CN107410351B - Regulating agent for grapes - Google Patents
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- CN107410351B CN107410351B CN201710464195.9A CN201710464195A CN107410351B CN 107410351 B CN107410351 B CN 107410351B CN 201710464195 A CN201710464195 A CN 201710464195A CN 107410351 B CN107410351 B CN 107410351B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/08—Amines; Quaternary ammonium compounds containing oxygen or sulfur
- A01N33/10—Amines; Quaternary ammonium compounds containing oxygen or sulfur having at least one oxygen or sulfur atom directly attached to an aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a regulating agent for grapes, which is prepared into a soluble solution, a suspending agent, wettable powder or water dispersible granules by a compound colorant and auxiliary materials, wherein the compound colorant is prepared by uniformly mixing 2, 4-dichlorobenzoyl aminocyclopropionic acid and an active auxiliary agent, and the active auxiliary agent is brassinolide, diethyl aminoethyl hexanoate or yield-increasing amine. The regulating agent disclosed by the invention is safe and efficient, has a good coloring effect on grapes, increases coloring speed, has few side effects, and can improve the quality of the grapes, increase the marketability of the grapes and improve economic benefits.
Description
Technical Field
The invention belongs to the technical field of plant growth regulators, and particularly relates to a regulating agent for grapes.
Background
The grape has a large planting area in China, and is one of the main fruit trees cultivated in China. The color of the grape is an important index of appearance quality, the same variety of the grape can be completely colored, and the color of the grape with the selling price far higher than that of the grape with poor coloring is mainly determined by the content of anthocyanin in the grape peel. Anthocyanin in grape pericarp accumulates from the color-changing period to the maturation period to the maximum. The coloring of grapes is very complex, and factors such as soil organic matter content, soil fertility, tree vigor, hormone secretion level, illumination, temperature, moisture, fruiting amount and the like exist.
At present, apart from enhancing water and fertilizer and illumination management, the research on the application of grape coloring also has wide application range by using plant growth regulators to increase coloring speed, for example, patent CN201310248018.9, and the used plant growth regulators mainly focus on ethephon, abscisic acid and other plant growth regulators. However, a large number of field tests and applications find that the phenomenon that the leaves of the grape trees fall, the fruits crack, the fruit grains are threshed, the fruits are not storage-resistant and the like are easily caused by singly applying the ethephon preparation; abscisic acid is sensitive to light, is unstable and easy to decompose in the using process, is expensive and increases the cost.
Disclosure of Invention
In order to overcome the defects and limitations of the conventional regulator on grape coloring, the invention provides a regulator for grapes, which is convenient to prepare, has lower cost and can ensure that the grapes are safely and uniformly colored.
In order to achieve the purpose, the invention adopts the technical scheme that:
a regulating medicament for grapes is prepared by preparing a soluble solution, a suspending agent, wettable powder or water dispersible granules from a compound colorant and auxiliary materials, wherein the compound colorant is prepared by uniformly mixing 2, 4-dichlorobenzoyl aminocyclopropionic acid and an active auxiliary agent, and the active auxiliary agent is one of brassinolide, diethyl aminoethyl hexanoate and yield-increasing amine (DCPTA);
when the active auxiliary agent is brassinolide, the weight ratio of the 2, 4-dichlorobenzoyl amino cyclopropanecarboxylic acid to the brassinolide in the compound colorant is 1: 0.0001-0.05, and optimally, the weight ratio of the 2, 4-dichlorobenzoyl amino cyclopropanecarboxylic acid to the brassinolide in the compound colorant is 1: 0.001 to 0.005; when the active auxiliary agent is diethyl aminoethyl hexanoate, the weight ratio of the 2, 4-dichlorobenzoyl aminocyclopropionic acid to the diethyl aminoethyl hexanoate in the compound colorant is 1: 0.1 to 0.5; when the active additive is yield-increasing amine, the weight ratio of the 2, 4-dichlorobenzoyl aminocyclopropionic acid to the yield-increasing amine in the compound colorant is 1: 0.1 to 0.5.
Preferably, when the regulating medicament is soluble, the auxiliary material comprises an emulsifier and water; every 100 weight portions of the regulating medicament is prepared from the following raw materials in parts by weight: 1.0001-55 parts of compound colorant, 1-30 parts of emulsifier and the balance of water.
Preferably, each 100 parts by weight of the regulating medicament is prepared from the following raw materials in parts by weight: 5.05-23 parts of compound colorant, 5-15 parts of emulsifier and the balance of water; wherein the emulsifier is one or more of tween-80, alkylphenol polyoxyethylene, octylphenol polyoxyethylene ether and fatty alcohol polyoxyethylene ether.
Preferably, when the regulating medicament is a suspending agent, the auxiliary materials comprise an emulsifier, a thickener, an antifreezing agent and water; every 100 weight portions of the regulating medicament is prepared from the following raw materials in parts by weight: 5.0001-55 parts of compound colorant, 3-20 parts of emulsifier, 0.1-3 parts of thickener, 1-10 parts of antifreeze and the balance of water.
Preferably, each 100 parts by weight of the regulating medicament is prepared from the following raw materials in parts by weight: 5.05-33 parts of compound colorant, 5-10 parts of emulsifier, 0.5-1 part of thickener, 1-5 parts of antifreeze and the balance of water; wherein the emulsifier is one or more of tween-80, alkylphenol polyoxyethylene, octylphenol polyoxyethylene ether and fatty alcohol polyoxyethylene ether; the thickening agent is one or more than two of xanthan gum, sodium carboxymethylcellulose, magnesium aluminum silicate and polyacrylamide; the antifreezing agent is ethylene glycol or urea.
Preferably, when the regulating medicament is wettable powder, the auxiliary materials comprise a dispersing agent, a wetting agent, a disintegrating agent and a carrier; every 100 weight portions of the regulating medicament is prepared from the following raw materials in parts by weight: 0.5001-85 parts of compound colorant, 0.5-20 parts of dispersant, 0.5-10 parts of wetting agent and the balance of carrier.
Preferably, each 100 parts by weight of the regulating medicament is prepared from the following raw materials in parts by weight: 1.0001-85 parts of compound colorant, 1-15 parts of dispersant, 1-5 parts of wetting agent and the balance of carrier; wherein the dispersant is one or more than two of naphthalene sulfonate formaldehyde condensate, polycarboxylate, sodium lignosulfonate and calcium lignosulfonate; the wetting agent is one or more than two of sodium dodecyl sulfate, fatty alcohol-polyoxyethylene ether (wetting penetrating agent JFC) and sulfate anionic compounds; the carrier is one or more than two of kaolin, bentonite, diatomite, calcium carbonate, white carbon black and attapulgite.
Preferably, when the regulating medicament is water dispersible granules, the auxiliary materials comprise a dispersing agent, a wetting agent, a disintegrating agent and a carrier, and each 100 parts by weight of the regulating medicament is prepared from the following raw materials in parts by weight: 0.501-85 parts of compound colorant, 0.5-20 parts of dispersant, 0.5-10 parts of wetting agent, 3-20 parts of disintegrating agent and the balance of carrier.
Preferably, the regulating medicament is prepared from the following raw materials in percentage by weight: 1.001-85 parts of compound colorant, 1-15 parts of dispersant, 1-5 parts of wetting agent, 5-10 parts of disintegrating agent and the balance of carrier; wherein the dispersant is one or more than two of naphthalene sulfonate formaldehyde condensate, polycarboxylate, sodium lignosulfonate and calcium lignosulfonate; the wetting agent is one or more than two of sodium dodecyl sulfate, fatty alcohol-polyoxyethylene ether and sulfate anionic compounds; the disintegrating agent is one or more than two of ammonium sulfate, sodium sulfate and soluble starch; the carrier is one or more than two of kaolin, bentonite, diatomite, calcium carbonate, white carbon black and attapulgite.
Except for 2, 4-dichlorobenzamide cyclopropanecarboxylic acid, the raw materials are all common commercial products, wherein the naphthalene sulfonate formaldehyde condensate can be selected from Morwet D425, benzyl naphthalene sulfonate formaldehyde condensate (dispersant CNF), formaldehyde condensate of methyl sodium naphthalene sulfonate (dispersant MF) and sodium salt of 2-naphthalene sulfonate formaldehyde polymer (dispersant NNO), the polycarboxylate can be selected from Terspersese 2700 and Geropon T/36, and the alkyl naphthalene sulfonate can be selected from isopropyl naphthalene sulfonate, diisobutyl naphthalene sulfonate and Morwet EFW.
The preparation method of the 2, 4-dichlorobenzamide cyclopropanecarboxylic acid comprises the following steps:
(1) under the condition of ice-water bath, dropwise adding a toluene solution of thionyl chloride into a toluene solution of 2, 4-dichlorobenzoic acid, heating and refluxing for 6-10 hours, concentrating under reduced pressure, and evaporating the solvent to dryness to obtain 2, 4-dichlorobenzoyl chloride;
(2) dissolving 1-aminocyclopropionic acid and sodium hydroxide in water, adding the 2, 4-dichlorobenzoyl chloride obtained in the step (1) at room temperature, stirring for 7-15 hours, filtering, adding concentrated hydrochloric acid into the filtrate, filtering again, and drying the solid to obtain the compound preparation;
wherein the mass ratio of the 2, 4-dichlorobenzoic acid to the thionyl chloride to the 1-aminocyclopropionic acid to the sodium hydroxide is 5.8: 6.5-7.5: 9.5-10.5: 7.5 to 8.5.
The synthetic route is as follows:
when the regulating agent is used, the regulating agent can be sprayed on the whole plant or sprayed or soaked on the fruit cluster according to the local climate and the water and fertilizer conditions of crops.
The 2, 4-dichlorobenzamide cyclopropanecarboxylic acid belongs to an anti-adversity inducer, has the similar effect as the elicitor, has good coloring effect on the grapes, increases coloring speed, has less side effect, can improve the quality of the grapes, increases the commodity of the grapes and improves economic benefit; it also can cause the generation of ethylene in the plant, and indirectly promote the coloring of the fruits such as grape. The invention adopts the 2, 4-dichlorobenzamide cyclopropanecarboxylic acid and the active auxiliary agent (brassinolide/diethyl aminoethyl hexanoate/yield-increasing amine) to be used together, is safer and more efficient, and plays an important role in improving the fruit quality.
Drawings
FIG. 1 is a graph of the coloring effect of grapes after administration.
Detailed Description
In order to make the technical purpose, technical solutions and advantages of the present invention clearer, the technical solutions of the present invention are further described with reference to specific examples, which are intended to explain the present invention and are not to be construed as limiting the present invention, and those who do not specify a specific technique or condition in the examples follow the techniques or conditions described in the literature in the art or follow the product specification.
The 2, 4-dichlorobenzamide cyclopropanecarboxylic acid described in the following examples was prepared using the following procedure:
(1) dissolving 0.58 g of 2, 4-dichlorobenzoic acid in 20 mL of toluene to obtain a toluene solution of 2, 4-dichlorobenzoic acid, dissolving 0.71 g of thionyl chloride in 10 mL of toluene to obtain a toluene solution of thionyl chloride, dropwise adding the toluene solution of thionyl chloride into the toluene solution of 2, 4-dichlorobenzoic acid under the condition of ice-water bath, heating and refluxing for 8 hours, concentrating under reduced pressure after the reaction is finished, and evaporating the solvent and residual thionyl chloride to obtain yellow oily liquid, namely 2, 4-dichlorobenzoyl chloride;
(2) adding 1.0 g of 1-aminocyclopropionic acid, 0.8g of sodium hydroxide and 30 mL of deionized water into a 100 mL round-bottom flask with a thermometer, uniformly stirring, dropwise adding the 2, 4-dichlorobenzoyl chloride obtained in the step (1) at room temperature, stirring for reacting for 7-13 hours after dropwise adding, carrying out suction filtration, adding concentrated hydrochloric acid into filtrate to separate out a large amount of solids, filtering, and drying filter residues to obtain a white solid, namely the 2, 4-dichlorobenzoyl aminocyclopropionic acid.
Example 1
A regulating medicament for grapes is prepared from the following raw materials in parts by weight per 100 parts by weight: 5.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 0.005 parts of brassinolide, 803 parts of tween-803, and the balance of a solvent, wherein the solvent is prepared from ethanol and water according to a mass ratio of 50: 42 are mixed evenly.
Weighing the raw materials according to the proportion, adding the raw materials into a stirring tank, completely dissolving, and detecting to be qualified to obtain the regulating agent capable of being in a solution dosage form.
Example 2
A regulating medicament for grapes is prepared from the following raw materials in parts by weight per 100 parts by weight: 10.0 parts of 2, 4-dichlorobenzoyl amino cyclopropanecarboxylic acid, 0.01 part of brassinolide, 803 parts of tween-803, 0.2 part of xanthan gum, 1.0 part of magnesium aluminum silicate, 5.0 parts of glycol and the balance of water.
Weighing the raw materials according to the proportion, adding the raw materials into a stirring tank, uniformly mixing and shearing, circulating through a sand mill for 3 times, grinding to obtain a qualified particle size, and detecting to obtain the suspension type regulating agent.
Example 3
A regulating medicament for grapes is prepared from the following raw materials in parts by weight per 100 parts by weight: 10.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 0.05 part of brassinolide, 4 parts of dispersing agent MF, 5 parts of calcium lignosulphonate, 1.5 parts of sodium dodecyl sulfate, 6 parts of ammonium sulfate, 3 parts of soluble starch and the balance of kaolin.
Weighing the raw materials according to the proportion, mixing the raw materials in a cone mixer for 30min, passing through an airflow pulverizer, pulverizing to 95 percent, passing through a 400-mesh sieve, adding about 10 percent of water, uniformly stirring, putting into an extrusion granulator for granulation, and detecting after drying the granules to obtain the regulating medicament of the water dispersible granule formulation.
Example 4
The regulating agent for the grapes is wettable powder, and every 100 parts by weight of the regulating agent is prepared from the following raw materials in parts by weight: 10.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 0.03 part of brassinolide, 5.0 parts of dispersant NNO, 1.0 part of sodium dodecyl sulfate and the balance of bentonite.
Example 5
A regulating medicament for grapes is soluble and is prepared from the following raw materials in parts by weight per 100 parts by weight: 20.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 10 parts of diethyl aminoethyl hexanoate, 10 parts of fatty alcohol-polyoxyethylene ether and the balance of a solvent, wherein the solvent is prepared from ethanol and water according to a mass ratio of 50: 42 are mixed evenly.
Example 6
The regulating medicament for the grapes is in a suspension type, and each 100 parts by weight of the regulating medicament is prepared from the following raw materials in parts by weight: 40.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 12 parts of diethyl aminoethyl hexanoate, 5 parts of alkylphenol polyoxyethylene, 0.5 part of sodium carboxymethyl cellulose, 1.0 part of urea and the balance of water.
Example 7
The regulating medicament for the grapes is water dispersible granules, and each 100 parts by weight of the regulating medicament is prepared from the following raw materials in parts by weight: 60.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 12 parts of diethyl aminoethyl hexanoate, 1 part of dispersing agent MF, 5 parts of lauryl sodium sulfate, 5 parts of soluble starch and the balance of light calcium carbonate.
Example 8
The regulating agent for the grapes is wettable powder, and every 100 parts by weight of the regulating agent is prepared from the following raw materials in parts by weight: 80.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 8 parts of diethyl aminoethyl hexanoate, 5.0 parts of dispersant NNO, 1.0 part of sodium dodecyl sulfate and the balance of diatomite.
Example 9
A regulating medicament for grapes is soluble and is prepared from the following raw materials in parts by weight per 100 parts by weight: 20.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 10 parts of yield-increasing amine, 10 parts of tween-8015 parts and the balance of a solvent, wherein the solvent is prepared from ethanol and water according to a mass ratio of 50: 42 are mixed evenly.
Example 10
The regulating medicament for the grapes is in a suspension type, and each 100 parts by weight of the regulating medicament is prepared from the following raw materials in parts by weight: 40.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 12 parts of yield-increasing amine, 0 part of tween-8010 part, 0.2 part of xanthan gum, 1.0 part of magnesium aluminum silicate, 5.0 parts of ethylene glycol and the balance of water.
Example 11
The regulating medicament for the grapes is water dispersible granules, and each 100 parts by weight of the regulating medicament is prepared from the following raw materials in parts by weight: 50.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 12 parts of yield-increasing amine, 5 parts of dispersing agent MF, 5 parts of calcium lignosulphonate, 5 parts of sodium dodecyl sulfate, 5 parts of ammonium sulfate, 5 parts of soluble starch and the balance of attapulgite.
Example 12
The regulating agent for the grapes is wettable powder, and every 100 parts by weight of the regulating agent is prepared from the following raw materials in parts by weight: 10.0 parts of 2, 4-dichlorobenzoyl aminocyclopropionic acid, 5 parts of yield-increasing amine, 20.0 parts of dispersant NNO, 10.0 parts of sodium dodecyl sulfate and the balance of white carbon black.
Test of field drug effect
Test time: year 2017, month 3.
Test site: yunnan, red river.
Test agents: the modulating agent prepared in example 2 (denoted as agent one); a ethephon aqua (marked as agent II) with the mass fraction of 40 percent; 5% of S-abscisic acid (marked as medicament III). The dilution treatment for the administration of the different agents is shown in table 1.
And (3) test crops: grapes; the grape variety is summer black, grows for 3 years, has a plant spacing of 80cm and a row spacing of 1.5m, and is applied when the transverse diameter of fruit grains is 10-12mm in the early coloring stage.
The application time is as follows: 2017.3.7, respectively; the application times are as follows: it is used once in the whole growth period.
16 days after the application, the content of soluble solids in the fruit granules is detected, and the result is shown in table 2; and the phytotoxicity performance was examined, and the results are shown in table 3.
Table 1 different agent treatments
TABLE 2 soluble solids content 16 days after dosing
TABLE 3 drug injury Performance of each drug
The following coloration criteria were followed:
level 0: completely green;
level 1: coloring a little, wherein pink fruit grains account for 1% -10% of the whole ear;
and 2, stage: the colored fruit grains (pink) account for 10-50% of the fruit cluster;
and 3, level: the colored fruit grains account for 50-100% of the whole spike;
4, level: all are colored. Part of black fruit grains appear, and the black fruit grains account for 1-50% of the whole ear;
and 5, stage: the total colored brown fruit grains are more and account for 50-100% of the total spike.
The coloring effect of grapes after application is shown in fig. 1, in which it can be seen that grapes applied according to number 2 were all colored at grade 5, grapes applied according to number 4 were grade 3, and grapes treated with water were grade 1 16 days after application.
Through tests, examples 1 and 3 to 12 all have the coloring effect equivalent to that of example 2.
In conclusion, the regulating medicament can obviously promote the coloring of summer black grapes, can color 50% of the grapes after 6 days, and can completely mature the grapes after 16 days, increase the color blackening fruit powder, improve the solid content to 19.2% and obviously increase the fruit quality compared with a blank control.
Claims (8)
1. A regulating agent for grapes is characterized in that a compound colorant and auxiliary materials are prepared into a soluble solution, a suspending agent, wettable powder or water dispersible granules, the compound colorant is prepared by uniformly mixing 2, 4-dichlorobenzoyl aminocyclopropionic acid and an active auxiliary agent, and the active auxiliary agent is brassinolide, diethyl aminoethyl hexanoate or yield-increasing amine; when the active auxiliary agent is brassinolide, the weight ratio of the 2, 4-dichlorobenzoyl amino cyclopropanecarboxylic acid to the brassinolide in the compound colorant is 1: 0.001 to 0.005; when the active auxiliary agent is diethyl aminoethyl hexanoate, the weight ratio of the 2, 4-dichlorobenzoyl aminocyclopropionic acid to the diethyl aminoethyl hexanoate in the compound colorant is 1: 0.1 to 0.5; when the active additive is yield-increasing amine, the weight ratio of the 2, 4-dichlorobenzoyl aminocyclopropionic acid to the yield-increasing amine in the compound colorant is 1: 0.24 to 0.5.
2. The conditioning agent for grapes according to claim 1, characterized in that: when the regulating medicament is soluble, the auxiliary materials comprise an emulsifier and a solvent; every 100 weight portions of the regulating medicament is prepared from the following raw materials in parts by weight: 5.05-23 parts of compound colorant, 5-15 parts of emulsifier and the balance of water; wherein the emulsifier is one or more of tween-80, alkylphenol polyoxyethylene and fatty alcohol polyoxyethylene.
3. The conditioning agent for grapes according to claim 1, characterized in that: when the regulating agent is a suspending agent, the auxiliary materials comprise an emulsifier, a thickening agent, an antifreezing agent and water; every 100 weight portions of the regulating medicament is prepared from the following raw materials in parts by weight: 5.0001-55 parts of compound colorant, 3-20 parts of emulsifier, 0.1-3 parts of thickener, 1-10 parts of antifreeze and the balance of water.
4. The regulating agent for grapes according to claim 3, characterized in that, per 100 parts by weight of regulating agent, it is made from the following raw materials: 5.05-33 parts of compound colorant, 5-10 parts of emulsifier, 0.5-1 part of thickener, 1-5 parts of antifreeze and the balance of water; wherein the emulsifier is one or more of tween-80, alkylphenol polyoxyethylene and fatty alcohol polyoxyethylene ether; the thickening agent is one or more than two of xanthan gum, sodium carboxymethylcellulose, magnesium aluminum silicate and polyacrylamide; the antifreezing agent is ethylene glycol or urea.
5. The conditioning agent for grapes according to claim 1, characterized in that: when the regulating agent is wettable powder, the auxiliary materials comprise a dispersing agent, a wetting agent and a carrier; every 100 weight portions of the regulating medicament is prepared from the following raw materials in parts by weight: 0.5001-85 parts of compound colorant, 0.5-20 parts of dispersant, 0.5-10 parts of wetting agent and the balance of carrier.
6. The regulating agent for grapes according to claim 5, characterized in that, per 100 parts by weight of regulating agent, it is made from the following raw materials: 1.0001-85 parts of compound colorant, 1-15 parts of dispersant, 1-5 parts of wetting agent and the balance of carrier; wherein the dispersant is one or more than two of naphthalene sulfonate formaldehyde condensate, polycarboxylate, sodium lignosulfonate and calcium lignosulfonate; the wetting agent is one or more than two of sodium dodecyl sulfate, fatty alcohol-polyoxyethylene ether and sulfate anionic compounds; the carrier is one or more than two of kaolin, bentonite, diatomite, calcium carbonate, white carbon black and attapulgite.
7. The conditioning agent for grapes according to claim 1, characterized in that: when the regulating medicament is water dispersible granules, the auxiliary materials comprise a dispersing agent, a wetting agent, a disintegrating agent and a carrier, and each 100 parts by weight of the regulating medicament is prepared from the following raw materials in parts by weight: 0.501-85 parts of compound colorant, 0.5-20 parts of dispersant, 0.5-10 parts of wetting agent, 3-20 parts of disintegrating agent and the balance of carrier.
8. The conditioning agent for grapes according to claim 7, characterized in that: the regulating medicament is prepared from the following raw materials in percentage by weight: 1.001-85 parts of compound colorant, 1-15 parts of dispersant, 1-5 parts of wetting agent, 5-10 parts of disintegrating agent and the balance of carrier; wherein the dispersant is one or more than two of naphthalene sulfonate formaldehyde condensate, polycarboxylate, sodium lignosulfonate and calcium lignosulfonate; the wetting agent is one or more than two of sodium dodecyl sulfate, fatty alcohol-polyoxyethylene ether and sulfate anionic compounds; the disintegrating agent is one or more than two of ammonium sulfate, sodium sulfate and soluble starch; the carrier is one or more than two of kaolin, bentonite, diatomite, calcium carbonate, white carbon black and attapulgite.
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| CN201710464195.9A CN107410351B (en) | 2017-06-19 | 2017-06-19 | Regulating agent for grapes |
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| CN112825862B (en) * | 2020-12-31 | 2022-03-22 | 郑州郑氏化工产品有限公司 | Functional composition suitable for coloring various fruits and method for promoting fruit coloring |
| CN113317322B (en) * | 2021-06-18 | 2022-04-05 | 郑州郑氏化工产品有限公司 | Soluble solution containing aryl formamide cyclopropanecarboxylic acid and preparation method thereof |
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| CN1765182A (en) * | 2005-09-09 | 2006-05-03 | 南京农业大学 | Method for promoting fruit coloration |
| CN102057906A (en) * | 2010-12-10 | 2011-05-18 | 常大勇 | Fruit coloring adjunct and method for promoting fruit coloring with same |
| CN102391147A (en) * | 2011-09-27 | 2012-03-28 | 中国农业大学 | Preparation and activity of aryl formyl amino cyclopropanecarboxylic acid |
| CN104094971A (en) * | 2014-07-25 | 2014-10-15 | 江苏农林职业技术学院 | Cultivating method used for coloring grape fruit |
| CN104430339A (en) * | 2014-12-19 | 2015-03-25 | 山东奥维特生物科技有限公司 | Abscisic acid composition for coloring grapes |
| CN105341001A (en) * | 2015-12-15 | 2016-02-24 | 界首市鲜天下家庭农场 | Agent for promoting grape coloring and production increase |
| CN106386816A (en) * | 2016-08-31 | 2017-02-15 | 四川龙蟒福生科技有限责任公司 | Composition, preparation and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02270802A (en) * | 1989-04-12 | 1990-11-05 | Kyowa Hakko Kogyo Co Ltd | Method for promoting coloring of grape |
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2017
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| CN1765182A (en) * | 2005-09-09 | 2006-05-03 | 南京农业大学 | Method for promoting fruit coloration |
| CN102057906A (en) * | 2010-12-10 | 2011-05-18 | 常大勇 | Fruit coloring adjunct and method for promoting fruit coloring with same |
| CN102391147A (en) * | 2011-09-27 | 2012-03-28 | 中国农业大学 | Preparation and activity of aryl formyl amino cyclopropanecarboxylic acid |
| CN104094971A (en) * | 2014-07-25 | 2014-10-15 | 江苏农林职业技术学院 | Cultivating method used for coloring grape fruit |
| CN104430339A (en) * | 2014-12-19 | 2015-03-25 | 山东奥维特生物科技有限公司 | Abscisic acid composition for coloring grapes |
| CN105341001A (en) * | 2015-12-15 | 2016-02-24 | 界首市鲜天下家庭农场 | Agent for promoting grape coloring and production increase |
| CN106386816A (en) * | 2016-08-31 | 2017-02-15 | 四川龙蟒福生科技有限责任公司 | Composition, preparation and application thereof |
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