused with the utensil is not resistant to scraping and water bubbles, and the production efficiency is low.
In this example 3, the same one-dimensional code or two-dimensional code on the surface of the implement falls off after the implement is soaked in the normal temperature water for 96 hours and the high temperature 100 ℃ boiled water for 96 hours in the same one-hundred-grid test as in example 1, and the implement is not resistant to scraping.
Example 4
A production process for pasting a high-temperature-resistant two-dimensional code or one-dimensional code on ceramic or glass comprises the following steps:
s1, printing high-temperature-resistant transparent coating frits on water transfer printing paper by using a 500-mesh screen, uniformly mixing superfine coating frits and stained paper ink mixing oil according to a ratio of 1:0.4 to prepare frit ink, rolling the frit ink uniformly by using an ink press with a pressure of 100MPa, printing, putting into a drying box after printing, and drying at a temperature of 45 ℃ for half an hour;
s2, generating a two-dimensional code or one-dimensional code template to be printed by using computer software;
s3, cutting the dried water transfer paper into A4 paper, printing a designed two-dimensional code or one-dimensional code template on the cut water transfer paper by using a laser printer, printing carbon powder in the laser printer by using Fe2O 3-containing superfine carbon powder, and taking the glue-containing surface of the water transfer paper as a printing surface during printing;
s4, printing a coating on the printing surface of the printed water transfer paper by using a 400-mesh screen, wherein the printing coating is prepared by selecting an 800-DEG melting-point superfine solution block and passing through an 800-mesh screen;
s5, uniformly mixing the superfine soluble block with the stained paper ink mixing oil according to the mass ratio of 1:0.4 of the superfine soluble block to the stained paper ink mixing oil to prepare soluble block ink, and then uniformly rolling the soluble block ink by using an ink press with the pressure of 50 MPa;
s6, fully printing the rolled solution block ink on water transfer paper printed with two-dimensional codes or one-dimensional codes by using a 100-mesh silk screen, and naturally airing for 12 hours after printing;
and S7, printing the pattern paper cover oil on the dried water transfer printing paper by using a 60-mesh silk screen, and naturally airing for 12 hours.
S8, cutting the produced two-dimensional code or one-dimensional code water transfer paper into single bodies, immersing the single bodies in water for half a minute to remove the film, sticking the one-dimensional code or the two-dimensional code after the film removal on ceramic or glass, extruding water by a scraper to enable the one-dimensional code or the two-dimensional code to be tightly attached to the surface of a device, airing the device and then putting the device into a kiln; the baking temperature is 500-800 ℃; the baked two-dimensional code or one-dimensional code is already fused on the surface of the ware, the two-dimensional code or one-dimensional code fused with the ware is not resistant to scraping and water bubbles, and the production efficiency is low.
In this example 4, the same one-dimensional code or two-dimensional code on the surface of the object partially falls off and is not resistant to knife-cutting in the same one-grid test as in example 1, after the object is soaked in normal-temperature water for 96 hours and in boiled water at a high temperature of 100 ℃ for 96 hours.
Example 5
A production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional codes or one-dimensional codes comprises the following steps:
s1, printing high-temperature-resistant transparent coating frits on water transfer printing paper by using a 500-mesh screen, uniformly mixing superfine coating frits and stained paper ink mixing oil according to a ratio of 1:0.4 to prepare frit ink, rolling the frit ink uniformly by using an ink press with a pressure of 100MPa, printing, putting into a drying box after printing, and drying at a temperature of 45 ℃ for half an hour;
s2, generating a two-dimensional code or one-dimensional code template to be printed by using computer software;
s3, cutting the dried water transfer paper into A4 paper, printing a designed two-dimensional code or one-dimensional code template on the cut water transfer paper by using a laser printer, printing carbon powder in the laser printer by using Fe2O 3-containing superfine carbon powder, and taking the glue-containing surface of the water transfer paper as a printing surface during printing;
s4, printing a coating on the printing surface of the printed water transfer paper by using a 300-mesh screen, wherein the printing coating is prepared by selecting an 800-DEG melting point superfine dissolving block and passing through an 800-mesh screen;
s5, uniformly mixing the superfine soluble block and the stained paper ink mixing oil according to the mass ratio of 1:0.2 of the superfine soluble block to the stained paper ink mixing oil to prepare soluble block ink, and then uniformly rolling the soluble block ink by using an ink press with the pressure of 50 MPa;
s6, fully printing the rolled solution block ink on water transfer paper printed with two-dimensional codes or one-dimensional codes by using a 300-mesh silk screen, and naturally airing for 12 hours after printing;
and S7, printing the pattern paper cover oil on the dried water transfer printing paper by using a 60-mesh silk screen, and naturally airing for 12 hours.
S8, cutting the produced two-dimensional code or one-dimensional code water transfer paper into single bodies, immersing the single bodies in water for half a minute to remove the film, sticking the one-dimensional code or the two-dimensional code after the film removal on ceramic or glass, extruding water by a scraper to enable the one-dimensional code or the two-dimensional code to be tightly attached to the surface of a device, airing the device and then putting the device into a kiln; the baking temperature is 500-800 ℃; the baked two-dimensional code or one-dimensional code is already fused on the surface of the ware, the two-dimensional code or one-dimensional code fused with the ware is not resistant to scraping and water bubbles, and the production efficiency is low. The obtained effect was inferior to that of example 1.
In this example 5, the same one-dimensional code or two-dimensional code on the surface of the implement falls off after the implement is soaked in the normal temperature water for 96 hours and the high temperature 100 ℃ boiled water for 96 hours in the same one-hundred-grid test as in example 1, and the implement is not resistant to scraping.
Example 6
A production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional codes or one-dimensional codes comprises the following steps:
s1, printing high-temperature-resistant transparent coating frits on water transfer printing paper by using a 500-mesh screen, uniformly mixing superfine coating frits and stained paper ink mixing oil according to a ratio of 1:0.4 to prepare frit ink, then uniformly rolling the frit ink by using an ink press with a pressure of 50-100MPa, then printing, and then putting into a drying box to dry at a temperature of 45 ℃ for half an hour;
s2, generating a two-dimensional code or one-dimensional code template to be printed by using computer software;
s3, cutting the dried water transfer paper into A4 paper, printing a designed two-dimensional code or one-dimensional code template on the cut water transfer paper by using a laser printer, printing carbon powder in the laser printer by using Fe2O 3-containing superfine carbon powder, and taking the glue-containing surface of the water transfer paper as a printing surface during printing;
s4, printing a coating on the printing surface of the printed water transfer paper by using a 300-mesh screen, wherein the printing coating is prepared by selecting an 800-DEG melting point superfine dissolving block and passing through an 800-mesh screen;
s5, uniformly mixing the superfine soluble block and the stained paper ink mixing oil according to the mass ratio of 1:0.3 of the superfine soluble block to the stained paper ink mixing oil to prepare soluble block ink, and then uniformly rolling the soluble block ink by using an ink press with the pressure of 50 MPa;
s6, fully printing the rolled solution block ink on water transfer paper printed with two-dimensional codes or one-dimensional codes by using a 300-mesh silk screen, and naturally airing for 12 hours after printing;
and S7, printing the pattern paper cover oil on the dried water transfer printing paper by using a 60-mesh silk screen, and naturally airing for 12 hours.
S8, cutting the produced two-dimensional code or one-dimensional code water transfer paper into single bodies, immersing the single bodies in water for half a minute to remove the film, sticking the one-dimensional code or the two-dimensional code after the film removal on ceramic or glass, extruding water by a scraper to enable the one-dimensional code or the two-dimensional code to be tightly attached to the surface of a device, airing the device and then putting the device into a kiln; the baking temperature is 500-800 ℃; the baked two-dimensional code or one-dimensional code is already fused on the surface of the ware, the two-dimensional code or one-dimensional code fused with the ware is not resistant to scraping and water bubbles, and the production efficiency is low.
In this example 6, the two-dimensional code or the one-dimensional code on the surface of the implement falls off after the implement is soaked in the normal-temperature water for 96 hours and the high-temperature 100 ℃ boiled water for 96 hours in the same one-hundred-grid test as in example 1, and the implement is not resistant to scraping.
Example 7
A production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional codes or one-dimensional codes comprises the following steps:
s1, printing high-temperature-resistant transparent coating frits on water transfer printing paper by using a 500-mesh screen, uniformly mixing superfine coating frits and stained paper ink mixing oil according to a ratio of 1:0.4 to prepare frit ink, rolling the frit ink uniformly by using an ink press with a pressure of 100MPa, printing, putting into a drying box after printing, and drying at a temperature of 45 ℃ for half an hour;
s2, generating a two-dimensional code or one-dimensional code template to be printed by using computer software;
s3, cutting the water transfer paper into A4 paper, printing a designed two-dimensional code or one-dimensional code template on the cut water transfer paper by using a laser printer, printing carbon powder in the laser printer by using Fe2O 3-containing superfine carbon powder, and taking the glue-containing surface of the water transfer paper as a printing surface during printing;
s4, printing a coating on the printing surface of the printed water transfer paper by using a 300-mesh screen, wherein the printing coating is prepared by selecting an 800-DEG melting point superfine dissolving block and passing through an 800-mesh screen;
s5, uniformly mixing the superfine soluble block and the stained paper ink mixing oil according to the mass ratio of 1:0.5 of the superfine soluble block to the stained paper ink mixing oil to prepare soluble block ink, and then uniformly rolling the soluble block ink by using an ink press with the pressure of 50 MPa;
s6, fully printing the rolled soluble block ink on water transfer printing paper printed with two-dimensional codes or one-dimensional codes by using a 300-mesh silk screen, and naturally airing for 12 hours after printing;
and S7, printing the pattern paper cover oil on the dried water transfer printing paper by using a 60-mesh silk screen, and naturally airing for 12 hours.
S8, cutting the produced two-dimensional code or one-dimensional code water transfer paper into single bodies, immersing the single bodies in water for half a minute to remove the film, sticking the one-dimensional code or the two-dimensional code after the film removal on ceramic or glass, extruding water by a scraper to enable the one-dimensional code or the two-dimensional code to be tightly attached to the surface of a device, airing the device and then putting the device into a kiln; the baking temperature is 500-800 ℃; the baked two-dimensional code or one-dimensional code is already fused on the surface of the ware, the two-dimensional code or one-dimensional code fused with the ware is not resistant to scraping and water bubbles, and the production efficiency is low.
In this example 7, the same one-dimensional code or two-dimensional code on the surface of the implement falls off after the implement is soaked in the normal temperature water for 96 hours and the high temperature 100 ℃ boiled water for 96 hours in the same one-hundred-grid test as in example 1, and the implement is not resistant to scraping.
The results from the above 7 examples gave:
the parameters in example 1 best fit the actual production and best results are obtained.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description describes embodiments, not every embodiment includes only a single technical solution, and such description is for clarity only, and those skilled in the art should take the description as a whole, and the technical solutions in the embodiments may be appropriately combined to form other embodiments that those skilled in the art can understand.
Claims (6)
1. A production process for ceramic or glass pasting high-temperature-resistant firing of two-dimensional codes or one-dimensional codes is characterized in that: the method comprises the following steps:
s1, printing the high-temperature resistant transparent coating frit on the water transfer printing paper by using a 100-500-mesh screen, and mixing the superfine coating frit and the stained paper ink-mixing oil according to the ratio of 1:0.2-0.5, uniformly mixing to prepare frit ink, uniformly rolling the frit ink by using an ink press with the pressure of 50-100MPa, printing, and then putting into a drying box to dry at the temperature of 45 ℃ for half an hour;
s2, generating a template of a two-dimensional code or a one-dimensional code to be printed by using computer software, or a pipeline code, a database code, a fixed code and a website code;
s3, cutting the dried water transfer paper into A4 or A3 paper, and printing a two-dimensional code or a one-dimensional code template to be printed in the production of computer software on the coating of the cut water transfer paper by a laser printer;
s4, printing a coating on the printing surface of the printed water transfer paper by using a 100-mesh screen and a 500-mesh screen again;
s5, mixing the superfine coating frits and the stained paper varnish according to the ratio of 1:0.2-0.5, evenly mixing to prepare frit ink, and then uniformly rolling the frit ink by using an ink press with the pressure of 50-100 MPa;
s6, fully printing the rolled frit ink on water transfer paper printed with two-dimensional codes or one-dimensional codes by using a 100-mesh and 500-mesh screen mesh, and then drying the water transfer paper in a drying box at the drying temperature of about 45 ℃ for half an hour;
s7, printing the pattern paper cover oil on the dried water transfer paper by using a 50-80 mesh silk screen, and drying for half an hour at the temperature of 45 ℃ by using a drying box;
s8, cutting the produced two-dimensional code or one-dimensional code water transfer paper into single bodies, immersing the single bodies in water for half a minute to remove the film, sticking the one-dimensional code or the two-dimensional code after the film removal on ceramic or glass, extruding water by a scraper to enable the one-dimensional code or the two-dimensional code to be tightly attached to the surface of a device, airing the device and then putting the device into a kiln; the baking temperature is 500-800 ℃; the baked two-dimensional code or one-dimensional code is already fused on the surface of the ware, is not afraid of knife scraping and water bubble and is always fused with the ware;
the toner for the selenium drum of the laser printer mainly comprises the following components in percentage by mass: 20-30% FeO crystal particles, 50-60% polyacrylate-styrene copolymer, 10-20% charge regulator CCA and fluidizing agent SiO2Surface modifiers polyethylene and polypropylene paraffin; SiO22The total amount of the polyethylene and the polypropylene paraffin accounts for a little bit more than the proportion of 20-30 percent of FeO crystal particles; the iron content in the carbon powder is high, after printing, a two-dimensional code or a one-dimensional code is pasted in the next procedure, wherein the iron element and oxygen generate chemical reaction in the high-temperature firing process to generate ferroferric oxide 3Fe +2O2=Fe3O4The ferroferric oxide is black and can be permanently stored and scanned after being adhered to the surface of the ceramic;
the ultrafine coating frit consists of 20-36.5% SiO by mass molecule number2、3.5%Al2O3、5%K2O、2%Na2O、20-40%PbO、13-40%B2O3Grinding and sieving with 200 mesh sieve, then placing into a ball mill, ball-milling into powder, and sieving with 1000 mesh sieve.
2. The ceramic or glass-bonded high-temperature-resistant-firing two-dimensional code or one-dimensional code producer according to claim 1The process is characterized by comprising the following steps: the carbon powder in the laser printer contains Fe2O3The superfine carbon powder is printed.
3. The production process of the ceramic or glass pasted high temperature resistant fired two-dimensional code or one-dimensional code as claimed in claim 1, characterized in that: the glue-containing surface printing layer surface of the water transfer printing paper is a printing surface during laser printing.
4. The production process of the ceramic or glass pasted high temperature firing resistant two-dimensional code or one-dimensional code as claimed in claim 1, wherein: the printing coating adopts transparent or white or semitransparent frit, and the fineness of the frit is about 2000 meshes.
5. The production process of the ceramic or glass pasted high temperature firing resistant two-dimensional code or one-dimensional code as claimed in claim 1, wherein: the printing coating is prepared by printing the high-temperature-resistant transparent coating frit by using a 100-500-mesh screen, and the melting temperature of the printing coating is 500-800 ℃.
6. The production process of the ceramic or glass pasted high temperature firing resistant two-dimensional code or one-dimensional code as claimed in claim 1, wherein: in S5, the mass ratio of the superfine coating frit to the stained paper varnish is 1:0.4, the ink was homogenized to prepare a frit ink.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011502283.1A CN112552069B (en) | 2020-12-17 | 2020-12-17 | Production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional code or one-dimensional code |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011502283.1A CN112552069B (en) | 2020-12-17 | 2020-12-17 | Production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional code or one-dimensional code |
Publications (2)
Publication Number | Publication Date |
---|---|
CN112552069A CN112552069A (en) | 2021-03-26 |
CN112552069B true CN112552069B (en) | 2022-06-07 |
Family
ID=75063467
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011502283.1A Active CN112552069B (en) | 2020-12-17 | 2020-12-17 | Production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional code or one-dimensional code |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112552069B (en) |
Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3796618A (en) * | 1970-04-23 | 1974-03-12 | G Lehming | Method of decorating ceramic wall and floor tiles |
EP0601317A2 (en) * | 1992-12-04 | 1994-06-15 | Nitto Denko Corporation | Label substrate, ink, and label |
TW310412B (en) * | 1996-07-05 | 1997-07-11 | Hocheng Corp | Barcode label for ceramic products |
US6481353B1 (en) * | 2000-10-31 | 2002-11-19 | International Imaging Materials, Inc | Process for preparing a ceramic decal |
US20030044582A1 (en) * | 2001-08-28 | 2003-03-06 | Sakoske George Emil | Screen printing process |
CN201002378Y (en) * | 2007-01-29 | 2008-01-09 | 上海佳彩包装材料有限公司 | False-proof transfer-printing label for glass and ceramic products |
CN101445324A (en) * | 2007-11-26 | 2009-06-03 | 东进世美肯株式会社 | Low melting point frit paste composition and sealing method for electric element using the same |
JP2011180471A (en) * | 2010-03-03 | 2011-09-15 | Nippon Electric Glass Co Ltd | Laminate sheet for firing, adherend with identification label stuck thereto and method for manufacturing the adherend |
CN105415906A (en) * | 2015-10-20 | 2016-03-23 | 泸州金鑫科技有限公司 | Anti-fake two-dimension code printing process |
CN105819690A (en) * | 2016-03-21 | 2016-08-03 | 江苏高淳陶瓷股份有限公司 | Preparation method of polychrome enamel decor ware |
CN108274911A (en) * | 2018-01-19 | 2018-07-13 | 上海高诚创意科技集团有限公司 | The method that water at low temperature transfers radium-shine marble paper |
CN108284676A (en) * | 2018-02-06 | 2018-07-17 | 上海高诚创意科技集团有限公司 | A kind of transfer of ceramic water has the function of the method for concealed anti-false marble paper |
CN110555492A (en) * | 2019-07-15 | 2019-12-10 | 华南理工大学 | Preparation method of high-imitation micro-display two-dimensional code |
CN111197269A (en) * | 2018-11-20 | 2020-05-26 | 唐山福来瓷科技有限公司 | Production process of special paper capable of printing ceramic green body and firing two-dimensional code one-dimensional code |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6057076A (en) * | 1998-07-06 | 2000-05-02 | Xerox Corporation | Toner composition and processes thereof |
JP5535588B2 (en) * | 2009-11-25 | 2014-07-02 | 浜松ホトニクス株式会社 | Glass welding method and glass layer fixing method |
EP2982656A1 (en) * | 2010-09-03 | 2016-02-10 | Corning Incorporated | Process for sealing a glass package and resulting glass package |
CN104200746B (en) * | 2013-08-27 | 2017-06-27 | 成都天钥科技有限公司 | A kind of glass or the false proof preparation method for reviewing mark of ceramic |
CN105293909B (en) * | 2015-11-10 | 2019-03-29 | 福建省德化铭丰金花纸有限公司 | In-glaze decoration embossment bottom material, in-glaze decoration marble paper and its manufacture craft with its production |
KR20190046457A (en) * | 2017-10-26 | 2019-05-07 | 고문성 | Ceramic Paint for Gravure Printing and the Method of Making Tempered Glass and Tempered Tile Including the Same |
CN116945791A (en) * | 2018-12-06 | 2023-10-27 | 唐山福来瓷科技有限公司 | Production process for sticking ceramic green compact and firing two-dimensional code or one-dimensional code at high temperature |
CN109968847A (en) * | 2019-05-06 | 2019-07-05 | 陈色丽 | A kind of bar code making method |
-
2020
- 2020-12-17 CN CN202011502283.1A patent/CN112552069B/en active Active
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3796618A (en) * | 1970-04-23 | 1974-03-12 | G Lehming | Method of decorating ceramic wall and floor tiles |
EP0601317A2 (en) * | 1992-12-04 | 1994-06-15 | Nitto Denko Corporation | Label substrate, ink, and label |
TW310412B (en) * | 1996-07-05 | 1997-07-11 | Hocheng Corp | Barcode label for ceramic products |
US6481353B1 (en) * | 2000-10-31 | 2002-11-19 | International Imaging Materials, Inc | Process for preparing a ceramic decal |
US20030044582A1 (en) * | 2001-08-28 | 2003-03-06 | Sakoske George Emil | Screen printing process |
CN201002378Y (en) * | 2007-01-29 | 2008-01-09 | 上海佳彩包装材料有限公司 | False-proof transfer-printing label for glass and ceramic products |
CN101445324A (en) * | 2007-11-26 | 2009-06-03 | 东进世美肯株式会社 | Low melting point frit paste composition and sealing method for electric element using the same |
JP2011180471A (en) * | 2010-03-03 | 2011-09-15 | Nippon Electric Glass Co Ltd | Laminate sheet for firing, adherend with identification label stuck thereto and method for manufacturing the adherend |
CN105415906A (en) * | 2015-10-20 | 2016-03-23 | 泸州金鑫科技有限公司 | Anti-fake two-dimension code printing process |
CN105819690A (en) * | 2016-03-21 | 2016-08-03 | 江苏高淳陶瓷股份有限公司 | Preparation method of polychrome enamel decor ware |
CN108274911A (en) * | 2018-01-19 | 2018-07-13 | 上海高诚创意科技集团有限公司 | The method that water at low temperature transfers radium-shine marble paper |
CN108284676A (en) * | 2018-02-06 | 2018-07-17 | 上海高诚创意科技集团有限公司 | A kind of transfer of ceramic water has the function of the method for concealed anti-false marble paper |
CN111197269A (en) * | 2018-11-20 | 2020-05-26 | 唐山福来瓷科技有限公司 | Production process of special paper capable of printing ceramic green body and firing two-dimensional code one-dimensional code |
CN110555492A (en) * | 2019-07-15 | 2019-12-10 | 华南理工大学 | Preparation method of high-imitation micro-display two-dimensional code |
Also Published As
Publication number | Publication date |
---|---|
CN112552069A (en) | 2021-03-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106277793B (en) | A kind of glaze of high temperature gold colored glaze face brick, brick and preparation method thereof | |
CN104961502B (en) | A kind of raw material thickness glaze imitates crystallite texture glazed tile and preparation method thereof | |
EP3604258B1 (en) | Method for manufacturing a decorated semi-transparent ceramic sheet | |
CN112499971B (en) | Crystal flash dry particle, crystal flash ceramic tile and preparation method thereof | |
CN109551912A (en) | A kind of ceramic green pasted with high temperature-resistant fires the production technology of two dimensional code or one-dimension code | |
CN114644530B (en) | One-glaze two-side ceramic rock plate, one-glaze two-side transparent glaze and preparation method thereof | |
CN104130024A (en) | High-temperature bright-red printing glaze, preparation method and preparation method of glazed tile | |
CN108129027A (en) | There are the crystallization glazed tile of friable mica effect, parent glaze and preparation method thereof in surface | |
CN105293909B (en) | In-glaze decoration embossment bottom material, in-glaze decoration marble paper and its manufacture craft with its production | |
CN109293399A (en) | One kind having stone pattern embossing feeling dry granular brick and preparation method thereof | |
CN113666774B (en) | Soft-light marble tile with mold effect and preparation method thereof | |
CN105293912B (en) | A kind of glaze brick producing process with matte surface | |
CN114773093B (en) | Dry grain glaze, ceramic tile with time stamp effect and preparation method thereof | |
CN110451802A (en) | A kind of mica sheet decorative porcelain glazed tile and preparation method thereof | |
CN105130193A (en) | Low-temperature matte reaction glaze and production method thereof | |
CN108641483A (en) | A kind of ceramic ink jet printing ink and preparation method thereof promoting color development | |
CN106699146A (en) | Semi-polished ceramic glazed tile having fluorescent effect and manufacturing method thereof | |
CN113716967A (en) | Ceramic tile with flashing effect and preparation method thereof | |
CN108484114A (en) | A kind of glaze Imitation Rock Porcelain Tiles of high additive polished waste material and preparation method thereof | |
CN114149246B (en) | Production method of ceramic with cosmetic clay decoration | |
CN112374762A (en) | Moon white glaze for jun porcelain and preparation method thereof | |
CN106219976A (en) | A kind of combined decoration metallic Ceramic Tiles and manufacture method thereof | |
CN112552069B (en) | Production process for ceramic or glass pasting high-temperature-resistant firing two-dimensional code or one-dimensional code | |
CN108046751A (en) | A kind of ceramic material and its ceramic | |
CN113998993B (en) | Carved stone-like ceramic polished tile and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |