A kind of composition pesticide containing Benfuracard micro and its application
Technical field
A kind of composition pesticide of the present invention, more particularly to a kind of composition pesticide containing Benfuracard micro and its
The application of crops root-knot nematodes is prevented and treated, belongs to technical field of pesticide.
Background technology
Plant nematode mainly includes:Meloidogyne (Meloidogyne), kidney shape turbatrix
(Rotylenchulus), cyst roundworm (Heterodera (Heterodera)), root spot nematode (Pratylenchus
(Pratykenchus)).Eelworm harm influences the absorption of Plant To Nutrient and moisture, returns phytopathogen invasion and provides just
Profit.At present, problems be present in the chemical agent for preventing and treating root-knot nematode:(1) residues of pesticides are high, and (2) input cost is high, and (3) are anti-
Effect is not notable enough, and (4) have much room for improvement to the yield and quality of crop.
Benfuracard micro is carbofuran low toxicityization derivative, and insecticidal effect is close to carbofuran, but toxicity only has carbofuran
1/10th.It is a kind of wide spectrum, systemic insecticide, suitable for rice, corn and soybean, potato, sugarcane, cotton, vegetable
The crops such as dish, fruit tree, prevent and treat various pests.
Tioxazafen, chemical name:3- phenyl -5- (thiophene -2- bases) -1,2,4- oxadiazoles.Meng Shan is opened for 2008
The non-stifling property nematode agent of hair, because its is more environmentally friendly, use is safer, and the influence to people is smaller, and the ideal for being described as lythidathion is replaced
Dai Pin, indoor and field experiment show, the reference product of the performance of the new nematicide equivalent to or better than current commercialization.
It is reported that tioxazafen is to the soy bean cyst roundworm of soybean, root-knot nematode, kidney shape nematode, and the pratylenchus on corn, root knot
The phytopathy original nematode such as nematode, long line worm, kidney shape nematode, root-knot nematode on cotton is respectively provided with fabulous bioactivity.
Up to now, there is not yet Benfuracard micro and the open source literature of tioxazafen compoundings.
The content of the invention
It is an object of the invention to provide a kind of composition pesticide containing Benfuracard micro, help to delay nematode to produce
Resistance, improve prevention effect, reduce effective ingredient consumption and use cost etc..
Inventor after a large amount of Seiving Tests, is having been surprisingly found that Benfuracard micro and tioxazafen by certain ratio
After example mixture, there is notable synergistic effect to plant root-knot nematode, with obtainable can be prevented and treated using only single active component
Effect is compared, and is used in mixed way and more preferable prevention effect is provided to parasitic nematode.
The present composition has synergistic function, and is therefore particularly suitable for preventing and treating plant nematode, especially
In vegetables, fruit tree, medicinal plant, cereal crop, oil crops, sugar crop, cotton crudefiber crop, gardening gardens class plant
Parasitic nematode.
Composition pesticide provided by the invention, it is characterised in that:Contain active ingredient Benfuracard micro and tioxazafen.
Both mass ratioes are 1:50-50:1, preferred mass ratio is 1:30-30:1, more preferably mass ratio is 1:10-10:1.
The present composition can also prevent and treat various crops such as vegetables, and (such as cucumber, beans, tomato, potato and Curcurbitaceae are planted
Thing), it is banana, pseudo-ginseng, coffee, corn, fruits, rice, wheat, barley, oat, rye, soybean, peanut, ornamental plant, sweet
Harmful organism on the plant such as sugarcane, cotton and in seed.
The present composition is particularly suitable for preventing and treating plant nematode, such as Pratylenchidae (Pratykenchus
Spp), Radopholus similis Throne (Radopholous similis), fuller's teasel Ditylenchus dipsaci (Ditylenchus dipsaci), partly wear
Pierce nematode (Tylenchulus semipenetrans), Heterodera kind (Heterodera spp.), ball Heterodera
Kind (Globodera spp.), Meloidogyne kind (Meloidogyne spp.), kidney shape turbatrix kind (Rotylenchulus
Spp.), Aphelenchoides kind (Aphelenchoides spp.), minute hand Turbatrix kind (Longidorus spp.), sword nematode
Category kind (Xiphinema spp.), burr Turbatrix kind (Trichodorus spp.), Bursaphelenchus kind
(Bursaphelenchus spp.)。
It is preferred that the present composition is used to prevent and treat the oil crops such as vegetables, fruit tree, medicinal plant, soybean and peanut, standing grain
The nematodiasis of cereal, rice, wheat, cotton, flowers etc., as cucumber root-knot nematode, tomato root-knot eelworm, capsicum root-knot nematode,
Citrus root-knot nematode, soy bean cyst roundworm, peanut root-knot nematode etc..
The present composition can be prepared into the formulation of suitable agricultural use with known method, active ingredient in preparation
Total content is 5%-80%, and remaining is pesticide adjuvant composition.
The composition pesticide of the present invention can be formulated as spraying or carrying out soil or the particle of seed treatment after being available for dilution
Agent, water dispersible granules, suspending agent, microemulsion, aqueous emulsion, microcapsule suspending agent and suspension seed-coating agent.
Preparation is prepared in a known way, such as is prepared by the way that active component is mixed with solvent and/or carrier, if desired
If use other pesticide adjuvant compositions such as emulsifying agent and dispersant.
Insecticide-applying way can take spraying, pouring root, soak seed, get rid of and apply, spread fertilizer over the fields, ditch spread, spreading manuer in holes, preferred ditch when preventing and treating nematode
Apply, spread manuer in holes, the soil treatment such as pouring root or leaching root, seed soaking, seed pelleting processing.
Compared with prior art, had the beneficial effect that caused by composition pesticide of the present invention:(1) compared with single dose, synergy is bright
It is aobvious, improve prevention effect;(2) field dosage can be greatly decreased, reduce the possibility for causing poisoning, poisoning, reduce life
Production and use cost, and can effectively reduce environmental pollution and residues of pesticides;(3) mechanism of action of active ingredient is mutual not in composition
It is identical, the single selection pressure to nematode is reduced, is advantageous to overcome nematode resistance to produce and delay the drug-fast generation of nematode
Speed;(4) nematicidal composition has good preventive effect to all kinds of nematodes.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, present invention specific examples below
Illustrate, but the present invention is only limited to absolutely not these examples.
The synergistic function of the present composition can pass through following experiment explanation:
Assays Example:Benfuracard micro compounds the Toxicity Determination to cucumber root-knot nematode with tioxazafen
Experiment
Subjects:Meloidogyne incognita (Meloidogyne incognita)
Evaluation method is pot-culture method.The pieces of an egg aseptic water washing of picking root-knot nematode, is placed in culture dish from tomato root
Wet filter paper on, add 20ml sterilized waters, hatch at 20 DEG C -25 DEG C, obtain age consistent 2 instar larvaes, diluted with sterilized water
To 200/ml.2 instar larvaes are inoculated with the leaf phase of cucumber two, using root injection method, take 5ml nematodes inoculation liquid to inject rhizosphere soil
It is interior, 24h soil conservations 70%-80% humidity after inoculation.It is standby after cucumber inoculation root-knot nematode.
Active component is made into mother liquor after dissolving on request, being then diluted to suitable concentration with purified water carries out root irrigation.
Cucumber seedling is placed in phjytotron after chemicals treatment, then 25-30 DEG C, 12h alternation of light and darkness, relative humidity 35%-
30d is cultivated under the conditions of 50%.Each to repeat the basin of random searching 4, each processing amounts to 16 basin cucumber of investigation.Grade scale is in
Magnificent people's republic's national standard《Pesticide field efficacy medicine test criterion (one)》.
Diseased plant stage division is as follows:
0 grade:Root system is without insect gall;
1 grade:Root system has a small amount of small insect gall;
3 grades:2/3rds root systems are covered with small insect gall;
5 grades:Root system is covered with small insect gall and has secondary insect gall;
7 grades:Root system forms fibrous root group;
Computational methods:
The expection effect (i.e. theoretical prevention effect, %) of mixture of active principles determined using Colby formula and with observation
To effect compare:
Colby formula:E=X+Y-X*Y/100
E:When active components A concentration is a in composition, compositions contemplated when active component B concentrations are b is imitated
Power,
X:Effect when active components A dosage is a;
Y:Effect when active component B dosages are b.
When the prevention effect observed exceedes expected preventive effect, explanation has synergistic effect.
Benfuracard micro and tioxazafen compounding to cucumber root tie lines worm indoor virulence determination test result referring to table 1,
2。
Toxicity Determination result of the test of the 1. single active component of table to cucumber root-knot nematode
The Benfuracard micro of table 2. and tioxazafen compound the Toxicity Determination result of the test to cucumber root-knot nematode
Result of the test shows, Benfuracard micro and tioxazafen compounding preventing and treating cucumber root-knot nematodes, matches 50:1-1:
When between 50, all with synergistic effect.
Composition pesticide of the present invention can be prepared into granule, the water-dispersible grain of suitable agricultural use with known method
Agent, suspending agent, microemulsion, aqueous emulsion, microcapsule suspending agent and suspension seed-coating agent.Illustrated, be formulated with specific embodiment below
Middle percentage is mass percent.Active component refers to Benfuracard micro and tioxazafen, active component in present specification
100% purity meter is pressed, in the application of reality, is converted according to active compound actual purity used, difference filler or dilution
Agent adjusts, and below repeats no more.
First, suspending agent processing and application example
The each components such as active component, wetting dispersing agent, thickener, carrier and water are well mixed in the ratio of formula, passed through
Suspending agent is obtained after grinding and/or high speed shear.
Embodiment 1:51% Benfuracard micro tioxazafen suspending agents Benfuracard micro 50%, tioxazafen
1%, methyl naphthalene sulfonate formaldehyde condensate 10%, sodium lignin sulfonate 10%, xanthans 1%, organosilicon 1%, glycerine
5%, water complements to 100%.
The embodiment is applied to preventing and treating capsicum root knot nematode disease.51% Benfuracard micro tioxazafen suspending agents are pressed
Effective ingredient consumption 200g a.i./hm2With being diluted with water leaching, the prevention effect of 30 days and 60 days is respectively 84.2% He after medicine
81.3%.The Benfuracard micro suspending agent of comparison medicament 5% and 10%tioxazafen suspending agents press effective ingredient consumption 225g
a.i./hm2, in kind use.The preventive effect of 30 days and 60 days is respectively 67.6% He after 5% Benfuracard micro suspending agent medicine
61.8%;The preventive effect of 30 days and 60 days is respectively 74.5% and 70.8% after 10%tioxazafen suspending agent medicines.Rosickyite gram hundred
Synergistic effect is obvious after prestige compounds with tioxazafen, is significantly better than single dose to the preventive effect of capsicum root-knot nematode.
The Benfuracard micro tioxazafen suspending agents of embodiment 2 51%
Benfuracard micro 1%, tioxazafen 50%, thermally coupled distillation columns 8%, carboxymethyl cellulose
1%, white carbon 1%, glycerine 4%, water complements to 100%.
The embodiment is applied to preventing and treating tomato root-knot eelworm.By 51% Benfuracard micro tioxazafen suspending agents by having
Imitate Ingredient Amount 200g a.i./hm2It is diluted with water carry out root irrigation, the prevention effect of 30 days and 60 days is respectively after medicine
84.1% and 81.5%.The Benfuracard micro suspending agent of comparison medicament 5% and 10%tioxazafen suspending agents press active ingredient
Dosage 225g a.i./hm2, in kind use, the preventive effect difference of 30 days and 60 days after 5% Benfuracard micro suspending agent medicine
For 71.4% and 67.8%;The preventive effect of 30 days and 60 days is respectively 73.4% He after 10%tioxazafen suspending agent medicines
74.5%.Synergistic effect is obvious after Benfuracard micro compounds with tioxazafen, and the preventive effect of tomato root-knot eelworm is significantly better than
Single dose.
2nd, aqueous emulsion processing and application example
Active component, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase;Under high velocity agitation, by oil phase plus
Enter in water and be well mixed, aqueous emulsion is made.
Embodiment 3:10% Benfuracard micro tioxazafen aqueous emulsions Benfuracard micro 5%, tioxazafen 5%,
1-METHYLPYRROLIDONE 10%, calcium dodecyl benzene sulfonate 5%, agriculture breast 600#5%, water complement to 100%.
The embodiment is applied to preventing and treating cucumber root-knot nematode.By 10% Benfuracard micro tioxazafen aqueous emulsions by having
Imitate Ingredient Amount 200g a.i./hm2With being diluted with water leaching, the prevention effect of 30 days and 60 days is respectively 89.4% He after medicine
86.2%.The Benfuracard micro missible oil of comparison medicament 5% and 20%tioxazafen missible oil by effective ingredient consumption 225g a.i./
hm2, in kind use.The preventive effect of 30 days and 60 days is respectively 73.1% and 70.4% after 5% Benfuracard micro missible oil medicine;
The preventive effect of 30 days and 60 days is respectively 75.8% and 76.3% after 20%tioxazafen missible oil medicines.Benfuracard micro with
Synergistic effect is obvious after tioxazafen compoundings, is significantly better than single dose to the preventive effect of cucumber root-knot nematode.
3rd, microemulsion processing and application example
Active component, solvent, cosolvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase;By water-soluble substances plus
Enter in water, homogeneous aqueous phase in dissolving, it is under agitation, oil phase is mixed with water uniformly, microemulsion is made.
Embodiment 4:31% Benfuracard micro tioxazafen microemulsion Benfuracard micro 1%, tioxazafen30%,
1-METHYLPYRROLIDONE 10%, isopropanol 10%, agriculture breast 500#5%, agriculture breast 1601#5%, water complement to 100%.
The embodiment is applied to preventing and treating sponge gourd root-knot nematode.By 31% Benfuracard micro tioxazafen microemulsions by having
Effect 8g/100 kilograms of seed of composition is diluted with water seed soaking, and the prevention effect of 30 days and 60 days is respectively 72.9% He after medicine
71.3%.The Benfuracard micro missible oil of comparison medicament 5% and 20%tioxazafen missible oil press 10g/100 kilograms of kind of active ingredient
Son, in kind use, investigate within 30 days and 60 days after medicine, 5% Benfuracard micro missible oil preventive effect is 62.4% He
53.7%;20%tioxazafen missible oil preventive effects are respectively 66.1% and 60.3.After Benfuracard micro compounds with tioxazafen
Synergistic effect is obvious, is significantly better than single dose to the preventive effect of sponge gourd root-knot nematode.
Embodiment 5:31% Benfuracard micro tioxazafen microemulsions Benfuracard micro 30%, tioxazafen
1%, 1-METHYLPYRROLIDONE 10%, isopropanol 10%, agriculture breast 500#5%, agriculture breast 1601#5%, water complements to 100%.
The embodiment is applied to preventing and treating great Jiang root-knot nematodes.By 31% Benfuracard micro tioxazafen microemulsions by having
Imitate Ingredient Amount 200g a.i./hm2It is diluted with water pouring root, the prevention effect of 30 days and 60 days is respectively 84.2% He after medicine
81.7%.The Benfuracard micro missible oil of comparison medicament 5% and 20%tioxazafen missible oil press effective ingredient consumption 225g
a.i./hm2, in kind use, the preventive effect of 30 days and 60 days is respectively 74.1% He after 5% Benfuracard micro missible oil medicine
72.5%;The preventive effect of 30 days and 60 days is respectively 76.8% and 72.6% after 20%tioxazafen missible oil medicines.Benfuracard micro
Synergistic effect is obvious after being compounded with tioxazafen, is significantly better than single dose to the preventive effect of great Jiang root-knot nematodes.
4th, suspension seed-coating agent processing and application example
Embodiment 6:11% Benfuracard micro tioxazafen suspension seed-coating agents
Benfuracard micro 10%, tioxazafen 1%, APES (dispersant) 3%, pull open powder (wetting
Agent) 1%, xanthans (thickener) 0.2%, the aqueous emulsion of dimethyl polysiloxane fluid (defoamer) of ethylene glycol (antifreezing agent) 4%, 20%
0.4%th, acrylic resin (film forming agent) 2%, sodium benzoate (preservative) 0.25%, colouring agent, water are supplemented to 100%, according to
Prepared by conventional method can obtain 11% Benfuracard micro tioxazafen suspension seed-coating agents.
The embodiment is applied to balsam pear root-knot nematode.11% Benfuracard micro tioxazafen suspension seed-coating agents are pressed
250g/100kg seed of bitter gourd is dressed seed, and the prevention effect of 30 days and 60 days is respectively 84.3% and 80.2% after medicine.Comparison medicament
5% Benfuracard micro suspension seed-coating agent and 20%tioxazafen suspension seed-coating agents are dressed seed by 300g/100kg seed of bitter gourd.
The preventive effect of 30 days and 60 days is respectively 71.7% and 73.5% after 5% Benfuracard micro suspension seed-coating agent medicine;20%
The preventive effect of 30 days and 60 days is respectively 74.8% and 72.1% after tioxazafen suspension seed-coating agent medicines.Benfuracard micro with
Synergistic effect is obvious after tioxazafen compoundings, is significantly better than single dose to the preventive effect of balsam pear root-knot nematode.
5th, microcapsule suspending agent processing and application example
Embodiment 7:33% Benfuracard micro tioxazafen microcapsule suspending agents
Benfuracard micro 3%, tioxazafen 30%, macromolecule cyst material polymer MDI3%, solvent linseed oil
5% and S-200 solvent naphthas 9%, emulsifying agent triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer 3.5%, dispersant
Negel 5%.Above-mentioned active ingredient, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, is emulsified
Agent, dispersant is soluble in water is prepared into homogeneous aqueous phase, in a shear condition, oil phase is added in aqueous phase solution, is prepared into emulsion,
Stirring is lower to add 10% ethylenediamine solution 4%, is warming up to 65 DEG C of insulation reaction 4.0h, and two kinds of materials occur anti-in oil-water interfaces
Should, form high score ascus wall, you can 33% Benfuracard micro tioxazafen microcapsule suspending agents are made.The embodiment is applied to
Romaine lettuce root-knot nematode.By 33% Benfuracard micro tioxazafen microcapsule suspending agents by effective ingredient consumption 200g a.i./
hm2With being diluted with water leaching, the prevention effect of 30 days and 60 days is respectively 83.5% and 84.8% after medicine.The rosickyite of comparison medicament 5%
Carbofuran microcapsule suspending agent presses effective ingredient consumption 300g a.i./hm2, 10%tioxazafen microcapsule suspending agents by effectively into
Divide dosage 225g a.i./hm2, in kind use.30 days and 60 days anti-after 5% Benfuracard micro microcapsule suspending agent medicine
Effect is respectively 72.1% and 73.7%;The preventive effect of 30 days and 60 days is respectively after 10%tioxazafen microcapsule suspending agent medicines
76.4% and 77.2%.Synergistic effect is obvious after Benfuracard micro compounds with tioxazafen, to the preventive effect of romaine lettuce root-knot nematode
Significantly better than single dose.
6th, water dispersible granules processing and application example
Active component, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, through air-flow crushing
Into wettable powder, add a certain amount of water mixing extruding and make material.Water dispersible granules are obtained after drying and sieving.
Embodiment 8:80% Benfuracard micro tioxazafen water dispersible granules
Benfuracard micro 15%, tioxazafen 65%, Negel 4%, sodium lignin sulfonate 2%, dodecane
Base sodium sulphate 5%, amine sulfate 2%, kaolin complements to 100%.
The embodiment is applied to preventing and treating wheat cyst roundworm.By 80% Benfuracard micro tioxazafen water dispersible granules
By effective ingredient consumption 200g a.i./hm2With being diluted with water leaching, the prevention effect of 30 days and 60 days is respectively 84.2% after medicine
With 81.3%.The Benfuracard micro suspending agent of comparison medicament 5% and 10%tioxazafen suspending agents press effective ingredient consumption
225g a.i./hm2, in kind use.The preventive effect of 30 days and 60 days is respectively after 5% Benfuracard micro suspending agent medicine
73.1% and 66.4%;The preventive effect of 30 days and 60 days is respectively 75.7% and 74.3% after 10%tioxazafen suspending agent medicines.
Synergistic effect is obvious after Benfuracard micro compounds with tioxazafen, is significantly better than single dose to the preventive effect of wheat cyst roundworm.
7th, granule processing and application example
Active component, other auxiliary elements are well mixed successively in the ratio of formula, is coated and granule is made
Embodiment 9:10% Benfuracard micro tioxazafen granules Benfuracard micro 5%, tioxazafen 5%,
White carbon 6%, adhesive 1%, colouring agent 0.5%, granular calcium carbonate complements to 100%.
The embodiment is applied to preventing and treating banana root-knot nematode.By 10% Benfuracard micro tioxazafen granules by having
Imitate Ingredient Amount 200g a.i./hm2Ditch spread is handled, and the prevention effect of 30 days and 60 days is respectively 80.3% and 75.2% after medicine.
The Benfuracard micro granule of comparison medicament 0.5% presses effective ingredient consumption 300g a.i./hm2, 5%tioxazafen granules
By effective ingredient consumption 225g a.i./hm2, in kind use, 30 days and 60 after 0.5% Benfuracard micro Granular pesticide
It preventive effect is respectively 71.4% and 63.2%;The preventive effect of 30 days and 60 days is respectively after 5%tioxazafen Granular pesticides
74.3% and 72.1%.Synergistic effect is obvious after Benfuracard micro compounds with tioxazafen, to the preventive effect of banana root-knot nematode
Significantly better than single dose.
Embodiment 10:5% Benfuracard micro tioxazafen granules
Benfuracard micro 2%, tioxazafen 3%, adhesive 1%, colouring agent 0.5%, dispersant 0.5%, silica sand are mended
Enough to 100%.
The embodiment is applied to preventing and treating peanut root-knot nematode.By 5% Benfuracard micro tioxazafen granules by having
Imitate Ingredient Amount 200g a.i./hm2Ditch spread is handled, and the prevention effect of 30 days and 60 days is respectively 84.2% and 83.2% after medicine.
The Benfuracard micro granule of comparison medicament 0.5% presses effective ingredient consumption 300g a.i./hm2, 5%tioxazafen granules
By effective ingredient consumption 225g a.i./hm2, in kind use.30 days and 60 after 0.5% Benfuracard micro Granular pesticide
It preventive effect is respectively 75.1% and 67.8%;The preventive effect of 30 days and 60 days is respectively after 5%tioxazafen Granular pesticides
74.3% and 75.7%.Synergistic effect is obvious after Benfuracard micro compounds with tioxazafen, to the preventive effect of peanut root-knot nematode
Significantly better than single dose.