CN108129027A - There are the crystallization glazed tile of friable mica effect, parent glaze and preparation method thereof in surface - Google Patents
There are the crystallization glazed tile of friable mica effect, parent glaze and preparation method thereof in surface Download PDFInfo
- Publication number
- CN108129027A CN108129027A CN201810089354.6A CN201810089354A CN108129027A CN 108129027 A CN108129027 A CN 108129027A CN 201810089354 A CN201810089354 A CN 201810089354A CN 108129027 A CN108129027 A CN 108129027A
- Authority
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- China
- Prior art keywords
- glaze
- crystallization
- frit
- glazed tile
- preparation
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- Granted
Links
- 238000002425 crystallisation Methods 0.000 title claims abstract description 77
- 230000008025 crystallization Effects 0.000 title claims abstract description 77
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- 239000010445 mica Substances 0.000 title claims abstract description 33
- 229910052618 mica group Inorganic materials 0.000 title claims abstract description 33
- 230000000694 effects Effects 0.000 title claims abstract description 27
- 239000013078 crystal Substances 0.000 claims abstract description 42
- 239000007787 solid Substances 0.000 claims abstract description 25
- 238000010304 firing Methods 0.000 claims abstract description 23
- 235000013339 cereals Nutrition 0.000 claims abstract description 10
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 9
- 239000003973 paint Substances 0.000 claims abstract description 9
- 235000009566 rice Nutrition 0.000 claims abstract description 9
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 35
- 239000000843 powder Substances 0.000 claims description 30
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 27
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 26
- 239000000377 silicon dioxide Substances 0.000 claims description 23
- 238000002156 mixing Methods 0.000 claims description 17
- 239000011787 zinc oxide Substances 0.000 claims description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 16
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 15
- 229910052681 coesite Inorganic materials 0.000 claims description 15
- 229910052906 cristobalite Inorganic materials 0.000 claims description 15
- 229910052682 stishovite Inorganic materials 0.000 claims description 15
- 229910052905 tridymite Inorganic materials 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 13
- 229910052593 corundum Inorganic materials 0.000 claims description 13
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 12
- 239000010433 feldspar Substances 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 235000013312 flour Nutrition 0.000 claims description 9
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 8
- 239000004327 boric acid Substances 0.000 claims description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 8
- 238000010791 quenching Methods 0.000 claims description 8
- 230000000171 quenching effect Effects 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- KKKYJLNWARAYSD-UHFFFAOYSA-N hexacalcium;tetraborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] KKKYJLNWARAYSD-UHFFFAOYSA-N 0.000 claims description 7
- 239000010977 jade Substances 0.000 claims description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 6
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 235000019353 potassium silicate Nutrition 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- 239000000454 talc Substances 0.000 claims description 5
- 229910052623 talc Inorganic materials 0.000 claims description 5
- 235000012222 talc Nutrition 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000004568 cement Substances 0.000 claims description 3
- 210000003298 dental enamel Anatomy 0.000 claims description 3
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims description 3
- 238000007688 edging Methods 0.000 claims description 2
- 239000010437 gem Substances 0.000 claims description 2
- 229910001751 gemstone Inorganic materials 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 239000011591 potassium Substances 0.000 claims 3
- 229910052700 potassium Inorganic materials 0.000 claims 3
- 239000000203 mixture Substances 0.000 abstract description 34
- 239000004575 stone Substances 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 8
- 238000005457 optimization Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000008859 change Effects 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 27
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 241000209094 Oryza Species 0.000 description 7
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 5
- 229910000027 potassium carbonate Inorganic materials 0.000 description 5
- VLCQZHSMCYCDJL-UHFFFAOYSA-N tribenuron methyl Chemical compound COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 VLCQZHSMCYCDJL-UHFFFAOYSA-N 0.000 description 5
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000011449 brick Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- YMHOBZXQZVXHBM-UHFFFAOYSA-N 2,5-dimethoxy-4-bromophenethylamine Chemical compound COC1=CC(CCN)=C(OC)C=C1Br YMHOBZXQZVXHBM-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 206010010904 Convulsion Diseases 0.000 description 1
- 206010052128 Glare Diseases 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 238000003854 Surface Print Methods 0.000 description 1
- 241000545067 Venus Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000036461 convulsion Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005713 exacerbation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 230000036449 good health Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
There are the crystallization glazed tile of friable mica effect, parent glaze and preparation method thereof in the surface of the present invention, including frit, parent glaze, crystallization crystal grain and overglaze.The present invention is not on the basis of existing glazed tile production technology is made great change, emphasis is to the formula composition of frit, the formula composition of parent glaze, the formula composition of crystallization crystal grain, the formula composition of overglaze, preferred and firing process optimization of crystallization crystallite size etc., it is in unglazed shape to make glazed tile product surface obtained, finger touches glaze paint smooth, no concave-convex sense, pattern texture is clear, it is natural, imitative stone is true to nature, under light-illuminating, surface shows various crystalline solid not of uniform size such as natural friable mica, these crystalline solid are transparent in the glaze body for being embedded in parent glaze, small person such as needle point, big person's such as grain of rice, and send out the radiance of glittering, as an array of stars to blaze shining in the night sky, with unique decorative and artistry；The technology has stronger universality simultaneously, is easy in industry promote.
Description
Technical field：
The present invention relates to the crystallization glaze paints that the preparing technical field of glazed tile more particularly to a kind of surface have friable mica effect
Brick, parent glaze and preparation method thereof.
Background technology：
Friable mica is the argillaceous limestone of slight silicon, includes iron sulfide crystallization, big person such as walnut, the small person such as grain of rice, shape
It is different, as cameo incrustation is in black jade, as an array of stars to blaze shining in the night sky.Friable mica is also a kind of lucky stone,
Signify opportunity, help and seek wealth, amass great fortunes, and fated high official can virtually be attracted to arrive.In India's legend, friable mica
It is that one kind is made a vow stone, exorcises evil spirits, it is said that long periods of wear has mysterious divinity, have blood pressure lowering, arresting convulsion of calming the nerves
And the effect of improving sleep, it is also one of luck for wealth stone, can promote luck for wealth and focused energy, therefore friable mica is first-class watches
Stone has very high reserve value, is favored by people.But the friable mica place of production is few, storage is rare, expensive, therefore uses
To do the ornament materials of house, then price crosses gold, as can developing this in the Wall or floor tile technology of mass automatic production
There is the crystallization glazed tile product of friable mica effect on kind surface, by the paving of common Wall or floor tile, and coordinates the design of indoor light,
Will necessarily make at home it is rich and honour elegant, the luck for wealth is prosperous, good health and a long life, so as to which the function of glazed tile is increased to a new boundary.
Invention content：
It is an object of the invention to overcome disadvantages mentioned above, crystallization glazed tile, the base that there be friable mica effect on a kind of surface are provided
Plinth glaze and preparation method thereof, on the basis of great change is not made to existing glazed tile production technology, by frit
Formula composition, the formula composition of parent glaze, the formula composition of crystallization crystal grain, the formula composition of overglaze, crystallization crystallite size it is excellent
Choosing, the adjustment of firing process and optimization etc., are permitted so as to which the crystallization glazed tile product surface of preparation be made to be precipitated such as natural friable mica
Many more crystalline solid, the small person of these crystalline solid such as needle point, the big person such as grain of rice are transparent in the glaze body for being embedded in parent glaze,
Unglazed shape is presented in product surface, and it is 7~10 to measure product surface glossiness with WGG60-E4 Grossmeters, and glaze is touched with finger
Face, smooth, no concave-convex sense, under skew ray or light-illuminating, these crystalline solid send out the radiance of glittering, as tiny
Cameo incrustation in black jade, as an array of stars to blaze shining in the night sky, there is unique decorative and artistry, while the skill
Art has stronger universality, is easy in industry promote.
In order to solve the above technical problems, the invention is realized by the following technical scheme：
There is the preparation method of the crystallization glazed tile of friable mica effect on a kind of surface of the present invention, includes the following steps：
A, the preparation of frit：
The weight percent of the component of frit is：
SiO266.8%~67.8%, Al2O38.5%~9.5%, CaO 8.5%~9.5%, MgO 1.5%~
2.5%, K2O 3.6%~4.6%, Na2O 2.4%~3.4%, ZrO23.5%~4.5%, B2O30.8%~1.8%, institute
The sum of some components are 100%；
Granularity containing said components is respectively less than to the raw material of 150 mesh：Silica flour, feldspar powder, alumina powder, calcium carbonate, talcum
Powder, potassium carbonate, sodium carbonate, zirconium English powder and boric acid are melted according to said components range dispensing, mixing machine mixing, frit tank furnace,
1520 DEG C~1540 DEG C of melted temperature range, then water quenching is into frit granules, drying frit；
B, the preparation of parent glaze：
The weight percent of the component of parent glaze is：
SiO240.4%~41.4%, Al2O318%~19%, CaO 9.2%~10.2%, MgO 3%~4%,
K2O 1.8%~2.8%, Na2O 0.6%~1.2%, ZrO26.5%~7.5%, B2O30.4%~1.2%, BaO 2%
~3%, ZnO 7.5%~8.5%, loss on ignition 3%~4%；The sum of all components are 100%；
By the weight percent content of above-mentioned parent glaze component, choose corresponding proportion above-mentioned steps A be prepared it is molten
Block, calcium carbonate, burns talcum, alumina powder, zirconium silicate, barium carbonate, zinc oxide, calcium tetraborate, kaolin and additional at feldspar powder
Weight percent is 0.4%~1% auxiliary material, and it is fine crushing into the sieve that fineness is 325 mesh sieve through ball milling to add suitable water
Remaining is mass percent 0.3%~0.6% and containing the glaze slip that mass percent is 28%~31% moisture, is sieved through removing iron to obtain the final product
Parent glaze；
Wherein additional auxiliary material includes carboxymethyl cellulose, sodium tripolyphosphate and waterglass；
C, the preparation of crystallization crystal grain：
The weight percent of the component of crystallization crystal grain is：
SiO265%~66%, Al2O38%~9%, CaO 11%~12%, MgO 0.2%~0.6%, K2O 5%
~5.8%, Na2O 1.4%~2.2%, ZnO 4.2%~5.2%, B2O31.4%~2.4%, PbO 1.8%~2.6%；
The sum of all components are 100%；
Granularity containing said components is respectively less than to the raw material of 150 mesh：Silica flour, feldspar powder, alumina powder, calcium carbonate, talcum
Powder, potassium carbonate, sodium carbonate, zinc oxide, boric acid and red lead powder, according to said components range dispensing, mixing machine mixing, frit pond
Kiln is melted, and melted temperature range is 1500 DEG C~1520 DEG C, and then water quenching is into particle, then dries, is broken into the mesh of 40 mesh~180
Fine grained to get crystallization crystal grain；
D, the preparation of overglaze, prepares by weight：
1~10 part of the crystallization crystal grain that 100 parts of the parent glaze that above-mentioned steps B is prepared is prepared with above-mentioned steps C,
It is mixed evenly up to overglaze；
E, the preparation and firing of product：
On the glazed tile green body for normally having applied ground-coat enamel, the overglaze that above-mentioned steps D is prepared first is applied, then by print
Flower applies prime cement, enters back into roller kilns glaze firing, ranging from 1125 DEG C~1135 DEG C of maximum sintering temperature, firing time ranging from 45
~90 minutes, and ensure that the firing time of 1020 DEG C~1080 DEG C of temperature regions accounts for the 25% of total firing time, then through overground
While to get finished product.
The invention further relates to the crystallization glazed tiles that there is friable mica effect on a kind of surface, have gold by foregoing surface
The preparation method of the crystallization glazed tile of star stone effect is prepared.
The present invention advanced optimize for：
The crystallization glazed tile finished surface that there is friable mica effect on the surface being prepared is precipitated such as natural friable mica to be permitted
The more crystalline solid, the small person of these crystalline solid such as needle point, the big person such as grain of rice, is transparent in the glaze body for being embedded in parent glaze, into
Unglazed shape is presented in product surface, and it is 7~10 to measure finished surface glossiness with WGG60-E4 Grossmeters, and it is fine and smooth that finger touches glaze paint
Smoothly, no concave-convex sense, under skew ray or light-illuminating, these crystalline solid send out the radiance of glittering, such as a tiny jewel
It is embedded in black jade, as an array of stars to blaze shining in the night sky.
The invention further relates to a kind of preparation method for the parent glaze for being used to prepare crystallization glazed tile, wherein：
The weight percent of the component of parent glaze is：
SiO240.4%~41.4%, Al2O318%~19%, CaO 9.2%~10.2%, MgO 3%~4%,
K2O 1.8%~2.8%, Na2O 0.6%~1.2%, ZrO26.5%~7.5%, B2O30.4%~1.2%, BaO 2%
~3%, ZnO 7.5%~8.5%, loss on ignition 3%~4%；The sum of all components are 100%；
By the weight percent content of above-mentioned parent glaze component, the frit of corresponding proportion, feldspar powder, calcium carbonate, burning are chosen
Talcum, alumina powder, zirconium silicate, barium carbonate, zinc oxide, calcium tetraborate, kaolin and added weight percentage for 0.4%~
1% auxiliary material, add suitable water through ball milling it is fine crushing into fineness be 325 mesh sieve tail over as mass percent 0.3%
~0.6% and containing the glaze slip that mass percent is 28%~31% moisture, it is sieved through removing iron up to parent glaze；Wherein additional is auxiliary
Raw material is helped to include carboxymethyl cellulose, sodium tripolyphosphate and waterglass；
The weight percent of the component of the wherein described frit is：
SiO266.8%~67.8%, Al2O38.5%~9.5%, CaO 8.5%~9.5%, MgO 1.5%~
2.5%, K2O 3.6%~4.6%, Na2O 2.4%~3.4%, ZrO23.5%~4.5%, B2O30.8%~1.8%, institute
The sum of some components are 100%；
Granularity containing said components is respectively less than to the raw material of 150 mesh：Silica flour, feldspar powder, alumina powder, calcium carbonate, talcum
Powder, potassium carbonate, sodium carbonate, zirconium English powder and boric acid are melted according to said components range dispensing, mixing machine mixing, frit tank furnace,
1520 DEG C~1540 DEG C of melted temperature range, then water quenching is into frit granules, drying frit.
The invention further relates to a kind of parent glazes for being used to prepare crystallization glazed tile, are analysed according to being described previously for preparing
The preparation method of the parent glaze of brilliant glazed tile is prepared.
The various crystalline solid such as iron sulfide in natural friable mica of finished surface crystallization prepared by the present invention, these knots
The small person of crystal such as needle point, the big person such as grain of rice, are transparent in the glaze body for being embedded in parent glaze, and unglazed shape is presented in finished surface, use
It is 7~10 that WGG60-E4 Grossmeters, which measures finished surface glossiness, and glaze paint is touched with finger, smooth, no concave-convex sense,
Under skew ray or light-illuminating, these crystalline solid send out the radiance of glittering, as tiny cameo incrustation is in black jade, seem
Shining an array of stars to blaze in the night sky has unique decorative and artistry, while the technology has stronger universality, is easy to
In industry promote.
There are the crystallization glazed tile of friable mica effect, parent glaze and preparation method thereof in a kind of surface of the present invention, by molten
The optimization of block formula composition and parent glaze formula composition：
On the one hand parent glaze is ensure that after high temperature firing, unglazed shape is presented, glossiness only has 7~10, to set off crystallization by contrast
The dazzling starlight of crystal grain；On the other hand, in turn ensure that parent glaze melt body in high temperature has suitable viscosity and melt capacity, it will not
Because the too low melt capacity of viscosity is too strong, crystallization crystal grain is fused into one and lost the precipitation of crystal, while will not be because of viscosity mistake
High melt capacity is too low, and crystallization crystal grain cannot be sunk to due to gravity inside parent glaze closely to be inlayed together with parent glaze,
Crystallization crystal grain is caused to be raised in basic glaze paint, influence product surface smoothness in addition can be insecure because of crystallization die bonder
It is and easy to fall off.Therefore Al is controlled in parent glaze formula composition2O3And SiO2Total content account for parent glaze composition percentage be
58.4%~60.4% and suitable silica alumina ratio, while also added suitable viscosity to glaze melt body and melt capacity rises
The K of adjustment effect2O、Na2O, the oxides such as CaO, MgO, ZnO.Because K2O and Na2O is monovalence network modifying oxide,
In glaze melting process, they have extremely strong " suspension " effect, can significantly reduce the melting temperature and high temperature viscosity of glaze, CaO with
MgO is divalent network modifying oxide, can release free oxygen at high temperature, destroys network structure, makes the reduction of glaze melt viscosity, carries
The mobility of high glaze is good antiflux ingredient, but when temperature reduces, and can connect network breakpoint, make close structure,
Viscosity increases, and accelerates the curing of glaze melt, therefore monovalence network modifying oxide is also controlled in parent glaze formula composition
Ensure that glaze melt has suitable viscosity with the ratio of divalent network modifying oxide.ZnO in glaze there is good help to melt work
With, can play the role of to the mechanical strength of glaze, elasticity, melting behaviour, heat resistance it is good, can also increase in addition glaze into
Ripe temperature range, but dosage should not be excessive, otherwise can improve refractoriness, the viscosity of glaze, while CaO, MgO, ZnO oxide are to nothing
The formation of light glaze also acts as facilitation.In addition, suitable four boron is also added to green state in parent glaze formula composition
On the one hand sour calcium raw material can provide insufficient B in being formed because of frit2O3Ingredient；On the other hand, because calcium tetraborate has low water
Dissolubility through the present inventor the study found that calcium tetraborate is added in green state in parent glaze, is handled by post-production, is had
Slight is precipitated containing boron component, and what is be precipitated forms a kind of good suspension containing boron component and carboxymethyl cellulose and waterglass
Agent, this suspending agent can prevent crystallization crystal grain because than it is great due to the split-phase that generates with parent glaze precipitate, make crystallization crystal grain in base
It is uniformly dispersed in plinth glaze.By the optimization to crystallization crystal grain formula composition, it on the one hand ensure that crystallization crystal grain is forged in high temperature
Highly transparent is presented after burning, so as to not interfere with the integrality of surface printing pattern, otherwise can be hidden due to opacifying power is too strong
Lid printed patterns influence the color development and integrality of product surface pattern；On the other hand also there is strong reflex to light,
Make product under light illumination, these crystallization physical efficiencys being precipitated send out the starlight of glittering.Therefore add in crystallization crystal grain formula composition
Having added in right amount can play the transparency of glaze and glossiness the PbO of strong facilitation.Meanwhile the beginning of crystallization crystal grain and parent glaze
Suitable difference will be had by melting temperature, and it is one that otherwise crystallization crystal grain can melt too low melted completely with parent glaze of temperature in high temperature because of the beginning
Body loses crystalline solid.Therefore Al is controlled in the formula composition of crystallization crystal grain2O3With SiO2Total content, with ensure crystallization crystalline substance
The beginning of grain melts temperature.It is made up of opposite glaze formula and the optimization of crystallization crystallite size, ensure that the crystallization that product surface is precipitated
The large and small distribution of body is no such as an array of stars to blaze shining in the night sky naturally, the natural effect of small person such as needle point, the big person such as grain of rice is presented
The glossiness of product surface then can be excessively influenced because of crystalline solid, so as to lose the effect that powerful contrast is formed with parent glaze, such as
First crystalline solid specification list can seem stiff, lose natural effect.By the optimization to firing process, ensure 1020 DEG C~
The firing time of 1080 DEG C of temperature regions accounts for the 25% of total firing time, on the one hand ensure that crystallization crystal grain can fill in high temperature
Melting is divided to form the vitreum of highly transparent, it is ensured that the transparency and glossiness of crystallization crystal grain, and will not be due to temperature is excessively high
The liquid phase of flowing is formed, in order to avoid fuse into completely in parent glaze and lose crystalline solid；On the other hand, parent glaze melt body is also ensured
Viscosity, enable crystallization crystal grain proportion effect be lowered into parent glaze melt body in inlay naturally, otherwise can be because of temperature
The amount of liquid phase spent in low parent glaze melt body is inadequate, and crystallization crystal grain cannot sink in the melt body of parent glaze and raised in surface influence
The smoothness of product surface；Or because temperature is excessively high, amount of liquid phase is excessive, melt capacity is too strong and melts crystallization crystal grain completely and loses
Crystalline solid；Meanwhile kept the temperature in this region, the growth of crystal in crystallization crystal grain is also helped, forms such as natural friable mica
Crystal as interior iron sulfide crystallization.
It is following excellent that a kind of surface of the present invention has the crystallization glazed tile of friable mica effect, parent glaze and preparation method thereof to have
Point：
1st, due to optimizing the formula of the composition of frit, the formula composition of parent glaze, the formula composition of crystallization crystal grain, overglaze
Composition, preferred, firing process the adjustment of crystallization crystallite size and optimization etc., so as to make the crystallization glazed tile product surface of preparation
Various crystalline solid such as iron sulfide in natural friable mica are precipitated, the small person of these crystalline solid such as needle point, the big person such as grain of rice are in
Transparence is embedded in parent glaze body, and unglazed shape is presented in product surface, and finished surface gloss is measured with WGG60-E4 Grossmeters
It is 7~10 to spend, and glaze surface is touched with finger, smooth, no concave-convex sense, and pattern texture is clear, naturally, imitative stone is true to nature, oblique
Under light or light-illuminating, these crystalline solid send out the radiance of glittering, as tiny cameo incrustation is in black jade, as night
Aerial shining an array of stars to blaze has unique decorative and artistry.
2nd, product surface flatness, the modulus of rupture, flexural strength, resistance to acid and alkali, wearability, radioactivity, the Lead and cadmium
Amount reaches the requirement of GB/T4100-2015, GB6566-2010 and HJ/T297-2006 standard.
3rd, the product uses existing glazed tile production technology, makes under the distinctive illumination of natural friable mica, the vulcanization included
The effect that iron crystalline solid can send out glittering radiance is able to copy on glaze paint brick product, it is easy to accomplish industrialized scale.So as to make
Glaze paint brick product with high-grade decorative while also with ornamental value, collection and friable mica specific functionality, thus
The function of glazed tile is made to be increased to a new boundary.
Description of the drawings：
Fig. 1 is the process flow chart for preparing the crystallization glazed tile that there is friable mica effect on surface of the invention.
Specific embodiment：
The present invention is described in further detail with reference to embodiment.
Embodiment 1
There is the preparation method of the crystallization glazed tile of friable mica effect on a kind of surface, includes the following steps：
A, the preparation of frit：
Chemical composition composition such as the following table 1 of frit：
The chemical composition table (weight percent, %) of table 1, frit
| Component | SiO2 | Al2O3 | CaO | MgO | K2O | Na2O | ZrO2 | B2O3 |
| 1# | 66.8 | 9.5 | 9 | 2.5 | 4.5 | 2.4 | 3.5 | 1.8 |
| 2# | 67.3 | 9 | 9.5 | 1.5 | 4.6 | 2.9 | 3.9 | 1.3 |
| 3# | 67.8 | 8.5 | 8.5 | 2 | 4.5 | 3.4 | 4.5 | 0.8 |
| 4# | 67.8 | 8.7 | 9.2 | 2.2 | 3.6 | 3.2 | 4 | 1.3 |
| 5# | 67.5 | 9.4 | 9.3 | 1.8 | 4.1 | 2.6 | 4.2 | 1.1 |
Prepare frit：The granularity that corresponding proportion is chosen by the chemical composition of table 1 is respectively less than the silica flour of 150 mesh, length
Mountain flour, alumina powder, calcium carbonate, talcum powder, potassium carbonate, sodium carbonate, zirconium English powder, boric acid raw material carry out dispensing, in mixing machine
Mixing is melted in frit tank furnace, and melted temperature range is 1520 DEG C~1540 DEG C, and then water quenching is dried into frit granules
Up to frit.
B, the preparation of parent glaze：
The chemical composition of parent glaze such as the following table 2：
The chemical composition table (weight percent, %) of table 2, parent glaze
| Component | SiO2 | Al2O3 | CaO | MgO | K2O | Na2O | ZrO2 | B2O3 | BaO | Zn0 | Loss on ignition |
| 1# | 40.4 | 19 | 9.7 | 4 | 2.3 | 1.2 | 7.2 | 1.2 | 2.5 | 8.5 | 4 |
| 2# | 40.9 | 19 | 10.2 | 3.5 | 2.7 | 0.9 | 7.5 | 0.8 | 2 | 8.5 | 4 |
| 3# | 41.4 | 19 | 9.2 | 3 | 2.8 | 1.2 | 7.5 | 0.4 | 3 | 8.5 | 4 |
| 4# | 41.4 | 18.5 | 10 | 3.8 | 1.8 | 0.6 | 7.5 | 1 | 3 | 8.4 | 4 |
| 5# | 41.3 | 18 | 10.2 | 4 | 2.6 | 1.2 | 7 | 1.2 | 3 | 8 | 3.5 |
| 6# | 40.8 | 19 | 10.2 | 4 | 2.8 | 1.2 | 6.5 | 1.2 | 3 | 7.5 | 3.8 |
| 7# | 40.4 | 18 | 10.2 | 4 | 2.8 | 1.2 | 7.5 | 1.2 | 3 | 8.5 | 3.2 |
| 8# | 41.2 | 19 | 10.2 | 4 | 2.8 | 1 | 7.3 | 0.9 | 2.8 | 7.8 | 3 |
Prepare parent glaze：By table 2 chemical composition choose corresponding proportion above-mentioned steps A be prepared frit,
Feldspar powder, calcium carbonate burn talcum, alumina powder, zirconium silicate, barium carbonate, zinc oxide, calcium tetraborate, kaolin and outer exacerbation
The auxiliary material that percentage is 0.4%~1% is measured, adds suitable water through ball milling the tailing over for 325 mesh sieve fine crushing into fineness
For mass percent 0.3%~0.6% and containing the glaze slip that mass percent is 28%~31% moisture, it is sieved through removing iron up to base
Plinth glaze；Wherein additional auxiliary material includes carboxymethyl cellulose, sodium tripolyphosphate and waterglass.
The parent glaze is in mat glaze after being burnt at a temperature of 1125 DEG C~1135 DEG C, is measured with WGG60-E4 glossiness
It is 7~10 to measure surface gloss.
Parent glaze in the present invention can also carry out the collocation of corresponding proportion with various common crystallization crystal grain in the art,
Obtain the crystallization glazed tile of different-effect.
C, the preparation of crystallization crystal grain：
The chemical composition of crystallization crystal grain such as the following table 3：
The chemical composition table (weight percent, %) of table 3, crystallization crystal grain
| Component | SiO2 | Al2O3 | CaO | MgO | K2O | Na2O | Zn0 | B2O3 | PbO |
| 1# | 65 | 9 | 11 | 0.4 | 5 | 2.2 | 4.2 | 1.4 | 1.8 |
| 2# | 65.5 | 8.5 | 11.2 | 0.6 | 5 | 1.8 | 4.2 | 1.4 | 1.8 |
| 3# | 66 | 8 | 11 | 0.2 | 5.8 | 1.4 | 4.2 | 1.4 | 2 |
| 4# | 65 | 8 | 11.5 | 0.2 | 5.2 | 1.4 | 4.2 | 1.9 | 2.6 |
| 5# | 65 | 8 | 11 | 0.2 | 5.4 | 1.4 | 4.4 | 2.4 | 2.2 |
| 6# | 65 | 8.1 | 12 | 0.3 | 5 | 1.5 | 4.7 | 1.5 | 1.9 |
| 7# | 65.2 | 8.1 | 11.2 | 0.3 | 5 | 1.5 | 5.2 | 1.5 | 2 |
Prepare crystallization crystal grain：The quartz of 150 mesh is respectively less than by the granularity of the chemical composition selection corresponding proportion of table 3
Powder, feldspar powder, alumina powder, calcium carbonate, talcum powder, potassium carbonate, sodium carbonate, zinc oxide, boric acid, red lead powder raw material, are matched
Material, in mixing machine mixing, be melted in frit tank furnace, melted temperature range is 1500 DEG C~1520 DEG C, then water quenching into
Particle, then dry, be broken into the fine grained of the mesh of 40 mesh~180 to get crystallization crystal grain.
The crystallization crystal grain can be transparent the glaze body for being embedded in parent glaze after 1125 DEG C~1135 DEG C high temperature firings
In, the awns that glares is sent out under light-illuminating, shining is blazed.
D, the preparation of overglaze：
Prepare formula composition ingredient such as the following table 4 of overglaze：
The formula composition component list (parts by weight) of table 4, overglaze
Prepare overglaze：By the formula composition component list of 4 overglaze of table weigh parent glaze that above-mentioned steps B is prepared with it is above-mentioned
The crystallization crystal grain that step C is prepared be mixed together stir evenly up to overglaze it is spare.
E, the preparation of product：
The overglaze that above-mentioned steps D is prepared is applied on the adobe surface for normally having applied ground-coat enamel, is needed further according to product design
Printing ornament is carried out with silk-screen plate or offset printing roller or ink jet printer, then by applying prime cement, enters back into roller kilns glaze firing, highest firing
Temperature range is 1125 DEG C~1135 DEG C, firing time ranging from 45~90 minutes, and ensures 1020 DEG C~1080 DEG C humidity provinces
The firing time in domain accounts for the 25% of total firing time, is then got product by edging.
The present invention has the preparation method of the crystallization glazed tile of friable mica effect, the glazed tile being prepared by above-mentioned surface
Product, surface are seemed in unglazed shape, and it is 7~10 to measure product surface glossiness with WGG60-E4 Grossmeters, product pattern line
It is true to nature to clear clear, imitative stone, touching glaze paint, smooth, no concave-convex sense, and surface with finger is precipitated various such as natural Venus
Crystalline solid in stone as iron sulfide, these crystalline solid are transparent in the glaze body for being embedded in parent glaze, and small person such as needle point, big person are such as
The grain of rice, under skew ray or light-illuminating, these crystalline solid send out the radiance of glittering, as tiny cameo incrustation is in black jade
In, as an array of stars to blaze shining in the night sky, there is unique decorative and artistry.
Product indices such as the following table 5 after testing.
Table 5：Product quality inspection result
In conclusion above-described embodiment is only presently preferred embodiments of the present invention, not make any form to the present invention
On limitation；The those of ordinary skill of all industry can swimmingly implement the present invention by described above；But all to be familiar with sheet special
The technical staff of industry without departing from the scope of the present invention, makes a little using disclosed above technology contents
Perhaps the equivalent variations for changing, modifying and developing are the equivalent embodiment of the present invention；Meanwhile all substantive skills according to the present invention
The change of any equivalent variations, modification and the differentiation that art makees above example, still fall within technical scheme of the present invention
Within protection domain.
Claims (5)
1. there is the preparation method of the crystallization glazed tile of friable mica effect on a kind of surface, it is characterised in that：
It includes the following steps：
A, the preparation of frit：
The weight percent of the component of frit is：
SiO266.8%~67.8%, Al2O38.5%~9.5%, CaO 8.5%~9.5%, MgO 1.5%~2.5%,
K2O 3.6%~4.6%, Na2O 2.4%~3.4%, ZrO23.5%~4.5%, B2O30.8%~1.8%, all groups
/ and be 100%；
Granularity containing said components is respectively less than to the raw material of 150 mesh：Silica flour, feldspar powder, alumina powder, calcium carbonate, talcum powder, carbon
Sour potassium, sodium carbonate, zirconium English powder and boric acid are melted according to said components range dispensing, mixing machine mixing, frit tank furnace, are melted
1520 DEG C~1540 DEG C of temperature range, then water quenching is into frit granules, drying frit；
B, the preparation of parent glaze：
The weight percent of the component of parent glaze is：
SiO240.4%~41.4%, Al2O318%~19%, CaO 9.2%~10.2%, MgO 3%~4%, K2O
1.8%~2.8%, Na2O 0.6%~1.2%, ZrO26.5%~7.5%, B2O30.4%~1.2%, BaO 2%~
3%, ZnO 7.5%~8.5%, loss on ignition 3%~4%；The sum of all components are 100%；
By the weight percent content of above-mentioned parent glaze component, frit, length that the above-mentioned steps A of corresponding proportion is prepared are chosen
Mountain flour, burns talcum, alumina powder, zirconium silicate, barium carbonate, zinc oxide, calcium tetraborate, kaolin and added weight at calcium carbonate
Percentage be 0.4%~1% auxiliary material, add suitable water through ball milling it is fine crushing into fineness be 325 mesh sieve tail over for
Mass percent 0.3%~0.6% and the glaze slip containing mass percent for 28%~31% moisture are sieved through removing iron up to basis
Glaze；
Wherein additional auxiliary material includes carboxymethyl cellulose, sodium tripolyphosphate and waterglass；
C, the preparation of crystallization crystal grain：
The weight percent of the component of crystallization crystal grain is：
SiO265%~66%, Al2O38%~9%, CaO 11%~12%, MgO 0.2%~0.6%, K2O 5%~
5.8%, Na2O 1.4%~2.2%, ZnO 4.2%~5.2%, B2O31.4%~2.4%, PbO 1.8%~2.6%；Institute
The sum of some components are 100%；
Granularity containing said components is respectively less than to the raw material of 150 mesh：Silica flour, feldspar powder, alumina powder, calcium carbonate, talcum powder, carbon
Sour potassium, sodium carbonate, zinc oxide, boric acid and red lead powder are melted according to said components range dispensing, mixing machine mixing, frit tank furnace
System, melted temperature range are 1500 DEG C~1520 DEG C, and then water quenching is into particle, then dry, to be broken into 40 mesh~180 purposes thin
Particle is to get crystallization crystal grain；
D, the preparation of overglaze, prepares by weight：
1~10 part of the crystallization crystal grain that 100 parts of the parent glaze that above-mentioned steps B is prepared is prepared with above-mentioned steps C, mixing
It stirs evenly up to overglaze；
E, the preparation and firing of product：
On the glazed tile green body for normally having applied ground-coat enamel, first apply the overglaze that above-mentioned steps D is prepared, then by stamp, apply
Prime cement enters back into roller kilns glaze firing, ranging from 1125 DEG C~1135 DEG C of maximum sintering temperature, ranging from 45~90 points of firing time
Clock, and ensure 1020 DEG C~1080 DEG C of temperature regions firing time account for the 25% of total firing time, then by edging to get
Finished product.
2. there is the crystallization glazed tile of friable mica effect on a kind of surface, it is characterised in that：
The preparation method for having the crystallization glazed tile of friable mica effect by surface described in claim 1 is prepared.
3. there is the crystallization glazed tile of friable mica effect on surface according to claim 2, it is characterised in that：
The crystallization glazed tile finished surface that there is friable mica effect on the surface being prepared is precipitated various such as natural friable mica
Crystalline solid, the small person of these crystalline solid such as needle point, the big person such as grain of rice are transparent in the glaze body for being embedded in parent glaze, assembled watch
Unglazed shape is presented in face, and it is 7~10 to measure finished surface glossiness with WGG60-E4 Grossmeters, and finger touches glaze paint exquisiteness and puts down
Sliding, no concave-convex sense, under skew ray or light-illuminating, these crystalline solid send out the radiance of glittering, such as a tiny jewel edge
In black jade, as an array of stars to blaze shining in the night sky.
4. a kind of preparation method for the parent glaze for being used to prepare crystallization glazed tile, it is characterised in that：
The weight percent of the component of parent glaze is：
SiO240.4%~41.4%, Al2O318%~19%, CaO 9.2%~10.2%, MgO 3%~4%, K2O
1.8%~2.8%, Na2O 0.6%~1.2%, ZrO26.5%~7.5%, B2O30.4%~1.2%, BaO 2%~
3%, ZnO 7.5%~8.5%, loss on ignition 3%~4%；The sum of all components are 100%；
By the weight percent content of above-mentioned parent glaze component, choose the frit of corresponding proportion, feldspar powder, calcium carbonate, burn talcum,
Alumina powder, zirconium silicate, barium carbonate, zinc oxide, calcium tetraborate, kaolin and added weight percentage are 0.4%~1%
Auxiliary material, add suitable water through ball milling it is fine crushing into fineness be 325 mesh sieve tail over for mass percent 0.3%~
0.6% and containing the glaze slip that mass percent is 28%~31% moisture, it is sieved through removing iron up to parent glaze；Wherein additional auxiliary
Raw material includes carboxymethyl cellulose, sodium tripolyphosphate and waterglass；
The weight percent of the component of the wherein described frit is：
SiO266.8%~67.8%, Al2O38.5%~9.5%, CaO 8.5%~9.5%, MgO 1.5%~2.5%,
K2O 3.6%~4.6%, Na2O 2.4%~3.4%, ZrO23.5%~4.5%, B2O30.8%~1.8%, all groups
/ and be 100%；
Granularity containing said components is respectively less than to the raw material of 150 mesh：Silica flour, feldspar powder, alumina powder, calcium carbonate, talcum powder, carbon
Sour potassium, sodium carbonate, zirconium English powder and boric acid are melted according to said components range dispensing, mixing machine mixing, frit tank furnace, are melted
1520 DEG C~1540 DEG C of temperature range, then water quenching is into frit granules, drying frit.
5. a kind of parent glaze for being used to prepare crystallization glazed tile, it is characterised in that：
The preparation method of the parent glaze according to claim 4 for being used to prepare crystallization glazed tile is prepared.
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| CN110746117A (en) * | 2019-11-13 | 2020-02-04 | 蒙娜丽莎集团股份有限公司 | Colored seeding glaze and positioning crystal ceramic tile prepared by using colored seeding glaze |
| CN110746117B (en) * | 2019-11-13 | 2021-11-16 | 蒙娜丽莎集团股份有限公司 | Colored seeding glaze and positioning crystal ceramic tile prepared by using colored seeding glaze |
| CN111977980A (en) * | 2020-08-31 | 2020-11-24 | 吴利军 | Red copper color crystal glaze and firing method thereof |
| CN111977980B (en) * | 2020-08-31 | 2022-06-03 | 吴利军 | Red bronze crystal glaze and firing method thereof |
| CN112500196A (en) * | 2020-11-25 | 2021-03-16 | 蒙娜丽莎集团股份有限公司 | Ceramic tile with stereoscopic gem particle feeling glaze and preparation method thereof |
| CN113387580A (en) * | 2021-07-14 | 2021-09-14 | 佛山市陶莹新型材料有限公司 | Starlight glaze and preparation method thereof |
| CN113651607A (en) * | 2021-08-12 | 2021-11-16 | 广东宏宇新型材料有限公司 | Ceramic tile with night sky and river decoration effect |
| CN114292131A (en) * | 2021-12-28 | 2022-04-08 | 新明珠集团股份有限公司 | Glazed tile with bright star effect on surface and preparation method thereof |
| CN114276121A (en) * | 2021-12-29 | 2022-04-05 | 新明珠集团股份有限公司 | Ceramic tile with starlight stereoscopic effect and preparation method thereof |
| CN114426397A (en) * | 2022-01-10 | 2022-05-03 | 蒙娜丽莎集团股份有限公司 | Preparation method of snow-powder fritted glaze and ceramic tile with snow-powder effect |
| CN114426397B (en) * | 2022-01-10 | 2023-01-24 | 蒙娜丽莎集团股份有限公司 | Preparation method of snow-powder fritted glaze and ceramic tile with snow-powder effect |
| CN114262208A (en) * | 2022-01-17 | 2022-04-01 | 江西富利高新材料有限公司 | Large-particle dry particle superposed matte glaze ceramic plate and preparation method thereof |
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Denomination of invention: Crystalline glazed tiles with Venus stone effect on the surface, basic glaze and their preparation methods Granted publication date: 20200901 Pledgee: Guangdong Qingyuan Rural Commercial Bank Co.,Ltd. Yuantan Branch Pledgor: GUANGDONG HONGHAI CERAMICS INDUSTRIAL Co.,Ltd. Registration number: Y2024980006544 |