CN107387043A - A kind of method that spontaneous multicomponent gas displacement in coal seam improves coal bed gas recovery ratio - Google Patents

A kind of method that spontaneous multicomponent gas displacement in coal seam improves coal bed gas recovery ratio Download PDF

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Publication number
CN107387043A
CN107387043A CN201710692053.8A CN201710692053A CN107387043A CN 107387043 A CN107387043 A CN 107387043A CN 201710692053 A CN201710692053 A CN 201710692053A CN 107387043 A CN107387043 A CN 107387043A
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coal
coal seam
spontaneous
well
seam
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CN107387043B (en
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王超文
贾春生
彭小龙
朱苏阳
邓鹏�
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Southwest Petroleum University
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses the method that a kind of spontaneous multicomponent gas displacement in coal seam improves coal bed gas recovery ratio, comprise the following steps:S1, selection target region;S2, according to the coal of target area composition and coal seam water environment, select and cultivate the coalification microorganism fungus kind of suitable one's respective area;S3, cultured coalification microorganism fungus kind injected into coal seam, the coal dust dissolved in coal seam fracture and duct forms coal solution;S4, insoluble matter remaining in coal solution degradation bacterium resolution process coal solution and coal seam fracture is injected into coal seam;S5, by the angry thing aqueous solution injection by step S4 processing after coal seam in;S6, closing well head carry out stewing well processing;S7, after stewing well, into coal seam injecting air carries out displacement.The advantages of present invention is increased production using microbiological transformation technology and ammonium bicarbonate aqueous solution, simple with technique, low energy consumption, and the existing Technology development such as pollution-free hardly matches.

Description

A kind of method that spontaneous multicomponent gas displacement in coal seam improves coal bed gas recovery ratio
Technical field
The present invention relates to coal-bed gas exploitation field, and in particular to a kind of alternately injection spontaneous multicomponent gas displacement in coal seam of gas-liquid The method for improving coal bed gas recovery ratio.
Background technology
Coal bed gas is a kind of high-efficiency cleaning energy, is national strategy resource, is a kind of important unconventional petroleum resources.I State's coal bed gas resource enriches, and reserves are huge, widely distributed.Coal bed gas is distributed in coal seam as a kind of special petroleum resources, Domestic multiple coal blocks have carried out cbm development at present, but most research paneling effects are undesirable, main cause Determined by geologic(al) factors such as coal seam low pressure low porosity and low permeabilities, be secondly recovery method imperfection, exploitation measure is not in place to be caused.
Coal seam degree of consolidation is relatively low, and a large amount of coal dusts are contained in hole, blocks Properties of Water-gas Flowing Through Porous Media passage.Coal is a kind of complicated big Molecule, there is the labyrinth material of polycyclic aromatic hydrocarbons (PAH).Therefore bacterium such as pseudomonad for the aromatic ring that can degrade etc. can be selected to carry out Vehicle treated, the compound after degraded have water-soluble materials such as phenols, carboxylic class, hydroxyl class, aldehydes and the molten thing of a small amount of coal Deng impurity.Coalification microorganism can be with the pulverized coal particle easily degraded on the coal dust in Solution fissure hole and coal seam hole wall and hole The pointed projections of wall point and hole wall surface, while discharge a large amount of heat energy.Patent 2015102091512 discloses a kind of coal seam Biological plugging releasing method, cleat in coal blocking particles are digested using the incoalation of microorganism, extension crack passage, lifting coal Body gas permeability, realize that cracks in coal seam de-plugging is dredged.
Anaerobe (such as methagen) is a kind of strain of the molten thing of coal of processing well, can be divided the molten thing of coal Solution obtains methane, the material such as ethane and ethanol, so as to further loose and clear up seepage channel.
The main component of coal bed gas is methane, and methane molecule is with adsorbed state preservation and matrix of coal surface.By retrieval with Literature survey, coal bed methane exploring method is mostly direct carbon dioxide injection displacement or progress huff and puff to improve coal bed gas at present Yield.Patent 2013100327663 discloses a kind of use and multielement hot fluid injection coal seam is carried out into single well stimulation so as to improve The method of coal bed gas recovery ratio.Patent 2016104593734 discloses a kind of molten by being implanted sequentially inflating medium to subterranean coal Liquid system, active aqueous systems and bubble release agent solution system slug, carbon dioxide foam systems are spontaneously generated in underground and carry out individual well Handle up improve Production of Coal-bed Gas Wells method.
Above method can preferably provide a kind of technical method for improving coal bed gas recovery ratio, but there is also certain Deficiency.For example microorganism solution blocking method is dredged to the coal dust of cracks in coal seam, solves the problems, such as coal dust blocking well.But This method does not have the desorption rate for accelerating adsorbed gas, and metabolite caused by after microorganism incoalation is not examined Consider, part metabolite is likely to cause the secondary blocking in coal seam.And gas the methods of handling up, has upset the continuous mining in coal seam System, the continuous mining of stabilization and coal bed gas well on pulverized coal particle bring certain influence.
The content of the invention
It is an object of the invention to solve at least the above and/or defect, and provide at least will be described later it is excellent Point.
A further object of the invention is that solve in the prior art, and microorganism solution blocking method can not accelerate the desorption of adsorbed gas Speed, and metabolite caused by after microorganism incoalation does not have subsequent treatment, part metabolite is likely to cause coal The problem of secondary blocking of layer;Gas method of handling up can upset the continuous mining system in coal seam simultaneously, to the stabilization of pulverized coal particle And the continuous mining of coal bed gas well brings the technical problems such as certain influence.
In order to realize these purposes and further advantage of the invention, the invention provides a kind of spontaneous multicomponent gas displacement in coal seam The method for improving coal bed gas recovery ratio, it comprises the following steps:
S1, selection target region;
S2, according to the coal of target area composition and coal seam water environment, select and cultivate the coalification microorganism of suitable one's respective area Strain;
S3, cultured coalification microorganism fungus kind injected into coal seam, the coal dust dissolved in coal seam fracture and duct forms coal Solution;
S4, insoluble matter remaining in coal solution degradation bacterium resolution process coal solution and coal seam fracture is injected into coal seam;
S5, by the angry thing aqueous solution injection by step S4 processing after coal seam in;
S6, closing well head carry out stewing well processing;
S7, after stewing well, into coal seam injecting air carries out displacement.
Preferably, in the step S1, target area should be the well group of the less well pattern improvement of well spacing, gas output per well Relatively low, seam construction is relatively flat, the preferable region of roof and floor seal.
Preferably, the coalification microorganism fungus kind injection rate is no more than 0.01PV in the range of single well-controlled, notes per hour Enter amount and be no more than 6m3
Preferably, the coal solution degradation bacterium is anaerobic methane bacillus.
Preferably, the anaerobic methane bacillus dosage is 1/5th of solvable coal microorganism fungus kind injection rate, per small When the controlling of injecting quantity in 10m3Below.
Preferably, the angry thing aqueous solution is saturation NH4HCO3The aqueous solution, injection rate 0.05PV, injection pressure are low In coal seam fracture pressure.
Preferably, the time of the stewing well processing is 10~15 days.
Preferably, injection rate is less than 180m to the air per hour3, then stop after injecting air and breaking through gas recovery well Gas injection.
The present invention is advantageous in that:
One, this method have carried out multiple breaking block treatment to coal seam seepage channel, are more beneficial for coal seam air water and are split in hole Flowing in seam, wherein second of de-plugging process product is methane, further increase coal bed gas content.
Secondly, inject ammonium bicarbonate aqueous solution after microorganism de-plugging, it injects coal seam and is thermally decomposed to generate CO2And NH3Category In the spontaneous multicomponent gas in coal seam, CO2And NH3Absorption property on matrix of coal surface is better than CH4, especially NH3, NH3Between coal Interaction it is stronger, almost CO210 times or so of action effect between coal, adsorption capacity are far longer than methane and coal Adsorption capacity, therefore CO2And NH3The methane of coal seam absorption can be largely replaced, improves methane output;And utilize microorganism coal This property of change process heat release, generate ammonia for ammonium bicarbonate breaks down and carbon dioxide provides heat energy, avoid and coal seam is carried out Extra heating.
Thirdly, product after the ammonium hydrogen carbonate that remains in coal seam water and microorganism incoalation etc. can be used as agriculture plant The materials such as growth promoter, nonstaining property, ground produced water treatment flow can be facilitated.
Four, this method displacement source of the gas is air, cost-effective without any pollution, safe and efficient, is reached with the cost of minimum The purpose of displacement is arrived so that production-increasing function area is bigger, while reduces the external strain for having desorbed subterranean zone, prevents strain Largely multiplied in coal seam, destroy the prototype structure of coal, preferably kept coal seam prime stratum environment, ensure that follow-up colliery is opened Adopt.
Five, the present invention is increased production using microbiological transformation technology and ammonium bicarbonate aqueous solution, and whole method was implemented The continuous mining of producing well in journey, the continuity of mining is not interrupted, contributes to the exploitation of coal bed gas, low energy consumption simple with technique, Pollution-free the advantages of waiting Technology development incomparable.
Brief description of the drawings
The spontaneous multicomponent gas displacement in coal seam of Fig. 1 present invention improves the process chart of coal bed gas recovery ratio.
Each step effect schematic diagram of Fig. 2 the inventive method, label in figure:Produce well 1, injection well 11, stratum 2, coal seam 3rd, coalification microorganism fungus kind sphere of action 4, coal solution degradation bacterium sphere of action 5, multicomponent gas displacement methane scope 6, injection are empty Gas scope 7.
Embodiment
The preferred embodiments of the present invention are illustrated below in conjunction with accompanying drawing, it will be appreciated that described herein preferred real Apply example to be merely to illustrate and explain the present invention, be not intended to limit the present invention.
A kind of method that spontaneous multicomponent gas displacement in coal seam improves coal bed gas recovery ratio, its technological process is as shown in figure 1, tool Body comprises the following steps:
The suitable volume increase target area of S1, first selection, the region should be the well group of the less well pattern improvement of well spacing, individual well Gas production is relatively low, and seam construction is relatively flat, the preferable region of roof and floor seal.
S2, according to the coal of selected areas composition and coal seam water environment, select and cultivate the coalification microorganism of suitable one's respective area Strain, the strain are solvable coal microorganism.
S3, cultured coalification microorganism fungus kind is injected to coal seam, injection rate is no more than 0.01PV in the range of single well-controlled, Injection rate is no more than 6m per hour3.Coalification microorganism fungus kind injection coal seam had into 3 effects:Firstth, containing a large amount of in coal seam Coal dust, coalification microorganism can dissolve the coal dust in coal seam fracture and duct, dredge seepage channel;Secondth, microorganism can be with molten The coal dust and the pointed projections point and hole wall surface of hole wall easily degraded on solution coal seam hole wall, increase the area of seepage channel, Increase coal seam permeability;3rd, the process of biosolubilization coal dust is an exothermic process, and big calorimetric is released in course of dissolution Amount, increase coal seam temperature.Coal seam temperature is higher, is more advantageous to the desorption of methane gas in coal seam, increases gas well yield, meanwhile, Coal seam temperature is higher, is more advantageous to ammonium hydrogen carbonate in subsequent step S5 and is thermally decomposed to generate NH3And CO2, displace the methane of absorption Gas.
After S4, injection coalification microorganism fungus kind are completed, start to inject coal solution degradation bacterium processing coal solution, preferably anaerobism Methagen, anaerobic methane bacillus dosage are 1/5th of solvable coal microorganism fungus kind injection rate, per hour the controlling of injecting quantity In 10m3Below.A series of compounds are generated after microorganism incoalation, the compound after degraded has phenols, carboxylic class, hydroxyl class, aldehyde Water-soluble material such as class, also containing a small amount of insoluble complicated organic matter of macromolecular not soluble in water.The methagen of injection Part insoluble matter can be degraded Deng coal solution processing bacterium, metabolite is acetic acid, methane etc..The purpose of this step be in order to Insoluble matter remaining in coal seam fracture is removed in degraded, dredges seepage channel, while degradation bacteria metabolism produces methane, increases coal seam first Alkane content.
S5, by the angry thing aqueous solution injection by step S4 processing after coal seam in, the angry thing of injection is generally water-soluble Liquid, the aqueous solution are easy to inject coal seam.Preferable angry thing is saturation NH4HCO3The aqueous solution, injection rate 0.05PV, inject pressure Less than coal seam fracture pressure, Surface heat source should be completely cut off in injection process, prevents that the angry thing aqueous solution from being thermally decomposed on ground.Carbon Sour hydrogen ammonium is a kind of common chemical raw material, and a kind of crops chemical fertilizer.Its property is unstable, and more than 36 DEG C are decomposed into CO2、NH3And H2O, 60 DEG C of decomposable asymmetric choice nets are complete, and reaction equation is:
S6, closing well head carry out stewing well processing, and it is 10~15 days to boil in a covered pot over a slow fire the well time.In the case of normal geothermal gradient, buried depth 800m coal seam temperature typically can reach more than 40 DEG C, plus (the hair of the molten coal of biology of heat caused by microorganism decomposition coal dust The caloric value of heat and raw coal is roughly the same, about the 94%~97% of raw coal), coal seam temperature is enough the NH for making injection4HCO3Point Solution produces substantial amounts of NH3And CO2.And NH3And CO2Adsorption capacity be all much larger than methane, especially NH3, NH3Phase between coal Interaction is stronger, almost CO210 times or so of action effect between coal, adsorption capacity is far longer than the absorption of methane and coal Ability.Therefore, NH3And CO2There is the methane gas that time enough displaces coal surface absorption, so that substantial amounts of methane fills Decompose and inhale, methane gas is full of coal seam hole.
S7, after stewing well, into coal seam injecting air carries out displacement.Injection rate is less than 180m to air per hour3, work as note Enter after air breaks through gas recovery well and then stop gas injection.NH3And CO2The reaction for displacing methane gas all occurs near injection well, And injection well distal end coal seam action effect is slower, injection air can be to the coalification microorganism above injected and the angry thing aqueous solution Displacement is carried out, makes the increase of its sphere of action, the methane increase of displacement.Increase the pressure difference between injection well and producing well simultaneously, add Fast coal seam fluid neuron network speed, improves methane output.
The spontaneous multicomponent gas displacement in coal seam that Fig. 2 concrete images depict the present invention improves each of coal bed gas recovery ratio method Step acts on schematic diagram.
In summary, the present invention relates to a kind of gas-liquid, alternately the spontaneous multicomponent gas displacement in injection coal seam improves coal bed gas The method of recovery ratio.Wherein, coalification microorganism fungus kind solution, coal solution degradation bacterium solution and the life that step S3~S5 is implanted sequentially The gas thing aqueous solution is liquid, and step S7 injects air, therefore referred to as gas-liquid is alternately injected;Ammonium hydrogen carbonate is thermally decomposed in coal seam Generate NH3And CO2, generate methane gas after injecting coal solution degradation bacterium, therefore referred to as spontaneous multicomponent gas.This method can dredge Ammonium bicarbonate aqueous solution is injected on the basis of logical coal seam seepage channel, it is decomposed in the presence of the high temperature of coal seam and produces titanium dioxide Carbon and ammonia, so as to improve methane output, and, low energy consumption simple with technique, it is pollution-free to wait Technology development not compare The advantages of plan.
The above described is only a preferred embodiment of the present invention, any formal limitation not is made to the present invention, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any to be familiar with this professional technology people Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification For the equivalent embodiment of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit according to the present invention Any simple modification, equivalent change and modification made to above example, in the range of still falling within technical solution of the present invention.

Claims (8)

1. a kind of method that spontaneous multicomponent gas displacement in coal seam improves coal bed gas recovery ratio, it is characterised in that comprise the following steps:
S1, selection target region;
S2, according to the coal of target area composition and coal seam water environment, select and cultivate the coalification microorganism fungus kind of suitable one's respective area;
S3, cultured coalification microorganism fungus kind injected into coal seam, the coal dust dissolved in coal seam fracture and duct forms coal solution;
S4, insoluble matter remaining in coal solution degradation bacterium resolution process coal solution and coal seam fracture is injected into coal seam;
S5, by the angry thing aqueous solution injection by step S4 processing after coal seam in;
S6, closing well head carry out stewing well processing;
S7, after stewing well, into coal seam injecting air carries out displacement.
2. the method that the spontaneous multicomponent gas displacement in coal seam as claimed in claim 1 improves coal bed gas recovery ratio, it is characterised in that In the step S1, target area should be the well group of the less well pattern improvement of well spacing, and gas output per well is relatively low, and seam construction is more It is flat, the preferable region of roof and floor seal.
3. the method that the spontaneous multicomponent gas displacement in coal seam as claimed in claim 2 improves coal bed gas recovery ratio, it is characterised in that The coalification microorganism fungus kind injection rate is no more than 0.01PV in the range of single well-controlled, and injection rate is no more than 6m per hour3
4. the method that the spontaneous multicomponent gas displacement in coal seam as claimed in claim 1 improves coal bed gas recovery ratio, it is characterised in that The coal solution degradation bacterium is anaerobic methane bacillus.
5. the method that the spontaneous multicomponent gas displacement in coal seam as claimed in claim 4 improves coal bed gas recovery ratio, it is characterised in that The anaerobic methane bacillus dosage is 1/5th of solvable coal microorganism fungus kind injection rate, and the controlling of injecting quantity is in 10m per hour3 Below.
6. the method that the spontaneous multicomponent gas displacement in coal seam as claimed in claim 5 improves coal bed gas recovery ratio, it is characterised in that The angry thing aqueous solution is saturation NH4HCO3The aqueous solution, injection rate 0.05PV, injection pressure are less than coal seam fracture pressure.
7. the method that the spontaneous multicomponent gas displacement in coal seam as claimed in claim 6 improves coal bed gas recovery ratio, it is characterised in that The time of the stewing well processing is 10~15 days.
8. the method that the spontaneous multicomponent gas displacement in coal seam as claimed in claim 7 improves coal bed gas recovery ratio, it is characterised in that Injection rate is less than 180m to the air per hour3, then stop gas injection after injecting air and breaking through gas recovery well.
CN201710692053.8A 2017-08-14 2017-08-14 A kind of method that the spontaneous multicomponent gas displacement in coal seam improves coal bed gas recovery ratio Expired - Fee Related CN107387043B (en)

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CN111088971A (en) * 2018-10-24 2020-05-01 中国石油化工股份有限公司 Method for improving yield of common thick oil by utilizing heat produced by microbial fermentation

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CN111088971A (en) * 2018-10-24 2020-05-01 中国石油化工股份有限公司 Method for improving yield of common thick oil by utilizing heat produced by microbial fermentation

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